D. Miguel

发表

Octapodal corannulene porphyrin-based assemblies: allosteric behavior in fullerene hosting.

H. Barbero, S. Ferrero, D. Miguel, 2020, The Journal of organic chemistry.

Metallamacrocycle formation through dimerization of metal bioconjugates derived from amino acids and peptides.

D. Miguel, R. García‐Rodríguez, C. Álvarez, 2016, Dalton transactions.

Porphyrin-based systems containing polyaromatic fragments: decoupling the synergistic effects in aromatic-porphyrin-fullerene systems

H. Barbero, S. Ferrero, D. Miguel, 2020, RSC advances.

η6-Hexahelicene complexes of iridium and ruthenium: running along the helix.

L. García-Escudero, J. Martín-Álvarez, H. Barbero, 2012, Inorganic chemistry.

Coordination versus coupling of dicyanamide in molybdenum and manganese pyrazole complexes.

J. Martín-Álvarez, D. Miguel, C. Álvarez, 2012, Inorganic chemistry.

Activation of two C-H bonds of NHC N-methyl groups on triosmium and triruthenium carbonyl clusters.

D. Miguel, J. A. Cabeza, E. Pérez-Carreño, 2008, Dalton transactions.

Pyrazolylamidino‐ and Bis(pyrazole)manganese(I) Complexes

D. Miguel, F. Villafañe, M. Arroyo, 2005 .

Copper complexes for the promotion of iminopyridine ligands derived from β-alanine and self-aldol additions: relaxivity and cytotoxic properties.

J. Martín-Álvarez, G. Rogez, D. Miguel, 2019, Dalton transactions.

Copper Complexes in the Promotion of Aldol Addition to Pyridine-2-carboxaldehyde: Synthesis of Homo- and Heteroleptic Complexes and Stereoselective Double Aldol Addition.

H. Barbero, D. Miguel, R. García‐Rodríguez, 2018, Inorganic chemistry.

Pyrazolylamidino ligands from coupling of acetonitrile and pyrazoles: a systematic study.

C. Strohmann, D. Miguel, F. Villafañe, 2014, Inorganic chemistry.

Homo- and heteropolymetallic 3-(2-pyridyl)pyrazolate manganese and rhenium complexes.

A. Pombeiro, D. Miguel, R. García‐Rodríguez, 2014, Dalton transactions.

Triple bridged anionic dimetallic complexes from cis-[Mo(η3-methallyl)Cl(CO)2(NCMe)2] and pyrazolates

D. Miguel, F. Villafañe, Sonia Bajo, 2012 .

Molybdenum- and tungsten(II) monometallic 3-(2-pyridyl)pyrazole and bimetallic 3-(2-pyridyl)pyrazolate complexes.

A. Pombeiro, D. Miguel, F. Villafañe, 2012, Dalton transactions.

Tetranuclear organometallic complexes containing Mo2O4(2+) and allylmolybdenum(II) moieties.

D. Miguel, F. Villafañe, Paloma Paredes, 2010, Dalton transactions.

fac-Acetato-bis(pyrazole) complexes: A systematic study on intra- and intermolecular hydrogen bonds

D. Miguel, R. García‐Rodríguez, F. Villafañe, 2009 .

Non-covalent interactions at bis(pyrazole)silver(i) or -gold(i) cations.

D. Miguel, F. Villafañe, M. Arroyo, 2009, Dalton transactions.

Hexaruthenium and octaruthenium carbonyl cluster complexes derived from 2-amino-6-methylpyridine : Novel coordination modes for 2-imidopyridines

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2006 .

Dual-Tweezer Behavior of an Octapodal Pyrene Porphyrin-Based System as a Host for Fullerenes.

H. Barbero, S. Ferrero, D. Miguel, 2019, The Journal of organic chemistry.

Assembling nonplanar polyaromatic units by click chemistry. Study of multicorannulene systems as host for fullerenes.

L. García-Escudero, G. Aullón, J. Martín-Álvarez, 2015, Organic letters.

Second-sphere coordination complex via hydrogen bonding: Synthesis, characterization, X-ray crystal structure determination and packing of hexaamminecobalt(III) chloride di(para-nitrobenzoate)

Julio Pérez, D. Miguel, Rajender Sharma, 2006 .

ON/OFF metal-triggered molecular tweezers for fullerene recognition.

H. Barbero, S. Ferrero, D. Miguel, 2021, Chemical communications.

Carbonyl complexes of manganese, rhenium and molybdenum with ethynyliminopyridine ligands

L. García-Escudero, D. Miguel, José A. Turiel, 2006 .

Activation of a 1,10-phenanthroline ligand on a rhenium tricarbonyl complex.

Dolores Morales, Julio Pérez, Eva Hevia, 2005, Chemical communications.

Indene and pseudoazulene discotic liquid crystals: a synthetic and structural study.

T. Torroba, M. Ros, M. R. de la Fuente, 2005, Chemistry.

Alkylation and metalation of binuclear anions containing a novel tricyclohexylphosphonioethanetrithiolate ligand S(SR)CC(PCy3)S

D. Miguel, Yongqiang Ma, Qinglan Xie, 2004 .

Amidino ligands obtained from the coupling of 1-methylcytosine and nitrile: a new method to incorporate biomolecules into luminescent Re(CO)3 complexes.

J. Martín-Álvarez, D. Miguel, F. Villafañe, 2015, Dalton transactions.

Reactivity of molybdenum and rhenium hydroxo-carbonyl complexes toward organic electrophiles.

S. García‐Granda, Dolores Morales, Julio Pérez, 2004, Chemistry.

From Induced-Fit Assemblies to Ternary Inclusion Complexes with Fullerenes in Corannulene-Based Molecular Tweezers

H. Barbero, D. Miguel, C. Álvarez, 2022, The Journal of organic chemistry.

Cyclopentathiadiazines, Cyclohepta- and Cyclopentadithiazoles: New Materials and a Rich Heterocyclic Chemistry of Cyclic Enaminonitriles†

T. Torroba, D. Miguel, A. G. Neo, 2005 .

Cyclopentathiadiazines, new heterocyclic materials from cyclic enaminonitriles.

T. Torroba, D. Miguel, A. G. Neo, 2005, Chemical communications.

Ruthenium-cluster-mediated activation of all bonds of a methyl group of 6,6'-dimethyl-2,2'-bipyridine and 2,9-dimethyl-1,10-phenanthroline: transformation of the latter into a 2-alkenyl-9-methyl-1,10-phenanthroline ligand.

D. Miguel, J. A. Cabeza, I. del Río, 2006, Chemistry.

Easy activation of two C-H bonds of an N-heterocyclic carbene N-methyl group.

D. Miguel, J. A. Cabeza, M. Sánchez-Vega, 2005, Chemical communications.

1,4-thiazepines, 1,4-benzothiazepin-5-ones, and 1,4-benzothioxepin orthoamides via multicomponent reactions of isocyanides.

T. Torroba, M. García-Valverde, S. Marcaccini, 2003, The Journal of organic chemistry.

Beyond click chemistry: spontaneous C-triazolyl transfer from copper to rhenium and transformation into mesoionic C-triazolylidene carbene.

L. García-Escudero, D. Miguel, R. García‐Rodríguez, 2012, Chemical communications.

Molybdenum amido complexes with single Mo-N bonds: synthesis, structure, and reactivity.

S. García‐Granda, Marta E. G. Mosquera, Dolores Morales, 2003, Chemistry.

Syntheses, solid structures, and behavior in solution of [MI2(CO)3(pyrazole)2] complexes (M = Mo, W)

J. Martín-Álvarez, C. Strohmann, D. Miguel, 2017 .

Insertion of unsaturated organic electrophiles into molybdenumbond-alkoxide and rheniumbond-alkoxide bonds of neutral, stable carbonyl complexes.

S. García‐Granda, Julio Pérez, Eva Hevia, 2002, Chemistry.

Simple 1-dicyanomethylene-2-chloro-3-aminoindene push-pull chromophores: applications in cation and anion sensing.

T. Torroba, R. Quesada, S. Basurto, 2010, Organic & biomolecular chemistry.

Synthesis of tris(3-pyridyl)aluminate ligand and its unexpected stability against hydrolysis: revealing cooperativity effects in heterobimetallic pyridyl aluminates.

J. Martín-Álvarez, Alex J. Plajer, D. Miguel, 2021, Dalton transactions.

Tris(2-pyridyl) Bismuthines: Coordination Chemistry, Reactivity, and Anion-Triggered Pyridyl Coupling.

D. Wright, A. Bond, Alex J. Plajer, 2020, Inorganic chemistry.

The Combination of Organometallic {Mo(η3-allyl)(CO)2(phen)} Fragments and Hard Aquo and Hydroxo Ligands: Controlled Synthesis and Structural Characterization

Dolores Morales, Julio Pérez, V. Riera, 2002 .

An easily accessed molybdenum Lewis acid as a catalyst for imine aziridination

S. García‐Granda, Dolores Morales, Julio Pérez, 2002 .

Synthesis and crystal structure of [(η3-C3H5)(CO)2Mo(μ-S2CPCy3)-Mo(η3-CH2CMeCH2)(CO)2]

Mei Wang, V. Riera, C. Bois, 2001 .

Schiff plus click: one-pot preparation of triazole-substituted iminopyridines and ring opening of the triazole ring.

L. García-Escudero, D. Miguel, R. García‐Rodríguez, 2013, Dalton transactions.

Molybdenum carbonyl complexes with pyridylimino acidato ligands.

D. Miguel, R. García‐Rodríguez, 2006, Dalton transactions.

Synthesis of thiomorpholines by an intramolecular Ugi reaction

T. Torroba, M. García-Valverde, S. Marcaccini, 2002 .

Synthesis of new copper(I) complexes with tris(2-pyridyl) ligands. Applications to carbene and nitrene transfer reactions.

L. García-Escudero, Dolores Morales, Julio Pérez, 2009, Dalton transactions.

σ-Alkynyl complexes of manganese(I) as η2-bonding ligands for Group 1B metal–ligand fragments. X-Ray crystal structure of [Mn2Cu(µ-CCBut)2(CO)6(dppe)2]PF6·0.5CH2Cl2

X. Solans, V. Riera, G. A. Carriedo, 1987 .

3‐(Pyridin‐2‐yl)imidazo[1,5‐a]pyridine (Pyridylindolizine) as Ligand in Complexes of Transition and Main‐Group Metals

J. Martín-Álvarez, D. Miguel, R. García‐Rodríguez, 2015 .

Complexes with 3-(pyridin-2-yl)imidazo[1,5-a]pyridine ligands by spontaneous dimerization of pyridine-2-carboxaldehyde within the coordination sphere of manganese(II) in a one-pot reaction.

D. Miguel, R. García‐Rodríguez, C. Álvarez, 2012, Dalton transactions.

Luminescent cis-Bis(bipyridyl)ruthenium(II) Complexes with 1,2-Azolylamidino Ligands: Photophysical, Electrochemical Studies, and Photocatalytic Oxidation of Thioethers

T. Torroba, J. Martín-Álvarez, Pablo Domingo-Legarda, 2021, Inorganic chemistry.

Dirhenium Complexes with S2CPR3 Bridges Donating Four and Eight Electrons — X-ray Structures of [Re2(CO)8{μ-η1;η1-S2CPCy3}] and {Re2(CO)6{μ-η3;-S2CPCy3}] and [Re2(CO)6{μ-η2; η3-S2CPCy3}]

S. García‐Granda, V. Riera, D. Miguel, 1997 .

New Types of (Arene)ruthenium Alkynyl Complexes

Dolores Morales, V. Riera, C. Menéndez, 2001 .

Pyrazole complexes as anion receptors.

Julio Pérez, Sonia Nieto, V. Riera, 2006, Chemistry.

Synthesis and Structure of an Asymmetric Binuclear Phenylhydrazonato Anionic Complex of Palladium Containing a Pd−C(aryl) Bondcis to a Pd−N(amido) Bond

S. García‐Granda, J. Cuevas, G. García-Herbosa, 2001 .

Synthesis of beta-lactams from a N-rhenaimine: effect of the transition metal on the energetic profile of the Staudinger reaction.

S. García‐Granda, P. Campomanes, Julio Pérez, 2003, Journal of the American Chemical Society.

A new route for the synthesis of an alkylideneamido complex

Dolores Morales, Julio Pérez, D. Miguel, 2008 .

Macrocycle formation by proton-template-induced dimerization of complexes with (alkoxoimino)pyridine.

J. Martín-Álvarez, D. Miguel, R. García‐Rodríguez, 2012, Inorganic chemistry.

Iminopyridine complexes of manganese, rhenium, and molybdenum derived from amino ester methylserine and peptides Gly-Gly, Gly-Val, and Gly-Gly-Gly: self-assembly of the peptide chains.

D. Miguel, R. García‐Rodríguez, C. Álvarez, 2012, Inorganic chemistry.

DIASTEREOSPECIFIC DIMERIZATION IN BRIDGING AMIDO COMPLEXES OF DIPALLADIUM

S. García‐Granda, J. Cuevas, G. García-Herbosa, 1997 .

Mononuclear ruthenium complexes containing chiral aminooxazolines: Syntheses, X-ray studies and catalytic activity

Robert A. Gossage, I. D. Rı́o, D. Miguel, 2007 .

The different reactivity of 2-aminopyridines and 2-pyridone with [Ru3(CO)12]. X-Ray crystal structure of [Ru3(µ-H)(µ3-anpy)(CO)9](hanpy = 2-anilinopyridine)

V. Riera, D. Miguel, J. A. Cabeza, 1990 .

New [Mo(eta3-allyl)(CO)2L3]+ complexes with monodentate or tridentate nitrogen-donor ligands.

Dolores Morales, Julio Pérez, Sonia Nieto, 2005, Dalton transactions.

Pyridine-2-carboxaldehyde as ligand: synthesis and derivatization of carbonyl complexes.

D. Miguel, R. García‐Rodríguez, C. Álvarez, 2007, Dalton transactions.

Synthesis and reactivity of new (methoxy)methyl complexes of manganese(I) and rhenium(I)

Julio Pérez, Eva Hevia, V. Riera, 2006 .

Triruthenium carbonyl clusters derived from chiral aminooxazolines: synthesis and catalytic activity.

I. da Silva, Robert A. Gossage, D. Miguel, 2006, Dalton transactions.

Synthesis of cationic carbonyl complexes of manganese(I) with bidentate ligands

M. Laguna, V. Riera, D. Miguel, 1981 .

Unexpected orthopalladation of acetophenonephenylhydrazone

S. García‐Granda, G. García-Herbosa, D. Miguel, 2002 .

η3-Allyl molybdenum dithiophosphate and dithiophosphinate complexes with uni- and bidentate nitrogen donor ligands. X-ray structure of [Mo2(η3-C3H5)2(CO)4{S2P(OEt)2}2(μ-NH2NH2)]

S. García‐Granda, V. Riera, D. Miguel, 1995 .

Molybdenum and rhenium carbonyl complexes containing thiolato ligands

Julio Pérez, Eva Hevia, D. Miguel, 2019, Journal of Organometallic Chemistry.

A new reactivity pattern of low-valent transition-metal hydroxo complexes: straightforward synthesis of hydrosulfido complexes via reaction with carbon disulfide.

Dolores Morales, Julio Pérez, Eva Hevia, 2003, Chemical communications.

Seven-coordinate molybdenum complexes containing SnRCl2 and phosphorodithioate. X- Ray structure of [Mo(CO)2{P(OMe)3}2{S2P(OEt)2}(SnBuCl2)]

S. García‐Granda, V. Riera, D. Miguel, 1993 .

Whole microwave syntheses of pyridylpyrazole and of Re and Ru luminescent pyridylpyrazole complexes

T. Torroba, J. Martín-Álvarez, G. García-Herbosa, 2019, Inorganica Chimica Acta.

Ruthenium-platinum carbonyl cluster complexes with bridging methylene, methylidyne, and carbido ligands; crystal structures of the compounds [Ru2Pt(μ-CH2)(μ-CO)(CO)2{P(cyclo-C6H11)3}(η-C5H5)2], [Ru2Pt2(μ-H)(μ4-CH)(μ-CO)(CO)2(PPr3i)2(η-C5H5)2], and [Ru2Pt2(μ-H)2(μ4-C)(μ-CO)2(PPr3i)2(η-C5H5)2]

P. Sherwood, D. Davies, J. Jeffery, 1990 .

The first pyrazole molybdenum(0) complexes: cis-[Mo(CO)4(Hdmpz)2] crystallizes as a NH⋯OC hydrogen-bonded dimer

D. Miguel, F. Villafañe, M. Arroyo, 2003 .

Carbonyl complexes of manganese, rhenium and molybdenum with 2-pyridylimino acid ligands

D. Miguel, R. García‐Rodríguez, C. Álvarez, 2007 .

Non-covalent interactions between anions and a cationic rhenium diamine complex : structural characterization of the supramolecular adducts

Julio Pérez, Sonia Nieto, V. Riera, 2006 .

A new coordination mode for (pyrid-2-yl)thiolate (L) ligands: Synthesis and characterization of [Ru6(μ3-H)(μ5-κ2-L)(μ-CO)(CO)15]

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2007 .

An Analogue of Cymantrene [(Î·5-C5H5)Mn(CO)3] That Contains a Dimetalladithiacyclopentadienyl ring This work was supported by DGES and MCyT-PNI(Projects PB97-0470-C02-01 and BQU2000-0219). We are very grateful to Dr. Julio PÃ©rez and Prof. Gabino A. Carriedo for helpful discussions.

Dolores Morales, D. Miguel, V. Riera, 2002 .

An analogue of cymantrene [(eta5-C5H5)Mn(CO)3] that contains a dimetalladithiacyclopentadienyl ring.

S. García‐Granda, Dolores Morales, V. Riera, 2002, Angewandte Chemie.

Phosphinecarbon disulfide adducts, S2CPR3: versatile ligands in coordination chemistry

Agustín Galindo, Julio Pérez, D. Miguel, 1999 .

Heterodinuclear complexes of rhenium and molybdenum with bridging S2CPR3 ligands

V. Riera, D. Miguel, J. Pérez-Martínez, 1994 .

Seven-coordinate molybdenum-tin complexes containing phosphorodithioato and phosphoniodithioformate. X-Ray structure of [Mo(CO)2S2P(OEt)2(S2CPCy3)(SnPhCl2)] · CH2Cl2

V. Riera, D. Miguel, Georgina Barrado, 1994 .

Novel heterobimetallic complexes with S2CPR3(κ-S,S′)(κ-S,C,S′) bridges. X-Ray structure of [MnMo(CO)6(μ-Br)-(μ-S2CPiPr3)]

S. García‐Granda, V. Riera, D. Miguel, 1991 .

Ring opening and closing in (CO)n(L)MnI complexes where L = S2CPCy3 or diphosphine. Novel complexes containing the Mn(μ-L)AuC6F5 entity where L = S2CPCy3 or dppm

V. Riera, D. Miguel, J. Miguel, 1991 .

Manganese complexes with S2CPEt3 ligands. X-Ray crystal structures of cis-trans-[Mn(CO)2(PEt3)2(S2CPEt3)]ClO4 and cis-trans-[Mn(CO)2(PEt3)2(S2CH)]

V. Riera, C. Bois, D. Miguel, 1990 .

The reduction and oxidation of cationic carbonyl complexes of manganese with phosphoniodithioformate: X-ray crystal structure of [Mn(CO)4(S2CPCy3)]ClO4

S. García‐Granda, V. Riera, G. A. Carriedo, 1996 .

Manganese(I) complexes with (tricyclohexylphosphonio)dithiocarboxylate as chelate and unidentate ligand. X-Ray crystal structure of fac-[Mn(CO)3{S2CP(C6H11)3}2]ClO4·H2O

V. Riera, C. Bois, D. Miguel, 1987 .

The influence of nitrosyl and allyl ligands on the formation of metalmetal bonds in bimetallic complexes containing S2CPCy3 bridges

Mei Wang, V. Riera, D. Miguel, 2000 .

Building of dithiocarbamate and dithiocarbimate ligands within a heterobimetallic core

S. García‐Granda, Dolores Morales, V. Riera, 2003 .

Reactivity of N-Heterocyclic Carbenes with [Ru3(CO)12] and [Os3(CO)12]. Influence of Ligand Volume and Electronic Effects

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2008 .

The thermal and photochemical reactions of [Ru3(CO)12] with tetraethyldiphosphite. X-ray structure of [Ru3(CO)10{μ-(EtO)2POP(OEt)2}]

V. Riera, D. Miguel, J. A. Cabeza, 1990 .

From an N-methyl N-heterocyclic carbene to carbyne and carbide ligands via multiple C-H and C-N bond activations.

D. Miguel, J. A. Cabeza, M. Sánchez-Vega, 2008, Angewandte Chemie.

Synthesis and characterization of a tetraruthenium butterfly cluster containing a quadruply-bridging ligand derived from an N,N′-dipyrid-2-ylurea

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2007 .

Octahedral alkylidyne complexes of tungsten with chelating ligands as precursors for polynuclear compounds. Crystal structures of [W(CR)(CO)2(dmpe)(NCS)] and [Co2W(µ3-CR)(CO)8(dmpe)Br](R = C6H4Me-4, dmpe = Me2PCH2CH2PMe2)

V. Riera, C. Bois, G. A. Carriedo, 1990 .

Hexaruthenium carbonyl cluster complexes with basal edge-bridged square pyramidal metallic skeleton: efficient synthesis of 2-imidopyridine derivatives and determination of their reactive sites in carbonyl substitution reactions.

V. Riera, D. Miguel, J. A. Cabeza, 2004, Inorganic chemistry.

Activation of all bonds of a methyl group attached to an organic fragment.

I. da Silva, V. Riera, D. Miguel, 2004, Angewandte Chemie.

Transformations of -methylene-diruthenium complexes into tetranuclear metal clusters with 4-methylidyne and 4-carbido groups: X-ray crystal structures of [Ru2Pt2(-H)(4-CH)(-CO)(CO)2(PPri 3)2(?-C5H5)2] and [Ru2Pt2(-H)2(4-C)(-CO)2(PPri 3)2(?-C5H5)2]

P. Sherwood, D. Davies, J. Jeffery, 1987 .

Improved synthesis, solution and solid-state structure, and reactivity of [Ru2(µ-SePh)2(CO)6]

S. García‐Granda, V. Riera, D. Miguel, 1991 .

Second-sphere interaction of anions with a weakly binding metal complex host: probing the effect of counteranions.

J. Steed, K. M. Anderson, Julio Pérez, 2008, Dalton transactions.

Enhanced association for C70 over C60 with a metal complex with corannulene derivate ligands.

L. García-Escudero, J. Martín-Álvarez, D. Miguel, 2014, Dalton transactions.

Intramolecular carboboration of carbonyl ligands to form boroxycarbenes.

D. Miguel, R. García‐Rodríguez, C. Álvarez, 2012, Chemical communications.

Multivalent Molecular Shuttles – Effect of Increasing the Number of Centers in Switchable Catalysts

H. Barbero, D. Miguel, C. Álvarez, 2015 .

Pyrazole complexes as anion receptors: effects of changing the metal, the pyrazole substitution pattern, and the number of pyrazole ligands.

A. Rheingold, J. Golen, Julio Pérez, 2007, Inorganic chemistry.

Biimidazole and bis(amide)bipyridine molybdenum carbonyl complexes as anions receptors.

M. Mcpartlin, Dolores Morales, Julio Pérez, 2007, Inorganic chemistry.

Cationic fac-tris(pyrazole) complexes as anion receptors.

Julio Pérez, Sonia Nieto, V. Riera, 2005, Chemical communications.

Synergistic Effect of Tetraaryl Porphyrins Containing Corannulene and Other Polycyclic Aromatic Fragments as Hosts for Fullerenes. Impact of C60 in a Statistically Distributed Mixture of Atropisomers.

H. Barbero, S. Ferrero, D. Miguel, 2016, The Journal of organic chemistry.

Rhenium-mediated coupling of acetonitrile and pyrazoles. New molecular clefts for anion binding.

Julio Pérez, Sonia Nieto, D. Miguel, 2006, Inorganic chemistry.

Synthesis of (η3‐Allyl)bromodicarbonylbis(pyrazole)molybdenum(II) and Reactivity towards [Au(acac)PPh3]: Structure and Dynamic Behavior of the Monometallic Pyrazole and Heterometallic Pyrazolate Complexes

D. Miguel, F. Villafañe, Paloma Paredes, 2003 .

Metal complexes with two different hydrogen-bond donor ligands as anion hosts.

Julio Pérez, Sonia Nieto, V. Riera, 2009, Chemical communications.

Luminescent rhenium(I) tricarbonyl complexes with pyrazolylamidino ligands: photophysical, electrochemical, and computational studies.

M. Knorr, G. Ulrich, J. Martín-Álvarez, 2015, Dalton transactions.

Manganese cationic pyrazolylamidino complexes

D. Miguel, F. Villafañe, P. Gómez-Iglesias, 2008 .

Stereoselective aldol addition to rhenium(I) complexes and reversible dimerization with epimerization of the metal center.

D. Miguel, R. García‐Rodríguez, C. Álvarez, 2013, Chemistry.

pH-Driven dynamic stereoinduction: epimerization upon dimerization in rhenium(I) complexes.

D. Miguel, R. García‐Rodríguez, C. Álvarez, 2011, Chemical communications.

Seven-coordinate molybdenum-tin and tungsten-tin complexes containing phosphates and tetramethylthiourea: X-ray structure of [Mo(CO)2{P(OMe)3}3 (SnBuCl2)Cl]

S. García‐Granda, V. Riera, D. Miguel, 1993 .

Substituted seven-coordinate molybdenum-tin and tungsten-tin complexes from M(CO)6, BuSnCl3 and phosphites. X-ray structure of [Mo(CO)2{P(OMe)3}3(SnBuCl2)Cl]

S. García‐Granda, V. Riera, D. Miguel, 1991 .

Luminescent Rhenium(I)tricarbonyl Complexes Containing Different Pyrazoles and Their Successive Deprotonation Products: CO2 Reduction Electrocatalysts.

T. Torroba, J. Lloret‐Fillol, J. Martín-Álvarez, 2020, Inorganic chemistry.

New synthetic routes to cationic rhenium tricarbonyl bipyridine complexes with labile ligands.

A. Rheingold, Julio Pérez, Eva Hevia, 2002, Inorganic chemistry.

Self-Resetting Bistable Redox Molecular Machines for Fullerene Recognition

H. Barbero, D. Miguel, C. Álvarez, 2022, Organic letters.

Synthesis of the compounds [Re(CR)(CO)2(η5-C9H7)][BF4] (R = C6H4Me-4 or C6H3Me2-2,6) and the preparation of complexes with FeRe bonds

D. Miguel, F. Gordon, A. Stone, 1988 .

Octahedral Alkylidyne Complexes of Tungsten with Chelating Ligands as Precursors for Polynuclear Compounds. Crystal Structures of (W(. tplbond.CR)(CO)2(dmpe)(NCS)) and (Co2W(μ3‐CR)(CO)8(dmpe)Br) (R: C6H4Me‐4, dmpe: Me2PCH2CH2PMe2).

V. Riera, C. Bois, G. A. Carriedo, 1991 .

σ-Alkynyl complexes of manganesse as ligands. Preparation, crystal structure and reactivity of {[Co2(CO)6][μ-PhCCMn(CO)4(PCy3)]} (Cy = cyclohexyl)

V. Riera, G. A. Carriedo, D. Miguel, 1988 .

Manganese(I) carbonyls with σ-bonded alkynyl ligands. The crystal structure of [Co2 (CO)6][PhCCMn(CO)4{P(C6H11)3}]

V. Riera, G. A. Carriedo, D. Miguel, 1984 .

Molybdenum and Tungsten Tricarbonyl Complexes with the Tripodal Ligands [nBuSn(2-pyridyl)3] and [RSn(methylthiomethyl)3]

Dolores Morales, Julio Pérez, V. Riera, 2001 .

Reactivity of Indene, Fluorene, Azulene, and Acenaphthylene with a Basal-Edge-Bridged Square-Pyramidal Hexaruthenium Dihydride

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2007 .

Synthesis, Structure, and Reactivity of the Complexes Fe(η3-S2CPR3)(CO)3. Electronic Factors Affecting the Dichotomy between η2 and η3 Coordination Modes in Transition Metal Complexes of Dithiocarboxy Ligands

Agustín Galindo, C. Mealli, V. Riera, 1996 .

Trialkylphosphine-carbon disulfide adducts as eight-electron bridging ligands. X-ray structures of dimanganese complex [Mn2(CO)6(.mu.-S2CPCy3)] and [Mn2(CO)4(.mu.-S2CPCy3)(.mu.-dppm)]

Montserrat Gómez, X. Solans, V. Riera, 1991 .

Synthesis of asymmetric heterotrimetallic gold clusters containing Mo, W, and Mn

Mei Wang, Julio Pérez, V. Riera, 2003 .

Molybdenum alkynyls as alkynyl transfer reagents.

S. García‐Granda, Julio Pérez, V. Riera, 2002, Chemical communications.

A homodinuclear complex of manganese containing novel ligand, Mn2(CO)6(μ-H){μ-S(SC3H5)CC(PPr3i)S}

D. Miguel, Yongqiang Ma, Lei Yu, 2003 .

Preparation and reactivity of mono- and binuclear nitrosyl molybdenum complexes containing S2CPCy3 ligands. Crystal structure of [(OC)2(ON) Mo(μ-Br) (μ-S2CPCy3) Mo(CO)2(PEt3)]

Mei Wang, V. Riera, C. Bois, 1997 .

Nonanuclear Ruthenium Carbonyl Cluster Complexes with a Novel Metallic Skeleton: Pentagonal Bipyramid with Two Equatorial Edges Spanned by Metal Atoms

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2006 .

Reactivity of Arenes, Cycloheptatriene, and Dicyclopentadiene with a Basal Edge-Bridged Square Pyramidal Hexaruthenium Dihydride

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2006 .

Reactivity of Diphenylbutadiyne with a Hexaruthenium Dihydride. Unusual 1,1- and trans-1,2-Additions of Two Hydrogen Atoms to an Internal CC Triple Bond §

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2006 .

Reactivity of Diphenylacetylene with a Basal Edge-Bridged Square-Pyramidal Hexaruthenium Cluster. Characterization of Penta-, Hexa-, and Heptanuclear Alkyne Derivatives

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2005 .

SELECTIVE METAL TO CARBON BOND FORMATION IN THE SYNTHESIS OF THE FIRST RHENIUM COMPLEXES WITH S2CPCY3 LIGANDS. X-RAY STRUCTURES OF MNRE(CO)6(MU -S2CPC Y3) AND RE2(CO)8(MU -S2CPCY3)

S. García‐Granda, V. Riera, D. Miguel, 1991 .

The first examples of insertion of SnCl2 into the MnCl and ReCl bonds of octahedral complexes: X-ray structure of [Mn(CO)3(SnCl3)(S2CPCy3)] · CH2Cl 2

S. García‐Granda, V. Riera, D. Miguel, 1992 .

Reactivity of 8e S2CPR3 bridges with nucleophiles: formation of phosphoniodithioformate esters as novel 7e bridging ligands. X-ray structures of NEt4[Mn2(CO)6(.mu.-S2CH)] and [Mn2(CO)6(.mu.-H){.mu.-ClCH2SC(S)P(c-C6H11)3}]

S. García‐Granda, V. Riera, D. Miguel, 1991 .

A Phosphane–Dithioformate Adduct as a Five‐Electron Bridging Ligand [Mn2(CO)6{S2C(H)P(cyclo‐C6H11)3}2]

X. Solans, V. Riera, D. Miguel, 1989 .

Reversible Isomerization via Migration of SnPh3 in S2CPCy3-Bridged Heterobinuclear Compounds. X-ray Structures of [(CO)3Re(μ-S2CPCy3)Mo(SnPh3)(CO)3] and [(CO)3(Ph3Sn)Re(μ-S2CPCy3)Mo(CO)3]

Julio Pérez, V. Riera, C. Bois, 1999 .

Intramolecular Interactions Leading to Quasicubane Cages. Crystal Structure of [Mo2(NO)2(CO)4{μ-κ2;κ1-S2C(H)PCy3}2]

Mei Wang, V. Riera, C. Bois, 1998 .

Carbon−Sulfur Bond Cleavage of S2CPR3 Ligands in Dinuclear Complexes Promoted by Reduction and Protonation

S. García‐Granda, V. Riera, D. Miguel, 1998 .

Synthesis of a Tetrametallic Acetylene. X-ray Structures of [{(CO)3Mo(μ-S2CPCy3)Mn(CO)3}2- (μ4-η1:η1:η1‘:η1‘-C2)] and [[(CO)3Mo(μ-CCPh)(μ-S2CPCy3)Mn(CO)3]

T. S. Janik, D. Churchill, M. Churchill, 1998 .

Hydride Addition to Coordinated S2CPR3 Ligands in Mononuclear Mn and Re Complexes: Phosphane‐dithioformate Adducts as Five‐electron Bridging Ligands

X. Solans, V. Riera, D. Miguel, 1996 .

Reduction reactions of binuclear manganese-molybdenum complexes containing S2CPR3 and bidentate P-donor bridges. X-Ray structure of [MnMo(SnPh3)(CO)4(μ-tedip)(μ-S2CPCy3)]

S. García‐Granda, V. Riera, D. Miguel, 1995 .

DOMINATION OF ELECTRONIC FACTORS IN THE SELECTIVE METAL TO CARBON BOND FORMATION IN BINUCLEAR MANGANESE-MOLYBDENUM COMPLEXES WITH S2CPR3 BRIDGES

S. García‐Granda, V. Riera, D. Miguel, 1994 .

Areneruthenium complexes with S2CPR3 and trichlorostannate

V. Riera, D. Miguel, B. Alvarez, 1994 .

Heterodinuclear Complexes Containing S2CPR3 as Asymmetric Bridges between Cobalt and Metals of Group 7 (Manganese, Rhenium) or Group 6 (Molybdenum, Tungsten): Selective Cobalt-Carbon Bond Formation. X-ray Structures of [MnCo(CO)5(.mu.-S2CPCy3)] and [MoCo(.eta.3-C3H5)(CO)4(.mu.-S2CPCy3)].cntdot.CH2Cl

V. Riera, C. Bois, D. Miguel, 1994 .

Homo- and Heterobimetallic, Mixed Valence MII/M0 Complexes of Molybdenum and Tungsten with S2CPR3 Ligands. X-ray Structure of [(.eta.3-C3H5)(CO)2Mo(.mu.-Br)(.mu.-S2CPCy3)Mo(CO)3]

S. García‐Granda, V. Riera, D. Miguel, 1994 .

Desulfurization and carbon-carbon coupling in the reaction of the anions [MnM(CO)6(.mu.-H)(.mu.-S2CPCy3)]- (M = manganese, rhenium) with carbon disulfide. X-ray structure of [Li(THF)3][Mn2(CO)6(.mu.-H){.mu.-S(S)C:C(PCy3)S}]

S. García‐Granda, V. Riera, D. Miguel, 1994 .

Metal-metal bond formation and rearrangement of the S2CPR3 ligands in binuclear manganese-molybdenum complexes. X-ray structure of [MnMo(SnPh3)(CO)6(.mu.-S2CPPr-iso3)]

S. García‐Granda, V. Riera, D. Miguel, 1993 .

S2CPR3 adducts as binucleating ligands. Novel heterobimetallic complexes with S2CPR3 bridges of eight and six electrons. X-ray structure of [MnMo(CO)6(.mu.-Br)(.mu.-S2CPPr3-iso)] and [MnMo(CO)5(.mu.-Br)(.mu.-S2CPCy3)(.mu.-tedip)]

S. García‐Granda, V. Riera, D. Miguel, 1993 .

S2CPR3 adducts as bridging ligands in tricobalt clusters. X-Ray structure of [Co3(CO)7(μ3-CH)(μ-S2CPCy3)]

S. García‐Granda, V. Riera, D. Miguel, 1992 .

Stable Intermediates in the Addition and Elimination of SnBuCl3 at Molybdenum Centers by Cleavage or Formation of an SnCl Bond: Crystal Structure of [Mo(CO)2(PCy3)‐(μ‐Cl)(μ‐S2CPCy3)(BuSnCl2)] · CH2Cl2

S. García‐Granda, V. Riera, D. Miguel, 1992 .

The first cationic heterobinuclear complexes with bridging S2CPR3 ligands. X-ray structure of [(η6-C6Me6)Ru(μ-Cl)(μ-S2CPCy3)W(CO)3]PF6 · CH2Cl2

S. García‐Granda, V. Riera, D. Miguel, 1992 .

New bonding mode of tricyclohexylphosphoniodithiocarboxylate (S2CPCy3) as an eight-electron donor. Synthesis, reactivity, and X-ray crystal structure of [Mn2(CO)6(S2CPCy3)]

X. Solans, V. Riera, M. Font-altaba, 1987 .

Novel Heterobimetallic Complexes with S2CPR3(ϰ‐S,S′)(ϰ‐S,C, S′) Bridges. X‐Ray Structure of (MnMo(CO)6(μ‐Br)(μ‐S2CPiPr3)).

S. García‐Granda, V. Riera, D. Miguel, 1992 .

Manganese(I) Complexes with (Tricyclohexylphosphonio)dithiocarboxylate as Chelate and Unidentate Ligand. X-Ray Crystal Structure of fac-(Mn(CO)3(S2CP(C6H11)3)2)ClO4·H2O.

V. Riera, C. Bois, D. Miguel, 1988 .

Migrations of the Carbon Atom of the SC(H)PR3 Ligand in the Reduction/Protonation Processes of Heterodinuclear Mn−Re Complexes†

S. García‐Granda, V. Riera, D. Miguel, 2001 .

Coupling of η3-Allyl and Alkyne in Molybdenum Carbonyl Complexes

S. García‐Granda, V. Riera, D. Miguel, 1998 .

Improved Synthesis, Solution and Solid-State Structure, and Reactivity of (Ru2(μ-SePh)2(CO)6).

S. García‐Granda, V. Riera, D. Miguel, 1991 .

From cyclopentanone oximes to bis[1,2,3]dithiazolo-s-indacenes, cyclopenta[c][1,2]thiazine, pentathiepino-, tetrathiino-, and thienocyclopenta[1,2,3]dithiazoles as a rich source of new materials.

T. Torroba, D. Miguel, T. Rodriguez, 2005, The Journal of organic chemistry.

Affinity modulation of photoresponsive hosts for fullerenes: light-gated corannulene tweezers.

H. Barbero, S. Ferrero, D. Miguel, 2016, Chemical communications.

Thermal and Photochemical Reactions of (Ru3(CO)12) with Tetraethyldiphosphite. X-Ray Structure of (Ru3(CO)10(μ-(EtO)2POP(OEt)2)).

V. Riera, D. Miguel, J. A. Cabeza, 1990 .

Synthesis of manganese(I) carbonyls with σ-bonded alkynyl ligands

V. Riera, D. Miguel, 1985 .

Chemical constituents from Terminalia glabrescens

D. Miguel, W. Garcez, F. Garcez, 2003 .

Second-sphere coordination complexes via hydrogen bonding: Synthesis, characterization of [Co(NH3)6](XO3)3·nH2O (X=Br, I) and single crystal X-ray structure determination of [Co(NH3)6](BrO3)3·0.5H2O

Julio Pérez, D. Miguel, Rajender Sharma, 2006 .

1,4‐Thiazepines, 1,4‐Benzothiazepin‐5‐ones, and 1,4‐Benzothioxepin Orthoamides via Multicomponent Reactions of Isocyanides.

T. Torroba, M. García-Valverde, S. Marcaccini, 2003 .

Synthesis of thiadiazole, dithietane, and imine derivatives of the [1,2]dithiolo[1,4]thiazine ring system.

T. Torroba, O. Rakitin, D. Miguel, 2001, The Journal of organic chemistry.

The first structurally characterized acetanilidocomplex of palladium (II) and the maximum hardness principle. A sample of trans choice in square-planar complexes

J. Cuevas, G. García-Herbosa, D. Miguel, 2002 .

Palladium Complexes with the Tridentate Dianionic Ligand Pyridine-2,6-dicarboxylate, dipic. Crystal Structure of [Pd(dipic)(PBu(3))](2).

S. García‐Granda, P. Espinet, D. Miguel, 1996, Inorganic chemistry.

A new addition-rearrangement of [1,4]thiazine-2-thiones with aryl-1,2,4-triazoline-3,5-diones

T. Torroba, D. Miguel, N. García, 2003 .

Formation of a 1-azaallenylidene ligand by reaction of an amido complex with tetracyanoethylene.

Dolores Morales, Julio Pérez, V. Riera, 2002, Inorganic chemistry.

Unexpected chemoselectivity in the Schiff condensation of amines with eta(2)(C,O)- eta(1)(O)-coordinated aldehyde.

D. Miguel, R. García‐Rodríguez, C. Álvarez, 2010, Dalton Transactions.

New octahedral rhenium(I) tricarbonyl amido complexes

Julio Pérez, Eva Hevia, V. Riera, 2002 .

Different sites of insertion in the reaction of isocyanates with [Re(N(R)Ar)(CO)3(bipy)] (R = H or Me): N-H vs. Re-N.

Julio Pérez, Eva Hevia, V. Riera, 2002, Chemical communications.

Cation- and Anion-Mediated Supramolecular Assembly of Bismuth and Antimony Tris(3-pyridyl) Complexes

D. Wright, D. Miguel, C. Álvarez, 2021, Inorganic chemistry.

Second-sphere interaction of anions with a weakly binding metal complex host: probing the effect of counteranions.

J. Steed, K. M. Anderson, Julio Pérez, 2008, Dalton transactions.

Reactivity of molybdenum and rhenium hydroxo complexes toward organic electrophiles: reactions that afford carboxylato products

Dolores Morales, Julio Pérez, Eva Hevia, 2006 .