C. Frech

发表

Mizoroki–Heck Reactions Catalyzed by Dichloro{bis[1‐(dicyclohexylphosphanyl)piperidine]}palladium: Palladium Nanoparticle Formation Promoted by (Water‐Induced) Ligand Degradation

M. Oberholzer, R. Gerber, C. Frech, 2012 .

[Pd(Cl)2{P(NC5H10)(C6H11)2}2]--a highly effective and extremely versatile palladium-based Negishi catalyst that efficiently and reliably operates at low catalyst loadings.

C. Frech, Jeanne L. Bolliger, 2010, Chemistry.

Transition metal-free amination of aryl halides-A simple and reliable method for the efficient and high-yielding synthesis of N-arylated amines

C. Frech, Jeanne L. Bolliger, 2009 .

Rationally designed pincer-type heck catalysts bearing aminophosphine substituents: Pd IV intermediates and palladium nanoparticles.

O. Blacque, C. Frech, Jeanne L. Bolliger, 2008, Chemistry.

Short, facile, and high-yielding synthesis of extremely efficient pincer-type suzuki catalysts bearing aminophosphine substituents.

O. Blacque, C. Frech, Jeanne L. Bolliger, 2007, Angewandte Chemie.

P Csp(3) P and P Csp(2) P palladium(II) hydride pincer complexes: small structural difference-large effect on reactivity.

T. Fox, R. Gerber, C. Frech, 2010, Chemistry.

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

M. Oberholzer, C. Frech, 2014, Journal of visualized experiments : JoVE.

Negishi cross-coupling reaction catalyzed by an aliphatic, phosphine based pincer complex of palladium. biaryl formation via cationic pincer-type Pd(IV) intermediates.

O. Blacque, R. Gerber, C. Frech, 2011, Dalton transactions.

Access to 2‐Aminopyridines – Compounds of Great Biological and Chemical Significance

M. Oberholzer, C. Frech, Jeanne L. Bolliger, 2011 .

Suzuki Cross‐Coupling Reactions Catalyzed by an Aliphatic Phosphine‐Based Pincer Complex of Palladium: Evidence for a Molecular Mechanism

O. Blacque, R. Gerber, C. Frech, 2009 .

Highly Convenient, Clean, Fast, and Reliable Sonogashira Coupling Reactions Promoted by Aminophosphine‐Based Pincer Complexes of Palladium Performed under Additive‐ and Amine‐Free Reaction Conditions

C. Frech, Jeanne L. Bolliger, 2009 .

Mizoroki–Heck reactions catalyzed by palladium dichloro-bis(aminophosphine) complexes under mild reaction conditions. The importance of ligand composition on the catalytic activity

M. Oberholzer, C. Frech, 2013 .

Observation of binuclear palladium clusters upon ESI-MS monitoring of the Suzuki–Miyaura cross-coupling catalyzed by a dichloro-bis(aminophosphine) complex of palladium

D. Schröder, C. Frech, D. Agrawal, 2011 .

Processes Involved in the Reduction of a Cyclometalated Palladium(II) Complex

D. Milstein, G. Leitus, C. Frech, 2008 .

Redox-induced collapse and regeneration of a pincer-type complex framework: a nonplanar coordination mode of palladium(II).

L. Shimon, D. Milstein, C. Frech, 2005, Angewandte Chemie.

Development of Rhenium Catalysts for Amine Borane Dehydrocoupling and Transfer Hydrogenation of Olefins

Yanfeng Jiang, T. Fox, O. Blacque, 2009 .

Experimental and Theoretical Aspects of Palladium Pincer‐Catalyzed C–C Cross‐Coupling Reactions

C. Frech, 2014 .

Pincer-type Heck catalysts and mechanisms based on Pd(IV) intermediates: a computational study.

O. Blacque, C. Frech, 2010, Chemistry.

Negishi cross-coupling reactions catalyzed by an aminophosphine-based nickel system: a reliable and general applicable reaction protocol for the high-yielding synthesis of biaryls.

R. Gerber, C. Frech, 2011, Chemistry.

The 1,3-Diaminobenzene-Derived Aminophosphine Palladium Pincer Complex {C6H3[NHP(piperidinyl)2]2Pd(Cl)} – A Highly Active Suzuki–Miyaura Catalyst with Excellent Functional Group Tolerance

C. Frech, Jeanne L. Bolliger, 2010 .

Dichloro-bis(aminophosphine) complexes of palladium: highly convenient, reliable and extremely active suzuki-miyaura catalysts with excellent functional group tolerance.

C. Frech, Jeanne L. Bolliger, 2010, Chemistry.

Methylene transfer from SnMe groups mediated by a rhodium(I) pincer complex: Sn-C, C-C, and C-H bond activation.

L. Shimon, D. Milstein, C. Frech, 2007, Chemistry.

Cyanation of aryl bromides with K4[Fe(CN)6] catalyzed by dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium, a molecular source of nanoparticles, and the reactions involved in the catalyst-deactivation processes.

M. Oberholzer, R. Gerber, C. Frech, 2012, Chemistry.

Ligand-Controlled Formation of a Low-Valent Pincer Rhodium(I)-Dioxygen Adduct Bearing a Very Short O O Bond

L. Shimon, D. Milstein, C. Frech, 2006 .

Facile synthetic access to rhenium(II) complexes: activation of carbon-bromine bonds by single-electron transfer.

Yanfeng Jiang, T. Fox, O. Blacque, 2010, Chemistry.

Highly selective dehydrogenative silylation of alkenes catalyzed by rhenium complexes.

Yanfeng Jiang, T. Fox, O. Blacque, 2009, Chemistry.

Alkyne hydrothiolation catalyzed by a dichlorobis(aminophosphine) complex of palladium: selective formation of cis-configured vinyl thioethers.

R. Gerber, C. Frech, 2012, Chemistry.

Highly selective dehydrogenative silylation of alkenes catalyzed by rhenium complexes.

Yanfeng Jiang, T. Fox, O. Blacque, 2009, Chemistry.

Reactions of [Re(NO)2(PR3)2][BArF4] complexes with phenylacetylene

H. Berke, H. Schmalle, C. Frech, 2004 .

From Alkynes to Carbenes Mediated by [Re(Br)(H)(NO)(PR3)2] (R = Cy, iPr) Complexes

Yanfeng Jiang, T. Fox, O. Blacque, 2009 .

Metal nitrosyl reactivity: Acetonitrile-promoted insertion of an alkylidene into a nitrosyl ligand with fission of the NO bond.

O. Blacque, H. Berke, H. Schmalle, 2006, Chemistry.

Ligand controlled dioxygen oxidation of rhenium nitrosyl complexes.

O. Blacque, H. Berke, H. Schmalle, 2006, Dalton transactions.

Unprecedented ROMP activity of low-valent rhenium-nitrosyl complexes: Mechanistic evaluation of an electrophilic olefin metathesis system.

O. Blacque, H. Berke, Peter Chen, 2006, Chemistry.

Reactions within Molecular Single Crystals of Inorganic and Organometallic Compounds: Recent Advances and Implications for Catalysis

C. Frech, 2010 .

Direct observation of reductive elimination of methyl iodide from a rhodium(III) pincer complex: the importance of sterics.

D. Milstein, C. Frech, 2006, Journal of the American Chemical Society.

Dinitrosyl rhenium complexes for ring-opening metathesis polymerization (ROMP)

O. Blacque, H. Berke, C. Frech, 2006 .

Hydrolysis of ammonia borane catalyzed by aminophosphine-stabilized precursors of rhodium nanoparticles: ligand effects and solvent-controlled product formation.

O. Blacque, R. Gerber, C. Frech, 2011, Chemistry.

DsbA-mediated Disulfide Bond Formation and Catalyzed Prolyl Isomerization in Oxidative Protein Folding (*)

F. Schmid, C. Frech, 1995, The Journal of Biological Chemistry.

The Mizoroki–Heck Reaction. Edited by Martin Oestreich.

C. Frech, 2009 .

Book review: The Mizoroki-Heck reaction / edited by Martin Oestreich. John Wiley & Sons, Hoboken 2009

C. Frech, 2009 .

Bis[2,6-bis(dipiperidin-1-ylphosphanyloxy)phenyl]bromidopalladium(II)

O. Blacque, C. Frech, Jeanne L. Bolliger, 2007 .

Negishi cross-coupling reaction catalyzed by an aliphatic, phosphine based pincer complex of palladium. biaryl formation via cationic pincer-type Pd(IV) intermediates.

O. Blacque, R. Gerber, C. Frech, 2011, Dalton transactions.

Dichloro-bis(aminophosphine) complexes of palladium: highly convenient, reliable and extremely active suzuki-miyaura catalysts with excellent functional group tolerance.

C. Frech, Jeanne L. Bolliger, 2010, Chemistry.