J. Enemark

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Dielectric Resonator for Ka-Band Pulsed EPR Measurements at Cryogenic Temperatures: Probehead Construction and Applications

T. Meade, A. Blank, A. Astashkin, 2012, Applied magnetic resonance.

Electronic Structure of the d1 Bent-metallocene Cp2VCl2: A Photoelectron and Density Functional Study

D. Lichtenberger, N. Gruhn, J. Enemark, 2008 .

Electron transfer studies of dithiolate complexes: effects of ligand variation and metal substitution

Frank Inscore, J. Enemark, Anne E. McElhaney, 2002 .

Characterization of chloride-depleted human sulfite oxidase by electron paramagnetic resonance spectroscopy: experimental evidence for the role of anions in product release.

A. Astashkin, Asha Rajapakshe, K. Meyers, 2010, Biochemistry.

Sulfite-oxidizing enzymes

G. Tollin, U. Kappler, Changjian Feng, 2007, JBIC Journal of Biological Inorganic Chemistry.

The active sites of molybdenum- and tungsten-containing enzymes.

J. McMaster, J. Enemark, 1998, Current opinion in chemical biology.

Molybdenum(VI)-dioxo complexes with sterically bulky ligands

J. Enemark, J. T. Spence, P. Subramanian, 1984 .

Stoichiometry of electron uptake and the effect of anions and pH on the molybdenum and heme reduction potentials of sulfite oxidase

R. Sunde, J. Enemark, J. T. Spence, 1991 .

ELECTRON PARAMAGNETIC RESONANCE STRUCTURAL STUDIES OF MOLYBDENUM(V)-OXO COMPLEXES

R. D. Taylor, N. Chasteen, J. Enemark, 1979 .

The nuclear magnetic resonance properties of chromium, molybdenum and tungsten compounds

R. Brownlee, A. G. Wedd, J. Enemark, 1985 .

Ab initio orbital studies of molybdenum-95, oxygen-17, and sulfur-33 chemical shielding in transition-metal compounds

M. Barfield, J. Combariza, J. Enemark, 1991 .

Ab initio molecular orbital studies of chemical shielding in transition-metal compounds: 95Mo shielding in molybdate and thiomolybdate [MoOnS(4−n)]2− anions

J. Facelli, M. Barfield, J. Combariza, 1989 .

Intramolecular electron transfer in sulfite-oxidizing enzymes: elucidating the role of a conserved active site arginine.

G. Tollin, U. Kappler, Asha Rajapakshe, 2009, Biochemistry.

A Study of Transition Metal Compounds Containing the Tricyanomethanide Ion

R. H. Holm, J. Enemark, 1964 .

A voltammetric study of interdomain electron transfer within sulfite oxidase.

S. Elliott, F. Armstrong, Changjian Feng, 2002, Journal of the American Chemical Society.

Pulsed dipolar spectroscopy distance measurements in biomacromolecules labeled with Gd(III) markers.

T. Meade, A. Astashkin, A. Raitsimring, 2011, Journal of magnetic resonance.

Principles of structure, bonding, and reactivity for metal nitrosyl complexes

J. Enemark, R. Feltham, 1974 .

A Treatise on Dinitrogen Fixation: Sections I and II: Inorganic and Physical Chemistry and Biochemistry

J. Enemark, 1980 .

Determination of the distance between the Mo(V) and Fe(III) heme centers of wild type human sulfite oxidase by pulsed EPR spectroscopy.

A. Astashkin, Asha Rajapakshe, Matthew J Cornelison, 2012, The journal of physical chemistry. B.

Metal-sulfur valence orbital interaction energies in metal-dithiolene complexes: determination of charge and overlap interaction energies by comparison of core and valence ionization energy shifts.

D. Lichtenberger, L. T. Lockett, J. Enemark, 2011, Inorganic chemistry.

Implications for the mechanism of sulfite oxidizing enzymes from pulsed EPR spectroscopy and DFT calculations for "difficult" nuclei.

A. Astashkin, A. Raitsimring, J. Enemark, 2011, Faraday discussions.

26.5–40 GHz Ka‐band pulsed EPR spectrometer

A. Astashkin, A. Raitsimring, J. Enemark, 2006 .

Insights into the Nature of Mo(V) Species in Solution: Modeling Catalytic Cycles for Molybdenum Enzymes.

C. G. Young, Dennis H. Evans, A. Astashkin, 2009, Inorganica chimica acta.

Optimization of Pulsed-DEER Measurements for Gd-Based Labels: Choice of Operational Frequencies, Pulse Durations and Positions, and Temperature

E. Walter, T. Meade, A. Astashkin, 2013, Applied magnetic resonance.

Structures of Complexes of Reduced Nitrogen Ligands

J. Enemark, Maki Sato, 1983 .

Models for the molybdenum-phosphate interactions in oxo-type molybdoenzymes and their cofactors

J. Enemark, Ulrich Kusthardt, 1987 .

Syntheses, structures, and spectroscopic properties of six-coordinate mononuclear oxo-molybdenum(V) complexes stabilized by the hydrotris(3,5-dimethyl-1-pyrazolyl)borate ligand

K. Barnhart, D. Collison, J. Enemark, 1987 .

{Moco}n, (n = 0-8): A general formalism for describing the highly covalent molybdenum cofactor of sulfite oxidase and related Mo enzymes.

J. Enemark, 2022, Journal of inorganic biochemistry.

K. Metalloproteins

F. Neese, D. Goldfarb, A. Astashkin, 2009, JBIC Journal of Biological Inorganic Chemistry.

Studies of the Mo(V) Center of the Y343F Mutant of Human Sulfite Oxidase by Variable Frequency Pulsed EPR Spectroscopy.

K. Rajagopalan, A. Astashkin, Changjian Feng, 2008, Inorganica chimica acta.

Six-coordinate molybdenum nitrosyls with a single ene-1,2-dithiolate ligand

M. Carducci, Frank Inscore, J. Enemark, 2002 .

Structures of three novel polynuclear oxo- and sulfidomolybdenum complexes containing the hydrotris(3,5-dimethyl-1-pyrazolyl)borate ligand

C. G. Young, S. Roberts, J. Enemark, 1988 .

The First Mononuclear Molybdenum(V) Complex with a Terminal Sulfido Ligand: (HB(Me2C3N2H)3)MoSCl2.

C. G. Young, D. Collison, J. Enemark, 1987 .

Syntheses, Structures, and Spectroscopic Properties of Six-Coordinate Mononuclear Oxo-Molybdenum(V) Complexes Stabilized by the Hydrotris(3,5-dimethyl-1-pyrazolyl)borate Ligand.

K. Barnhart, D. Collison, J. Enemark, 1987 .

Stereochemical control of valence. IV. Comparison of the structures and chemical reactivities of five- and six-coordinate diarsine complexes of the cobalt nitrosyls {CoNo}38 group

J. Enemark, R. Feltham, J. Riker-Nappier, 1975 .

HIGH-RESOLUTION EPR SPECTROSCOPY OF MO ENZYMES. SULFITE OXIDASES: STRUCTURAL AND FUNCTIONAL IMPLICATIONS.

A. Astashkin, A. Raitsimring, J. Enemark, 2010, Biological magnetic resonance.

Electronic spectral studies of molybdenyl complexes. 2. MCD spectroscopy of [MoOS4]- centers.

M. Carducci, E. Solomon, J. McMaster, 2001, Inorganic chemistry.

Multifrequency ESEEM Spectroscopy of Sulfite Oxidase in Phosphate Buffer: Direct Evidence for Coordinated Phosphate.

A. Pacheco, P. Borbat, P. Basu, 1996, Inorganic chemistry.

A SINGLE MODEL DISPLAYING ALL THE IMPORTANT CENTERS AND PROCESSES INVOLVED IN CATALYSIS BY MOLYBDOENZYMES CONTAINING [MOVIO2]2 ACTIVE-SITES

C. G. Young, A. G. Wedd, J. Enemark, 1992 .

Dioxomolybdenum(VI) complexes of the hydrotris(3,5-dimethyl-1-pyrazolyl)borate ligand. Synthesis and oxygen atom transfer reactions

C. G. Young, M. Carducci, S. Roberts, 1990 .

Pulsed EPR investigations of systems modeling molybdenum enzymes: hyperfine and quadrupole parameters of oxo-17O in [Mo 17O(SPh)4]-.

F. Neese, A. Astashkin, A. Raitsimring, 2005, Journal of the American Chemical Society.

Determination of the g-tensors and their orientations for cis,trans-(L-N2S2)Mo(V)OX (X = Cl, SCH2Ph) by single-crystal EPR spectroscopy and molecular orbital calculations.

F. Neese, M. Carducci, A. Astashkin, 2005, Inorganic chemistry.

Purification of prosthetically intact sulfite oxidase from chicken liver using a modified procedure.

R. Sunde, J. Enemark, C. Kipke, 1989, Archives of biochemistry and biophysics.

Investigation of metal–dithiolate fold angle effects: Implications for molybdenum and tungsten enzymes

D. Lichtenberger, N. Gruhn, Frank Inscore, 2003, Proceedings of the National Academy of Sciences of the United States of America.

Molybdenum(VI)-Dioxo, Molybdenum(V)-Oxo, and Molybdenum(IV)-Oxo Complexes with 2,3:8,9-Dibenzo-1,4,7,10-tetrathiadecane. Models for the Molybdenum Binding Site of the Molybdenum Cofactor

S. Merbs, J. Enemark, J. T. Spence, 1985 .

Synthesis and characterization of mononuclear oxomolybdenum(V) complexes with aliphatic diolato, dithiolato, or alkoxo ligands: effect of chelate ring size on the properties of the metal center

D. Collison, J. Enemark, F. Mabbs, 1990 .

Structures of Metal Nitrosyls

J. Enemark, R. Feltham, 2007 .

Palladium and platinum complex resulting from the addition of hydrazine to coordinated isocyanide

A. Balch, A. Burke, J. Enemark, 1970 .

Complexes containing the Mo2O52+ core: preparation, properties and crystal structure of Mo2O5[(CH3)2NCH2CH2NHCH2C(CH3)2S]2

J. Enemark, E. Stiefel, J. L. Corbin, 1983 .

Synthetic analogues and reaction systems relevant to the molybdenum and tungsten oxotransferases.

R. H. Holm, J. Enemark, Jun-Jieh Wang, 2004, Chemical reviews.

Bioinorganic chemistry of pterin-containing molybdenum and tungsten enzymes

C. G. Young, J. Enemark, C. G. Young, 1993 .

Structure of tris[2-aminobenzenethiolato(2-)-N,S]molybdenum(VI), Mo(NHC6H4S)3

J. Enemark, K. Yamanouchi, 1978 .

95Mo NMR spectra of dioxomolybdenum(VI) complexes

K. A. Christensen, J. Enemark, P. Miller, 1981 .

Remote ligand substituent effects on the properties of oxo-Mo(V) centers with a single ene-1,2-dithiolate ligand

Frank Inscore, J. Enemark, Anne E. McElhaney, 2002 .

Synthesis and Characterization of Mononuclear Oxomolybdenum(V) Complexes with Aliphatic Diolato, Dithiolato, or Alkoxo Ligands: Effect of Chelate Ring Size on the Properties of the Metal Center.

D. Collison, J. Enemark, F. Mabbs, 1990 .

Some aspects of the bioinorganic chemistry of molybdenum

J. Enemark, Kathleen Bizot Swedo, 1979 .

Molybdenum complexes of aliphatic thiols. The structures of the syn and anti isomers of the di-.mu.-sulfido-bis(sulfido-1,2-dimercaptoethanatomolybdate(V)) anion, [Mo2S4(S2C2H4)2]2-

J. Enemark, Glenn Bunzey, 1978 .

Crystal and molecular structure of tetra-n-butylammonium di-.mu.-sulfido-bis(oxo-1,1-dicyanoethylene-2,2-dithiolatomolybdate(V)), [(n-C4H9)4N]2[Mo2O2S2(S2C2(CN)2)2]

J. Enemark, J. Gelder, 1976 .

A TRIPLY BRIDGED BINUCLEAR MOLYBDENUM(V) COMPOUND CONTAINING TWO KINDS OF BRIDGING THIOPHENOLATE GROUPS

W. Newton, J. Enemark, K. Yamanouchi, 1977 .

Role of Conserved Tyrosine 343 in Intramolecular Electron Transfer in Human Sulfite Oxidase*

G. Tollin, K. Rajagopalan, Changjian Feng, 2003, The Journal of Biological Chemistry.

EPR Studies of Oxo-Molybdenum(V) Complexes with Sulfur Donor Ligands: Implications for the Molybdenum Center of Sulfite Oxidase.

J. Enemark, I. Dhawan, 1996, Inorganic chemistry.

Molecular Structure and Electronic Properties of Oxomolybdenum(V) Catecholate Complexes

M. Bruck, P. Basu, J. Enemark, 1995 .

Spectroscopic and electrochemical studies of monomeric oxomolybdenum(V) complexes with five-membered chelate rings and alkoxo or alkanethiolato ligands

J. Enemark, C. Chang, 1991 .

Molybdenum(VI)-dioxo complexes with linear and tripodal tetradentate ligands: models for the molybdenum(VI/V) centers of the molybdenum hydroxylases and related enzymes. 1. Syntheses and structures

Raghuvir Singh, Gang. Peng, M. Bruck, 1989 .

Crystal and molecular structure of chlorotriphenylphosphonium bis(cis-1,2-bis(trifluoromethyl)ethene-1,2-dithiolato)gold, [PCl(C6H5)3][Au(S2C2(CF3)2)2]

J. Ibers, J. Enemark, 1968 .

Oxidation of 1,1-dimethylhydrazine by cupric halides. Isolation of a complex of 1,1-dimethyldiazene and a salt containing the 1,1,5,5-tetramethylformazanium ion

A. Balch, J. Enemark, Kathleen F. Bizot, 1975 .

Redox reactions between oxomolybdenum(IV) and tetratolylporphinatoiron(III) complexes

A. Pacheco, M. LaBarre, J. Enemark, 1994 .

Multinuclear NMR studies of electron distributions: /sup 14/N, /sup 13/C, and /sup 95/Mo spectra of nitrosyl and thionitrosyl complexes of chromium, molybdenum, and tungsten

D. Lichtenberger, J. Enemark, M. Minelli, 1984 .

Molybdenum-95 NMR measurements of dioxomolybdenum(VI) complexes. 3. Inverse halogen dependence of molybdenum chemical shift of [MoO2]2+ complexes

J. Enemark, J. T. Spence, P. Subramanian, 1984 .

The crystal and molecular structure of tetraethylammonium hydrotris(3,5-dimethylpyrazolyl)boratotricarbonylmolybdenum(0), [NEt4][Mo(CO)3HB(C5H7N2)3]

J. Enemark, C. P. Marabella, 1982 .

Isolation of [{HB(Me2pz)3}MoO2(OC6H4S)]2, a binuclear Mo(VI) complex containing a disulfide bond

S. Roberts, J. Enemark, W. Cleland, 1988 .

Four-coordinate metal nitrosyls. I. Structure of azidonitrosylbis(triphenylphosphine)nickel, Ni(N3)(NO)(PPh3)2

J. Enemark, 1971 .

Pulsed electron paramagnetic resonance spectroscopy of (33)S-labeled molybdenum cofactor in catalytically active bioengineered sulfite oxidase.

F. Neese, A. Belaidi, A. Astashkin, 2014, Inorganic chemistry.

Destabilizing d.pi.-p.pi. orbital interactions and the alkylation reactions of iron(II)-thiolate complexes

D. Lichtenberger, M. Ashby, J. Enemark, 1988 .

Mononuclear and Binuclear Molybdenum Complexes of the Tris(3,5-dimethyl-1-pyrazolyl)methane Ligand

C. Grittini, M. Bruck, J. Enemark, 1995 .

He I valence photoelectron spectra of oxomolybdenum(V) complexes containing diolato or alkoxide ligands

D. Lichtenberger, A. Rai-Chaudhuri, J. Enemark, 1990 .

Addition of borohydride ion to coordinated isocyanides: the structure of π-C5H5Fe(CO)[(CHNCH3)2BH2]

W. Butler, J. Enemark, 1973 .

Monomeric molybdenum(V) complexes. 2. Comparison of the structures of cis-oxochlorobis(8-mercaptoquinolinato)molybdenum(V) and cis-dioxobis(8-mercaptoquinolinato)molybdenum(VI)

J. Enemark, K. Yamanouchi, 1979 .

Crystal and molecular structure of tris(ethylenediamine)cobalt pentacyanonitrosylchromate dihydrate, [Co(C2H8N2)3][Cr(CN)5(NO)].2H2O

L. L. Reed, M. J. Steuck, J. Enemark, 1970 .

Structural, spectroscopic and electrochemical studies on a new Mo(VI) catecholate complex

G. Morris, C. Garner, J. Enemark, 1986 .

New oxovanadium bis(1,2-dithiolate) compounds that mimic the hydrogen-bonding interactions at the active sites of mononuclear molybdenum enzymes.

M. Carducci, J. Enemark, H. Selby, 2002, Inorganic chemistry.

Molecular Structure of the Dimer of Bis(cis-1,2-bis(trifluoromethyl)ethylene-1,2-dithiolate)cobalt

W. Lipscomb, J. Enemark, 1965 .

X-ray photoelectron spectra of palladium and platinum complexes of carbenoid and related ligands

A. Balch, P. Brant, J. Enemark, 1976 .

The molybdenum:sulfur bond distance in di-.mu.-sulfido-bis[sulfido(N,N-diethyldithiocarbamato)molybdenum(V)]

J. Enemark, J. Huneke, 1978 .

Effects of temperature and pressure on the molecular and electronic structure of N,N′-ethylenebis(salicylideneiminato)nitrosyliron, Fe(NO)(salen)

P. L. Johnson, J. Ferraro, K. Haller, 1979 .

Four-coordinate metal nitrosyls. 2. Structures of NiX(NO)(P(C6H5)3)2 complexes

K. Haller, J. Enemark, 1978 .

Structural chemistry of the {CoNO}8 group. III. The structure of N,N'-ethylenebis(salicylideneiminato)nitrosylcobalt(II), Co(NO)(salen)

K. Haller, J. Enemark, 1978 .

Stereochemical control of valence. 5. Comparison of the molecular and electronic structures of five- and six-coordinate o-phenylenebis(dimethylarsine) complexes of the {FeNO}7 group

P. L. Johnson, J. Enemark, R. Feltham, 1977 .

Structural chemistry of the {CoNO}8 (cobalt mononitrosyl) group. Structure of trans-perchloratonitrosylbis(ethylenediamine)cobalt perchlorate, [Co(NO)(C2N2H8)2(OClO3)][ClO4]

P. L. Johnson, J. Enemark, R. Feltham, 1976 .

Three-dimensional structural investigation of bis(dimethyldithiocarbamato)nitrosylcobalt: CoNO(S2CNMe2)2

J. Enemark, R. Feltham, 1972 .

Structure of nitrosyltetracarbonylmanganese(0), Mn(NO)(CO)4

J. Ibers, J. Enemark, B. Frenz, 1969 .

Structure of nitrosyltricarbonyltriphenylphosphinemanganese, Mn(NO)(CO)3(P(C6H5)3)

J. Ibers, J. Enemark, 1968 .

The Molecular Structure of Nitrosyldicarbonylbis(Triphenylphosphine)Manganese, M(NO)(CO)2(PPh3)2

J. Ibers, J. Enemark, 1967 .

Spectroscopic Evidence for a Unique Bonding Interaction in Oxo-Molybdenum Dithiolate Complexes: Implications for σ Electron Transfer Pathways in the Pyranopterin Dithiolate Centers of Enzymes

Frank Inscore, J. Enemark, M. Kirk, 1999 .

Structural and Spectroscopic Characterization of a Monooxomono(dithiolene)molybdenum(V) Compound and Its Implications for the low pH Form of Sulfite Oxidase

A. Pacheco, J. Enemark, I. Dhawan, 1994 .

Molecular Basis of Sulfite Oxidase Deficiency from the Structure of Sulfite Oxidase

D. Rees, H. Schindelin, C. Kisker, 1997, Cell.

Ligand K-Edge and Metal L-Edge X-ray Absorption Spectroscopy and Density Functional Calculations of Oxomolybdenum Complexes with Thiolate and Related Ligands: Implications for Sulfite Oxidase

K. Hodgson, Y. Izumi, B. Hedman, 1999 .

Structure of the active site of sulfite oxidase. X-ray absorption spectroscopy of the Mo(IV), Mo(V), and Mo(VI) oxidation states.

R. Prince, G. George, S. Cramer, 1989, Biochemistry.

Mo2(S2)[S2C2(C6H5)2]4: a novel quadruply bridged binuclear molybdenum compound containing a disulfur ligand

W. Newton, J. Enemark, K. Yamanouchi, 1982 .

Electronic structure of bent titanocene complexes with chelated dithiolate ligands.

N. Gruhn, J. Enemark, Matthew A. Cranswick, 2004, Inorganic chemistry.

Geometrical control of the active site electronic structure of pyranopterin enzymes by metal-dithiolate folding: aldehyde oxidase.

J. Enemark, Hemant Joshi, 2004, Journal of the American Chemical Society.

A Catalytic Cycle Related to Molybdenum Enzymes Containing [MoVIO2]2+ Oxidized Active Sites

C. G. Young, M. Bruck, A. G. Wedd, 1996 .

Mononuclear oxo- and sulfidomolybdenum(IV) complexes: syntheses and crystal structures of [HB(Me2C3N2H)3]MoE(S2CNEt2) (E = O, S) and related complexes

C. G. Young, S. Roberts, J. Enemark, 1987 .

L-edge spectroscopy of molybdenum compounds and enzymes

G. George, S. Cramer, S. Roberts, 1990 .

Tetraphenylphosphonium Salts of [Mo2(S)N(s2)6‐N]2‐ Thioanions and Derivatives

D. Coucouvanis, J. Enemark, A. Hadjikyriacou, 2007 .

Cycloaddition of alkenes and alkynes to CpFe(CO)2PR2 to give [cyclic] Cp(CO)FePR2C:CC:O heterometallacycles

M. Ashby, J. Enemark, 1987 .

Molybdenum(VI) and molybdenum(V) complexes with N,N'-dimethyl-N,N'-bis(2-mercaptophenyl)ethylenediamine: electrochemical and electron paramagnetic resonance models for the molybdenum(VI/V) centers of the molybdenum hydroxylases and related enzymes

Raghuvir Singh, M. Bruck, A. G. Wedd, 1987 .

A chemical approach to systematically designate the pyranopterin centers of molybdenum and tungsten enzymes and synthetic models.

P. Basu, J. Enemark, B. Fischer, 1998, Journal of inorganic biochemistry.

Electron transfer in sulfite oxidase: effects of pH and anions on transient kinetics.

G. Tollin, J. Enemark, E. Sullivan, 1993, Biochemistry.

A paramagnetic complex possessing two oxo-Mo(V) centers

P. Basu, J. Enemark, 1997 .

EPR studies of weakly coupled oxomolybdenum (V) and low-spin iron (III) porphyrin centers

N. Shokhirev, P. Basu, A. Raitsimring, 1995 .

Metal–Dithiolene Bonding Contributions to Pyranopterin Molybdenum Enzyme Reactivity

J. Enemark, M. Kirk, Jing Yang, 2020, Inorganics.

Photoelectron spectra of potassium salts of hydrotris(pyrazol-1-yl)borates: electronic structure of the electron withdrawing scorpionates Tp(CF3)2, Tp*Cl and comparison to Tp* and Tp

M. Carducci, D. Lichtenberger, N. Gruhn, 2004 .

An MCD spectroscopic study of the molybdenum active site in sulfite oxidase: insight into the role of coordinated cysteine.

A. Pacheco, J. McMaster, J. Enemark, 2000, Journal of inorganic biochemistry.

Vibrational Control of Covalency Effects Related to the Active Sites of Molybdenum Enzymes.

D. Lichtenberger, J. Enemark, B. Stein, 2018, Journal of the American Chemical Society.

Synthesis, characterization, and oxygen atom transfer reactions of {HB(Me2C3N2H)3}MoO{S2P(OR)2} and {HB(Me2C3N2H)3}MoO2{.eta.1-S2P(OEt)2}

C. G. Young, S. Roberts, J. Enemark, 1988 .

Understanding the origin of metal-sulfur vibrations in an oxo-molybdenum dithiolene complex: relevance to sulfite oxidase.

Frank Inscore, J. Enemark, M. Kirk, 2006, Inorganic Chemistry.

Structural Studies of Molybdenum Complexes

J. Enemark, K. Yamanouchi, J. Huneke, 1980 .

Sulfite-oxidizing enzymes

U. Kappler, J. Enemark, 2015, JBIC Journal of Biological Inorganic Chemistry.

Applications of pulsed EPR spectroscopy to structural studies of sulfite oxidizing enzymes().

A. Astashkin, A. Raitsimring, J. Enemark, 2013, Coordination chemistry reviews.

Characterization of chloride-depleted human sulfite oxidase by EPR spectroscopy: experimental evidence for the role of anions in product release

A. Astashkin, Asha Rajapakshe, K. Meyers, 2011 .

Pulsed EPR investigations of the Mo(V) centers of the R55Q and R55M variants of sulfite dehydrogenase from Starkeya novella

U. Kappler, A. Astashkin, P. Bernhardt, 2010, JBIC Journal of Biological Inorganic Chemistry.

Exchangeable oxygens in the vicinity of the molybdenum center of the high-pH form of sulfite oxidase and sulfite dehydrogenase.

F. Neese, U. Kappler, A. Astashkin, 2009, Physical chemistry chemical physics : PCCP.

Toward modeling the high chloride, low pH form of sulfite oxidase: Ka-band ESEEM of equatorial chloro ligands in oxomolybdenum(V) complexes.

A. Astashkin, J. Enemark, E. L. Klein, 2007, Journal of inorganic biochemistry.

Investigation of the coordination structures of the molybdenum(v) sites of sulfite oxidizing enzymes by pulsed EPR spectroscopy.

A. Astashkin, A. Raitsimring, J. Enemark, 2006, Dalton transactions.

Bonding in the Syn and Anti Isomers of Di-µ-sulfido-bis(sulfido(l,2-diinercaptoethanato)molybdate(V)) Anions

D. Lichtenberger, J. Enemark, T. Chandler, 1981 .

MO2(S2)(S2C2(C6H5)2)4: A NOVEL QUADRUPLY BRIDGED BINUCLEAR MOLYBDENUM COMPOUND CONTAINING A DISULFUR LIGAND

W. Newton, J. Enemark, K. Yamanouchi, 1982 .

Structural studies of the molybdenum center of mitochondrial amidoxime reducing component (mARC) by pulsed EPR spectroscopy and 17O-labeling.

F. Bittner, R. Mendel, A. Astashkin, 2011, Biochemistry.

Identity of the exchangeable sulfur-containing ligand at the Mo(V) center of R160Q human sulfite oxidase.

D. Goldfarb, A. Astashkin, Asha Rajapakshe, 2012, Inorganic chemistry.

Structures and reaction pathways of the molybdenum centres of sulfite-oxidizing enzymes by pulsed EPR spectroscopy.

A. Astashkin, A. Raitsimring, J. Enemark, 2008, Biochemical Society transactions.

Mononuclear Oxo- and Sulfidomolybdenum(IV) Complexes: Syntheses and Crystal Structures of (HB(Me2C3N2H)3)MoE(S2CNEt2) (E: O, S) and Related Complexes.

C. G. Young, S. Roberts, J. Enemark, 1987 .

Preparation and characterization of binuclear complexes of molybdenum(III) and molybdenum(V) via oxidative decarbonylation. Reactions of LMo(CO)3 (L = 1,5,9-triazacyclododecane) and crystal structure of anti-[L2Mo2O4](ClO4)2.2H2O

C. G. Young, M. Guttmann, K. Wieghardt, 1985 .

Control of the reactivity and coordination number of a 16-electron complex by .pi.-donating thiolate ligands

M. Ashby, J. Enemark, 1986 .

Monodentate dialkyldithiocarbamate complexes of molybdenum(III). The synthesis and X-ray strucural characterization of {HB(3,5-Me2C3N2H)3}Mo-(S2CNEt2)(ν1-S2CNEt42)

C. G. Young, S. Roberts, J. Enemark, 1986 .

Evaluation of Molybdenum−Sulfur Interactions in Molybdoenzyme Model Complexes by Gas-Phase Photoelectron Spectroscopy. The “Electronic Buffer” Effect

N. Gruhn, J. Enemark, Barry L. Westcott, 1998 .

Monomeric molybdenum(V) complexes. 1. Structure of bis(2-amidobenzenethiolato)(diethyldithiocarbamato)molybdenum(V), Mo(NHC6H4S)2(S2CN(C2H5)2)

J. Enemark, K. Yamanouchi, 1978 .

Reactions of bisoxinato complexes of tetraoxodimolybdenum(2+). I. Preparation and structure of the novel coordination compound .mu.-(2-mercaptoethanolato-S:O)-.mu.-oxo-bis[oxo-8-hydroxyquinolinatomolybdenum(V)]

J. Enemark, G. Haight, D. Boston, 1975 .

The first mononuclear molybdenum(V) complex with a terminal sulfido ligand: dichloro[hydrotris(3,5-dimethyl-1-pyrazolyl)borato]sulfidomolybdenum

C. G. Young, D. Collison, J. Enemark, 1987 .

Bis[0-phenylenebis(dimethylarsine)]iron complexes with nitric oxide, carbon monoxide, acetonitrile, and other small molecules

J. Enemark, R. Feltham, T. Nappier, 1975 .

A molybdenum-95 and nitrogen-14 nuclear magnetic resonance study of six-co-ordinate hydrotris(3,5-dimethyl-1-pyrazolyl)borate complexes containing a sixteen-electron {Mo(NO)}4 core

C. G. Young, J. McCleverty, Christopher J. Jones, 1987 .

Chicken liver sulfite oxidase. Kinetics of reduction by laser-photoreduced flavins and intramolecular electron transfer.

G. Tollin, M. Cusanovich, R. Sunde, 1988, Biochemistry.

Molybdenum(VI) and Molybdenum(V) Complexes with N,N′-Dimethyl-N,N′-bis(2-mercaptophenyl)ethylenediamine. Electrochemical and Electron Paramagnetic Resonance Models for the Molybdenum(VI/V) Centers of the Molybdenum Hydroxylases and Re

Raghuvir Singh, M. Bruck, A. G. Wedd, 1988 .

Dioxomolybdenum(VI) Complexes of Tripodal Nitrogen-Donor Ligands: Syntheses and Spectroscopic, Structural, and Electrochemical Studies, Including the Generation of EPR-Active Molybdenum(V) Species in Solution.

C. G. Young, Colleen M. Doyle, C. Grittini, 1995, Inorganic chemistry.

Structural and functional analogue of the active site of polysulfide reductase from Wolinella succinogenes.

S. Sarkar, K. Pal, J. Enemark, 2004, Inorganic chemistry.

Synthesis, Characterization, and Oxygen Atom Transfer Reactions of (HB(Me2C3N2H)3)MoO(S2P(OR)2) and (HB(Me2C3N2H)3)MoO2(η1‐S2P(OEt)2).

C. G. Young, S. Roberts, J. Enemark, 1988 .

Trimethylsilyloxo complexes of oxomolybdenum(V)

C. G. Young, M. Bruck, A. G. Wedd, 1996, JBIC Journal of Biological Inorganic Chemistry.

Consensus structures of the Mo(v) sites of sulfite-oxidizing enzymes derived from variable frequency pulsed EPR spectroscopy, isotopic labelling and DFT calculations.

J. Enemark, 2017, Dalton transactions.

Kinetic and Thermodynamic Effects of Mutations of Human Sulfite Oxidase

G. Tollin, Asha Rajapakshe, J. Enemark, 2012, Chemistry & biodiversity.

Effects of large-scale amino acid substitution in the polypeptide tether connecting the heme and molybdenum domains on catalysis in human sulfite oxidase.

G. Tollin, J. Enemark, Kayunta Johnson‐Winters, 2010, Metallomics : integrated biometal science.

Effects of interdomain tether length and flexibility on the kinetics of intramolecular electron transfer in human sulfite oxidase.

G. Tollin, A. Astashkin, Asha Rajapakshe, 2010, Biochemistry.

Inhibition of intramolecular electron transfer in sulfite oxidase by anion binding

G. Tollin, J. Enemark, E. Sullivan, 1992 .

The nature of the phosphate complex of sulphite oxidase from electron-paramagnetic-resonance studies.

R. Prince, G. George, R. Sunde, 1988, The Biochemical journal.

Nature of the oxomolybdenum-thiolate pi-bond: implications for Mo-S bonding in sulfite oxidase and xanthine oxidase.

J. Enemark, M. Kirk, R. McNaughton, 2004, Inorganic chemistry.

Analogues for the molybdenum center of sulfite oxidase: oxomolybdenum(V) complexes with three thiolate sulfur donor atoms.

M. Carducci, M. Mader, J. Enemark, 2000, Inorganic chemistry.

Covalently linked oxomolybdenum(V) and iron(III) porphyrin centers: Synthetic models for the molybdenum-iron interaction in sulfite oxidase

M. LaBarre, P. Basu, A. Raitsimring, 1994 .

Crystal and molecular structure of [SnLCl3]]. The single-crystal electron paramagnetic resonance spectra of [MoE(L)Cl2] and [MoO(L)(NCS)2] diluted in [SnLCl3] [E=O or S;L=tris(3,5-dimethylpyrazolyl)hydroborate]

M. Bruck, P. A. Wexler, D. Collison, 1994 .

Chemical and Physical Coupling of Oxomolybdenum Centers and Iron Porphyrins: Models for the Molybdenum—Iron Interaction in Sulfite Oxidase

M. LaBarre, A. Raitsimring, J. Enemark, 1993 .

Oxomolybdenum(V)/Iron(III) Porphyrinate Complexes: Effect of Axial Ligand Plane Orientation on Complex Stability, Reduction Potential, and NMR and EPR Spectra.

F. Walker, P. Basu, A. Raitsimring, 1997, Inorganic chemistry.

NMR Studies of Hindered Ligand Rotation, Magnetic Anisotropy, Curie Behavior, Proton Spin Relaxation, and Ligand Exchange in Some Novel Oxomolybdenum(V)/Iron(III) Porphyrinate Complexes

F. Walker, N. Shokhirev, P. Basu, 1995 .

Electronic spectral studies of molybdenyl complexes: implications for oxomolybdenum enzymes

M. Carducci, E. Solomon, C. E. Brown, 1994 .

ESEEM Investigations of the High pH and Low pH Forms of Chicken Liver Sulfite Oxidase

A. Pacheco, A. Raitsimring, J. Enemark, 1998 .

Structural studies of the molybdenum center of the pathogenic R160Q mutant of human sulfite oxidase by pulsed EPR spectroscopy and 17O and 33S labeling.

K. Rajagopalan, A. Astashkin, Changjian Feng, 2008, Journal of the American Chemical Society.

Crystal structure of tris(quinoxaline-2,3-dithiolato)molybdate(V); a distorted trigonal prismatic complex

S. Boyde, M. Bruck, C. Garner, 1987 .

Structure and properties of tris(quinoxaline-2,3-dithiolato)molybdate(IV)

S. Boyde, C. Garner, J. Enemark, 1987 .

Mononuclear and Binuclear Molybdenum(V) Complexes of the Ligand N,N‘-Dimethyl-N,N‘-bis(2-mercaptophenyl)ethylenediamine: Geometric Isomers

K. R. Barnard, C. Grittini, R. Gable, 1997 .

Essential role of conserved arginine 160 in intramolecular electron transfer in human sulfite oxidase.

G. Tollin, K. Rajagopalan, Changjian Feng, 2003, Biochemistry.

The pH dependence of intramolecular electron transfer rates in sulfite oxidase at high and low anion concentrations

G. Tollin, A. Pacheco, J. Enemark, 1999, JBIC Journal of Biological Inorganic Chemistry.

37. Potassium Pentafluorooxomolybdate(V)

J. Enemark, M. C. Chakravorti, S. Pandit, 2007 .

Preparation and structure of a compound containing a triply bridged binuclear Mo(V) cation and the [MoOCl4(H2O)]− anion

W. Newton, J. Enemark, K. Yamanouchi, 1977 .

Molybdenum complexes of aliphatic thiols. Isolation and characterization of two isomeric forms of the redox active binuclear molybdenum(V) anion, di-.mu.-sulfido-bis(sulfido-1,2-dimercaptoethanato)molybdate(2-))

D. T. Sawyer, J. Enemark, J. K. Howie, 1977 .

95Mo NMR studies of dioxo, oxo-sulfido, oxo-selenido, and disulfido complexes of molybdenum (VI)

K. Wieghardt, J. Enemark, M. Minelli, 1983 .

Monomeric molybdenum(V) complexes. 4. The structure of tetraphenylarsonium oxodichloro(N-2-oxophenylsalicylideniminato)molybdate(V), [Ph4As] [MoOCl2(SalphO)]

J. Enemark, S. Yamada, K. Yamanouchi, 1984 .

Triply bridged molybdenum(V) dimers. Crystal and molecular structure of .mu.-(2-mercaptoethanolato-S,O)-.mu.-sulfido-bis[oxo(N,N-diethyldithiocarbamato)molybdenum(V)], Mo2O2S(SCH2CH2O)(S2CN(C2H5)2)2

J. Enemark, K. Yamanouchi, J. Huneke, 1978 .

Kinetic results for mutations of conserved residues H304 and R309 of human sulfite oxidase point to mechanistic complexities.

G. Tollin, J. Enemark, Kayunta Johnson‐Winters, 2014, Metallomics : integrated biometal science.

Effects of mutating aromatic surface residues of the heme domain of human sulfite oxidase on its heme midpoint potential, intramolecular electron transfer, and steady-state kinetics.

G. Tollin, Asha Rajapakshe, K. Meyers, 2013, Dalton transactions.

Structures of the Mo(V) forms of sulfite oxidase from Arabidopsis thaliana by pulsed EPR spectroscopy.

B. Hood, R. Mendel, R. Hille, 2005, Biochemistry.

Pulsed EPR studies of a bacterial sulfite-oxidizing enzyme with pH-invariant hyperfine interactions from exchangeable protons.

U. Kappler, A. Astashkin, Changjian Feng, 2005, Inorganic chemistry.

17O ESEEM evidence for exchange of the axial oxo ligand in the molybdenum center of the high pH form of sulfite oxidase.

A. Astashkin, Changjian Feng, A. Raitsimring, 2005, Journal of the American Chemical Society.

The Mo−OH proton of the low-pH form of sulfite oxidase: Comparison of the hyperfine interactions obtained from pulsed ENDOR, CW-EPR and ESEEM measurements

K. Rajagopalan, J. Johnson, A. Astashkin, 2002 .

Pulsed EPR studies of the exchangeable proton at the molybdenum center of dimethyl sulfoxide reductase

K. Rajagopalan, A. Astashkin, K. Nelson, 2002, JBIC Journal of Biological Inorganic Chemistry.

Probing the role of a conserved salt bridge in the intramolecular electron transfer kinetics of human sulfite oxidase

G. Tollin, J. Enemark, R. Berry, 2013, JBIC Journal of Biological Inorganic Chemistry.

Intramolecular electron transfer in sulfite-oxidizing enzymes: probing the role of aromatic amino acids

G. Tollin, Asha Rajapakshe, K. Meyers, 2012, JBIC Journal of Biological Inorganic Chemistry.

Elucidating the catalytic mechanism of sulfite oxidizing enzymes using structural, spectroscopic, and kinetic analyses.

G. Tollin, Gordon Tollin, John H Enemark, 2010, Biochemistry.

Molecular Basis for Enzymatic Sulfite Oxidation

U. Kappler, A. Astashkin, S. Bailey, 2009, Journal of Biological Chemistry.

Direct demonstration of the presence of coordinated sulfate in the reaction pathway of Arabidopsis thaliana sulfite oxidase using 33S labeling and ESEEM spectroscopy.

R. S. Byrne, R. Hille, A. Astashkin, 2007, Journal of the American Chemical Society.

Kinetic and structural evidence for the importance of Tyr236 for the integrity of the Mo active site in a bacterial sulfite dehydrogenase.

G. Tollin, U. Kappler, G. Hanson, 2006, Biochemistry.

Intramolecular electron transfer in a bacterial sulfite dehydrogenase.

G. Tollin, U. Kappler, Changjian Feng, 2003, Journal of the American Chemical Society.

Pulsed EPR studies of nonexchangeable protons near the Mo(V) center of sulfite oxidase: direct detection of the alpha-proton of the coordinated cysteinyl residue and structural implications for the active site.

K. Rajagopalan, A. Astashkin, Changjian Feng, 2002, Journal of the American Chemical Society.

Molybdenum enzymes and sulfur metabolism.

J. Enemark, M. M. Cosper, 2002, Metal ions in biological systems.

Direct detection and characterization of chloride in the active site of the low-pH form of sulfite oxidase using electron spin echo envelope modulation spectroscopy, isotopic labeling, and density functional theory calculations.

F. Neese, A. Astashkin, Christoph Riplinger, 2009, Inorganic chemistry.

Effect of solution viscosity on intramolecular electron transfer in sulfite oxidase.

G. Tollin, Changjian Feng, J. Enemark, 2002, Biochemistry.

Pulsed ELDOR spectroscopy of the Mo(V)/Fe(III) state of sulfite oxidase prepared by one-electron reduction with Ti(III) citrate

A. Astashkin, A. Pacheco, R. Codd, 2002, JBIC Journal of Biological Inorganic Chemistry.

Reactions of tetrathiometalates, MS42-(M = Mo, W). Syntheses and properties of M2S42+-containing compounds. Structure of bis(tetraphenylphosphonium) bis(.mu.-sulfido)bis[sulfido(1,2-ethanedithiolato)tungstate(V)], [P(C6H5)4]2[W2S4(S2C2H4)2]

J. Enemark, E. Stiefel, W. Pan, 1984 .

Isovalent and Mixed-Valent Dinuclear .mu.-Oxo and .mu.-Oxo .mu.-Disulfido Complexes of Molybdenum(V) and Molybdenum(VI)

C. G. Young, A. G. Wedd, J. Enemark, 1994 .

BONDING IN THE SYN AND ANTI ISOMERS OF DI-μ-SULFIDO-BIS(SULFIDO(1,2-DIMERCAPTOETHANATO)MOLYBDATE(V)) ANIONS

D. Lichtenberger, J. Enemark, T. Chandler, 1981 .

Synthesis and characterization of mononuclear bis(para-substituted phenolato)oxomolybdenum(V) complexes : dependence of the molecular properties upon remote substituent effects

M. Carducci, J. Enemark, C. Chang, 1993 .

Synthesis and characterization of tetrasulfidomolybdenum(IV) complexes of hydrotris(3,5-dimethyl-1-pyrazolyl)borate and the x-ray crystal structure of {HB(3,5-Me2C3N2H)3}MoCl(S4).cntdot.0.5Et2O

C. G. Young, M. Bruck, J. Enemark, 1990 .

Nitridomolybdenum Complexes of Tris(3,5-dimethylpyrazol-1-yl)Hydroborate and the X-Ray Crystal-Structure of {HB(3,5-Me2C3N2H)3)MoN(N3)2

C. G. Young, M. Bruck, P. A. Wexler, 1990 .

The EPR spectra and electronic structures of low-symmetry oxo-molybdenum(V) complexes

D. Collison, J. Enemark, W. Cleland, 1986 .

ELECTRON PARAMAGNETIC RESONANCE STRUCTURAL STUDIES OF MOLYBDENUM(V)-OXO COMPLEXES

R. D. Taylor, N. Chasteen, J. Enemark, 1979 .

Preparation and Characterization of Binuclear Complexes of Molybdenum(III) and Molybdenum(V) via Oxidative Decarbonylation.

C. G. Young, M. Guttmann, K. Wieghardt, 1986 .

95Mo and 183W NMR studies of triply bonded dinuclear M(III) and related MC (M = Mo or W) complexes

C. G. Young, E. Kober, J. Enemark, 1987 .

SYNTHESIS AND MOLECULAR STRUCTURE OF MOLYBDENUM(V) DIMERS WITH MIXED OXO AND SULFIDO TERMINAL LIGANDS: REMOVAL OF TERMINAL SULFIDE BY TRIPHENYLPHOSPHINE AND CYANIDE

W. Newton, J. Enemark, K. Yamanouchi, 1979 .

Cycloaddition of alkynes to CpFe(CX)(CY)SR (CX, CY = CO, CS, CNCH3) to give [cyclic] RSFeC(:Y)C:C heterometallacycles

M. Ashby, J. Enemark, 1987 .

Syntheses, characterisation, infrared and 95Mo NMR spectroscopy of some coordinated oxo—molybdenum(VI) complexes

A. Pacheco, N. Rees, K. A. Christensen, 1997 .

Addition of methylamine to hexakis(methyl isocyanide)iron(II). Formation of an unusual chelating ligand

Joel S. Miller, A. Balch, J. Enemark, 1971 .

Diastereomer splitting in the 95Mo NMR spectra of compounds differing only in the Mo configuration

E. Frauendorfer, H. Brunner, J. Enemark, 1985 .

95Mo NMR investigation on cationic [C5H5Mo(CO)2L2]BF4 complexes (L = group 15 donor ligands

M. Bruck, P. A. Wexler, M. LaBarre, 1991 .

Stereochemical Control of Valence and Its Application to the Reduction of Coordinated NO and N(2).

J. Enemark, R. Feltham, 1972, Proceedings of the National Academy of Sciences of the United States of America.

Molybdenum-95 NMR studies of cis-dinitrosylmolybdenum complexes containing the [Mo(NO)2]2+ unit

J. Enemark, M. Minelli, J. L. Hubbard, 1984 .

Chelative addition of hydrazines to coordinated isocyanides. Structure of Chugaev's red salt

J. Parks, A. Balch, W. Butler, 1973 .

Intraprotein electron transfer in a two-domain construct of neuronal nitric oxide synthase: the output state in nitric oxide formation.

G. Tollin, Changjian Feng, J. Salerno, 2006, Biochemistry.

Structural investigation of Ba_6−3xLn_8+2xTi_18O_54 (x = 0.27, Ln = Sm) by single crystal x-ray diffraction in space group Pnma(No. 62)

D. Birnie, C. Rawn, M. Bruck, 1998 .

Crystal and molecular structure of the thiovanadyl complex (N,N'-ethylenebis(acetylacetonylideniminato)thiovanadium, V:S(acen)

K. M. Miller, J. Enemark, Maki Sato, 1981 .

Studies of distortional isomers : spectroscopic evidence that green cis, mer-dichlorotris(dimethylphenylphosphine)oxo-molybdenum(IV) is a mixture

K. Nebesny, M. LaBarre, T. Loehr, 1991 .

New insights into solvolysis and reorganization energy from gas-phase, electrochemical, and theoretical studies of oxo-Tp*Mo(V) molecules.

D. Lichtenberger, Aaron K. Vannucci, N. Gruhn, 2009, Inorganic chemistry.

Photoelectron spectroscopy and electronic structure calculations of d1 vanadocene compounds with chelated dithiolate ligands: implications for pyranopterin Mo/W enzymes.

D. Lichtenberger, N. Gruhn, J. Enemark, 2007, Inorganic chemistry.

Crystal structure and spectroscopic studies of [MoO2(L-Cys-OMe)2]

T. King, C. Garner, M. Ashby, 1984 .

Bis(benzenethiolato)nitrosyl [tris(3,5-dimethyl-1-pyrazolyl)hydroborato]-molybdenum(II) .

S. Roberts, J. Enemark, 1989, Acta Crystallographica Section C: Crystal Structure Communications.

Tarapacol 15‐Acetate, a New Diterpenoid from Grindelia tarapacana Phil.

C. Grittini, B. Timmermann, M. Bruck, 1996 .

Photoinduced Electron Transfer in Covalently Linked Oxomolybdenum(V) Porphyrin Systems.

Partha Basu, Tione Buranda, T. Buranda, 1997, Inorganic chemistry.

Probing the role of a conserved salt bridge in the intramolecular electron transfer kinetics of human sulfite oxidase

G. Tollin, J. Enemark, R. Berry, 2013, JBIC Journal of Biological Inorganic Chemistry.

Probing the electronic structure of [MoOS(4)](-) centers using anionic photoelectron spectroscopy.

Lai‐Sheng Wang, Xin Yang, Xue‐Bin Wang, 2002, Journal of the American Chemical Society.