D. Heller

发表

Ammine and amido complexes of rhodium: Synthesis, application and contributions to analytics

W. Baumann, H. Drexler, M. Horstmann, 2020 .

Hydrogenation of Itaconic Acid in Micellar Solutions: Catalyst Recycling with Cloud Point Extraction?

M. Schwarze, Marcel Schmidt, H. Drexler, 2018, Industrial & Engineering Chemistry Research.

Pressure dependent highly enantioselective hydrogenation of unsaturated beta-amino acid precursors.

A. Börner, H. Drexler, D. Heller, 2001, The Journal of organic chemistry.

On the enantioselective hydrogenation of isomeric β-acylamido β-alkylacrylates with chiral Rh(I) complexes—comparison of phosphine ligands and substrates

A. Börner, I. Komarov, J. You, 2002 .

Chiral β-Amino Acid Derivatives via Asymmetric Hydrogenation

C. Fischer, J. You, W. Baumann, 2003 .

Two precatalysts for application in asymmetric homogeneous hydrogenation.

H. Drexler, D. Heller, A. Meissner, 2014, Acta crystallographica. Section C, Structural chemistry.

(+)-Chlorido[(1,2,3,4-η;κP 2′)-2′-diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate

H. Drexler, D. Heller, A. Meissner, 2012, Acta crystallographica. Section E, Structure reports online.

β-Alkoxy- and β-Hydroxyalkylphosphanes as Ligands in the Stereoselective Hydrogenation — A Comparison

A. Börner, A. Kless, W. Baumann, 1995 .

Investigations into the formation and stability of cationic rhodium diphosphane η6-arene complexes.

W. Baumann, H. Drexler, D. Heller, 2012, Chemistry.

Part III. COD versus NBD precatalysts. Dramatic difference in the asymmetric hydrogenation of prochiral olefins with five-membered diphosphine Rh-hydrogenation catalysts

C. Fischer, W. Baumann, A. Spannenberg, 2001 .

Preparation and asymmetric hydrogenation of β-aryl-substituted β-acylaminoacrylates

C. Fischer, J. You, H. Drexler, 2003 .

BINAP: rhodium–diolefin complexes in asymmetric hydrogenation

S. Schulz, H. Drexler, D. Heller, 2010 .

Cationic Rh-bisphosphine-diolefin complexes as precatalysts for enantioselective catalysis––what information do single crystal structures contain regarding product chirality?

Ailing Sun, A. Spannenberg, H. Drexler, 2004 .

Cationic η6‐Coordinated BINAP Rhodium Complexes with Benzene and Toluene

H. Drexler, D. Heller, Carmen Selle, 2012 .

Cationic Rhodium-BINAP Complexes: Full Characterization of Solvate- and Arene-Bridged Dimeric Species

W. Baumann, C. Kohrt, H. Drexler, 2011 .

Asymmetric hydrogenation of dimethyl itaconate catalysed by rhodium chelates of aminophosphine phosphinites: A kinetic and NMR spectroscopical study

D. Heller, T. Freier, R. Kadyrov, 1996 .

Rhodium-complex-catalyzed asymmetric hydrogenation: transformation of precatalysts into active species.

A. Börner, W. Baumann, A. Spannenberg, 2008, Chemistry.

(η2,η2-Cycloocta-1,5-diene)[2-(diphenylphosphanylmethyl)pyridine-κ2N,P]rhodium(I) tetrafluoridoborate 1,2-dichloroethane monosolvate

H. Drexler, D. Heller, Siping Wei, 2016 .

In Situ Synthesis of Neutral Dinuclear Rhodium Diphosphine Complexes [{Rh(diphosphine)(μ2‐X)}2]: Systematic Investigations

W. Baumann, A. Spannenberg, H. Drexler, 2015 .

Synthesis of Rh(iii) thiophosphinito pincer hydrido complexes by base-free C-H bond activation at room temperature.

H. Drexler, D. Heller, T. Beweries, 2018, Chemical communications.

The economic use of precious chiral diphosphine ligands—DuPHOS and its rhodium(I) COD and NBD complexes

A. Börner, D. Heller, 2001 .

Catalytic and Structural Features of Hydroxy and Methoxy Groups as Hemilabile Coordinating Ligands in Chiral (Diphosphane)rhodium(I) Hydrogenation Catalysts

A. Börner, W. Baumann, A. Spannenberg, 1998 .

Selectivity from a kinetic point of view: nonlinear behavior of logarithmic product ratios as a function of the reciprocal temperature

D. Heller, H. Buschmann, 1998 .

Homogeneous catalytic transfer semihydrogenation of alkynes – an overview of hydrogen sources, catalysts and reaction mechanisms

H. Drexler, D. Heller, T. Beweries, 2020 .

Selective Hydrogenation of Alkynes Catalyzed by Trinuclear Rhodium Hydride Complexes of the Type [{(Rh[PP*]H)3(μ2‐H)3(μ3‐H)}(BF4)2]

M. Beller, C. Kohrt, D. Heller, 2013 .

Catalytic and Kinetic Studies of the Dehydrogenation of Dimethylamine Borane with an iPr Substituted Titanocene Catalyst

A. Schulz, D. Heller, T. Beweries, 2011 .

Control of selectivity in the cobalt(I)-catalysed cocyclisation of alkynes with nitriles

B. Heller, P. Wagler, G. Oehme, 1998 .

New pentacoordinated rhodium species as unexpected products during the in situ generation of dimeric diphosphine-rhodium neutral catalysts.

W. Baumann, H. Drexler, D. Heller, 2014, Chemistry.

Unusual deactivation in the asymmetric hydrogenation of itaconic acid

T. Schmidt, W. Baumann, H. Drexler, 2009 .

The major/minor concept: dependence of the selectivity of homogeneously catalyzed reactions on reactivity ratio and concentration ratio of the intermediates.

T. Schmidt, M. Hapke, H. Drexler, 2008, Chemistry, an Asian journal.

P/O Ligand Systems: Facile Synthesis, Structure, and Catalytic Tests of 2′‐Phosphanyl‐1,1′ ‐phenyl‐2‐ols and 2′‐Phosphanyl‐1,1′‐binaphthyl‐2‐ols

M. Kindermann, C. Fischer, D. Heller, 1997 .

A Kinetic Model for Selective Ethene Trimerization to 1‐Hexene by a Novel Chromium Catalyst System

Mohammed H. Al-Hazmi, Stephan Peitz, D. Heller, 2010 .

Reaction kinetics of the ethene tetramerization catalyst system CrCl3(THF)3, Ph2PN(iPr)PPh2 and MAO: The unexpected and unusual formation of odd-numbered 1-olefins

Stephan Peitz, Uwe Rosenthal, Normen Peulecke, 2009 .

Influence of process parameters on the reaction kinetics of the chromium-catalyzed trimerization of ethylene.

Bernd H. Müller, Mohammed H. Al-Hazmi, Stephan Peitz, 2010, Chemistry.

Reaction of the titanocene alkyne complex Cp2Ti(η2-Me3SiC2SiMe3) with methanol: Preparation and characterization of a novel trinuclear titanium complex [{Cp2Ti(OMe)}2{Ti(OMe)4}]

A. Spannenberg, D. Heller, V. Burlakov, 2008 .

Combination of spectroscopic methods: in situ NMR and UV/Vis measurements to understand the formation of group 4 metallacyclopentanes from the corresponding metallacyclopropenes.

Stephan Peitz, Wolfgang Baumann, Anke Spannenberg, 2009, Journal of the American Chemical Society.

Stable rac-[1,2-Ethylene-1,1‘-bis(η5-tetrahydroindenyl)]- zirconacyclopentanes. Syntheses, X-ray Crystal Structures, Stability, and Catalysis of Ethylene Polymerization

W. Baumann, D. Heller, R. Kempe, 1997 .

Development of an improved rhodium catalyst for z-selective anti-markovnikov addition of carboxylic acids to terminal alkynes.

A. Lumbroso, B. Breit, H. Drexler, 2013, Chemistry.

Kinetic and mechanistic investigations in homogeneous catalysis using operando UV/vis spectroscopy

Stephan Peitz, Wolfgang Baumann, Uwe Rosenthal, 2010 .

Coordination chemistry of new selective ethylene trimerisation ligand Ph2PN(iPr)P(Ph)NH(R) (R = iPr, Et) and tests in catalysis.

Mohammed H. Al-Hazmi, Stephan Peitz, S. Schulz, 2010, Dalton transactions.

Oxidative addition of CH2Cl2 to neutral dimeric rhodium diphosphine complexes

M. Ferro, Alberto Mannu, W. Baumann, 2018, Journal of Organometallic Chemistry.

Monomerisation of [Rh2(1,3-Bis-(Diphenylphosphino)-Propane)2(μ2-Cl)2] Detected by Pulsed Gradient Spin Echo Spectroscopy and 31P Nmr Monitoring of Metathesis Experiments

M. Ferro, D. Heller, A. Mannu, 2018, Journal of Chemical Research.

Investigations into the mechanism of the in situ formation of neutral dinuclear rhodium complexes

C. Kubis, E. Alberico, H. Drexler, 2019 .

Asymmetric Ring Opening of Benzo‐7‐oxabicyclo[2.2.1]heptadienes with Cationic Rhodium Complexes

A. Torrens, C. Kohrt, H. Drexler, 2010 .

Hydroxyalkylphosphines in asymmetric hydrogenations

A. Börner, A. Kless, D. Heller, 1995 .

Mechanistic investigations of the rhodium catalyzed propargylic CH activation.

D. Plattner, B. Breit, H. Drexler, 2014, Journal of the American Chemical Society.

New carbohydrate bisphosphites as chiral ligands

D. Heller, R. Kadyrov, R. Selke, 1998 .

SYNTHESIS OF THE FIRST WATER-SOLUBLE CHIRAL TETRAHYDROXY DIPHOSPHINE RH(I)CATALYST FOR ENANTIOSELECTIVE HYDROGENATION

A. Börner, D. Heller, J. Holz, 1999 .

Synthesis of a New Class of Functionalized Chiral Bisphospholane Ligands and the Application in Enantioselective Hydrogenations

A. Börner, D. Heller, J. Holz, 1998 .

Application of the term “relative enantioselectivity” as useful measure for comparison of chiral catalysts, demonstrated on asymmetric hydrogenation of amino acid precursors☆

D. Heller, R. Selke, H. Foken, 1993 .

Rhodium diphosphine complexes: a case study for catalyst activation and deactivation

E. Alberico, W. Baumann, H. Drexler, 2014 .

How Long Have Nonlinear Effects Been Known in the Field of Catalysis

B. Heller, C. Fischer, W. Baumann, 2000 .

Synthesis of an optically active hydroxy diphosphine, a new ligand for asymmetric catalysis

A. Börner, A. Kless, D. Heller, 1994 .

Synthesis and catalytic properties of an acyclic analogue of hydroxy norphos

W. Ruth, A. Börner, A. Kless, 1994 .

Asymmetric Hydrogenation. Dimerization of Solvate Complexes: Synthesis and Characterization of Dimeric [Rh(DIPAMP)]22+, a Valuable Catalyst Precursor

T. Schmidt, W. Baumann, H. Drexler, 2009 .

Two precatalysts for application in propargylic CH activation.

H. Drexler, D. Heller, S. Möller, 2019, Acta crystallographica. Section C, Structural chemistry.

Halide bridged trinuclear rhodium complexes and their inhibiting influence on catalysis

C. Kohrt, H. Drexler, D. Heller, 2013 .

Trinuclear rhodium complexes and their relevance for asymmetric hydrogenation.

W. Baumann, A. Spannenberg, H. Drexler, 2008, Chemistry, an Asian journal.

Novel contributions to the mechanism of the enantioselective hydrogenation of dimethyl itaconate with rhodium complexes.

C. Jäger, T. Schmidt, W. Baumann, 2008, Chemistry.

About the crystal structure of [Rh((S,S)-DIPAMP)-((Z)-2-benzoylamino-3-(3,4-dimethoxyphenyl)-methyl acrylate)]BF4 : Major or minor catalyst-substrate complex?

T. Schmidt, W. Baumann, H. Drexler, 2005 .

Are beta-acylaminoacrylates hydrogenated in the same way as alpha-acylaminoacrylates?

T. Schmidt, C. Fischer, Ailing Sun, 2005, Angewandte Chemie.

The inhibiting influence of aromatic solvents on the activity of asymmetric hydrogenations.

B. Heller, J. You, W. Baumann, 2002, Angewandte Chemie.

Nonlinear Temperature Behavior of Product Ratios in Selection Processes

D. Heller, H. Buschmann, H. Scharf, 1996 .

Oxidative Addition of Aryl Halides to Cationic Bis(phosphane)rhodium Complexes: Application in C–C Bond Formation

E. Alberico, W. Baumann, H. Drexler, 2017 .

Unravelling the reaction path of rhodium-MonoPhos-catalysed olefin hydrogenation.

J. D. de Vries, E. Alberico, L. Lefort, 2011, Chemistry.

The Influence of Substituents in Diphosphine Ligands on the Hydrogenation Activity and Selectivity of the Corresponding Rhodium Complexes as Exemplified by ButiPhane

K. Neymeyr, M. Sawall, S. Schulz, 2012 .

Studies on the polymerization of ethylene using a high-yield MgCl2-supported titanium catalyst, 2. Kinetic studies†

D. Heller, H. Fuhrmann, D. Bilda, 1992 .

Quantitative UV/Vis Spectroscopic Investigations of the In Situ Synthesis of Neutral μ2‐Chloro‐Bridged Dinuclear (Diphosphine)rhodium Complexes

D. Heller, A. Meissner, C. Pribbenow, 2014 .

Investigations into Metal Leaching from Polystyrene‐Supported Rhodium Catalysts

W. Baumann, H. Drexler, D. Heller, 2016 .

Insight into the Activation of In Situ Generated Chiral RhI Catalysts and Their Application in Cyclotrimerizations.

I. Thiel, F. Fischer, M. Hapke, 2017, Chemistry.

Chiral phosphinephosphites having axial and central chirality in asymmetric hydroformylations

A. Börner, A. Kless, C. Fischer, 1996 .

Conditions for maxima and minima as inversion points in the temperature dependence of selection processes

D. Heller, H. Buschmann, H. Neumann, 1999 .

Mechanistic insights into dehydrocoupling of amine boranes using dinuclear zirconocene complexes

K. Neymeyr, M. Sawall, A. Spannenberg, 2021 .

On the enantioselective hydrogenation of isomeric methyl 3-acetamidobutenoates with RhI complexes.

A. Börner, J. You, W. Baumann, 2002, Chemistry.

Dehydropolymerisation of Methylamine Borane and an N‐Substituted Primary Amine Borane Using a PNP Fe Catalyst

A. Lederer, S. Boye, A. Spannenberg, 2020, Chemistry.

Trinuclear rhodium hydride complexes.

W. Baumann, C. Kohrt, H. Drexler, 2011, Dalton transactions.

3 d metal ions in highly unusual eight-coordination: the phosphate-capped dodecapalladate(II) nanocube.

H. Kroto, N. Dalal, U. Kortz, 2012, Chemistry.

Investigations into the hydrogenation of diolefins and prochiral olefins employing the “Daniphos”-type ligandsDedicated to the memory of Professor Noel McAuliffe.

A. Spannenberg, H. Drexler, D. Heller, 2003 .

Molecular vibration spectroscopy studies on novel trinuclear rhodium-7-hydride complexes of the general type {[Rh(PP*)X]3(μ(2-X)3(μ3-X)}(BF4)2 (X = H, D).

A. Schulz, C. Kohrt, H. Drexler, 2012, Inorganic chemistry.

Formation of trinuclear rhodium-hydride complexes [{Rh(PP*)H}3-(μ2-H)3(μ3-H)][anion]2--during asymmetric hydrogenation?

W. Baumann, A. Spannenberg, C. Kohrt, 2013, Chemistry.

Kinetic models for catalytic selection processes as applied to asymmetric hydrogenation

D. Heller, D. Haberland, R. Thede, 1997 .

Kinetic Investigations of the Hydrogenation of Diolefin Ligands in Catalyst Precursors for the Asymmetric Reduction of Prochiral Olefins, II[1]

W. Baumann, D. Heller, R. Selke, 1996 .

Systematic investigations of the photocatalytic alkyne-nitrile heterotrimerisation to pyridine

B. Heller, G. Oehme, D. Heller, 1996 .

Catalyst Inhibition and Deactivation in Homogeneous Hydrogenation

J. G. Vries, D. Heller, A. D. Vries, 2008 .

[On glycosides of 3-hydroxypyridazines/pyridazones-(3). 11. On "glycosides of heterocyclic compounds"].

D. Heller, G. Wagner, 1966, Archiv der Pharmazie und Berichte der Deutschen Pharmazeutischen Gesellschaft.

Cooperative attractive interactions in asymmetric hydrogenations with dihydroxydiphosphine Rh(I) catalysts — a competition study

A. Börner, D. Heller, R. Kadyrov, 2000 .

Splitting of the nonlinear temperature dependence of selection processes into the temperature dependencies of the single reaction pathways

D. Heller, H. Buschmann, H. Neumann, 1997 .

Influence of a remote hydroxy group in the ligand on the reactivity of a chiral hydrogenation catalyst

A. Börner, A. Spannenberg, D. Heller, 1997 .

New Developments in the Origins of the Homochirality of Biologically Relevant Molecules

D. Heller, H. Buschmann, R. Thede, 2001 .

Synthesis and Characterization of Cationic Synphos‐Rhodium Complexes

V. Ratovelomanana-Vidal, H. Drexler, D. Heller, 2014 .

The Photoassisted (solar-driven) Synthesis of 2-substituted Pyridines by Cocyclization of Acetylene and Nitrile in Presence of Catalytic Amounts of Cobalt (I)-Complexes

B. Heller, G. Oehme, D. Heller, 1992 .

Activation, Deactivation and Reversibility Phenomena in Homogeneous Catalysis: A Showcase based on the Chemistry of Rhodium/Phosphine Catalysts.

E. Alberico, Drexler, H. Drexler, 2019, Catalysts.

The Mechanism of Rh(I)-Catalyzed Coupling of Benzotriazoles and Allenes Revisited: Substrate Inhibition, Proton Shuttling, and the Role of Cationic vs Neutral Species

H. Drexler, Nora Jannsen, D. Heller, 2024, Journal of the American Chemical Society.

New pentacoordinated rhodium species as unexpected products during the in situ generation of dimeric diphosphine-rhodium neutral catalysts.

W. Baumann, H. Drexler, D. Heller, 2014, Chemistry.

Reduction of the rotational ambiguity of curve resolution techniques under partial knowledge of the factors. Complementarity and coupling theorems

Klaus Neymeyr, Christian Fischer, Mathias Sawall, 2012 .