N. Connelly

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Chemical Redox Agents for Organometallic Chemistry

N. Connelly, W. Geiger, 1996 .

Allylic alkylation of complexed cyclo-octatetraene (cot)via the reaction of [Fe{P(OMe)3}(NO)2(η3-allyl)]+ with [M(CO)3(η4-cot)](M = Fe or Ru) derivatives; X-ray structure of [Ru(CO)2(PPh3)(η2,η3-C8H8R)][PF6]·0.5CH2Cl2[R = CH2C(Me)CH2]

A. Orpen, N. Connelly, J. Sheridan, 1990 .

Structure and bonding in low-spin octahedral manganese(II) carbonyls: ligand-set control of spin delocalisation

A. Orpen, G. Rosair, N. Connelly, 1993 .

Synthesis of the 17-electron cations [FeL(L′)(NO)2]+(L, L′= PPh3, OPPh3): structure and bonding in four-co-ordinate metal dinitrosyls, and implications for the identity of paramagnetic iron dinitrosyl complex catalysts

A. Orpen, H. Blackwell, J. Crossley, 1996 .

Potassium S2N-heteroscorpionates: structure and iridaboratrane formation.

A. Orpen, Alex Hamilton, M. Haddow, 2011, Dalton transactions.

Recent developments in transition metal nitrosyl chemistry

N. Connelly, 1972 .

Structural studies of [Pt(CNMe)4][M(mnt)2]n {M = Pd or Pt, mnt = [S2C2(CN)2]2–, n = 1 or 2}: structure-dependent paramagnetism of three crystal forms of [Pt(CNMe)4][Pt(mnt)2]2

A. Orpen, J. Crossley, G. R. Lewis, 1998 .

Oxidatively induced isomerisation of vinylidene ligands to alkynes: ESR spectra of paramagnetic vinylidene and alkyne arene metal complexes

A. Orpen, Antonio Martín, N. Connelly, 1999 .

Diphenylphosphide-bridged diiron derivatives of [Fe2(η5-C5H5)2(μ-H)(μ-PPh2)(CO)2]

Miguel A. Ruiz, N. Connelly, C. Álvarez, 2004 .

Synthesis, Reactions, and Molecular and Electronic Structure of the Radical Cation [Mo2(μ-C8Me8)(η-C5H5)2]+: An Intermediate in the Redox Activation of an Alkyl C−H Bond

A. Orpen, Bernhard Metz, N. Connelly, 1996 .

Quadrupole coupling effects in the electron spin resonance powder spectrum of an organoiridium radical cation

N. Connelly, P. Rieger, J. DeGray, 1990 .

Intramolecular electron transfer in linear trinuclear complexes of copper(I), silver(I) and gold(I) bound to redox-active cyanomanganese ligands

A. Orpen, J. Crossley, Antonio Martín, 1996 .

Zinc, cadmium and mercury complexes of redox-active cyanomanganese carbonyl ligands: intramolecular electron transfer through tetrahedral d10 metal centres

A. Orpen, M. Moreno, G. R. Lewis, 1998 .

Chemical Redox Agents for Organometallic Chemistry.

Neil G. Connelly, William E. Geiger, N. Connelly, 1996, Chemical reviews.

Redox Behavior of an Organometallic Palladium(II)/Palladium(IV) System. A New Method for the Synthesis of Cationic Palladium(IV) Complexes

E. Álvarez, J. Cámpora, Jorge A. López, 2005 .

New compounds of tetradentate Schiff bases with vanadium(IV) and vanadium(V)

P. Hitchcock, N. Connelly, G. J. Leigh, 1999 .

Synthesis, structure, and bonding of a cubane-like cobalt-nitrosyl complex, tetrakis-.mu.3-tert-butylimido-tetranitrosyltetracobalt. Stereochemical nonconformity of the metal cluster geometry to that predicted by a first-order Jahn-Teller effect

L. F. Dahl, N. Connelly, R. Gall, 1974 .

PARAMAGNETIC TETRAHEDRAL DINITROSYLIRON COMPLEXES CONTAINING REDOX-ACTIVE CYANOMANGANESE LIGANDS

A. Orpen, G. Rosair, N. Connelly, 1996 .

η2(3e)-vinyl complexes and one-electron transfer reactions: tris(pentafluorophenyl)borane as a one-electron oxidant

Jason M. Lynam, A. Burrows, N. Connelly, 2001 .

Oxidatively induced alkyne rotation in dicobalt complexes: structural tests of molecular orbital theory

A. Orpen, R. Aggarwal, M. Crespo, 1992 .

Organometallic chalcogen complexes. XIX. Stereochemical analyses of tetramercapto-bridged molybdenum(III) dimer, [Mo(h5-C5H5)(SCH3)2]2, containing a strong molybdenum-molybdenum interaction, and of its corresponding paramagnetic cation

L. F. Dahl, N. Connelly, 1970 .

Synthesis and electrochemistry of heterobridged gold(I) and gold(II) complexes of pyridine-2-thiolate. Crystal structures of [Au2{µ-(CH2)2PPh2}(µ-C5H4NS)] and [Au2{µ-(CH2)2PPh2}(µ-C5H4NS)Br2]

A. Laguna, M. Laguna, N. Connelly, 1995 .

Molybdenum-based alkyne–isocyanide coupling reactions: synthesis of a reactive diiminometallacyclopentene complex

David W. Smith, A. Orpen, K. M. Anderson, 2001 .

A novel route to rhodaboratranes [Rh(CO)(PR3){B(taz)3}]+ via the redox activation of scorpionate complexes [RhLL'Tt].

James C. Knight, A. Orpen, Alex Hamilton, 2009, Dalton transactions.

Redox activation of a B-H bond: a new route to metallaboratrane complexes.

A. Orpen, M. Haddow, Robin Blagg, 2006, Chemical communications.

The effect of micro-CN linkage isomerism and ancillary ligand set on directional metal-metal charge-transfer in cyanide-bridged dimanganese complexes.

A. Orpen, K. M. Anderson, C. Adams, 2007, Dalton transactions.

Solid state and solution structures of rhodium and iridium poly(pyrazolyl)borate diene complexes.

K. M. Anderson, C. Adams, N. Connelly, 2008, Dalton transactions.

Notes. Further comments on one-electron oxidation versus nitrosyl complex formation during the reactions of the nitrosyl cation with metal carbonyl derivativest

P. Ashford, R. L. Kelly, N. Connelly, 1982 .

Synthetic applications of organotransition-metal redox reactions

N. Connelly, 1989 .

Structural evidence for the participation of P–X σ* orbitals in metal–PX3 bonding

A. Orpen, N. Connelly, 1985 .

Structure and bonding in redox-active d 4 , d 5 , and d 6 alkyne complexes: metal-alkyne moieties as electron sinks

A. Orpen, J. Rankin, M. J. Quayle, 1996 .

SYNTHESIS, STRUCTURE, AND BONDING OF A CUBANE-LIKE COBALT-NITROSYL COMPLEX, CO4(NO)4(MU(3)-NC(CH3)3)4, STEREOCHEMICAL NONCONFORMITY OF THE METAL CLUSTER GEOMETRY TO THAT PREDICTED BY A FIRST-ORDER JAHN-TELLER EFFECT

L. F. Dahl, N. Connelly, R. Gall, 1974 .

Homo- and heterodinuclear complexes of the tetrakis(pyrazolyl)borate ligand.

K. M. Anderson, C. Adams, N. Connelly, 2010, Dalton transactions.

Synthesis and electrophilic reactivity of dicarbonyl(cyclohexadienyl)nitrosylmanganese cations

Y. Chung, N. Connelly, D. A. Sweigart, 1982 .

Iodination of triazenide-bridged rhodium and iridium complexes: oxidative addition vs. one-electron oxidation.

A. Orpen, M. Kandiah, C. Adams, 2007, Dalton transactions.

Novel dicarbonyl and carbonylnitrosyl tris(μ-triazenide) dirhodium complexes

A. Orpen, N. Connelly, Owen D. Hayward, 2002 .

Structural systematics: the role of P-A .sigma.* orbitals in metal-phosphorus .pi.-bonding in redox-related pairs of M-PA3 complexes (A = R, Ar, OR; R = alkyl)

A. Guy Orpen, A. Orpen, Neil G. Connelly, 1990 .

Dicarbonylnitrosylchromium complexes of methylbenzenes and methylcyclohexadienyls

R. L. Kelly, N. Connelly, 1975 .

Synthesis, Structure, and Electrochemistry of Mononuclear and Face-to-Face Binuclear Orthometalated Complexes of Palladium(II) with N-Monodentate or N(1),N(3)-Bridging 1,3-Di-p-tolyltriazenido Ligands. Dependence on Geometrical Arrangement of the Electronic Communication between Two Equivalent Redox

A. Orpen, J. Cuevas, G. García-Herbosa, 2001 .

Reductionoxidation properties of organo-transition metal complexes

N. Connelly, A. Loyns, 1991 .

The substitution chemistry of the tris(3,5-dimethylpyrazolyl)methanerhodium complex [Rh(CO)2{HC(pz′)3}]+

A. Orpen, C. Adams, N. Connelly, 2003 .

Redox-induced κ2–κ3 isomerisation in hydrotris(pyrazolyl)boratorhodium complexes: synthesis, structure and ESR spectroscopy of stabilised rhodium(II) species

A. Orpen, M. J. Quayle, N. Connelly, 2001 .

Redox-induced κ 2 -κ 3 isomerisation in rhodium hydrotris(3,5-dimethylpyrazolyl)borate chemistry: the stabilisation of square-pyramidal rhodium(II)

A. Orpen, M. J. Quayle, Bernhard Metz, 1996 .

Bonding modes, structures and fluxionality in rhodium and iridium tris(3,5-dimethylpyrazolyl)methane diene complexes.

K. M. Anderson, M. Haddow, N. Connelly, 2009, Dalton transactions.

Dalton communications. Synthesis, structural characterisation and electrochemistry of the tetranuclear compound [{Pd2(µ-RNNNR)2}2(µ-Cl)4](R = C6H4Me-p): a precursor to triazenido-bridged palladium(II) complexes

A. Orpen, J. Cuevas, G. García-Herbosa, 1995 .

The Electron-Transfer Reactions of Mononuclear Organotransition Metal Complexes

Neil G. Connelly, William E. Geiger, N. Connelly, 1984 .

New synthetic routes to face-to-face and open-book triazenide-bridged dirhodium bipyridyl complexes with the [Rh2]4+ core

A. Orpen, C. Mealli, G. Rosair, 1994 .

Reduction–oxidation properties of organotransition-metal complexes. Part 19. Carbonylruthenium catecholate and semiquinone complexes

I. Manners, N. Connelly, M. W. Whiteley, 1984 .

Homobinuclear cyanide-bridged linkage isomers containing the redox-active unit [(micro-XY)Ru(CO)2L(o-O2C6Cl4)] (XY=CN or NC).

A. Orpen, C. Adams, N. Connelly, 2007, Dalton transactions.

The catalysis of alkene isomerisation, oligomerisation, and polymerisation by cationic nitrosylrhodium complexes

N. Connelly, J. GreenMichael, P. T. Draggett, 1977 .

p-Substituent effects on the redox chemistry of the diaryltriazenido-bridged dirhodium complexes [Rh2(CO)4−n(PPh3)n(μ-p-XC6H4NNNC6H4X′-p)2] (n = 0–2)

N. Connelly, Paul G. Davis, E. Harry, 2000 .

Metal-metal charge transfer and solvatochromism in cyanomanganese carbonyl complexes of ruthenium and osmium.

A. Orpen, C. Adams, N. Connelly, 2006, Dalton transactions.

17-electron alkynyl complexes of cyclopentadienyliron(III)

C. Lapinte, N. Connelly, P. Rieger, 1993 .

The oxidative isomerisation of cis,cis-dicarbonylmanganese(I) derivatives; isolation of the resulting trans-dicarbonylmanganese(II) complexes and the X-ray structure of cis,cis-[MnBr(CO)2{P(OPh)3}(Ph2PCH2PPh2)]

A. Orpen, V. Riera, N. Connelly, 1988 .

Cationic nitrosyls of Ni, Co and Group VI metals

S. Bhaduri, N. Connelly, B.F.G. Johnson, 1972 .

The nitrosonium ion, NO+, and its versatility in transition metal organometallic synthesis

N. Connelly, J. Davies, 1972 .

Reaction of [Fe(CO)3(?4-cot)](cot = cyclo-octatetraene) with the tropylium ion: unusual rearrangement of cyclo-octatetraene and cycloheptatriene rings and the X-ray crystal structure of [Fe(CO)3(?4-styryl-cycloheptatriene)]

K. Broadley, P. Woodward, N. Connelly, 1981 .

Reaction of halide ion with [Cr(CO)2(η-C6Me6)(NO)][PF6]: stabilisation of the product by phosphine substitution and X-ray crystal structure of trans, trans-[Cr(I)(CO)2(PPh2Me)2(NO)]

P. Woodward, R. L. Kelly, N. Connelly, 1976 .

The X-ray structures of the redox-related pair [Co2(CO)2(µ-MeC2Me)(µ-dppm)2] and [Co2(CO)2(µ-MeC2Me)(µ-dppm)2][PF6], CH2Cl2(dppm = Ph2PCH2PPh2): an experimental test of the M.O. bonding scheme for the µ-alkyne complexes [M2(CO)6(µ-RC2R)]

A. Orpen, R. Aggarwal, M. Crespo, 1989 .

The effect of redox-active cyanomanganese(I) ligands on intramolecular electron transfer to, and alkyne alignment in, M(CO)(RC[triple bond, length as m-dash]CR)Tp' (M = Mo or W) units.

C. Adams, N. Connelly, S. Onganusorn, 2009, Dalton transactions.

Cyanide-bridged linkage isomers with catecholateruthenium(II) centres bound to Mn(I) or M(alkyne) units.

C. Adams, N. Connelly, S. Onganusorn, 2007, Dalton transactions.

Bi- and poly-metallic cyanide-bridged complexes of the redox-active cyanomanganese nitrosyl unit [Mn(CN)(PR3)(NO)(eta-C5H4Me)].

A. Orpen, K. M. Anderson, C. Adams, 2004, Dalton transactions.

Mixed valency in binuclear cyano-bridged manganese bis(carbonyl) complexes and stereochemical control of their oxidation. A molecular orbital study

S. Alvarez, S. García‐Granda, N. Connelly, 1993 .

Nomenclature of Inorganic Chemistry II

J. McCleverty, N. Connelly, J. A. McCleverty, 2001 .

Spin delocalisation and the geometry of redox-active cyanomanganesecarbonyl ligands in heteropolynuclear complexes of RH(I)

A. Orpen, G. Rosair, N. Connelly, 1993 .

Syntheses of dinuclear gold(I) ring complexes containing two different bridging ligands. Crystal structure of [Au2{µ-(CH2)2PPh2}(µ-S2CNEt2)]

A. Laguna, M. Laguna, N. Connelly, 1994 .

Activation of a µ3-ethylidyne ligand through oxidation–deprotonation: X-ray structure of [Ru3(µ3-CMe)(µ-CO)3(η-C5Me5)3][BF4]

A. Orpen, N. Connelly, Nigel J. Forrow, 1985 .

Redox routes to arenechromium complexes of two-, three- and four-electron alkynes; structure and bonding in paramagnetic [Cr(CO)L(η-RCCR)(η-arene)]+

A. Orpen, C. Adams, D. Harding, 2002 .

The reversible one-electron oxidation of arenechromium-dicarbonylacetylene complexes

N. Connelly, G. A. Johnson, 1974 .

The oxidative conversion of the N,S-bridged complexes [{RhLL'(μ-X)}2] to [(RhLL')3)(μ-X)2]+ (X = mt or taz): a comparison with the oxidation of N,N-bridged analogues.

A. Orpen, Alex Hamilton, S. Saithong, 2011, Dalton transactions.

Organometallic chalcogen complexes. XX. Stereochemical characterization of an oxidized iron-sulfur dimer, [Fe(h5-C5H5)(CO)(SCH3)]2+. Paramagnetic cation effectively containing a one-electron metal-metal bond

L. F. Dahl, N. Connelly, 1970 .

Transition metal dithiolene complexes. VI tetracarbonyl dithiolato compounds of manganese

J. McCleverty, N. Connelly, J. Locke, 1968 .

Complexes of rhenium and osmium polyhydrides with metallic Lewis acids: X-ray crystal structure of [Ag{ReH7(PPhPrI2)2}2][PF6]

J. Howard, J. Spencer, N. Connelly, 1984 .

Thiolates vs. halides as pi-donors: the redox-active alkyne complexes [M(SR)L(eta-R'C[triple bond]CR')L'] {M = Mo or W, L = CO or P(OMe)(3), L' = eta-C(5)H(5) and Tp'}.

A. Orpen, C. Adams, N. Connelly, 2009, Dalton Transactions.

Structural consequences of the one-electron reduction of d4 [Mo(CO)2(eta-PhC[triple bond]CPh)Tp']+ and the electronic structure of the d5 radicals [M(CO)L(eta-MeC[triple bond]CMe)Tp'] {L = CO and P(OCH2)3CEt}.

A. Orpen, E. McInnes, C. Adams, 2006, Dalton transactions.

Triphenylboron adducts of redox-active cyanomanganese ligands†

A. Orpen, N. Connelly, D. Bellamy, 1999 .

Organometallic Electrochemistry of Metal Alkyne and Related Complexes

N. Connelly, 1993 .

Coordination chemistry of a bulky redox-active cyanomanganese carbonyl ligand: N-bound tetrahedral complexes of 3d metals

A. Orpen, G. R. Lewis, N. Connelly, 2000 .

Triazenide-bridged dirhodium complexes containing redox-active cyanomanganese ligands

N. Connelly, A. Christofides, M. Bardají, 1996 .

Low-valent metal complexes as redoxactive ligands: New heteropolynuclear derivatives of manganese and rhenium cyanides and the crystal structure of [(o-phen) (OC)3Re(μ-CN)-Ru(CO)2(PPh3)(o-O2C6Cl4)]

A. Orpen, G. Rosair, N. Connelly, 1994 .

Heteropolynuclear complexes containing multiple redox sites: cyanometal ligand derivatives of the triazenido-bridged dirhodium fragment

N. Connelly, A. Christofides, M. Bardají, 1994 .

Reduction-Oxidation Properties of Organotransition-metal Complexes.

N. Connelly, Karen L. Amos, 1980 .

The chemical and electrochemical one-electron oxidation of diamidonaphthalene-bridged complexes; paramagnetic [Rh2]3+-containing A-frames

L. Oro, N. Connelly, J. Modrego, 1989 .

Electronic Structure of Ligand-Bridged Complexes Containing the [Rh2]3+ Core: ESR Spectroscopy, MO Calculations, and X-ray Structures of the Three Redox Pairs [Rh2(CO)2LL'{.mu.-PhNC(Me)NPh}2]z [z = 0, 1; L = L' = PPh3, P(OPh)3; L = PPh3, L' = P(OPh)3]

D. C. Boyd, M. Hill, A. Orpen, 1994 .

Isomerism in rhodium(I) N,S-donor heteroscorpionates: ring substituent and ancillary ligand effects.

A. Orpen, Alex Hamilton, M. Haddow, 2010, Dalton transactions.

Fluxional rhodium scorpionate complexes of the hydrotris(methimazolyl)borate (Tm) ligand and their static boratrane derivatives.

A. Orpen, Alex Hamilton, M. Haddow, 2010, Dalton transactions.

Reduction–oxidation properties of organotransition-metal complexes. Part 26. The synthesis of paramagnetic triazenido- and aryl(1-aryliminoethyl)amido-bridged dirhodium carbonyl derivatives containing the [Rh2]3+ core

N. Connelly, G. García, M. Gilbert, 1987 .

The synthesis of mixed-valence dirhodium carbonyl complexes, and the X-ray crystal structures of [{Rh(CO)(PPh3)(µ-RNNNR)}2] and [{Rh(CO)(PPh3)(µ-RNNNR)}2][PF6](R =p-tolyl)

A. Orpen, N. Connelly, M. Freeman, 1984 .

Cationic allyldinitrosyl complexes of iron

N. Connelly, J. Sheridan, P. Baker, 1979 .

Reduction–oxidation properties of organotransition-metal complexes. Part 29. Pentaphenylcyclopentadienyl complexes of ruthenium

I. Manners, N. Connelly, 1989 .

Palladium(I) .pi.-radicals. Electrochemical preparation and study of their reaction pathways

N. Connelly, W. Geiger, G. Lane, 1987 .

Stabilization of anion radicals by the pentaphenylcyclopentadienyl ligand. Evidence for symmetrical metal-C5R5 bonding in [(.eta.-C5Ph5)M(CO2)]- (M = Co, Rh).

N. Connelly, W. Geiger, P. Rieger, 1986 .

Reduction–oxidation properties of organotransition-metal complexes. Part 23. Pentaphenylcyclopentadienyl carbonyl complexes of cobalt and rhodium

N. Connelly, S. J. Raven, 1986 .

The electron-transfer properties of alkyne-bridged dipalladium complexes: synthesis and reactions of [Pd2(µ-PhC2Ph)(η-C5Ph5)2][PF6], and comments on the mechanism of the oxidative cleavage of binuclear organotransition-metal complexes

K. Broadley, N. Connelly, W. Geiger, 1986 .

Electrochemical routes to paramagnetic dinuclear and mononuclear palladium .pi. complexes stabilized by the pentaphenylcyclopentadienyl ligand

K. Broadley, N. Connelly, W. Geiger, 1983 .

Synthesis of asymmetric alkyne-bridged dipalladium complexes from the paramagnetic cation [Pd2( -PhCPh)( -C5Ph5)2]+; crystal structures of [Pd2(bipy)( -PhC2Ph)( -C5Ph5)][Pd2(NCMe)-(bipy)( -PhC2Ph)( -C5Ph5)][PF6]2.OEt2 and [Pd2(bipy){P(OPh)3}( -PhC2Ph)( -C5Ph5)][PF6]

A. Orpen, N. Connelly, W. Geiger, 1991 .

Reduction–oxidation properties of organotransition-metal complexes. Part 6. The isomerization, and one-electron oxidation, of syn- and anti-di-µ-arylthio-bis[(η-cyclopentadienyl)rhodium]

N. Connelly, G. A. Johnson, 1978 .

The electrochemistry of organotransition-metal complexes

N. Connelly, Karen R. Somers, 1976 .

Radical intermediates in the reductive isomerisation of octahedral manganese carbonyl bipyridyl complexes; electrochemistry, electron spin resonance spectroscopy and molecular-orbital calculations

F. J. Alonso, V. Riera, N. Connelly, 1994 .

COMPLEXES OF RHENIUM AND OSMIUM POLYHYDRIDES WITH METALLIC LEWIS ACIDS: X-RAY CRYSTAL STRUCTURE OF μ-ARGENTIOBIS(HEPTAHYDRIDOBIS(DIISOPROPYLPHENYLPHOSPHINE)RHENIUM(VII)) HEXAFLUOROPHOSPHATE

J. Howard, J. Spencer, N. Connelly, 1984 .

METAL CARBONYL CATIONS WITH CYCLIC PI-HYDROCARBON LIGANDS

P. Williard, N. Connelly, D. A. Sweigart, 1988 .

The d4/d3 redox pairs [MX(CO)(eta-RC[triple bond, length as m-dash]CR)Tp']z (z=0 and 1): structural consequences of electron transfer and implications for the inverse halide order.

A. Orpen, C. Adams, D. Harding, 2007, Dalton transactions.

Structure and bonding in the d4/d3 alkyne redox pairs [WX(CO)(MeCCMe)Tp′]z (X = F, Cl, Br and I; z = 0 and 1): halide stabilisation of electron deficient metal alkyne complexes

A. Orpen, D. Harding, N. Connelly, 1999 .

Isomerisation of [{Rh(µ-SR1)(η-C5H4R2)}2]: 1H nuclear magnetic resonance and electrochemical studies and the X-ray crystal structure of [anti-{Rh(µ-SPh)(η-C5H5)}2]

P. Woodward, N. Connelly, G. A. Johnson, 1977 .

Reduction-oxidation properties of organotransition-metal complexes. Part 8. Formation and reactivity of the radical cations [Fe(CO)3L2]+, and the mechanism of the oxidative elimination reaction of [Fe(CO)3L2] with halogens

N. Connelly, P. Baker, J. Maher, 1980 .

Transition-metal dithiolene complexes. Part XX. Dicyano-1,2-dithiolene complexes of rhenium

C. J. Jones, J. McCleverty, N. Connelly, 1971 .

The reductive dimerization of [W(NCMe)(MeC2Me)2(η-C5H5)]+: Synthesis and X-ray structure of the novel bis(metallacyclopentadiene) complex [W2(μ-σ,σ,η2,η2-C4Me4)2(η-C5H5)2]

A. Orpen, Antonio Martín, Bernhard Metz, 1995 .

Electron-Transfer-Induced Interconversion of Alkyne and Vinylidene Chromium Complexes: A Quantitative Study

Bernhard Metz, N. Connelly, W. Geiger, 1995 .

The d3/d2 alkyne complexes [MX2(eta-RC[triple bond, length as m-dash]CR)Tp']z (X = halide, z = 0 and 1+): final links in a d6-d2 redox family tree.

A. Orpen, K. M. Anderson, C. Adams, 2009, Dalton transactions.

Ligand-Induced and Reductively Induced Alkyne−Isocyanide Coupling Reactions of [Mo(CNBut)3(PhC⋮CPh)(η5-C5Me5)][BF4]

A. Orpen, K. M. Anderson, C. Adams, 2002 .

The d2/d3 alkyne redox pair [WF2(PhCCPh)Tp′]z (z = +1 or 0): missing links in a ‘redox family tree’

A. Orpen, K. M. Anderson, C. Adams, 2002 .

EPR and NMR spectroscopic studies of [MoL2(MeCCMe)Cp]z (L = P-donor ligand, z = 0 and 1): fluxionality in a metal–alkyne redox pair

C. Adams, N. Connelly, P. Rieger, 2001 .

Reduction of [ML(alkyne)2(η-C5R‘5)]+ (M = Mo or W, L = MeCN or CO, R‘ = H or Me, C5R‘5 = C5HPh4): Characterization of Radical Intermediates in the Reductive Coupling of Coordinated Alkynes

R. Winter, Bernhard Metz, N. Connelly, 1999 .

The stable radical cation [Mo2(µ-C8Me8)(η-C5H5)2]+: an intermediate in the redox activation of an alkyl C–H bond and a probe of metal–alkene bonding

A. Orpen, Bernhard Metz, N. Connelly, 1994 .

Reactions of co-ordinated ligands. Part 48. Reactivity studies of the octatrienediylidenedimolybdenum complexes [Mo2(µ-C8Me8)(η-C5H5)2] and [Mo2(µ-C8H4But4)(η-C5H5)2]. Crystal structures of [Mo2(µ-C8Me7CH2)(η-C5H5)2][CF3SO3], [Mo2(µ-C8Me8)(µ-Cl)(η-C5H5)2][SbCl4]·CH2Cl2, and [Mo2(µ-C8H4But4)(µMo,C-H)

L. Brammer, A. Orpen, S. Bott, 1990 .

The radical cation [Fe(CO)3(PPh3)2]+: novel source of iron(II) carbonyl complexes

K. Broadley, N. Connelly, P. Baker, 1980 .

Oxidative and thermal isomerization of phosphido-bridged molybdenum dicobalt clusters: x-ray crystal structures of the complexes [MoCo2(.mu.3-CC6H4Me-4)(.mu.-PPh2)(CO)6(.eta.-C5H5)] and [NEt4][MoCo2(.mu.3-CC6H4Me-4)(.mu.-PPh2)(CO)6(.eta.-C5H5)]

J. Jeffery, N. Connelly, M. R. Bradford, 1989 .

Binuclear diaryltriazenido- and aryl(1-aryliminoethyl)amido-complexes of rhodium

N. Connelly, Z. Demidowicz, Helen Daykin, 1979 .

Reduction–oxidation properties of organotransition-metal complexes. Part 21. Synthesis and X-ray structural characterisation of the redox-related pair of cyclohexadienyl complexes [Mn(CO)(dppe)(η5-C6H6Ph)] and [Mn(CO)(dppe)(η5-C6H6Ph)][PF6]·0.5CH2Cl2

A. Orpen, N. Connelly, J. Sheridan, 1985 .

Reduction–oxidation properties of organotransition-metal complexes. Part 5. The one-electron oxidation of tricarbonyl(η-cyclopentadienyl)-manganese derivatives and the reactivity of the resulting radical cations

N. Connelly, M. D. Kitchen, 1977 .

Novel N-bound thallium(I) complexes of redox-active cyanomanganese carbonyl ligands: cyanide as a µ3-κC∶κN∶κN triply bridging ligand

A. Orpen, M. Moreno, G. R. Lewis, 1998 .

Structure dependence on redox state and charge in [Fe4(μ3-S4)(η-C5H5)4]m[M(mnt)2]n (M = Ni or Pt, m, n = 1 or 2)

A. Orpen, G. R. Lewis, N. Connelly, 2000 .

Lewis Base Adducts of Cobalt and Iron Bis-I,2-dithiolenes

C. Winscom, J. McCleverty, N. Connelly, 1967, Nature.

ESR spectroscopic characterisation of a coordinated alkyne radical, and redox-induced vinylidene–alkyne complex isomerisation

A. Orpen, G. Rosair, N. Connelly, 1992 .

Acetonitrilecarbonyl and acetonitrilenitrosyl metal cations from the reactions of the nitrosonium ion, NO+, with transition-metal organometallics in acetonitrile

L. F. Dahl, N. Connelly, 1970 .

EPR spectra of [Cr(CO) 2 L(η-C 6 Me 6 ] + , L = PEt 3 , PPh 3 , P(OPh) 3 : analysis of line widths and determination of ground state configuration from interpretation of 3 1 P couplings

R. Pike, M. P. Castellani, N. Connelly, 1997 .

The oxidation of alkyne-bridged dimolybdenum complexes

M. Crespo, N. Connelly, C. Coates, 1988 .

Oxidation of cyanide-bridged dimanganese(I) complexes: redox-induced isomerisation as a probe of intermetallic interaction

M. Crespo, V. Riera, N. Connelly, 1991 .

Reduction-oxidation properties of organo-transition metal complexes. Part 33. Ligand-vs. metal-based oxidation of cyano-bridged catecholatoruthenium–manganese carbonyl compounds: the X-ray crystal structure of cis-[(dppe)(Et3P)(OC)2Mn(µ-CN)Ru(CO)2(PPh3)(o-O2C6Cl4)]·CH2Cl2

A. Orpen, N. Connelly, A. Christofides, 1991 .

One-electron transfer reactions of cyclooctatetraene (cot) complexes: electron spin resonance studies of 60CO γ-irradiated [Fe(CO)2L(η4-cot)][L = CO or P(OPh)3]

J. Wyatt, M. Symons, N. Connelly, 1991 .

Nomenclature of Inorganic Chemistry II: Recommendations 2000.

Jon A. McCleverty, J. McCleverty, N. Connelly, 2010 .

Polymorphism and pseudo-polymorphism in the crystal structures of [ML2]2[{M(mnt)2}2](M = Fe or Co, L = Cp or Cp*)

A. Orpen, G. R. Lewis, N. Connelly, 2002 .

Transition-metal dithiolenes. Part VII. Five- and six-co-ordinate Lewis-base complexes of cobalt and iron bisdithiolenes

C. Winscom, N. Atherton, J. McCleverty, 1969 .

Synthesis and electrophilic reactivity of dicarbonylnitrosyl(cyclohexadienyl)manganese cations: double nucleophilic addition to coordinated arenes

Y. Chung, N. Connelly, J. Sheridan, 1985 .

Stereo- and regio-specific CC bond formation via the coupling of electrophilic and nucleophilic organotransition-metal complexes: The x-ray crystal structure of [Ru(CO)2(PPh3)(η2,η3-C8H8R)][PF6]·0.5CH2Cl2 (R = CH2C(Me)CH2)

A. Orpen, N. Connelly, J. Sheridan, 1986 .

Reduction–oxidation properties of organotransition-metal complexes. Part 32. One-electron oxidation of [Co(η4-cot)-(η-C5Me5)](cot = cyclooctatetraene): redox-induced polycyclic ring transformations of the resulting dimer, and crystal structure of [Co2(η4:η′4-C16H16)(η-C5Me5)2]

A. Orpen, R. Aggarwal, N. Connelly, 1991 .

Allylation of cobalt-co-ordinated cyclo-octatetraene by the [Fe{P(OMe)3}(NO)2(η3-allyl)]+ cation: ring closure to 1,2,3,3a-tetrahydropentalenyl derivatives and the X-ray structure of [Co(η5-C8H8R)(η-C5Me5)][PF6][R = CH2C(Me)CH2]

A. Orpen, J. White, N. Connelly, 1988 .

Reaction of [Rh(η4-cot)(η-C5H5)](cot = cyclo-octatetraene) with [Fe{P(OMe)3}(NO)2(η3-CH2CHCH2)]+: allylic alkylation of a cyclopentadienyl ring

N. Connelly, M. Gilbert, 1990 .

Stereospecific endo hydride addition to cyclohexadienylmanganese complexes

W. Robinson, S. D. Ittel, Y. Chung, 1983 .

Allylic alkylation of co-ordinated cyanide: the synthesis and X-ray crystal structure of trans-[Mn(CO)(CNCH2CMe:CH2)*dppm)2][PF6].thf

A. Orpen, G. Rosair, N. Connelly, 1991 .

The reversible one-electron oxidation of trans-[Mn′L(CO)(Ph2PCH2PPh2)2]z+: synthesis and characterisation of stable manganese(II) derivatives

V. Riera, N. Connelly, G. A. Carriedo, 1987 .

Triazenide-bridged rhodium-palladium complexes: [I2Rh(mu-p-MeC6H4NNNC6H4Me-p)2Pd(eta(3)-C3H5)]-, a stable paramagnetic [RhPd]4+ species with a localised Rh(II) centre.

A. Orpen, M. Kandiah, C. Adams, 2006, Dalton transactions.

M...HNR interactions in imino-bound diaryltriazene complexes: structure and fluxionality.

A. Orpen, K. M. Anderson, M. Kandiah, 2004, Dalton transactions.

Reduction–oxidation properties of organotransition-metal complexes. Part 31. Reductive elimination, oxidative addition and substitution, and migratory insertion in pentaphenylcyclopentadienylruthenium nitrosyl chemistry

I. Manners, N. Connelly, P. Rieger, 1990 .

Structural consequences of electron transfer reactions. Pt. 17. One-electron oxidation of (N4-cot)RhCp: rearrangements of the radicalcation and of the resulting dimerization product

L. Brammer, A. Orpen, N. Connelly, 1988 .

Synthesis and reactivity of the tetrakis(acetonitrile)nitrosylrhodium dication

N. Connelly, Michael J. Green, T. A. Kuc, 1977 .

Reversible sequence of intramolecular associative and dissociative electron-transfer reactions in hydrotris(pyrazolylborate) complexes of rhodium.

N. Connelly, W. Geiger, David J. H. Emslie, 2003, Journal of the American Chemical Society.

Simple halogenonitrosyl anions of iron

N. Connelly, C. Gardner, 1976 .

Addition of cyclopropenylium and tropylium ions to cyclooctatetraene-cobalt and -rhodium cyclopentadienyl complexes

A. Orpen, N. Connelly, J. Slater, 1992 .

Cationic arenechromium-nitrosyls and -hydrides

N. Connelly, D. Ball, 1973 .

THE REACTION OF COORDINATED CYCLOOCTATETRAENE WITH ARENEDIAZONIUM IONS: AZO COUPLING VS. ARYLATION

N. Connelly, M. W. Whiteley, A. Lucy, 1983 .

Annelation of ring-opened arylcyclopropenium ions to co-ordinated cyclo-octatetraene, and the X-ray crystal structure of [Fe(CO)3(σ,η3-C11H9Ph3)]

J. Howard, K. Broadley, N. Connelly, 1985 .

Synthesis of styrylcycloheptatriene derivatives via the electrophilic addition of tropylium ions to [Fe(CO)3(η4-C8H8)]: X-ray crystal structure of tricarbonyl(1–4-η-7-styrylcyclohepta-1,3,5-triene)iron

K. Broadley, P. Woodward, N. Connelly, 1984 .

Synthesis and Structural Characterization of the First Isolated Homoleptic Organoplatinum(IV) Compound: [Pt(C6Cl5)4]

A. Orpen, J. Crossley, N. Connelly, 1995 .

Reduction–oxidation properties of organotransition-metal complexes. Part 25. The one-electron reduction of cationic cyclopentadienyl–cobalt and –rhodium nitrosyl derivatives

N. Connelly, W. Geiger, S. J. Raven, 1987 .

Reduction-Oxidation Properties of Organotransiton-Metal Complexes. Part 25. The One-Electron Reduction of Cationic Cyclopentadienyl-Cobalt and -Rhodium Nitrosyl Derivatives.

N. Connelly, W. Geiger, S. J. Raven, 1987 .

Electron Transfer-Induced cis−trans Isomerization of [Mn(CN)(CO)2{P(OPh)3}(Ph2PCH2PPh2)]: Solution and Solid State Voltammetric Studies

A. Bond, C. Hogan, A. Neufeld, 2003 .

The synthesis and structure of a paramagnetic Lewis base adduct of antimony pentachloride, trans-[MnII(CNSbCl5)(CO)2{P(OEt)3}(dppm)][SbCl6]†

A. Orpen, N. Connelly, Nathan C. Brown, 1999 .

Transition-metal derivatives of arenediazonium ions. Part 8. The reactions of nitrosonium and arenediazonium ions with 2,2′-bipyridyl and 1,10-phenanthroline derivatives of Group 6 metal carbonyls

N. Connelly, F. J. Lalor, David. Condon, 1977 .

Analysis of Electron Paramagnetic Resonance Spectra with Very Large Quadrupole Couplings

N. Connelly, P. Rieger, David J. H. Emslie, 2002 .