H. Akashi

发表

Magnetic susceptibility analysis of mixed metal cubane-type cluster complexes, [tetra-μ3-thiotris{tri(aqua)molybdenum}aquairon](4+)p-toluensulfonate heptahydrate and [tetra-μ3-thiotris{tri(aqua)molybdenum}aquanickel](4+)p-toluensulfonate heptahydrate

H. Akashi, N. Uryǔ, T. Shibahara, 1997 .

Photodynamic therapy with glycoconjugated chlorin photosensitizer

A. Morita, A. Maeda, H. Akashi, 2013 .

Presence and Future of the Advanced Photodynamic Therapy in Bile Duct Carcinomas

T. Nagayasu, H. Isomoto, A. Nanashima, 2013 .

Antitumor Effects in Gastrointestinal Stromal Tumors Using Photodynamic Therapy with a Novel Glucose-Conjugated Chlorin

T. Joh, T. Taguchi, S. Tanida, 2014, Molecular Cancer Therapeutics.

Small Molecule Therapeutics Antitumor Effects in Gastrointestinal Stromal Tumors Using Photodynamic Therapy with a Novel Glucose-Conjugated

T. Joh, T. Taguchi, S. Tanida, 2014 .

Dual Emission and Mechanofluorochromism of a V-Shaped π-System Composed of Disulfonyl-Substituted Dibenzocyclooctatetraenes.

A. Orita, Feng Xu, H. Akashi, 2016, Organic letters.

Chemistry of Anthracene-Acetylene Oligomers XV. Synthesis, Structures, and Dynamic Behavior of Chiral Anthrylene-Ethynylene Cyclic Tetramers and Related Derivatives and Resolution of Enantiomers

M. Yamasaki, H. Akashi, T. Shimasaki, 2010 .

Redetermination of di-μ-sulfido-bis{[(2R)-2-acetoxy-2-aminoethane-1-thiolato-κ2 N,S]oxidomolybdenum(V)}

H. Akashi, T. Shibahara, Yujiro Shiraga, 2010, Acta crystallographica. Section E, Structure reports online.

Absolute configuration and chiroptical properties of an enantiopure [5-chloro-2-(dimethylaminomethyl)phenyl]-phenylborane complex

H. Akashi, S. Toyota, T. Iwanaga, 2006 .

(R)‐2,2′‐Bis{[5‐(2‐phenylethynyl)thienyl]ethynyl}‐1,1′‐binaphthyl

H. Akashi, N. Imai, J. Otera, 2003 .

Immunogenic cell death due to a new photodynamic therapy (PDT) with glycoconjugated chlorin (G-chlorin)

T. Joh, Satoru Takahashi, Shugo Suzuki, 2016, Oncotarget.

Fluorescent Fluoro-Silicon(IV) Complexes with Schiff Base Ligands

M. Yamasaki, H. Akashi, T. Shibahara, 2013 .

Dephosphinylative [4 + 2] Benzannulation of Phosphinyl Ynamines: Application to the Modular Synthesis of Polycyclic Aromatic Amines.

A. Orita, H. Akashi, Y. Okuda, 2021, The Journal of organic chemistry.

Crystal Structure of Arsenazo III

M. Zenki, T. Yokoyama, H. Akashi, 1990 .

Syntheses and antitumor activities of D- and L-2'-deoxy-4'-thio pyrimidine nucleosides

Takuma Sasaki, J. Uenishi, H. Akashi, 1994 .

Crystal structural diversity of sulfur-bridged cysteinato dimolybdenum(V) complexes: The influence of counter metal cations

H. Akashi, T. Shibahara, Shinobu Ogasahara, 2012 .

Trimethylsilyl Group Assisted Stimuli Response: Self-Assembly of 1,3,6,8-Tetrakis((trimethysilyl)ethynyl)pyrene

A. Orita, Feng Xu, K. Ohta, 2017 .

Removal of Two Hydrogen Atoms from Ketones or Aldehyde: Reaction of a Sulfur-Bridged Incomplete Cubane-Type Molybdenum Cluster with Acetone, Acetaldehyde, Acetylacetone, Ethyl Acetoacetate, and Acetophenone

H. Takagi, H. Akashi, T. Shibahara, 2014 .

Fluorescent Tin(IV) Complexes with Schiff Base Ligands: Synthesis, Structures, and Fluorescence Lifetime

H. Takagi, Masayuki Takahashi, H. Akashi, 2012 .

Synthesis, Structure and Proton-Coupled Electron Transfer of μ-Oxo-μ-chloro and μ-Oxo-μ-alkoxo Dimeric Molybdenum(III) Ethylenediamine Complexes

H. Akashi, T. Shibahara, A. Ichimura, 2003 .

Antiferromagnetism induced by successive protonation of terminal phenol groups of a bis(μ-phenoxide)-bridged dicopper(II,II) complex

K. Nakajima, T. Tokii, H. Akashi, 2002 .

Effect of outer sphere anions on the structure and color of nitrosylpentaamminechromium complex

M. Mori, H. Akashi, T. Shibahara, 2002 .

Molybdenum–copper–sulfur Mo3CuS4 cubes

H. Akashi, T. Shibahara, 2000 .

Enantiopure anthrylene-ethynylene cyclic tetramer and racemization via rotation of anthracene unit about acetylenic axes.

H. Akashi, T. Shimasaki, S. Toyota, 2008, Organic letters.

Synthesis and structural characterization of [HxCp*TiMo5O18](3−x)− (x=0, 1, 2); new insights into protonation patterns in polyoxometalates

T. Hashimoto, Jinzhu Chen, A. Yagasaki, 2003 .

Supramolecular spin-crossover iron complexes based on imidazole-imidazolate hydrogen bonds.

S. Iijima, F. Dahan, J. Tuchagues, 2004, Inorganic chemistry.

Structures and Properties of 4-phpy, pyz, and 4,4′-bpy Adducts of Lantern-Type Dirhodium Complexes with µ-Formamidinato and µ-Carboxylato Bridges

Natsumi Yano, Y. Kataoka, M. Handa, 2021, Magnetochemistry.

Synthesis, structures, and magnetic properties of face-sharing heterodinuclear Ni(II)-Ln(III) (Ln = Eu, Gd, Tb, Dy) complexes.

N. Re, H. Ishida, H. Akashi, 2008, Inorganic chemistry.

Preparation and characterization of twin-cubane-type clusters with molybdenum-copper-sulfur cores: X-ray structure determination of [{(NH3)6(H2O)(OH)Mo3CuS4(O)}2]Cl4·8H2O

H. Akashi, T. Shibahara, 1998 .

Syntheses and Characterization of Cubane-Type Clusters with Molybdenum–Iron–Sulfur (Mo3FeS4) or Molybdenum–Nickel–Sulfur (Mo3NiS4) Cores. X-Ray Structures of [Mo3FeS4(H2O)10](CH3C6H4SO3)4·7H2O and [Mo3FeS4(H2O)(NH3)9]Cl4, and Discrete Variational (DV)-Xα Calculation of the Electronic Structures of [

H. Adachi, H. Akashi, T. Shibahara, 1995 .

Preparation and characterization of sulfur-capped trinuclear molybdenum(IV) complexes with Mo3O3S cores and of sulfur-bridged dinuclear molybdenum(V) complexes with Mo2O3S cores. Crystal and molecular structures of Ba[Mo3O3S(Hnta)3].10H2O and K2[Mo3O3S(cys)3].6H2O

H. Akashi, T. Shibahara, H. Kuroya, 1989 .

Crystal Structure of Isothiocyanato-N,N'-dimethyl-N,N'-bis(pyridine-2-ylmethyl)propane-1,3-diaminecopper(II) Perchlorate

M. Zenki, T. Yokoyama, A. Shiomi, 2011 .

Reaction of [Mo3S4(H2O)9]4+ with Cobalt and Mercury. Syntheses and X-Ray Structures of Double Cubane-Type Cluster, [(H2O)9Mo3S4CoCoS4Mo3(H2O)9](CH3·C6H4·SO3)8·18H2O and Sandwich Cubane-Type Cluster, [(H2O)9Mo3S4HgS4Mo3(H2O)9](CH3·C6H4·SO3)8·2OH2O

M. Yamasaki, H. Akashi, T. Shibahara, 1991 .

Sulfur‐Bridged Cubane‐Type (Mo4S4) and Incomplete Cubane‐Type (Mo3O4 – nSn; n = 1–4) Molybdenum Aqua Ions

D. Coucouvanis, H. Akashi, T. Shibahara, 2007 .

Cubane-type Mo3FeS44+ aqua ion and x-ray structure of [Mo3FeS4(NH3)9(H2O)]Cl4

H. Akashi, T. Shibahara, H. Kuroya, 1986 .

Magnetic and Electrochemical Properties of Lantern-Type Dinuclear Ru(II,III) Complexes with Axial Chloride Ions or Water Molecules

Kazuhito Inoue, Masaharu Kitashima, Natsumi Yano, 2019, Magnetochemistry.

Synthesis, Structures, and Magnetic Properties of Doubly Face-Sharing Heterotrinuclear NiII–LnIII–NiII (Ln = Eu, Gd, Tb, and Dy) Complexes

N. Re, H. Ishida, H. Akashi, 2008 .

Tetrasodium tetrahydroxytetrathiacalix[4]arenetetrasulfonate tetradecahydrate

H. Akashi, T. Yamauchi, 2003 .

Intramolecular ring opening of a 2,3-epoxy alcohol by a xanthate anionic center; stereospecific preparation of 2-mercapto-1,3-diol units

Y. Nishiyama, J. Uenishi, H. Akashi, 1994 .

Ferromagnetic NiII-GdIII interactions in complexes with NiGd, NiGdNi, and NiGdGdNi cores supported by tripodal ligands.

N. Re, H. Akashi, N. Matsumoto, 2004, Chemical communications.

MOLYBDENUM-IRON SULFIDE-BRIDGED DOUBLE CUBANES

Jie‐Sheng Huang, S. Mukerjee, R. H. Holm, 1997 .

Reaction of 2-(Alkylthiomethyl)phenyllithium with Copper(I) Halides and Structure and Properties of One of the Products—Copper(I) Complexes of 2,2′-Bis(alkylthiomethyl)biphenyl

H. Akashi, S. Nagaoka, M. Ōki, 1996 .

Synthesis and Structural Studies on Dimeric Organotin Cations

T. Fukuyama, A. Orita, H. Ikeda, 2000 .

Novel Dimeric Organotin Cations: Highly Effective Alcohol Acetylation Catalysts

H. Akashi, J. Otera, Y. Hamada, 1999 .

Photochromism of Dinuclear Tungsten Complexes with Disulfur and Ethylene-1,2-dithiolate Ligands.

H. Akashi, T. Shibahara, G. Sakane, 1997 .

Molybdenum Dithiolene Complexes: Trinuclear Mixed-Valence Complexes and Geometrical Isomers of Dinuclear Complexes

H. Takagi, K. Yamaguchi, H. Akashi, 2017 .

Isolation and X-ray structure determination of a sulphur-bridged incomplete cubane-type molybdenum(IV) aqua cluster, [Mo3S4(H2O)9](CH3·C6H4·SO3)4·9H2O

H. Akashi, T. Shibahara, H. Kuroya, 1990 .

Cubane-Type Molybdenum Aqua Ions. Preparation and Structures of [Mo4(μ3-O)(μ3-S)3(H2O)12]5+ and [Mo4(μ3-S)4(H2O)12]5+

H. Akashi, T. Shibahara, Hiroaki Tsuru, 1989 .

Preparation and x-ray structure of a mixed-metal double cubane-type aqua ion, [(H2O)9Mo3S4CuCuS4Mo3(H2O)9]8+

H. Akashi, T. Shibahara, H. Kuroya, 1988 .

Cubane-type mixed-metal clusters with molybdenum-nickel-sulfur Mo3NiS4 cores. Syntheses, characterization, and x-ray structures of [Mo3NiS4(H2O)10](CH3C6H4SO3)4.7H2O and Ca2.5[Mo3NiS4(Hnta)(nta)2Cl].14H2O

M. Yamasaki, H. Akashi, T. Shibahara, 1991 .

Synthesis and Characterization of Oxygen/Sulfur-Bridged Incomplete Cubane-Type Clusters, [M3S4(Tpe)3]+ and [M3OS3(Tpe)3]+ (M = Mo and W), and a Mixed-Metal Cubane-Type Cluster, [Mo3PdS4Cl(Tpe)3]

H. Akashi, T. Shibahara, Ryouichi Yoshida, 2013 .

Redox Chemistry of Dinuclear Molybdenum Dithiolene Complexes. Interconversion of the Bridging Disulfide and Sulfides

H. Takagi, H. Akashi, T. Shibahara, 2002 .

Synthesis and Characterization of Oxygen/Sulfur-Bridged Incomplete Cubane-Type Clusters, [Mo3OnS4−n (Tm)3]+ (n = 0–3)

H. Takagi, H. Akashi, T. Shibahara, 2014, Journal of Cluster Science.

Syntheses and characterization of oxygen/sulfur-bridged incomplete cubane-type clusters, [Mo3S4Tp3]+ and [Mo3OS3Tp3]+, and a mixed-metal cubane-type cluster, [Mo3FeS4ClTp3]. X-ray structures of [Mo3S4Tp3]Cl, [Mo3OS3Tp3]PF6, and [Mo3FeS4ClTp3].

H. Takagi, H. Akashi, T. Shibahara, 2006, Inorganic chemistry.

31P NMR Studies on Sulfur/Oxygen-Bridged Incomplete Cubane-Type Molybdenum Cluster Compounds. X-ray Structures of [Mo3OS3(DTP)4(CH3CN)] and [Mo3OS3(OAc)(DTP)2(Py)2(OC2H5)]

H. Ohtaki, H. Akashi, T. Shibahara, 1995 .

Cubane-Type Mo3FeS44+Aqua Ion and X-Ray Structure of (Mo3FeS4(NH3)9(H2O))Cl4.

H. Akashi, T. Shibahara, H. Kuroya, 1986 .

Oxo- and Alkoxo-Bridged Dimeric Molybdenum(III) Ethylenediamine Complexes

H. Akashi, T. Shibahara, A. Ichimura, 2000 .

Peroxidase-like catalytic activity of water-insoluble complex linked Fe(III)-thiacalix[4]arenetetrasulfonate with tetrakis(1-methylpyridinium-4-yl)porphine via ionic interaction.

H. Akashi, J. Odō, M. Inoguchi, 2009, Chemical & pharmaceutical bulletin.

Effects of a vanadate-support on the reactivity of theBis(Methallyl)Rhodium Complex [{(η3-C4H7)2Rh}2(V4O12)]2−. A comparison with the acetylacetonato complex

K. Isobe, A. Yagasaki, M. Abe, 1996 .

β-Methallylrhodium(III) supported on a vanadium oxide cluster: Synthesis, structure, and reaction

K. Isobe, A. Yagasaki, Y. Ozawa, 1991 .

A hexacarbonyldicobalt(0) complex of a `magazine‐rack' molecule, [(η2‐C32H20)Co2(CO)6]·CH2Cl2

Lasheng Jiang, H. Akashi, N. Imai, 2002 .

Novel cubane-type molybdenum-tin cluster complexes [(H2O)9Mo3S4SnS4Mo3(H2O)9]8+ and Mo3SnS4(aq)6+

H. Akashi, T. Shibahara, 1989 .

An Oxo- and Chloro-Bridged Dimeric Molybdenum(III) Ethylenediamine Complex

T. Ohtani, H. Akashi, T. Shibahara, 1999 .

Synthesis and Crystal Structure of a Sulfur-bridged Incomplete Cubane-type Molybdenum Cluster with a Tris(pyrazolyl)methanesulfonate Ligand

H. Akashi, Kazuhiro Moriwaki, Ryouichi Yoshida, 2014 .

One-Shot Double Amination of Sondheimer-Wong Diynes: Synthesis of Photoluminescent Dinaphthopentalenes.

Motoyuki Uejima, A. Orita, Tohru Sato, 2015, Organic letters.

Synthesis of [Cp*TiMo5O18]3−. Its unexpectedly high basicity and unexpected protonation site

A. Yagasaki, Jie Chen, H. Akashi, 1994 .

Mössbauer spectroscopic studies of cubane-type clusters of [Mo3FeS4(NH3)9(H2O)]Cl4 and [Mo3FeS4(H2O)10](pts)4.7H2O (pts−: CH3(C6H4)SO3−)

H. Sano, H. Akashi, T. Shibahara, 1990 .

Preparation and X-Ray Structure of a Mixed-Metal Double-Cubane-Type Aqua Ion ((H2O)9Mo3S4CuCuS4Mo3(H2O)9)8+.

H. Akashi, T. Shibahara, H. Kuroya, 1988 .

Synthesis of Ph2P(O)-stabilized Ynamines via C(sp)–N Bond Formation and Their Dephosphorylative Copper-catalyzed Click Reaction

A. Orita, H. Akashi, Y. Okuda, 2019 .

Crystal Structure ofα-AgVO3and Phase Relation of AgVO3

S. Kittaka, H. Akashi, Kosaku Matsuno, 1999 .

Green Oxidation of Amines to Imines Based on the Development of Novel Catalytic Systems Using Molecular Oxygen or Hydrogen Peroxide

A. Nomoto, A. Ogawa, H. Akashi, 2015, Synthesis.

Synthesis and X-Ray Structure of 4′-Thiothymidine

J. Uenishi, H. Akashi, Keiji Takahashi, 1993 .

Syntheses and Antitumor Activities of D- and L-2′-Deoxy-4′- thiopyrimidine Nucleosides.

J. Uenishi, H. Akashi, K. Takahashi, 1995 .

Cassane-type diterpenoids from Caesalpinia echinata (Leguminosae) and their NF-κB signaling inhibition activities.

Ken-ichiro Hayashi, H. Nozaki, N. Matsuura, 2015, Phytochemistry.

THE CRYSTAL STRUCTURES OF 2-AMINOPERIMIDINE

M. Zenki, T. Yokoyama, H. Akashi, 1995 .

A Novel Photodynamic Therapy Targeting Cancer Cells and Tumor-Associated Macrophages

T. Joh, Satoru Takahashi, Shugo Suzuki, 2014, Molecular Cancer Therapeutics.

Synthesis and Photophysical Properties of S-Mannosylated Chlorins and Their Effect on Photocytotoxicity in HeLa Cells

M. Inoue, J. Kikuchi, Takuya Sawada, 2018 .

Photodynamic Therapy Using Novel Glucose-conjugated Chlorin Increases Apoptosis of Cholangiocellular Carcinoma in Comparison with Talaporfin Sodium.

T. Nagayasu, A. Nanashima, S. Okazaki, 2016, Anticancer Research.

A tripodal ligand containing three imidazole groups inducing spin crossover in both Fe(II) and Fe(III) complexes; structures and spin crossover behaviors of the complexes

S. Iijima, H. Akashi, N. Matsumoto, 2004 .

Anticancer effects of novel photodynamic therapy with glycoconjugated chlorin for gastric and colon cancer.

T. Joh, Satoru Takahashi, H. Kataoka, 2011, Anticancer research.

Hydrogen bonding: further evidence for the cause of the color change of nitrosylpentaamminechromium (III) compounds. Crystal structures of [Cr(NO)(NH3)5](PF6)2 and [Cr(NO)(NH3)5]Cl(PF6)

H. Akashi, T. Shibahara, T. Yamauchi, 2004 .

DFT calculation and X-ray structure of nitrosyl pentaammine chromium complex

M. Mori, H. Akashi, T. Shibahara, 2001 .

Process-Controlled Regiodivergent Copper-Catalyzed Azide-Alkyne Cycloadditions: Tailor-made Syntheses of 4- and 5-Bromotriazoles from Bromo(phosphoryl)ethyne.

A. Orita, H. Akashi, Y. Okuda, 2020, Organic letters.

Dual Emission and Mechanofluorochromism of a V-Shaped π-System Composed of Disulfonyl-Substituted Dibenzocyclooctatetraenes.

A. Orita, Feng Xu, H. Akashi, 2016, Organic letters.