J. A. Cabeza

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A Germylene Supported by Two 2-Pyrrolylphosphane Groups as Precursor to PGeP Pincer Square-Planar Group 10 Metal(II) and T-Shaped Gold(I) Complexes.

Israel Fernández, J. A. Cabeza, J. Fernández-Colinas, 2019, Chemistry.

Reactions of phthalazine, quinazoline, 4,7-phenanthroline and 2,3'-bipyridine with ruthenium carbonyl.

J. A. Cabeza, Vanessa Pruneda, 2012, Dalton transactions.

QTAIM analysis of the bonding in Mo-Mo bonded dimolybdenum complexes.

J. A. Cabeza, J. F. Van der Maelen, Javier A. Cabeza, 2012, Inorganic chemistry.

Dichlorobis[(S)-2,3,5,6-tetrahydro-6-phenylimidazo[2,1-b]thiazole]nickel(II)

S. García‐Granda, I. D. Rı́o, J. A. Cabeza, 2005 .

Deprotonation of C-alkyl groups of cationic triruthenium clusters containing cyclometalated C-alkylpyrazinium ligands: experimental and computational studies.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2013, Chemistry.

Reactivity of a Bis(N-heterocyclic carbene) with Ruthenium Carbonyl. Synthesis of Mono- and Trinuclear Derivatives and Ligand Modification via C–H Bond Activation

J. A. Cabeza, E. Pérez-Carreño, M. Damonte, 2012 .

Activation of two C-H bonds of NHC N-methyl groups on triosmium and triruthenium carbonyl clusters.

D. Miguel, J. A. Cabeza, E. Pérez-Carreño, 2008, Dalton transactions.

Reactivity of a triruthenium alkenyl cluster complex with conjugated diynes : Coupling of two diyne molecules via a face-capping diyne intermediate

I. D. Rı́o, J. A. Cabeza, E. Pérez-Carreño, 2008 .

Reactions of μ3‐Alkenyl Triruthenium Carbonyl Clusters with Alkynes: Synthesis of Trinuclear μ‐//‐Alkyne, μ‐Vinylidene, and μ‐Dienoyl Derivatives

I. D. Rı́o, J. A. Cabeza, E. Pérez-Carreño, 2006 .

Reactivity of alkynes containing alpha-hydrogen atoms with a triruthenium hydrido carbonyl cluster: alkenyl versus allyl cluster derivatives.

S. García‐Granda, J. A. Cabeza, E. Pérez-Carreño, 2005, Chemistry.

Edge-bridging and face-capping coordination of alkenyl ligands in triruthenium carbonyl cluster complexes derived from hydrazines: synthetic, structural, theoretical, and kinetic studies.

S. García‐Granda, J. A. Cabeza, E. Pérez-Carreño, 2004, Chemistry.

Deprotonation of C-alkyl groups of cationic N-heterocyclic ligands.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2012, Dalton transactions.

Hexaruthenium and octaruthenium carbonyl cluster complexes derived from 2-amino-6-methylpyridine : Novel coordination modes for 2-imidopyridines

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2006 .

Dipyrromethane‐Based PGeP Pincer Methylgermyl and Methoxidogermyl Nickel and Palladium Complexes

J. A. Cabeza, P. García‐Álvarez, Carlos J. Laglera‐Gándara, 2021 .

Reactivity of the 1-azavinylidene cluster [Ru3(μ-H)(μ-NCPh2)(CO)10] with hydrogen, tertiary silanes and tertiary stannanes

V. Riera, C. Bois, J. A. Cabeza, 1998 .

Reactivity studies on cationic non-hydridic triruthenium carbonyl clusters. Reactions of [Ru3(μ3-ampy)(CO)10][BF4] with hydrogen, triethylsilane and triphenylstannane

I. D. Rı́o, V. Riera, J. A. Cabeza, 1998 .

Reactivity of a 1-Azavinylidene Ligand with Diphenylacetylene on a Ruthenium Carbonyl Cluster. A Remarkable Alkyne Insertion into a Metal−Nitrogen Bond

I. D. Rı́o, V. Riera, J. A. Cabeza, 1997 .

Reactivity of Amidinatosilylenes and Amidinatogermylenes with [PtMe2(η4-cod)]: cis- versus trans-[PtMe2L2] Complexes and Cyclometalation Reactions

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2020 .

[MnBrL(CO)4] (L = Amidinatogermylene): Reductive Dimerization, Carbonyl Substitution, and Hydrolysis Reactions

R. Gobetto, C. Nervi, J. A. Cabeza, 2016 .

Ruthenium-cluster-mediated activation of all bonds of a methyl group of 6,6'-dimethyl-2,2'-bipyridine and 2,9-dimethyl-1,10-phenanthroline: transformation of the latter into a 2-alkenyl-9-methyl-1,10-phenanthroline ligand.

D. Miguel, J. A. Cabeza, I. del Río, 2006, Chemistry.

Easy activation of two C-H bonds of an N-heterocyclic carbene N-methyl group.

D. Miguel, J. A. Cabeza, M. Sánchez-Vega, 2005, Chemical communications.

Reaction of [Ru3(CO)12] with Phenazine: Synthesis of C-Metalated Derivatives That Formally Arise from a C–H Oxidative Addition or a Long-Distance C-to-N Prototropy

J. A. Cabeza, P. García‐Álvarez, Vanessa Pruneda, 2012 .

Liquid Crystal Derivatives of Transition Metals (I): Tetracoordinated Copper (II) Complexes Derived From Schiffs Bases

J. Serrano, L. Oro, P. Romero, 1989 .

Two Types of σ-Allenyl Complexes from Reactions of Silylenes and Germylenes with Chromium Fischer Alkynyl(alkoxy)carbenes.

M. Gómez-Gallego, M. Sierra, Alba D Merinero, 2019, Chemistry.

The transition-metal chemistry of amidinatosilylenes, -germylenes and -stannylenes

J. A. Cabeza, P. García‐Álvarez, D. Polo, 2015 .

Reactivity of [Ru-3(CO)(12)] with a phosphine-functionalized Imidazol-2-ylidene and Its imidazolium salt

A. Kennedy, J. A. Cabeza, P. García‐Álvarez, 2011 .

Easy abstraction of a hydride anion from an alkyl C-H bond of a coordinated bis(N-heterocyclic carbene).

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2013, Chemical communications.

Intramolecularly Stabilized Heavier Tetrylenes: From Monodentate to Bidentate Ligands

J. A. Cabeza, P. García‐Álvarez, D. Polo, 2016 .

Ring opening and bidentate coordination of amidinate germylenes and silylenes on carbonyl dicobalt complexes: the importance of a slight difference in ligand volume.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2014, Chemistry.

Reactivity of a (bis-NHC)tricarbonylruthenium(0) complex with methyl triflate and methyl iodide. Formation of methyl- and acetylruthenium(II) derivatives: Experimental results and mechanistic DFT calculations

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2013 .

Synthesis and reactivity of cationic triruthenium clusters derived from 2-methyl- and 4-methylpyrimidines: from conventional cyclometalated ligands to novel types of N-heterocyclic carbenes.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2013, Chemistry.

The N-heterocyclic carbene chemistry of transition-metal carbonyl clusters.

J. A. Cabeza, P. García‐Álvarez, Javier A. Cabeza, 2011, Chemical Society reviews.

Reductive dimerization of triruthenium clusters containing cationic aromatic N-heterocyclic ligands.

J. A. Cabeza, E. Pérez-Carreño, Vanessa Pruneda, 2010, Chemistry.

Reactivity of a Quinoline-Tethered N-Heterocyclic Carbene with Polynuclear Ruthenium Carbonyls

J. A. Cabeza, E. Pérez-Carreño, M. Damonte, 2012 .

Reactivity of [Ru4(μ-H)4(CO)12] with bidentate ligands containing at least one N-heterocyclic carbene moiety

J. A. Cabeza, M. Damonte, M. G. Hernández-Cruz, 2012 .

Reactivity of Phosphine- and Thioether-Tethered N-Heterocyclic Carbenes with Ruthenium Carbonyl

A. Kennedy, J. A. Cabeza, P. García‐Álvarez, 2012 .

Different Reactivities of Pyrid-2-yl- and 6-Picol-2-yl-Functionalized NHC Ligands with [Ru3(CO)12]: C(sp2)−H and Double C(sp3)−H Bond Activation Reactions

J. A. Cabeza, P. García‐Álvarez, M. Damonte, 2011 .

Triruthenium and triosmium carbonyl clusters containing chiral bidentate NHC-thiolate ligands derived from levamisole.

I. da Silva, J. A. Cabeza, M. Sánchez-Vega, 2006, Dalton transactions.

Synthesis of mixed tin-ruthenium and tin-germanium-ruthenium carbonyl clusters from [Ru3(CO)12] and diaminometalenes (M = Sn, Ge).

J. A. Cabeza, P. García‐Álvarez, D. Polo, 2012, Inorganic chemistry.

Reactivity of diaminogermylenes with ruthenium carbonyl: Ru3Ge3 and RuGe2 derivatives.

J. A. Cabeza, P. García‐Álvarez, D. Polo, 2011, Inorganic chemistry.

Synthesis and some coordination chemistry of the PSnP pincer-type stannylene Sn(NCH2PtBu2)2C6H4, attempts to prepare the PSiP analogue, and the effect of the E atom on the molecular structures of E(NCH2PtBu2)2C6H4 (E = C, Si, Ge, Sn).

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2018, Dalton transactions.

Amidinatogermylene Metal Complexes as Homogeneous Catalysts in Alcoholic Media

J. A. Cabeza, P. García‐Álvarez, J. Fernández‐Colinas, 2016 .

Amidinatogermylene derivatives of ruthenium carbonyl: new insights into the reactivity of [Ru3(CO)12] with two-electron-donor reagents of high basicity.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2015, Inorganic chemistry.

PROTONATION OF TRIRUTHENIUM CARBONYL CLUSTER COMPLEXES CONTAINING A BRIDGING 1-AZAVINYLIDENE LIGAND. EXPERIMENTAL RESULTS AND EHMO CALCULATIONS

D. Ardura, I. D. Rı́o, V. Riera, 1998 .

Crystallographic report: [N,N′‐Bis‐(6‐methylpyrid‐2‐ylium)‐(1R,2R)‐1,2‐diaminocyclohexane] bis‐[(p‐cymene)‐ trichlororuthenate(II)]

S. García‐Granda, I. D. Rı́o, J. A. Cabeza, 2005 .

Reactions of CS2 and C(S)NPh Adducts of N-Heterocyclic Carbenes with [Ru3(CO)12]: Remarkable Reactivity of These Betaines Involving One or Two C–S Bond Activation Processes

J. A. Cabeza, P. García‐Álvarez, M. G. Hernández-Cruz, 2012 .

The cyclometallation of benzoic acid to give rhodium, iridium, and osmium C,O-benzoates. X-Ray structure determination of the dibenzoate [(C5Me5)Rh(OOCPh)2(H2O)]

H. Adams, J. Kisenyi, Glenn J. Sunley, 1987 .

Reactivity of [Os3(μ-H)2(CO)10] with N-Heterocyclic carbenes: A combined experimental and DFT computational study

I. D. Rı́o, D. Vázquez-García, J. A. Cabeza, 2010 .

Cyclometallation of Heavier Tetrylenes: Reported Complexes and Applications in Catalysis

J. A. Cabeza, P. García‐Álvarez, 2021, European Journal of Inorganic Chemistry.

Mesityl(amidinato)tetrylenes as ligands in iridium(i) and iridium(iii) complexes: silicon versus germanium and simple κ1-coordination versus cyclometallation.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2019, Dalton transactions.

Facile cyclometallation of a mesitylsilylene: synthesis and preliminary catalytic activity of iridium(iii) and iridium(v) iridasilacyclopentenes.

J. A. Cabeza, P. García‐Álvarez, Laura González-Álvarez, 2017, Chemical communications.

New biimidazole and bibenzimidazole derivatives: mono and binuclear palladium(II) or platinum(II) complexes and heterobinuclear palladium(II)-rhodium(I) or platinum(II)-rhodium(I) complexes

L. Oro, R. Usón, J. A. Cabeza, 1983 .

Gold(I) and platinum(II) azolates as ligands in cationic Rhodium(I) complexes

L. Oro, M. Ciriano, R. Usón, 1981 .

Mononuclear η6-p-cymeneosmium(II) complexes and their reactions with Al2Me6 and other methylating reagents

P. Maitlis, J. A. Cabeza, Javier A. Cabeza, 1985 .

Unexpected Zwitterionic Allenyls from Silylenes and a Fischer Alkynylcarbene: A Remarkable Silylene-Promoted Rearrangement.

M. Gómez-Gallego, M. Sierra, Alba D Merinero, 2019, Chemistry.

Dinuclear Methoxy, Cyclooctadiene, and Barrelene Complexes of Rhodium(I) and Iridium(I)

L. Oro, R. Usón, J. A. Cabeza, 2007 .

Alternative Conceptual Approach to the Design of Bifunctional Catalysts: An Osmium Germylene System for the Dehydrogenation of Formic Acid

Miguel A. Esteruelas, E. Oñate, J. A. Cabeza, 2021, Inorganic chemistry.

The Transition Metal Chemistry of PGeP and PSnP Pincer Heavier Tetrylenes

J. A. Cabeza, P. García‐Álvarez, Carlos J. Laglera‐Gándara, 2020, European Journal of Inorganic Chemistry.

Octahedral manganese(i) and ruthenium(ii) complexes containing 2-(methylamido)pyridine-borane as a tripod κ3N,H,H-ligand.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2017, Dalton transactions.

Amidinatogermylene Complexes of Copper, Silver, and Gold

J. A. Cabeza, P. García‐Álvarez, D. Polo, 2015 .

Reactivity Studies on a Binuclear Ruthenium(0) Complex Equipped with a Bridging κ(2)N,Ge-Amidinatogermylene Ligand.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2015, Inorganic chemistry.

Mononuclear ruthenium complexes containing chiral aminooxazolines: Syntheses, X-ray studies and catalytic activity

Robert A. Gossage, I. D. Rı́o, D. Miguel, 2007 .

Synthesis and reactivity of mono-, tri-, and poly-nuclear ruthenium carbonyl complexes containing the pyridine-2-thiolate ligand (pyS). Stepwise preparation of [Ru(pyS)2(CO)2] by reaction of [Ru3(CO)12] with pyridine-2-thiol

V. Riera, J. A. Cabeza, J. Fernández‐Colinas, 1990 .

The different reactivity of 2-aminopyridines and 2-pyridone with [Ru3(CO)12]. X-Ray crystal structure of [Ru3(µ-H)(µ3-anpy)(CO)9](hanpy = 2-anilinopyridine)

V. Riera, D. Miguel, J. A. Cabeza, 1990 .

The Important Role of Some Ancillary Ligands in the Chemistry of Carbonylmetal Cluster Complexes Selected Reactivity of Triruthenium Clusters Containing Deprotonated 2-Aminopyridines

J. A. Cabeza, 2002 .

Formation of cyclopentadienyl and ruthenacyclopentadienyl derivatives through ynenyl-diyne and ynenyl-alkyne couplings onto a triruthenium cluster core.

S. García‐Granda, J. A. Cabeza, N. Lugan, 2001, Chemistry.

Synthesis, structure and hydrogenation catalytic activity of [Ru3(μ3,η2-ampy)(μ,η1:η2-PhCCHPh)(CO)6(PPh3) (Hampy = 2-amino-6-methylpyridine)

L. Ouahab, V. Riera, J. A. Cabeza, 1994 .

Synthesis and reactivity of triruthenium carbonyl clusters containing bis(diphenylphosphino)methane and the face-bridging ligand 2-amido-6-methylpyridi

V. Riera, J. A. Cabeza, P. Andreu, 1992 .

Hydrogenation activity of [Ru3(μ-H)-(μ3-ampy)(CO)9] under homogeneous conditions (Hampy = 2-amino-6-methylpyridine)

V. Riera, J. A. Cabeza, A. Llamazares, 1992 .

Triruthenium carbonyl clusters derived from chiral aminooxazolines: synthesis and catalytic activity.

I. da Silva, Robert A. Gossage, D. Miguel, 2006, Dalton transactions.

From a Diphosphanegermylene to Nickel, Palladium, and Platinum Complexes Containing Germyl PGeP Pincer Ligands.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2017, Chemistry.

Synthesis and initial transition metal chemistry of the first PGeP pincer-type germylene.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2017, Chemical communications.

The reactions of the tri-µ-hydroxo-bis[η6-p-cymeneosmium(II)] cation with aldehydes and acids and the homogeneously catalysed oxidation of acetaldehyde and propionaldehyde with water. X-Ray structure of [(p-MeC6H4CHMe2)2Os2(µ-HCO2)(µ-OH)(µ-H)][PF6]

H. Adams, P. Maitlis, Arnold J. Smith, 1986 .

Di- and Trinuclear Ruthenium and Osmium Bis(2-pyridyl) Ketone Oximate Derivatives

C. Alvarez-Rúa, S. García‐Granda, J. Hwu, 2003 .

A Z-type PGeP pincer germylene ligand in a T-shaped palladium(0) complex.

J. A. Cabeza, P. García‐Álvarez, Carlos J. Laglera‐Gándara, 2020, Chemical communications.

A dipyrromethane-based diphosphane-germylene as precursor to tetrahedral copper(i) and T-shaped silver(i) and gold(i) PGeP pincer complexes.

Israel Fernández, J. A. Cabeza, P. García‐Álvarez, 2019, Dalton transactions.

Ruthenium(I) complexes containing bridging N-donor ligands: structure, synthesis and reactivity patterns

J. A. Cabeza, J. Fernández‐Colinas, Javier A. Cabeza, 1993 .

Organic Amides as Suitable Precursors to Stabilize Stannylenes

J. A. Cabeza, P. García‐Álvarez, D. Polo, 2013 .

Fully Borylated Methane and Ethane by Ruthenium-Mediated Cleavage and Coupling of CO.

Zhenyang Lin, A. Batsanov, M. Crestani, 2016, Angewandte Chemie.

The cyclometallation of benzoic acid and the X-ray crystal structure of [C5Me5Ir(O2CC6H4)(Me2SO)]

H. Adams, J. Kisenyi, Glenn J. Sunley, 1985 .

Cationic heterocycles as ligands: synthesis and reactivity with anionic nucleophiles of cationic triruthenium clusters containing C-metalated N-methylquinoxalinium or N-methylpyrazinium ligands.

J. A. Cabeza, E. Pérez-Carreño, Vanessa Pruneda, 2009, Chemistry.

A topological analysis of the bonding in [M2(CO)10] and [M3(μ-H)3(CO)12] complexes (M = Mn, Tc, Re)

J. A. Cabeza, J. F. V. D. Maelen, Javier A. Cabeza, 2016, Theoretical Chemistry Accounts.

Synthesis and Reactivity of Triruthenium Carbonyl Cluster Complexes Containing a Bridging 1-Azavinylidene Ligand Derived from Benzophenone Imine †

V. Riera, C. Bois, J. A. Cabeza, 1996 .

Extensive substitution, protonation, and methoxidation reactions of triruthenium carbonyl clusters containing 2-amino-6-methylpyridinato (.mu.3-ampy) as a face-bridging ligand. X-ray structures of [Ru3(.mu.-H)(.mu.3-ampy)(CO)7(PPh3)2] and [Ru3(.mu.-H)2(.mu.3-ampy)(CO2Me)(CO)6(PPh3)2].cntdot.MeOH

M. Pellinghelli, V. Riera, J. A. Cabeza, 1991 .

The addition of protons and metallic electrophiles to the electron-rich RuRu bond of [Ru2(μ,-dan)(CO)4(PiPr3)2]. X-ray structure of [Ru2(μ-AgPPh3)(μ-dan)(CO)4(PiPr3)2][BF4]·CH2Cl2 (dan=1,8-diamidonaphthalene)

S. García‐Granda, V. Riera, J. A. Cabeza, 1991 .

Protonation and deprotonation reactions of triruthenium nona- and octa-carbonyl clusters containing a µ3-2-amido-6-methylpyridine (µ3-ampy) ligand. X-Ray structures of [Ru3(µ-H)2(µ3-ampy)(CO)9][BF4] and of one of the two isolated isomers of [Ru3(µ-H)2(µ3-ampy)(CO)8(PPh3)][BF4]

V. Riera, C. Bois, J. A. Cabeza, 1990 .

Selective insertion of mercury(II) halides into the ruthenium–mercury bonds of trinuclear Ru2Hg clusters

S. García‐Granda, V. Riera, J. A. Cabeza, 1991 .

A new coordination mode for (pyrid-2-yl)thiolate (L) ligands: Synthesis and characterization of [Ru6(μ3-H)(μ5-κ2-L)(μ-CO)(CO)15]

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2007 .

Reactivity of 2‐(Diphenylphosphanyl)thiophenol (HSC6H4PPh2) with Ruthenium and Osmium Carbonyl Complexes; Breaking of HSC6H4PPh2 into Sulfide, Phenyl and Diphenylphosphanyl Ligands on a Triruthenium Cluster

S. García‐Granda, D. Ardura, V. Riera, 2000 .

Reversible Thermal Activation of a Triphenylphosphine P−C Bond on a Cationic Non-Hydridic Triruthenium Carbonyl Cluster Complex. Structural Characterization of a μ-η1:η2-Benzoyl Derivative

V. Riera, J. A. Cabeza, A. Río, 1997 .

Reactivity of [Ru3(μ-H)(μ-Me2pz)(CO)10] with 2,4-hexadiyne. Characterization of the first tetranuclear ynenyl complex

V. Riera, J. A. Cabeza, M. Rosales-Hoz, 2001 .

Reactivity of Diynes with a 1-Azavinylidene-Bridged Triruthenium Carbonyl Cluster. Insertion Reactions of Diynes into Ru−H, Ru−C, and Ru−N Bonds

F. Grepioni, V. Riera, J. A. Cabeza, 2000 .

Neutral and cationic diphenylphosphine and diphenylphosphido derivatives of a trinuclear ruthenium carbonyl cluster containing a bridging 1-azavinylidene ligand

I. D. Rı́o, V. Riera, J. A. Cabeza, 1997 .

Neutral and anionic pyrazolyl-bridged triruthenium carbonyl cluster complexes. Reactions with bis(diphenylphosphino) methane, triphenylphosphine and diphenylphosphine

I. D. Rı́o, V. Riera, J. A. Cabeza, 1996 .

Synthesis and reactivity of diphenylphosphine derivatives of [Ru3(μ-H)(μ3-ampy)(CO)9] and [Ru3(μ-H)2(μ3-ampy)(CO)9][BF4] (Hampy=2-amino-6-methylpyridine)

V. Riera, J. A. Cabeza, P. Andreu, 1991 .

Diphenylphosphine and diphenylphosphido derivatives of [Ru3(μ-H)(μ3-ampy)(CO)9] (Hampy = 2-amino-6-methylpyridine)

V. Riera, J. A. Cabeza, P. Andreu, 1990 .

Synthesis, characterization, reactivity, and catalytic hydrogenation activity of the hexanuclear hexahydrido carbonyl cluster compound [Ru6(μ-H)60(μ3,ν2-ampy)2(CO)14 ] (Hampy = 2-amino-6-methylpyridine)

I. D. Rı́o, V. Riera, J. A. Cabeza, 1995 .

A simple preparation of pyridine-derived N-heterocyclic carbenes and their transformation into bridging ligands by orthometalation.

D. Vázquez-García, J. A. Cabeza, E. Pérez-Carreño, 2009, Angewandte Chemie.

Reactivity of N-Heterocyclic Carbenes with [Ru3(CO)12] and [Os3(CO)12]. Influence of Ligand Volume and Electronic Effects

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2008 .

Tri- and binuclear ruthenium carbonyl complexes containing bridging ligands derived from ortho-substituted anilines. A comparative study of their syntheses using RuCl3 · nH2O or [Ru3(CO)12] as starting materials

S. García‐Granda, V. Riera, J. A. Cabeza, 1996 .

Homogeneous Hydrogenation of Diphenylacetylene Promoted by a Cationic Hydridoalkenyltriruthenium Cluster Complex. Kinetic Evidence for Cluster Catalysis

I. D. Rı́o, V. Riera, J. A. Cabeza, 1996 .

Incorporation of silanes and diphenylacetylene into face-bridged triruthenium carbonyl clusters. Attempted hydrosilylation of diphenylacetylene

S. García‐Granda, V. Riera, J. A. Cabeza, 1993 .

Synthesis and structural characterization of triruthenium cluster complexes containing bridging .eta.1-phenyl and terminal .eta.1-phenyl ligands arising from the cleavage of triphenylphosphine ligands

L. Ouahab, V. Riera, J. A. Cabeza, 1993 .

Incorporation of trialkylsilyl and trialkylstannyl groups into ruthenium carbonyl clusters. Carbonyl substitution versus trialkylsilane or trialkylstannane elimination in these clusters

L. Ouahab, V. Riera, J. A. Cabeza, 1992 .

Selective carbonyl substitution reactions on [Ru3(μ-H)(μ3-ampy)(CO)9] and on its protonated derivative. Crystal structure of [Ru3(μ-H)2(μ3-ampy)(CO)9][BF4] (Hampy = 2-amino-6-methylpyridine)

V. Riera, C. Bois, J. A. Cabeza, 1990 .

The thermal and photochemical reactions of [Ru3(CO)12] with tetraethyldiphosphite. X-ray structure of [Ru3(CO)10{μ-(EtO)2POP(OEt)2}]

V. Riera, D. Miguel, J. A. Cabeza, 1990 .

Reactivity of the Anionic Carbonyltrirhenium Cluster [Re3(µ-H)3(µ3-ampy)(CO)9]− − Synthesis of Neutral Phosphane and Alkenyl Derivatives

F. Grepioni, Rajiv Trivedi, V. Riera, 2000 .

From an N-methyl N-heterocyclic carbene to carbyne and carbide ligands via multiple C-H and C-N bond activations.

D. Miguel, J. A. Cabeza, M. Sánchez-Vega, 2008, Angewandte Chemie.

Synthesis and characterization of a tetraruthenium butterfly cluster containing a quadruply-bridging ligand derived from an N,N′-dipyrid-2-ylurea

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2007 .

Molecular clusters in homogeneous catalysis : kinetic and chemical evidence for the participation of triruthenium cluster complexes in a cluster-promoted catalytic hydrogenation of diphenylacetylene

V. Riera, J. A. Cabeza, A. Llamazares, 1993 .

Neutral Binuclear and Anionic Trinuclear Rhenium Carbonyl Complexes Containing Bridging Ligands Derived from 2-Amino- and 2-Mercaptopyridines

F. Grepioni, Rajiv Trivedi, V. Riera, 1998 .

Carbonyl Metal Clusters as Homogeneous Catalysts: Hydrogenation of Alkynes Mediated by Hydridotriruthenium Clusters Containing Bridging N-Donor Ligands

J. A. Cabeza, A. Llamazares, J. Fernández‐Colinas, 1995 .

Dicationic tetranuclear tetrahydrides of iridium, ruthenium, and osmium

P. Maitlis, B. Mann, C. Brevard, 1986 .

Pyrazolate bridged ruthenium(I) complexes. A convenient synthesis of ruthenium(I) compounds. The X-ray structure of bis-μ-(3,5-dimethylpyrazolate)bis(tricarbonyl-ruthenium(I)) (RuRu)

L. Oro, J. A. Cabeza, A. Tiripicchio, 1987 .

Hexaruthenium carbonyl cluster complexes with basal edge-bridged square pyramidal metallic skeleton: efficient synthesis of 2-imidopyridine derivatives and determination of their reactive sites in carbonyl substitution reactions.

V. Riera, D. Miguel, J. A. Cabeza, 2004, Inorganic chemistry.

Activation of all bonds of a methyl group attached to an organic fragment.

I. da Silva, V. Riera, D. Miguel, 2004, Angewandte Chemie.

Reactions of Conjugated Dienes with a Triruthenium Hydrido Carbonyl Cluster: Synthesis and Reactivity of Trinuclear Derivatives Having an Edge-Bridging Allyl Ligand

I. D. Rı́o, J. A. Cabeza, E. Pérez-Carreño, 2008 .

Carbonyl Metal Clusters as Homogeneous Catalysts: Hydrogenation of Alkynes Mediated by Hydridotriruthenium Clusters Containing Bridging N- Donor Ligands

J. A. Cabeza, A. Llamazares, J. Fernández‐Colinas, 2010 .

Reactivity of [Re3(μ-H)3(μ3-ampy)(CO)9]-. Preparation of Heteronuclear Re3Au Carbonyl Cluster Complexes Containing Face-Capping and Edge-Bridging Gold Atoms

F. Grepioni, Rajiv Trivedi, J. A. Cabeza, 2000 .

Expanding the coordination chemistry of donor-stabilized group-14 metalenes.

J. A. Cabeza, P. García‐Álvarez, D. Polo, 2013, Dalton transactions.

Diaminogermylene and diaminostannylene derivatives of gold(I): novel AuM and AuM2 (M = Ge, Sn) complexes.

J. A. Cabeza, P. García‐Álvarez, J. Fernández‐Colinas, 2012, Inorganic chemistry.

Improved synthesis, solution and solid-state structure, and reactivity of [Ru2(µ-SePh)2(CO)6]

S. García‐Granda, V. Riera, D. Miguel, 1991 .

Reactivity of [Ru4(μ-H)4(CO)12] with N-Heterocyclic Carbenes

I. D. Rı́o, D. Vázquez-García, J. A. Cabeza, 2009 .

Reactivity of Protons, Tertiary Stannanes, and Alkynes with a Triruthenium Dihydrido Cluster Containing a Face-Capping NHC Ligand

I. D. Rı́o, J. A. Cabeza, M. Sánchez-Vega, 2009 .

Facile C−S Bond Activation of Levamisole Hydrochloride on a Triruthenium Cluster Core

S. García‐Granda, I. D. Rı́o, V. Riera, 2002 .

Reversible Carbene Insertion into a Ge-N Bond and Insights into CO and Carbene Substitution Reactions Involving Amidinatogermylenes and Fischer Carbene Complexes.

M. Gómez-Gallego, M. Sierra, Alba D Merinero, 2018, Chemistry.

Trapping of Pyrid-2-ylidenes by [Ru3(CO)12]: Orthometalated Pyrid-2-ylidenes in Triruthenium Clusters

I. D. Rı́o, D. Vázquez-García, J. A. Cabeza, 2010 .

Mercury-bridged transition-metal clusters. Synthesis of pentanuclear Ru3HgM (M Mo, W, or Co) clusters and X-ray structure of [(Ru3(μ3,η2-ampy)(CO)9)-(μ3-Hg)Co(CO)4] (Hampy 2-amino-6-methylpyridine)

S. García‐Granda, V. Riera, J. A. Cabeza, 1992 .

Mercury—ruthenium mixed-metal carbonyl clusters containing 2-amido-6-methylpyridine (ampy) as a μ3,η2-ligand. Crystal structures of [Ru6(μ4-Hg)(μ3-ampy)2(CO)18]·2C4H8O and [Ru3(μ-HgBr)(μ3-ampy)(CO)9]

V. Riera, C. Bois, J. A. Cabeza, 1991 .

Rhodium(I) and rhodium(III) arene complexes with N-carbazolyltriphenylphosphinegold(I) and other polycyclic arene ligands

L. Oro, R. Usón, J. A. Cabeza, 1984 .

Photolysis of diruthenium hexacarbonyl tetrahedrane compounds in Nujol glass matrices

T. Bitterwolf, J. A. Cabeza, 2004 .

Derivative Chemistry of [Ru2(μ-bdt)(CO)6], a Binuclear Ruthenium(I) Carbonyl Complex Containing a Bridging Benzene-1,2-dithiolate Ligand

S. García‐Granda, D. Ardura, V. Riera, 1999 .

Synthesis and reactions with electrophiles and nucleophiles of the ruthenium(I) complex [Ru2(µ-C10H8N2)(CO)6]. Crystal structure of [Ru2(µ-C10H8N2)(CO)4{P(OPh)3}2](C10H10N2= 1,8-diaminonaphthalene)

M. Pellinghelli, V. Riera, J. A. Cabeza, 1991 .

IR studies and hydrogenation catalytic activity of heterogeneous catalysts prepared by thermal treatments of a face-bridged triruthenium carbonyl cluster supported on silica and alumina

A. Théolier, J. A. Cabeza, J. Fernández‐Colinas, 1995 .

Reactivity of Indene, Fluorene, Azulene, and Acenaphthylene with a Basal-Edge-Bridged Square-Pyramidal Hexaruthenium Dihydride

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2007 .

Triosmium carbonyl complexes containing bridging ligands derived from ortho-functionalized anilines

S. García‐Granda, D. Ardura, V. Riera, 1996 .

Theoretical topological analysis of the electron density in a series of triosmium carbonyl clusters

S. García‐Granda, J. A. Cabeza, J. F. V. D. Maelen, 2011 .

Reactions of [Ru2{μ-1,2-(NH)2C6H4}(CO)4(PPh3)2] with H+, NO+ and group 11 metal fragments. Syntheses of trinuclear Ru2M (M = Cu, Ag, Au) and pentanuclear Ru4Au clusters

V. Riera, J. A. Cabeza, A. Anillo, 1990 .

Conversion of a monodentate amidinate-germylene ligand into chelating imine-germanate ligands (on mononuclear manganese complexes).

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2014, Inorganic chemistry.

Hexaruthenium cluster complexes of basal edge-bridged square pyramidal metallic skeleton. First efficient synthesis and reactivity studiesElectronic supplementary information (ESI) available: synthetic procedures and complete spectroscopic and analytical data for all new compounds; experimental deta

J. A. Cabeza, I. Ro, S. Garca-Granda, 2003 .

Nonanuclear Ruthenium Carbonyl Cluster Complexes with a Novel Metallic Skeleton: Pentagonal Bipyramid with Two Equatorial Edges Spanned by Metal Atoms

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2006 .

Reactivity of Arenes, Cycloheptatriene, and Dicyclopentadiene with a Basal Edge-Bridged Square Pyramidal Hexaruthenium Dihydride

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2006 .

Reactivity of Diphenylbutadiyne with a Hexaruthenium Dihydride. Unusual 1,1- and trans-1,2-Additions of Two Hydrogen Atoms to an Internal CC Triple Bond §

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2006 .

Reactivity of Diphenylacetylene with a Basal Edge-Bridged Square-Pyramidal Hexaruthenium Cluster. Characterization of Penta-, Hexa-, and Heptanuclear Alkyne Derivatives

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2005 .

Triruthenium, Hexaruthenium, and Triosmium Carbonyl Derivatives of 2-Amino-6-phenylpyridine

J. A. Cabeza, 2004 .

REACTIVITY OF A CATIONIC NON-HYDRIDIC TRIRUTHENIUM CARBONYL CLUSTER COMPLEX WITH ANIONIC REAGENTS. SYNTHESIS OF NEW TRI- AND HEXANUCLEAR DERIVATIVES

F. Grepioni, V. Riera, J. A. Cabeza, 1997 .

Binuclear Iron(I), Ruthenium(I), and Osmium(I) Hexacarbonyl Complexes Containing a Bridging Benzene-1,2-dithiolate Ligand. Synthesis, X-ray Structures, Protonation Reactions, and EHMO Calculations †

S. García‐Granda, V. Riera, J. A. Cabeza, 1998 .

.eta.1-Aryl-bridged triruthenium cluster complexes

V. Riera, J. A. Cabeza, E. Pérez-Carreño, 1994 .

Reactivity of a Triruthenium Cluster Complex Containing a mu~3-eta^3(C,N~2) Ligand Derived from 2-Amino-7,8-benzoquinoline. Coupling of This Ligand with C~3 Fragments and Characterization of mu~3-Vinylidene and mu-Stannylene Derivatives

S. García‐Granda, I. D. Rı́o, V. Riera, 2004 .

Formation of a Diynedienyl Ligand by Coupling of Hexa-2,4-diyne and Hex-2-yn-4-en-4-yl Ligands onto a Triruthenium Cluster Core

S. García‐Granda, I. D. Rı́o, V. Riera, 2001 .

Advances in the Reactivity of Amido‐Bridged Binuclear Carbonylruthenium Complexes – Derivative Chemistry of the Cationic Complex [Ru2(μ‐dan)(μ‐H)(CO)6][BF4] (H2dan = 1,8‐Diaminonaphthalene)

V. Riera, J. A. Cabeza, Jorge García-Díez, 1998 .

Cationic and neutral 50-electron triruthenium carbonyl clusters containing three bridging diphenylphosphido ligands

F. Lahoz, J. A. Cabeza, Albert H. Martin, 1992 .

Methylidyne/diyne coupling reactions onto a triruthenium cluster core

S. García‐Granda, I. D. Rı́o, V. Riera, 2003 .

ALKYNE, TRIORGANOSILYL, AND TRIORGANOSTANNYL DERIVATIVES OF ANIONIC TRIRUTHENIUM CARBONYL CLUSTER COMPLEXES CONTAINING BRIDGING PYRAZOLYL LIGANDS

S. García‐Granda, V. Riera, J. A. Cabeza, 1995 .

Synthesis and reactivity of binuclear pyrazolate-bridged ruthenium(I) complexes. Crystal structures of bis[-(3,5-dimethylpyrazolato-NN?)-tricarbonylruthenium(I)](Ru?Ru) and bis[-(3,5-dimethylpyrazolato-NN?)]--iodo-bis[tricarbonylruthenium(II)]tri-iodide

L. Oro, J. A. Cabeza, D. Belletti, 1989 .

Notes. Nuclear magnetic resonance evidence for three different isomers of [Ru3(µ-H)(µ-bzim)(CO)9(PPh3)](bzim = benzimidazolate). Crystal structure of [Ru3(µ-H)(µ-bzim)(CO)10]·Me2CO

L. Oro, M. Pellinghelli, J. A. Cabeza, 1990 .

Tricyclohexylphosphine- versus Triphenylphosphine-Substituted Derivatives of a Face-Bridged Triruthenium Carbonyl Cluster Complex. A Comparative Study of Their Synthesis, Structure, and Catalytic Activity in the Homogeneous Hydrogenation of Diphenylacetylene

I. D. Rı́o, L. Ouahab, V. Riera, 1994 .

Synthesis and derivative chemistry of [Ru2(μ-PPh2) (μ-OH) 2(μ6-p-cymene) 2]+

V. Riera, J. A. Cabeza, F. Mulla, 1994 .

Influence of the bridging ligand on the substitution chemistry of neutral and cationic triruthenium carbonyl cluster complexes derived from 1,1-dimethylhydrazine

S. García‐Granda, I. D. Rı́o, V. Riera, 2003 .

Carbonyl substitution chemistry of neutral and cationic triruthenium cluster complexes derived from 1,1-dimethylhydrazine.: Incorporation of two and three phosphane ligands

S. García‐Granda, I. D. Rı́o, V. Riera, 2002 .

Ru3(CO)9(PPh3)3: a convenient starting material for the synthesis of binuclear ruthenium(I) complexes. Crystal structure of Ru2(μ-L2)(CO)4(PPh3)2 (H2L2 = 1,8-diaminonaphthalene)

V. Riera, J. A. Cabeza, Y. Jeannin, 1989 .

Carbonyl Clusters as Homogeneous Catalysts. Kinetic and Molecular Aspects of the Hydrogenation of Diphenylacetylene Promoted by an Alkenyl-Bridged Triruthenium Cluster Complex

S. García‐Granda, V. Riera, J. A. Cabeza, 1994 .

Preparation and Characterization of 92-Electron Hexahydridohexaruthenium Carbonyl Cluster Complexes. Their Potential Significance in Homogeneous Catalytic Hydrogenation

S. García‐Granda, V. Riera, F. López-Ortiz, 1994 .

Reactivity of a face-bridged trinuclear ruthenium carbonyl cluster with diphenylacetylene and triorganotin hydrides. Attempted hydrostannation of diphenylacetylene

S. García‐Granda, V. Riera, J. A. Cabeza, 1993 .

Kinetic and chemical evidence for the participation of mononuclear catalytic species in the homogeneous hydrogenation of diphenylacetylene promoted by an edge-bridged triruthenium carbonyl cluster complex

V. Riera, J. A. Cabeza, A. Llamazares, 1992 .

Synthesis and reactivity of mono- and hetero-nuclear rhodium(I) or iridium(I) complexes with 2-(2′-pyridyl)benzimidazole

L. Oro, R. Usón, J. A. Cabeza, 1983 .

Ruthenium Carbene Complexes Analogous to Grubbs-I Catalysts Featuring Germylenes as Ancillary Ligands

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2018 .

Steric effects in the reactions of amidinate germylenes with ruthenium carbonyl: isolation of a coordinatively unsaturated diruthenium(0) derivative

J. A. Cabeza, P. García‐Álvarez, J. Fernández‐Colinas, 2014 .

Phosphane-functionalized heavier tetrylenes: synthesis of silylene- and germylene-decorated phosphanes and their reactions with Group 10 metal complexes.

J. A. Cabeza, P. García‐Álvarez, Carlos J. Laglera‐Gándara, 2020, Dalton transactions.

Double C-H Bond Activation of an NHC N-Methyl Group on Triruthenium and Triosmium Carbonyl Clusters: A DFT Mechanistic Study

J. A. Cabeza, E. Pérez-Carreño, 2008 .

Topological Analysis of the Electron Density in the N-Heterocyclic Carbene Triruthenium Cluster [Ru3(μ-H)2(μ3-MeImCH)(CO)9] (Me2Im = 1,3-dimethylimidazol-2-ylidene)

S. García‐Granda, J. A. Cabeza, J. F. V. D. Maelen, 2009 .

Improved Synthesis, Solution and Solid-State Structure, and Reactivity of (Ru2(μ-SePh)2(CO)6).

S. García‐Granda, V. Riera, D. Miguel, 1991 .

Pyrazolate‐Bridged Ruthenium(I) Carbonyl Complexes

Richard A. Jones, L. Oro, J. A. Cabeza, 1997 .

Reactivity of Triosmium Carbonyl Clusters with 1,8-Diaminonaphthalene − Synthesis and Structural Characterization of Amido, Diamido, and C-Metalated Trinuclear Derivatives

H. Nöth, J. A. Cabeza, M. Rosales-Hoz, 2000 .

Reactivity of a cationic triruthenium hydridoalkenylcarbonyl cluster complex toward nucleophilic reagents. Carbonyl substitution versus alkene elimination reactions

I. D. Rı́o, V. Riera, J. A. Cabeza, 1996 .

Thermal and Photochemical Reactions of (Ru3(CO)12) with Tetraethyldiphosphite. X-Ray Structure of (Ru3(CO)10(μ-(EtO)2POP(OEt)2)).

V. Riera, D. Miguel, J. A. Cabeza, 1990 .

Rhodium(I) and iridium(I) π-arene complexes of indole and of N-indolylgold(I) derivatives. X-ray structure of [(Me3TFB)Rh(η6-HIn)]ClO4 (TFB = tetrafluorobenzobarrelene)

L. Oro, C. Foces-Foces, F. H. Cano, 1983 .

2-(Methylamido)pyridine-Borane: A Tripod κ(3)-N,H,H Ligand in Trigonal Bipyramidal Rhodium(I) and Iridium(I) Complexes with an Asymmetric Coordination of Its BH3 Group.

A. Kennedy, J. A. Cabeza, P. García‐Álvarez, 2016, Inorganic chemistry.

The chemical and electrochemical oxidation of pyridonate-bridged ruthenium(I) dimers. X-Ray structure of [Ru2(μ-pyO)2(CO)4(pyOH)2] (pyOH = 2-pyridone)

S. García‐Granda, G. Mori, V. Riera, 1991 .

Synthesis, Structure, and Photophysical Properties of Platinum(II) (N,C,N') Pincer Complexes Derived from Purine Nucleobases†.

Miguel A. Esteruelas, M. Sierra, J. A. Cabeza, 2023, Inorganic chemistry.

η2-edge-bridging and η3-face-capping coordination of conjugated ynenyl ligands in triruthenium carbonyl cluster complexes derived from 1,1-dimethylhydrazine

S. García‐Granda, I. D. Rı́o, J. A. Cabeza, 2005 .

η3-Edge-bridging versus η3-face-capping coordination of a conjugated ynenyl ligand on a triruthenium cluster core

S. García‐Granda, I. D. Rı́o, J. A. Cabeza, 2004 .

Reactivity of triosmium and triruthenium carbonyls with 2,2'-diamino-1,1'-binaphthalene. Synthesis of C- and N-metalated derivatives

S. García‐Granda, I. D. Rı́o, V. Riera, 2003 .

Reactivity of a Triruthenium Ynenyl Cluster Complex with Diynes: Cluster-Mediated Combination of up to Three Substituted Butadiyne Molecules into a Carbon-Rich Hydrocarbyl Ligand

S. García‐Granda, I. D. Rı́o, V. Riera, 2002 .

Triruthenium and triosmium carbonyl cluster complexes containing bridging ligands derived from 2-amino-7,8-benzoquinoline

S. García‐Granda, I. D. Rı́o, V. Riera, 2002 .

Triruthenium and Triosmium Carbonyl Cluster Complexes Containing Deprotonated Di(2-pyridyl)amine in Unusual Coordination Modes

S. García‐Granda, I. D. Rı́o, V. Riera, 2002 .

Approaches to Triosmium Carbonyl Cluster Compounds Derived from Benzophenone Imine. Characterization of Terminal Imino, Bridging Amido, and Orthometalated Imino Derivatives

F. Grepioni, I. D. Rı́o, V. Riera, 2000 .

Reactivity of [PPN][Ru3(.mu.-NO)(CO)10] with Tertiary Silanes and Stannanes

V. Riera, J. A. Cabeza, R. Franco, 1994 .

Reactivity of tertiary silanes and stannanes with an edge-bridged triruthenium carbonyl cluster complex

V. Riera, C. Bois, J. A. Cabeza, 1993 .

First Insertions of Carbene Ligands into Ge-N and Si-N Bonds.

M. Gómez-Gallego, M. Sierra, Alba D Merinero, 2017, Chemistry.

Two octahedral σ-borane metal (MnI and RuII) complexes containing a tripod κ3N,H,H-ligand: Synthesis, structural characterization, and theoretical topological study of the charge density

J. A. Cabeza, P. García‐Álvarez, J. F. Van der Maelen, 2020 .