D. Falvey

发表

AB INITIO CHARACTERIZATION OF PHENYLNITRENIUM AND PHENYLCARBENE : REMARKABLY DIFFERENT PROPERTIES FOR ISOELECTRONIC SPECIES

C. Cramer, F. Dulles, D. Falvey, 1994 .

Discrete Existence of Singlet Nitrenium Ions Revisited: Computational Studies of Non-Aryl Nitrenium Ions and Their Rearrangements

D. Falvey, 2018, ACS omega.

Model studies of DNA photorepair: radical anion cleavage of thymine dimers probed by nanosecond laser spectroscopy

S. Yeh, D. Falvey, 1991 .

MODEL STUDIES OF DNA PHOTOREPAIR: REDUCTION POTENTIALS OF THYMINE AND CYTOSINE CYCLOBUTANE DIMERS MEASURED BY FLUORESCENCE QUENCHING

D. Fenick, S. Yeh, D. Falvey, 1997 .

Field, Laboratory and Model Studies of CDOM

N. Blough, D. Falvey, 2002 .

Photoremovable protecting groups based on electron transfer chemistry.

D. Falvey, Chitra Sundararajan, 2004, Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology.

Photorelease of carboxylic and amino acids from N-methyl-4-picolinium esters by mediated electron transfer

D. Falvey, Chitra Sundararajan, 2006, Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology.

Photoinduced electron transfer cleavage of oxetane adducts of uracil and cytosine

D. Falvey, A. Joseph, 2002, Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology.

Mechanism of the photorelease of alcohols from the 9-phenyl-9-tritylone protecting group

D. Falvey, Andrea N. Zeppuhar, Kevin Hill-Byrne, 2019, Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology.

Generation of N,N-Di(4-bromophenyl)nitrenium Ion Under Acidic Conditions: Search for a Nitrenium Dication.

D. Falvey, Andrea N. Zeppuhar, 2020, The Journal of organic chemistry.

Nitrenium ion analogues of nonclassical carbocations: cyclopropylnitrenium, allylnitrenium, and azetidenium ions and mechanisms for their interconversion.

D. Falvey, 2015, Organic letters.

Visible Light Photorelease of Carboxylic Acids via Charge-Transfer Excitation of N-Methylpyridinium Iodide Esters.

D. Falvey, D. J. Kunsberg, Allison H Kipping, 2015, Organic letters.

2-(3,5-Dinitrophenyl)-1,3-dithiane carbanion: a benzylic anion with a low energy triplet state.

William H Coldren, D. Falvey, A. Winter, 2011, Journal of the American Chemical Society.

Model Studies of DNA Photorepair: Enthalpy of Cleavage of a Pyrimidine Dimer Measured by Photothermal Beam Deflection Calorimetry

S. Yeh, D. Falvey, M. Scannell, 1996, Photochemistry and photobiology.

Model studies of the (6-4) photoproduct DNA photolyase: Synthesis and photosensitized splitting of a thymine-5,6-oxetane

D. Falvey, G. Prakash, 1995 .

Synthesis and Photochemical Cleavage of Cis-Syn Pyrimidine Cyclobutane Dimer Analogs

D. Fenick, D. Falvey, H. Carr, 1995 .

Free Radical Rearrangements in Uracil Derivatives

D. Fenick, D. Falvey, 1994 .

Model studies of DNA photorepair : energetic requirements for the radical anion mechanism determined by fluorescence quenching

S. Yeh, D. Falvey, 1992 .

Photothermal Beam Deflection Calorimetry in Solution Photochemistry: Recent Progress and Future Prospects

D. Falvey, 1997, Photochemistry and photobiology.

In vitro studies on the photobiological properties of aloe emodin and aloin A.

W. Wamer, D. Falvey, P. Vath, 2003, Free radical biology & medicine.

Computational prediction of a ground-state triplet arylnitrenium ion and a possible ground-state triplet silylene

C. Cramer, D. Falvey, 1997 .

Singlet and triplet states in the reactions of nitrenium ions

D. Falvey, 1999 .

N-methyl-N-phenylnitrenium ion from photolysis of N-(methylphenylamino)-2,4,6-trimethylpyridinium tetrafluoroborate

D. Falvey, D. Chiapperino, 1997 .

Electronic Properties of Nitrenium Ions

D. Falvey, 2013 .

PHOTOGENERATED DIARYLNITRENIUM IONS : LASER FLASH PHOTOLYSIS AND PRODUCT STUDIES ON DIPHENYLNITRENIUM ION GENERATED FROM PHOTOLYSIS OF 1-(N,N-DIPHENYL AMINO)PYRIDINIUM IONS

D. Falvey, Ricardo J. Moran, 1996 .

Reactions of a Triplet Arylnitrenium Ion: Laser Flash Photolysis and Product Studies of N-tert-Butyl(2-acetyl-4-nitrophenyl)nitrenium Ion

S. Srivastava, D. Falvey, 1995 .

Photogenerated nitrenium ions : singlet and triplet state reactions of tert-butyl-(2-acetyl-4-methyl)phenyl nitrenium ion

R. J. Robbins, D. Falvey, 1994 .

Photogenerated arylnitrenium ions : absorption spectra and absolute rate constants for tert-butyl(4-halo-2-acetylphenyl)nitrenium ions measured by time-resolved laser spectroscopy

D. Falvey, G. Anderson, 1993 .

Photogenerated arylnitrenium ions : photoisomerization of the N-tert-butyl-3-methylanthranilium ion and spin-selective reactivity of the isomeric arylnitrenium ion

D. Falvey, Lu Yang, G. Anderson, 1993 .

The 3,5‐dinitroanilide anion: a singlet anilide anion with evidence for a thermally accessible triplet state

D. Falvey, R. R. Perrotta, 2013 .

Neophyl-like rearrangement of alkoxy radicals: direct detection of a bridged intermediate by time-resolved absorption spectroscopy

G. Schuster, D. Falvey, B. S. Khambatta, 1990 .

Vinyl cations substituted with beta pi-donors have triplet ground states.

D. Falvey, A. Winter, 2010, Journal of the American Chemical Society.

Photoinduced Electron Transfer to Pyrimidines and 5,6-Dihydropyrimidine Derivatives: Reduction Potentials Determined by Fluorescence Quenching Kinetics

D. Falvey, M. Scannell, A. S. Prakash, 1997 .

Protecting Groups That Can Be Removed through Photochemical Electron Transfer: Mechanistic and Product Studies on Photosensitized Release of Carboxylates from Phenacyl Esters

Daniel E. Falvey, Anamitro Banerjee, A. Banerjee, 1997 .

Picosecond time scale dynamics of perester photodecomposition: evidence for an acyloxy radical intermediate in the photolysis of tert-butyl 9-methylfluorene-9-percarboxylate

G. Schuster, D. Falvey, 1986 .

Photoreleasable protecting groups based on electron transfer chemistry. Donor sensitized release of phenacyl groups from alcohols, phosphates and diacids

Kwangjoo Lee, A. Banerjee, D. Falvey, 1999 .

Ketocoumarin dyes as electron mediators for visible light induced carboxylate photorelease

J. Borak, D. Falvey, 2010, Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology.

Solvent-dependent decarboxylation of 1,3-dimethylimdazolium-2-carboxylate.

D. Falvey, Derek M Denning, 2014, The Journal of organic chemistry.

Picosecond Time Scale Dynamics of Perester Photodecomposition: Evidence for an Acyloxy Radical Intermediate in the Photolysis of tert-Butyl 9-Methylfluorene-9-percarboxylate.

G. Schuster, D. Falvey, 1987 .

Direct Photolysis of Phenacyl Protecting Groups Studied by Laser Flash Photolysis: An Excited State Hydrogen Atom Abstraction Pathway Leads to Formation of Carboxylic Acids and Acetophenone

A. Banerjee, D. Falvey, 1998 .

Protecting Groups That Can Be Removed Through Photochemical Electron Transfer: Mechanistic and Product Studies on Photosensitized Release of Carboxylates from Phenacyl Esters.

Daniel E. Falvey, A. Banerjee, A. Banerjee, 1998 .

PHOTOGENERATED ARYLNITRENIUM IONS : REACTIONS OF N-TERT-BUTYL (2-ACETYL-4-SUBSTITUTED)PHENYL NITRENIUM IONS WITH ALCOHOLS AND WATER STUDIED BY LASER F LASH PHOTOLYSIS

R. J. Robbins, D. Falvey, Lu Yang, 1995 .

Dynamics of .alpha.-CH Deprotonation and .alpha.-Desilylation Reactions of Tertiary Amine Cation Radicals

P. Mariano, A. Albini, M. Freccero, 1994 .

Photoacid Generators Activated through Sequential Two-Photon Excitation: 1-Sulfonatoxy-2-alkoxyanthraquinone Derivatives.

D. Falvey, Andrea N. Zeppuhar, Steven M Wolf, 2021, The journal of physical chemistry. A.

Solvent-mediated photoinduced electron transfer in a pyridinium ionic liquid.

D. Falvey, R. Vieira, 2008, Journal of the American Chemical Society.

Photochemically Removable Protecting Groups Based on Covalently Linked Electron Donor−Acceptor Systems

D. Falvey, K.-Y. Lee and, 2000 .

Photochemical Reduction of CO2 Using 1,3-Dimethylimidazolylidene.

D. Falvey, Matthew D. Thum, Derek M Denning, 2015, Organic letters.

Dynamics of α-CH Deprotonation and α-Desilylation Reactions of Tertiary Amine Cation Radicals.

P. Mariano, A. Albini, M. Freccero, 2010 .

Chapter 9. Reaction mechanisms. Part (iv) Free-radical reactions

D. Falvey, 1998 .

Photochemically generated arylnitrenium ions: substituent effects on reactivity studied by laser flash photolysis.

D. Falvey, D. Chiapperino, Andrew C Kung, 2003, Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology.

Dynamics of Anilinium Radical α-Heterolytic Fragmentation Processes. Electrofugal Group, Substituent, and Medium Effects on Desilylation, Decarboxylation, and Retro-Aldol Cleavage Pathways

P. Mariano, Sun Wha Oh, D. Falvey, 1998 .

Protecting group release through photoinduced electron transfer: Wavelength control through sensitized irradiation

Kwangjoo Lee, A. Banerjee, D. Falvey, 1998 .

Visible light initiated release of calcium ions through photochemical electron transfer reactions

D. Falvey, Matthew D. Thum, Romina R. Heymann, 2017, Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology.

Photogelling colloidal dispersions based on light-activated assembly of nanoparticles.

S. Raghavan, D. Falvey, Rakesh Kumar, 2009, Journal of the American Chemical Society.

Photolytic release of carboxylic acids using linked donor-acceptor molecules: direct versus mediated photoinduced electron transfer to N-alkyl-4-picolinium esters.

D. Falvey, Chitra Sundararajan, 2005, Organic letters.

Protecting Group Release Through Photoinduced Electron Transfer: Wavelength Control Through Sensitized Irradiation.

Kwangjoo Lee, A. Banerjee, D. Falvey, 1998 .

Photoinduced C-C bond cleavage in dithiane-carbonyl adducts: a laser flash photolysis study.

A. Kutateladze, D. Falvey, P. Vath, 2001, Journal of Organic Chemistry.

Competitive singlet-singlet energy transfer and electron transfer activation of aryl azides: application to photo-cross-linking experiments

P. Nielsen, O. Buchardt, G. Schuster, 1988 .

Competitive Singlet-Singlet Energy Transfer and Electron Transfer Activation of Aryl Azides: Application to Photo-Cross-Linking Experiments.

P. Nielsen, O. Buchardt, G. Schuster, 1989 .

Structures of Reactive Nitrenium Ions: Time-Resolved Infrared Laser Flash Photolysis and Computational Studies of Substituted N-Methyl-N-arylnitrenium Ions

S. Srivastava, C. Cramer, M. Sullivan, 2000 .

Fast reactions of arylnitrenium ions with amino acids and proteins: a laser flash photolysis study

D. Falvey, Selina I. Thomas, 2006 .

Photochemically Generated Arylnitrenium Ions: Laser Flash Photolysis and Product Studies of the Photochemistry of N-tert-Butyl-3-methyl-6-chloroanthranilium Ions.

R. J. Robbins, D. Falvey, G. Anderson, 1996, Journal of Organic Chemistry.

Photolysis of thymine oxetanes produces triplet excited carbonyl compounds with high efficiency.

D. Falvey, A. Joseph, 2001, Journal of the American Chemical Society.

Photochemical generation and characterization of the 5-endo-10,11-dihydrodibenzoazepine nitrenium ion

D. Falvey, Edward S Chinn, 2022, Photochemical & Photobiological Sciences.

N,N-Di(4-halophenyl)nitrenium ions: nucleophilic trapping, aromatic substitution, and hydrogen atom transfer.

D. Falvey, Selina I. Thomas, 2007, The Journal of organic chemistry.

Diphenylnitrenium ion: cyclization, electron transfer, and polymerization reactions.

D. Falvey, S. McIlroy, Andrew C Kung, 2005, The Journal of organic chemistry.

Photogenerated Nitrenium Ions: A Search for Triplet-State Reactivity in the Chemistry of the Diphenylnitrenium Ion

D. Falvey, S. McIlroy, Ricardo J. Moran, 2000 .

EXPERIMENTAL CONFIRMATION OF THE IMINOCYCLOHEXADIENYL CATION-LIKE STRUCTURE OF ARYLNITRENIUM IONS: TIME-RESOLVED IR STUDIES OF DIPHENYLNITRENIUM ION

S. Srivastava, J. Toscano, D. Falvey, 1997 .

Reactions of N-methyl-N-(4-biphenylyl)nitrenium ion with electron-rich arenes: laser flash photolysis and product studies.

D. Falvey, D. Chiapperino, S. McIlroy, 2002, Journal of the American Chemical Society.

SUBSTITUENT EFFECTS ON THE LIFETIMES AND REACTIVITIES OF ARYLNITRENIUM IONS STUDIED BY LASER FLASH PHOTOLYSIS AND PHOTOTHERMAL BEAM DEFLECTION

R. J. Robbins, D. Falvey, D. M. Laman, 1996 .

Carbazolyl nitrenium ion: electron configuration and antiaromaticity assessed by laser flash photolysis, trapping rate constants, product analysis, and computational studies.

D. Falvey, A. Winter, H. H. Gibson, 2007, The Journal of organic chemistry.

Reactions of Diarylnitrenium Ions with Electron Rich Alkenes: An Experimental and Theoretical Study.

C. Cramer, D. Falvey, Ricardo J. Moran, 1997, The Journal of organic chemistry.

A photothermal beam deflection apparatus for the time‐resolved kinetic study of fast photophysical and photochemical processes

D. Falvey, D. M. Laman, 1996 .

Photochemistry and Phototoxicity of Aloe Emodin ¶

W. Wamer, D. Falvey, P. Vath, 2002, Photochemistry and photobiology.

Photochemistry and Phototoxicity of Aloe Emodin¶

W. Wamer, D. Falvey, P. Vath, 2002 .

Nitrenes and Nitrenium Ions: Falvey/Nitrenes and Nitrenium Ions

D. Falvey, A. Gudmundsdottir, 2013 .

Photorelease of carboxylic acids, amino acids, and phosphates from N-alkylpicolinium esters using photosensitization by high wavelength laser dyes.

D. Falvey, Chitra Sundararajan, 2005, Journal of the American Chemical Society.

Application of PET deprotection for orthogonal photocontrol of aqueous solution viscosity.

S. Raghavan, H. Lee, J. Borak, 2010, Chemical communications.

Uncaging Alcohols Using UV or Visible Light Photoinduced Electron Transfer to 9-Phenyl-9-tritylone Ethers.

D. Falvey, Nichole J. Pedowitz, Matthew D. Thum, 2015, Organic letters.

A new photolabile protecting group for release of carboxylic acids by visible-light-induced direct and mediated electron transfer.

J. Borak, D. Falvey, J. Brian Borak, 2009, The Journal of organic chemistry.

Photorelease of carboxylic acids mediated by visible-light-absorbing gold-nanoparticles.

J. Borak, D. Falvey, Susana López-Sola, 2008, Organic letters.

C-O bond fragmentation of 4-picolyl- and N-methyl-4-picolinium esters triggered by photochemical electron transfer.

D. Falvey, Chitra Sundararajan, 2004, The Journal of organic chemistry.

Elucidating complex triplet-state dynamics in the model system isopropylthioxanthone

Hannah M. Ogden, Sandra A. Gutierrez Razo, Steven M. Wolf, 2021, iScience.

Applications of photothermal beam deflection calorimetry to organic photochemistry

S. Yeh, D. Falvey, 1995 .

Free Radical Rearrangements in Uracil Derivatives.

D. Fenick, D. Falvey, 1995 .

Model Studies of the (6−4) Photoproduct Photolyase Enzyme: Laser Flash Photolysis Experiments Confirm Radical Ion Intermediates in the Sensitized Repair of Thymine Oxetane Adducts

D. Falvey, A. Joseph, A. S. Prakash, 2000 .

A simple route to fluids with photo-switchable viscosities based on a reversible transition between vesicles and wormlike micelles

S. Raghavan, D. Danino, E. Kesselman, 2013 .

Solvent-dependent photochemistry of 2,2,2-tribromoethyl-(2'-phenylacetate).

D. Falvey, Derek M Denning, 2013, The Journal of organic chemistry.

Photochemical heterolysis of 3,5-bis(dimethylamino)benzyl alcohols and esters: generation of a benzyl cation with a low-energy triplet state.

D. Falvey, A. Winter, R. R. Perrotta, 2011, Organic letters.

Photoinduced electron-transfer reactions in two room-temperature ionic liquids: 1-butyl-3-methylimidazolium hexafluorophosphate and 1-octyl-3-methylimidazolium hexafluorophosphate.

D. Falvey, R. Vieira, 2007, The journal of physical chemistry. B.

Effect of meta electron-donating groups on the electronic structure of substituted phenyl nitrenium ions.

C. Cramer, D. Falvey, A. Winter, 2004, Journal of the American Chemical Society.

Visible‐Light Photocatalytic Oxidation of DMSO for RAFT Polymerization †

D. Hong, D. Falvey, Andrea N. Zeppuhar, 2021, Photochemistry and photobiology.

State Dependent Photochemical and Photophysical Behavior of Dithiolate Ester and Trithiocarbonate RAFT Polymerization Agents.

Steven M. Wolf, D. Falvey, Matthew D. Thum, 2020, The journal of physical chemistry. A.

Photoreleasable Protecting Groups Triggered by Sequential Two-Photon Absorption of Visible Light: Release of Carboxylic Acids from a Linked Anthraquinone- N-Alkylpicolinium Ester Molecule.

D. Falvey, Matthew D. Thum, 2018, The journal of physical chemistry. A.

Photoremovable protecting groups based on electron transfer chemistry

D. Falvey, Chitra Sundararajan, 2004, Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology.

Substituent and Solvent Effects on the Stability of N-Heterocyclic Carbene Complexes with CO2.

D. Falvey, Derek M Denning, 2017, The Journal of organic chemistry.

Photochemical Sinks of Organic Pollutants in Estuarine and Near-Shore Environments

N. Blough, D. Falvey, 2001 .

Photochemical Oxidation of Water by 2-Methyl-1,4-benzoquinone: Evidence against the Formation of Free Hydroxyl Radical

N. Blough, Pamela P. Vaughan, D. Falvey, 2002 .

Rearrangement, Elimination, and Ring-Opening Reactions of Cyclopropyl-Substituted Nitrenium Ions: A Computational and Experimental Investigation.

D. Falvey, Donald Hong, 2024, The Journal of organic chemistry.

Aqueous photochemistry of methyl-benzoquinone.

N. Blough, Pamela P. Vaughan, D. Falvey, 2008, The journal of physical chemistry. A.

Radical anion reactions of cyclobutane derivatives; electron-transfer cleavage of dithymoquinone

R. J. Robbins, D. Falvey, 1993 .