O. S. Akkerman,

发表

An investigation of the di-Grignard approach to metallabenzocyclobutenes of group 14

F. Bickelhaupt, H. J. R. D. Boer, O. S. Akkerman,, 1987 .

1,2-dimagnesium derivatives of cyclopropane

F. Bickelhaupt, O. S. Akkerman,, J. Seetz, 1981 .

First synthesis of an olefin-coordinated platina(II) cyclobutane and its conversion into diphosphineplatina(II) cyclobutanes

F. Bickelhaupt, H. J. R. D. Boer, O. S. Akkerman,, 1987 .

X-Ray Structural Analyses of Organomagnesium Compounds

A. Spek, F. Bickelhaupt, O. S. Akkerman,, 1993 .

Formation of a distibacyclooctane; X‐ray crystal structure of 1,5‐dichloro‐1,3,3,5,7,7‐hexamethyl‐9‐oxa‐1,5‐distibabicyclo[3.3.1]nonane hydrochloride

A. Spek, F. Bickelhaupt, O. S. Akkerman,, 2010 .

Cyclic 1,8-napththalenediyl compounds containing group 14 hetero atoms

A. Spek, F. Bickelhaupt, O. S. Akkerman,, 1994 .

Four‐Membered 1,8‐Naphthalenediyl Transition Metallacycles

A. Spek, F. Bickelhaupt, O. S. Akkerman,, 1994 .

Intra-annular reactions of the (1,3-xylylene)-18-crown-5 system: synthesis and crystal structure of [2-(bromomagnesio)-1,3-xylylene]-18-crown-5, [2-(bromomercurio)-1,3-xylylene]-18-crown-5 and bis[(1,3-xylylene-18-crown-5)-2-yl]mercury

A. Spek, F. Bickelhaupt, O. S. Akkerman,, 1993 .

The remarkable crystal structure of the dimeric species [bis(ortho-anisyl)magnesium · THF]2

A. Spek, F. Bickelhaupt, O. S. Akkerman,, 1991 .

Intramolecularly coordinated arylmagnesium compounds: effects on the Schlenk equilibrium

A. Spek, F. Bickelhaupt, O. S. Akkerman,, 1991 .

The coordination modes of simple diarylmagnesium species: Some representative X-ray crystal structures

A. Spek, F. Bickelhaupt, P. Sluis, 1990 .

The crystal and molecular structure of polymeric [(dineopentylmagnesium)2 · (neopentylmagnesium bromide)2]n: an unsolvated alkylmagnesium species

A. Spek, F. Bickelhaupt, O. S. Akkerman,, 1989 .

Coordinational behavior of solvent-free diorganylzinc compounds: the remarkable x-ray structure of dimeric diphenylzinc

A. Spek, F. Bickelhaupt, O. S. Akkerman,, 1990 .

Deconvolution of composite metastable peaks: A new method for the determination of metastable transitions occurring in the first field free region

A. Noest, E. Evers, O. S. Akkerman,, 1977 .

Intramolecular coordination between magnesium and oxygen in cyclic organomagnesium compounds

F. Bickelhaupt, O. S. Akkerman,, G. Schat, 1982 .

The dimerization of some magnesacycloalkanes and benzomagnesacycloalkenes; the relation between ring size, ring strain and degree of association

F. Bickelhaupt, O. S. Akkerman,, G. Schat, 1982 .

A direct synthesis of 1,3-bis(bromomagnesio)propane

F. Bickelhaupt, C. Blomberg, O. S. Akkerman,, 1982 .

Some applications of the methylene di-Grignard reagent for the synthesis of main group IV organometallic compounds

F. Bickelhaupt, O. S. Akkerman,, J. Bruin, 1985 .

Bis(bromomagnesio)trimethylsilylmethane

F. Bickelhaupt, O. S. Akkerman,, M. Tinga, 1986 .

The first x-ray structure of a 1,1-di-Grignard compound: bis(bromomagnesio)bis(trimethylsilyl)methane

A. Spek, F. Bickelhaupt, O. S. Akkerman,, 1992 .

Preparation and reactivity of bis(bromomagnesio)bis(trimethylsilyl)methane

F. Bickelhaupt, N. Hommes, O. S. Akkerman,, 1989 .

Synthesis of metallacyclobutanes and metallacyclobutabenzenes of molybdenum and tungsten

F. Bickelhaupt, H. J. R. D. Boer, O. S. Akkerman,, 1988 .

First Four‐Membered Metallacycles of Rhenium

W. Herrmann, F. Bickelhaupt, H. J. R. D. Boer, 1987 .

The synthesis of four-membered spiro compounds of silicon and germanium: 2,2,6,6-tetramethyl-4-metallaspiro[3.3]heptanes

F. Bickelhaupt, O. S. Akkerman,, Y. V. D. Winkel, 1986 .

A new type of organometallic spiro compounds: 2,2,6,6-tetracyclopentadienyl-4-sila-2,6-dititanaspiro[3.3]heptane

F. Bickelhaupt, O. S. Akkerman,, G. Schat, 1986 .

A general synthesis of metallacyclobutanes

F. Bickelhaupt, O. S. Akkerman,, J. Seetz, 1985 .

A convenient synthesis of germacyclobutanes

F. Bickelhaupt, O. S. Akkerman,, J. Seetz, 1984 .

1,1-dicyclopentadienyl-3,3-dimethylvanada(IV)cyclobutane

O. S. Akkerman,, J. Seetz, G. Schat, 1984 .

First synthesis of stannacyclobutanes

F. Bickelhaupt, O. S. Akkerman,, J. Seetz, 1983 .

Zircona‐ and Hafnacyclobutenes—A New Route to Metallacyclobutanes

F. Bickelhaupt, O. S. Akkerman,, J. Seetz, 1983 .

Methylenedimagnesium dibromide as precursor of metal carbene complexes; preparation of titanacyclobutanes.

F. Bickelhaupt, O. S. Akkerman,, J. Bruin, 1983 .

A convenient synthesis of cyclobutanone

F. Bickelhaupt, O. S. Akkerman,, J. Seetz, 1983 .

On the nature of the radical pairs involved in the Grignard reaction

F. Bickelhaupt, C. Blomberg, O. S. Akkerman,, 1980 .

Interaction of diphenylzinc with 1,3-xylyl crown ethers. Crystal structures of three 1:1 complexes

A. Spek, F. Bickelhaupt, O. S. Akkerman,, 1991 .

Nuclear versus Side-Chain Bromination of Methyl-Substituted Anisoles by N-Bromosuccinimide

F. Bickelhaupt, G. Gruter, O. S. Akkerman,, 1994 .

Complexation of diphenylzinc with simple ethers. Crystal structures of the complexes Ph2Zn · glyme and Ph2Zn · diglyme

A. Spek, F. Bickelhaupt, O. S. Akkerman,, 1992 .

A remarkable halogen‐zinc exchange reaction; X‐ray crystal structure of (2‐iodozincio‐1,3‐xylylene)‐15‐crown‐4

A. Spek, F. Bickelhaupt, G. Gruter, 1993 .

In Quest of the Double Rotaxane Formation of the Bis(coronand) (1,5),(2,4)‐Durenetetrayl‐bis(18‐crown‐5) with Organomagnesium Compounds

A. Spek, M. Lutz, G. V. Klink, 2004 .

The Activation of Phenylmagnesium Compounds by Crown Ethers

A. Spek, F. Bickelhaupt, O. S. Akkerman,, 1988 .

The synthesis and structure of zinccacyclopentane, zincacyclohexane and zincacycloheptane

F. Bickelhaupt, O. S. Akkerman,, J. Seetz, 1982 .

CRYSTAL STRUCTURE OF SOLVENT FREE [2-(DIMETHYLAMINOMETHYL)PHENYL]ALUMINIUM DICHLORIDE

N. Veldman, A. Spek, M. Dam, 1995 .

Synthesis and X-ray crystal structure of 2-(methoxymethyl) phenyldicyclopentadienyltitanium(III)

N. Veldman, A. Spek, F. Bickelhaupt, 1997 .

Synthesis and Structure of ortho‐Phenylenezinc

N. Veldman, A. Spek, F. Bickelhaupt, 1996 .

The mean bond dissociation energy of the carbonmagnesium bond in bis(2,2-dimethylpropyl)magnesium

F. Bickelhaupt, E. Evers, O. S. Akkerman,, 2010 .

The synthesis and some applications of new 1,3-dilithiopropanes: dimethylbis(α-lithiobenzyl)silane and its germanium analogue

F. Bickelhaupt, O. S. Akkerman,, 1988 .

1,2-Dimetalated Benzene Derivatives (1,2-C6H4MCH3)n of Group 13 (M = Al, Ga, ln)

A. Spek, M. Dam, F. Bickelhaupt, 1999 .

Synthesis of cyclic bifunctional organomagnesium compounds. X-ray crystal structures of tetrameric organomagnesium clusters

A. Spek, F. Bickelhaupt, H. Kooijman, 1993 .

Unusual metalation and halogen-metal exchange reactions between 1,3-xylyl crown ethers and organomagnesium reagents. X-ray structure of 2-[(p-tert-butylphenyl)magnesio]-1,3-xylylene-18-crown-5. [Erratum to document cited in CA115(21):232313a]

A. Spek, F. Bickelhaupt, O. S. Akkerman,, 1992 .

Unusual metalation and halogen-metal exchange reactions between 1,3-xylyl crown ethers and organomagnesium reagents. X-ray structure of 2-[(p-tert-butylphenyl)magnesio]-1,3-xylylene-18-crown-5

A. Spek, F. Bickelhaupt, O. S. Akkerman,, 1991 .

X-ray structure of (1,3-xylyl-18-crown-5)diphenylmagnesium: an organometallic rotaxane

A. Spek, F. Bickelhaupt, O. S. Akkerman,, 1988 .

Crown ether Grignard reagents; x-ray structure of 2-(bromomagnesio)-1,3-xylyl-15-crown-4

A. Spek, F. Bickelhaupt, O. S. Akkerman,, 1988 .

Carbanions as Intermediates in the Synthesis of Grignard Reagents

F. Bickelhaupt, H. J. R. D. Boer, O. S. Akkerman,, 1988 .

The formation of 1,3‐di‐Grignard reagents from small‐ring 1,3‐dibromides

F. Bickelhaupt, O. S. Akkerman,, J. Seetz, 2010 .

1,3-BIS(BROMOMAGNESIO)-2,2-DIMETHYLPROPANE

F. Bickelhaupt, H. J. R. D. Boer, O. S. Akkerman,, 1988 .

THE MOLECULAR STRUCTURE OF A GERMACYCLOBUTANE BY GAS ELECTRON DIFFRACTION AND AB INITIO MOLECULAR ORBITAL CALCULATIONS

M. Tafipolsky, A. Haaland, F. Bickelhaupt, 1997 .

UNEXPECTED FORMATION OF THE FIRST DOUBLY BENZYLIC 1,1-DI-GRIGNARD REAGENT

F. Bickelhaupt, O. S. Akkerman,, H. J. D. de Boer,, 2001 .

Bis(bromomagnesio)trimethylsilylmethane.

F. Bickelhaupt, O. S. Akkerman,, M. Tinga, 1987 .

A versatile method for the synthesis of 1,3-metallatitanacyclobutanes

F. Bickelhaupt, O. S. Akkerman,, G. Schat, 1985 .

The First X-Ray Structure of a 1,1-Di-Grignard Compound: Bis( bromomagnesio)bis(trimethylsilyl)methane.

A. Spek, F. Bickelhaupt, O. S. Akkerman,, 1992 .

The Preparation and Reactivity of Bis(bromomagnesio)bis(trimethylsilyl)methane.

F. Bickelhaupt, N. Hommes, O. S. Akkerman,, 1990 .

Induction of higher coordination states in phenyl Grignard reagents by intramolecular coordination. Crystal structures of O-CH2(OCH2CH2)*OCH3-substituted phenylmagnesium bromides (n = 0-3)

A. Spek, F. Bickelhaupt, O. S. Akkerman,, 1991 .

1,8-NAPHTHALENEDIYLZINC

F. Bickelhaupt, O. S. Akkerman,, F. de Kanter, 2001 .

OLIGOMERIC 1,2-DIHYDRO-1-MAGNESACYCLOBUTA[a]NAPHTHALENE

F. Bickelhaupt, F. D. Kanter, O. S. Akkerman,, 2002 .

1-BROMO-2,6-BIS(CHLOROMAGNESIOMETHYL)BENZENE FROM THE ATTEMPTED SYNTHESIS OF A DOUBLY BENZYLIC 1,3,5-TRI-GRIGNARD REAGENT

F. Bickelhaupt, O. S. Akkerman,, F. de Kanter, 2001 .

Synthesis of Metallacyclobutanes and Metallacyclobutabenzenes of Molybdenum and Tungsten.

F. Bickelhaupt, H. J. R. D. Boer, O. S. Akkerman,, 1988 .

9,10-Dimetallatriptycenes of group 14: a novel synthetic approach from ortho-phenylenemagnesium.

N. Veldman, A. Spek, M. Dam, 1996 .

Interconversions of titanocene-methylene complexes

F. Bickelhaupt, O. S. Akkerman,, G. Schat, 1987 .

Metallacyclic Four-Membered Ring Systems: Two Independent Routes to Bis(cyclopentadienyl)titanacyclobutabenzene.

G. Erker, F. Bickelhaupt, Julian M. Wallis, 1986 .

Synthesis of 1,3-metallatitanacyclobutanes of group 4

F. Bickelhaupt, O. S. Akkerman,, G. Schat, 1985 .

Intraannular functionalization of the 1,3-phenylene-19-crown-6 system via bromine–lithium exchange

N. Veldman, A. Spek, F. Bickelhaupt, 1999 .

The synthesis of cis- and trans-1,2-dibromocyclopropane

F. Bickelhaupt, O. S. Akkerman,, J. Seetz, 1981 .

Syntheses of 1,3‐Dimetallacyclobutanes with the Methylene‐di‐Grignard Reagent.

F. Bickelhaupt, O. S. Akkerman,, G. Schat, 1986 .

The Synthesis of Four-Membered Spiro Compounds of Silicon and Germanium: 2,2,6,6-Tetramethyl-4-metallaspiro(3.3)heptanes.

F. Bickelhaupt, O. S. Akkerman,, Y. V. D. Winkel, 1987 .

Multiple Bonds Between Main Group Elements and Transition Metals. Part 35. First Four-Membered Metallacycles of Rhenium.

W. Herrmann, F. Bickelhaupt, H. J. R. D. Boer, 1987 .

(μ‐Methylene)bis(methylzirconocene): Preparation, Molecular Structure, and Thermal Disproportionation

A. Spek, M. Albrecht, G. Erker, 2004 .

NONCOVALENT INTERACTIONS IN ORGANOMETALLIC COMPOUNDS : FORMATION OF AN INTRAMOLECULAR METAL-CARBON ION PAIR IN ZIRCONIUM BORATE BETAINES

G. Erker, F. Bickelhaupt, O. S. Akkerman,, 1997 .

Formation of the first organometallic catenane

F. Bickelhaupt, G. Gruter, F. D. Kanter, 1993 .

FUNCTIONALIZATION OF 1,3-PHENYLENE-16-CROWN-5 VIA DIRECT LITHIATION

A. Spek, F. Bickelhaupt, H. Kooijman, 1996 .

X-ray structure of (1,3-xylyl-18-crown-5)diphenylmagnesium: an organometallic rotaxane

A. Spek, F. Bickelhaupt, O. S. Akkerman,, 1988 .

mu2-eta2-2-tert-Butylethyn-1-yl)(mu2-chloro)bis{{eta2-cyclopentadienyl)dimethylsilane]titanium}

A. Spek, F. Bickelhaupt, H. Kooijman, 2005 .

Complexation of bis(p-tert-butylphenyl)magnesium with 1,3-xylylene crown ethers and glymes

A. Spek, F. Bickelhaupt, O. S. Akkerman,, 1994 .

The formation of catenanes. The mobius strip approach revisited.

F. Bickelhaupt, G. Gruter, O. S. Akkerman,, 1996 .

Synthesis of bis(phosphine)-1,2-dihydroplatina(II)cyclobutabenzenes. Molecular structure of the 1,2-dihydroplatina(II)cyclobutabenzene [cyclic] Pt(CH2-o-C6H4)(PMe3)2

F. Bickelhaupt, M. Wit, C. H. Stam, 1989 .

Synthesis of Bis(phosphine)-1,2-dihydroplatina(II)cyclobutabenzenes. Molecular Structure of the Cyclic 1,2-Dihydroplatina(II)cyclobutabenzene Pt(CH2-o-C6H4)(PMe3)2.

F. Bickelhaupt, M. Wit, O. S. Akkerman,, 1989 .

O-Phenylenemagnesium tetramer: the first organomagnesium cluster

A. Spek, F. Bickelhaupt, O. S. Akkerman,, 1991 .

Optical activity of symmetrically substituted acetic acids. Part I: The stability against racemization of some ortho-alkyl-substituted diphenylacetic acids

O. S. Akkerman,, J. Coops, 2010 .

Optical activity of symmetrically substituted acetic acids. Part II: The synthesis of alkyl‐substituted diphenylacetic acids

O. S. Akkerman,, 2010 .

Carbanions as Intermediates in the Formation of Grignard Reagents

A. Spek, G. V. Klink, F. Bickelhaupt, 2002 .

The remarkable electron impact mass spectrum of (2-benzyl-1,3-xylylene)-15-crown-4: expulsion of triethylene glycol by double hydrogen transfer

D. Kuck, F. Bickelhaupt, G. Gruter, 1996 .

Intramolecular Coordination in Organometallic Compounds of Groups 2, 12, and 13

G. P. V. van Klink, F. Bickelhaupt, O. S. Akkerman,, 1995 .