P. García‐Álvarez

发表

A Germylene Supported by Two 2-Pyrrolylphosphane Groups as Precursor to PGeP Pincer Square-Planar Group 10 Metal(II) and T-Shaped Gold(I) Complexes.

Israel Fernández, J. A. Cabeza, J. Fernández-Colinas, 2019, Chemistry.

Deprotonation of C-alkyl groups of cationic triruthenium clusters containing cyclometalated C-alkylpyrazinium ligands: experimental and computational studies.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2013, Chemistry.

Deprotonation of C-alkyl groups of cationic N-heterocyclic ligands.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2012, Dalton transactions.

Direct C–H Metalation with Chromium(II) and Iron(II): Transition-Metal Host / Benzenediide Guest Magnetic Inverse-Crown Complexes

J. Klett, E. Rentschler, W. Clegg, 2009, Angewandte Chemie.

Hexaruthenium and octaruthenium carbonyl cluster complexes derived from 2-amino-6-methylpyridine : Novel coordination modes for 2-imidopyridines

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2006 .

Dipyrromethane‐Based PGeP Pincer Methylgermyl and Methoxidogermyl Nickel and Palladium Complexes

J. A. Cabeza, P. García‐Álvarez, Carlos J. Laglera‐Gándara, 2021 .

Expanding Mg-Zn hybrid chemistry: inorganic salt effects in addition reactions of organozinc reagents to trifluoroacetophenone and the implications for a synergistic lithium-magnesium-zinc activation.

D. Armstrong, W. Clegg, A. Kennedy, 2011, Chemistry.

Reactivity of Amidinatosilylenes and Amidinatogermylenes with [PtMe2(η4-cod)]: cis- versus trans-[PtMe2L2] Complexes and Cyclometalation Reactions

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2020 .

[MnBrL(CO)4] (L = Amidinatogermylene): Reductive Dimerization, Carbonyl Substitution, and Hydrolysis Reactions

R. Gobetto, C. Nervi, J. A. Cabeza, 2016 .

Shedding new light on ZnCl2-mediated addition reactions of Grignard reagents to ketones: structural authentication of key intermediates and diffusion-ordered NMR studies.

D. Armstrong, W. Clegg, A. Kennedy, 2011, Chemistry.

Reaction of [Ru3(CO)12] with Phenazine: Synthesis of C-Metalated Derivatives That Formally Arise from a C–H Oxidative Addition or a Long-Distance C-to-N Prototropy

J. A. Cabeza, P. García‐Álvarez, Vanessa Pruneda, 2012 .

Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations.

J. Klett, W. Clegg, A. Kennedy, 2010, Dalton transactions.

Structural Tracking of the Potassium-Mediated Magnesiation of Anisole

T. Tuttle, W. Clegg, A. Kennedy, 2009, Chemistry.

Unmasking representative structures of TMP-active Hauser and turbo-Hauser bases.

J. Klett, S. Weatherstone, A. Kennedy, 2008, Angewandte Chemie.

"LiZn(TMP)3", a zincate or a turbo-lithium amide reagent? DOSY NMR spectroscopic evidence.

J. Parkinson, P. García‐Álvarez, R. Mulvey, 2011, Angewandte Chemie.

Two Types of σ-Allenyl Complexes from Reactions of Silylenes and Germylenes with Chromium Fischer Alkynyl(alkoxy)carbenes.

M. Gómez-Gallego, M. Sierra, Alba D Merinero, 2019, Chemistry.

The transition-metal chemistry of amidinatosilylenes, -germylenes and -stannylenes

J. A. Cabeza, P. García‐Álvarez, D. Polo, 2015 .

Synthesis, structural elucidation, and diffusion-ordered NMR studies of homoleptic alkyllithium magnesiates: donor-controlled structural variations in mixed-metal chemistry

J. Klett, W. Clegg, A. Kennedy, 2012 .

Synthesis and characterization of an infinite sheet of metal-alkyl bonds: unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate.

J. Klett, W. Clegg, A. Kennedy, 2011, Chemical communications.

Reactivity of [Ru-3(CO)(12)] with a phosphine-functionalized Imidazol-2-ylidene and Its imidazolium salt

A. Kennedy, J. A. Cabeza, P. García‐Álvarez, 2011 .

Easy abstraction of a hydride anion from an alkyl C-H bond of a coordinated bis(N-heterocyclic carbene).

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2013, Chemical communications.

Intramolecularly Stabilized Heavier Tetrylenes: From Monodentate to Bidentate Ligands

J. A. Cabeza, P. García‐Álvarez, D. Polo, 2016 .

Ring opening and bidentate coordination of amidinate germylenes and silylenes on carbonyl dicobalt complexes: the importance of a slight difference in ligand volume.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2014, Chemistry.

Reactivity of a (bis-NHC)tricarbonylruthenium(0) complex with methyl triflate and methyl iodide. Formation of methyl- and acetylruthenium(II) derivatives: Experimental results and mechanistic DFT calculations

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2013 .

Synthesis and reactivity of cationic triruthenium clusters derived from 2-methyl- and 4-methylpyrimidines: from conventional cyclometalated ligands to novel types of N-heterocyclic carbenes.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2013, Chemistry.

The N-heterocyclic carbene chemistry of transition-metal carbonyl clusters.

J. A. Cabeza, P. García‐Álvarez, Javier A. Cabeza, 2011, Chemical Society reviews.

Reactivity of Phosphine- and Thioether-Tethered N-Heterocyclic Carbenes with Ruthenium Carbonyl

A. Kennedy, J. A. Cabeza, P. García‐Álvarez, 2012 .

Different Reactivities of Pyrid-2-yl- and 6-Picol-2-yl-Functionalized NHC Ligands with [Ru3(CO)12]: C(sp2)−H and Double C(sp3)−H Bond Activation Reactions

J. A. Cabeza, P. García‐Álvarez, M. Damonte, 2011 .

Synthesis of mixed tin-ruthenium and tin-germanium-ruthenium carbonyl clusters from [Ru3(CO)12] and diaminometalenes (M = Sn, Ge).

J. A. Cabeza, P. García‐Álvarez, D. Polo, 2012, Inorganic chemistry.

Reactivity of diaminogermylenes with ruthenium carbonyl: Ru3Ge3 and RuGe2 derivatives.

J. A. Cabeza, P. García‐Álvarez, D. Polo, 2011, Inorganic chemistry.

Synthesis and some coordination chemistry of the PSnP pincer-type stannylene Sn(NCH2PtBu2)2C6H4, attempts to prepare the PSiP analogue, and the effect of the E atom on the molecular structures of E(NCH2PtBu2)2C6H4 (E = C, Si, Ge, Sn).

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2018, Dalton transactions.

Amidinatogermylene Metal Complexes as Homogeneous Catalysts in Alcoholic Media

J. A. Cabeza, P. García‐Álvarez, J. Fernández‐Colinas, 2016 .

Amidinatogermylene derivatives of ruthenium carbonyl: new insights into the reactivity of [Ru3(CO)12] with two-electron-donor reagents of high basicity.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2015, Inorganic chemistry.

Reactions of CS2 and C(S)NPh Adducts of N-Heterocyclic Carbenes with [Ru3(CO)12]: Remarkable Reactivity of These Betaines Involving One or Two C–S Bond Activation Processes

J. A. Cabeza, P. García‐Álvarez, M. G. Hernández-Cruz, 2012 .

Main Group Multiple C–H/N–H Bond Activation of a Diamine and Isolation of A Molecular Dilithium Zincate Hydride: Experimental and DFT Evidence for Alkali Metal–Zinc Synergistic Effects

T. Tuttle, A. Kennedy, J. Saßmannshausen, 2011, Journal of the American Chemical Society.

Synthesis and structural chemistry of alkali metal tris(HMDS) magnesiates containing chiral diamine donor ligands.

A. Kennedy, P. García‐Álvarez, C. T. O'Hara, 2011, Dalton transactions.

Cyclometallation of Heavier Tetrylenes: Reported Complexes and Applications in Catalysis

J. A. Cabeza, P. García‐Álvarez, 2021, European Journal of Inorganic Chemistry.

Mesityl(amidinato)tetrylenes as ligands in iridium(i) and iridium(iii) complexes: silicon versus germanium and simple κ1-coordination versus cyclometallation.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2019, Dalton transactions.

Facile cyclometallation of a mesitylsilylene: synthesis and preliminary catalytic activity of iridium(iii) and iridium(v) iridasilacyclopentenes.

J. A. Cabeza, P. García‐Álvarez, Laura González-Álvarez, 2017, Chemical communications.

Structural and reactivity insights in Mg–Zn hybrid chemistry: Zn–I exchange and Pd-catalysed cross-coupling applications of aromatic substrates

K. Koszinowski, W. Clegg, A. Kennedy, 2014 .

Exposing the hidden complexity of stoichiometric and catalytic metathesis reactions by elucidation of Mg-Zn hybrids

A. Kennedy, Eva Hevia, P. García‐Álvarez, 2010, Proceedings of the National Academy of Sciences.

Synthesis, Structural Authentication, and Structurally Defined Metalation Reactions of Lithium and Sodium DA-Zincate Bases (DA = diisopropylamide) with Phenylacetylene†

Joaquín García‐Álvarez, R. Harrington, W. Clegg, 2008 .

Unexpected Zwitterionic Allenyls from Silylenes and a Fischer Alkynylcarbene: A Remarkable Silylene-Promoted Rearrangement.

M. Gómez-Gallego, M. Sierra, Alba D Merinero, 2019, Chemistry.

Diisopropylamide and TMP turbo-Grignard reagents: a structural rationale for their contrasting reactivities.

D. Armstrong, J. Parkinson, A. Kennedy, 2010, Angewandte Chemie.

The Transition Metal Chemistry of PGeP and PSnP Pincer Heavier Tetrylenes

J. A. Cabeza, P. García‐Álvarez, Carlos J. Laglera‐Gándara, 2020, European Journal of Inorganic Chemistry.

Octahedral manganese(i) and ruthenium(ii) complexes containing 2-(methylamido)pyridine-borane as a tripod κ3N,H,H-ligand.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2017, Dalton transactions.

Amidinatogermylene Complexes of Copper, Silver, and Gold

J. A. Cabeza, P. García‐Álvarez, D. Polo, 2015 .

Reactivity Studies on a Binuclear Ruthenium(0) Complex Equipped with a Bridging κ(2)N,Ge-Amidinatogermylene Ligand.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2015, Inorganic chemistry.

Structural insights into mono-amido tris-alkyl potassium aluminates

J. Klett, A. Kennedy, P. García‐Álvarez, 2010 .

Complexity in seemingly simple sodium magnesiate systems.

A. Kennedy, P. García‐Álvarez, J. Francos, 2014, Dalton transactions.

From a Diphosphanegermylene to Nickel, Palladium, and Platinum Complexes Containing Germyl PGeP Pincer Ligands.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2017, Chemistry.

Synthesis and initial transition metal chemistry of the first PGeP pincer-type germylene.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2017, Chemical communications.

Molecular structures of THF-solvated alkali-metal 2,2,6,6-tetramethylpiperidides finally revealed: X-ray crystallographic, DFT, and NMR (including DOSY) spectroscopic studies.

D. Armstrong, A. Kennedy, P. García‐Álvarez, 2011, Chemistry.

Reactions of (-)-sparteine with alkali metal HMDS complexes: conventional meets the unconventional.

A. Kennedy, P. García‐Álvarez, C. T. O'Hara, 2009, Chemical communications.

A Z-type PGeP pincer germylene ligand in a T-shaped palladium(0) complex.

J. A. Cabeza, P. García‐Álvarez, Carlos J. Laglera‐Gándara, 2020, Chemical communications.

A dipyrromethane-based diphosphane-germylene as precursor to tetrahedral copper(i) and T-shaped silver(i) and gold(i) PGeP pincer complexes.

Israel Fernández, J. A. Cabeza, P. García‐Álvarez, 2019, Dalton transactions.

Organic Amides as Suitable Precursors to Stabilize Stannylenes

J. A. Cabeza, P. García‐Álvarez, D. Polo, 2013 .

Fully Borylated Methane and Ethane by Ruthenium-Mediated Cleavage and Coupling of CO.

Zhenyang Lin, A. Batsanov, M. Crestani, 2016, Angewandte Chemie.

Structurally engineered deprotonation/alumination of THF and THTP with retention of their cycloanionic structures.

J. Klett, A. Kennedy, P. García‐Álvarez, 2010, Angewandte Chemie.

A new coordination mode for (pyrid-2-yl)thiolate (L) ligands: Synthesis and characterization of [Ru6(μ3-H)(μ5-κ2-L)(μ-CO)(CO)15]

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2007 .

Hexaruthenium carbonyl cluster complexes with basal edge-bridged square pyramidal metallic skeleton: efficient synthesis of 2-imidopyridine derivatives and determination of their reactive sites in carbonyl substitution reactions.

V. Riera, D. Miguel, J. A. Cabeza, 2004, Inorganic chemistry.

Expanding the coordination chemistry of donor-stabilized group-14 metalenes.

J. A. Cabeza, P. García‐Álvarez, D. Polo, 2013, Dalton transactions.

Diaminogermylene and diaminostannylene derivatives of gold(I): novel AuM and AuM2 (M = Ge, Sn) complexes.

J. A. Cabeza, P. García‐Álvarez, J. Fernández‐Colinas, 2012, Inorganic chemistry.

Reversible Carbene Insertion into a Ge-N Bond and Insights into CO and Carbene Substitution Reactions Involving Amidinatogermylenes and Fischer Carbene Complexes.

M. Gómez-Gallego, M. Sierra, Alba D Merinero, 2018, Chemistry.

Synergic Transformation of an Ethylenediamine to a Lithium 1,3-Diaza-2-zincacyclopentene via an Alkyllithium/Bis(alkyl)zinc Mixture

A. Kennedy, P. García‐Álvarez, R. Mulvey, 2010, Chemistry.

Conversion of a monodentate amidinate-germylene ligand into chelating imine-germanate ligands (on mononuclear manganese complexes).

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2014, Inorganic chemistry.

Nonanuclear Ruthenium Carbonyl Cluster Complexes with a Novel Metallic Skeleton: Pentagonal Bipyramid with Two Equatorial Edges Spanned by Metal Atoms

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2006 .

Reactivity of Arenes, Cycloheptatriene, and Dicyclopentadiene with a Basal Edge-Bridged Square Pyramidal Hexaruthenium Dihydride

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2006 .

Reactivity of Diphenylbutadiyne with a Hexaruthenium Dihydride. Unusual 1,1- and trans-1,2-Additions of Two Hydrogen Atoms to an Internal CC Triple Bond §

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2006 .

Reactivity of Diphenylacetylene with a Basal Edge-Bridged Square-Pyramidal Hexaruthenium Cluster. Characterization of Penta-, Hexa-, and Heptanuclear Alkyne Derivatives

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2005 .

Structural variations within group 1 (Li-Cs)+ (2,2,6,6-tetramethyl-1-piperidinyloxy)- complexes made via metallic reduction of the nitroxyl radical.

J. Klett, A. Kennedy, David V. Graham, 2009, Inorganic chemistry.

Ruthenium Carbene Complexes Analogous to Grubbs-I Catalysts Featuring Germylenes as Ancillary Ligands

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2018 .

Steric effects in the reactions of amidinate germylenes with ruthenium carbonyl: isolation of a coordinatively unsaturated diruthenium(0) derivative

J. A. Cabeza, P. García‐Álvarez, J. Fernández‐Colinas, 2014 .

Phosphane-functionalized heavier tetrylenes: synthesis of silylene- and germylene-decorated phosphanes and their reactions with Group 10 metal complexes.

J. A. Cabeza, P. García‐Álvarez, Carlos J. Laglera‐Gándara, 2020, Dalton transactions.

Synthesis and structural elucidation of a rare example of a tris(amido) potassium magnesiate

A. Kennedy, P. García‐Álvarez, B. Fleming, 2012 .

cis-2,6-Dimethylpiperidide: a structural mimic for TMP (2,2,6,6-tetramethylpiperidide) or DA (diisopropylamide)?

J. Klett, A. Kennedy, P. García‐Álvarez, 2010, Dalton Transactions.

2-(Methylamido)pyridine-Borane: A Tripod κ(3)-N,H,H Ligand in Trigonal Bipyramidal Rhodium(I) and Iridium(I) Complexes with an Asymmetric Coordination of Its BH3 Group.

A. Kennedy, J. A. Cabeza, P. García‐Álvarez, 2016, Inorganic chemistry.

Structural elucidation of homometallic anthracenolates synthesised via deprotonative metallation of anthrone.

J. Klett, W. Clegg, A. Kennedy, 2013, Dalton transactions.

Synthesis, Structure, and Photophysical Properties of Platinum(II) (N,C,N') Pincer Complexes Derived from Purine Nucleobases†.

Miguel A. Esteruelas, M. Sierra, J. A. Cabeza, 2023, Inorganic chemistry.

Synergic synthesis of benzannulated zincabicyclic complexes, alpha-zincated N ylides, through sodium-TMEDA-mediated zincation of a haloarene.

D. Armstrong, W. Clegg, A. Kennedy, 2009, Angewandte Chemie.

First Insertions of Carbene Ligands into Ge-N and Si-N Bonds.

M. Gómez-Gallego, M. Sierra, Alba D Merinero, 2017, Chemistry.

Two octahedral σ-borane metal (MnI and RuII) complexes containing a tripod κ3N,H,H-ligand: Synthesis, structural characterization, and theoretical topological study of the charge density

J. A. Cabeza, P. García‐Álvarez, J. F. Van der Maelen, 2020 .

From a PGeP Pincer-Type Germylene to Metal Complexes Featuring Chelating (Ir) and Tripodal (Ir) PGeP Germyl and Bridging (Mn2) and Chelating (Ru) PGeP Germylene Ligands

P. García‐Álvarez, E. Pérez-Carreño, J. Brugos, 2018 .