F. Visentin

发表

Improved Synthesis, Anticancer Activity and Electrochemical Characterization of Unusual Zwitterionic Palladium Compounds with a Ten‐Term Coordinative Ring.

Flavio Rizzolio, Giulia Moro, Ligia Maria Moretto, 2019, ChemistrySelect.

A critical review of palladium organometallic anticancer agents

S. Nolan, T. Scattolin, F. Visentin, 2021, Cell Reports Physical Science.

Synthesis and comparative study of the anticancer activity of η3-allyl palladium(II) complexes bearing N-heterocyclic carbenes as ancillary ligands

N. Demitri, F. Rizzolio, T. Scattolin, 2020 .

The addition of bromine and iodine to palladacyclopentadienyl complexes bearing bidentate heteroditopic P-N spectator ligands derived from differently substituted quinolinic frames. The unexpected evolution of the reaction.

V. Bertolasi, T. Scattolin, C. Santo, 2015, Dalton transactions.

The addition of halogens and interhalogens on palladacyclopentadienyl complexes bearing quinolyl-thioether as spectator ligands. A kinetic and computational study

V. Bertolasi, T. Scattolin, C. Santo, 2016 .

The unexpected case of reactions of halogens and interhalogens with halide substituted Pd(ii) σ-butadienyl complexes.

V. Bertolasi, T. Scattolin, C. Santo, 2016, Dalton transactions.

Synthesis of new allyl palladium complexes bearing purine-based NHC ligands with antiproliferative and proapoptotic activities on human ovarian cancer cell lines.

R. Gambari, I. Lampronti, N. Demitri, 2018, Dalton transactions.

Synthesis of novel allyl palladium complexes bearing purine based NHC and a water soluble phosphine and their catalytic activity in the Suzuki‐Miyaura coupling in water

P. Canton, N. Demitri, S. Paganelli, 2018 .

Palladacyclopentadienyl complexes bearing purine‐based N‐heterocyclic carbenes: A new class of promising antiproliferative agents against human ovarian cancer

R. Gambari, I. Lampronti, N. Demitri, 2019, Applied Organometallic Chemistry.

Synthesis and reactivity toward olefin exchange and oxidative addition of some platinum(0) olefin complexes with thioquinolines as spectator ligands

V. Bertolasi, T. Scattolin, C. Santo, 2017 .

Synthesis, characterization and a reactivity study of some allyl palladium complexes bearing bidentate hemi-labile carbene or mixed carbene/PPh3 ligands

V. Bertolasi, T. Scattolin, C. Santo, 2016 .

Synthesis, photophysical characterisation and metal ion binding properties of new ligands containing anthracene chromophores

L. Prodi, M. Montalti, N. Zaccheroni, 2004 .

Synthesis and anticancer activity of Pt(0)‐olefin complexes bearing 1,3,5‐triaza‐7‐phosphaadamantane and N ‐heterocyclic carbene ligands

R. Gambari, I. Lampronti, N. Demitri, 2021, Applied Organometallic Chemistry.

Synthesis of poly(pyridylthioether) dendrimers incorporating a Fe2(CO)6 cluster core

R. Seraglia, C. Santo, F. Visentin, 2005 .

Novel hetero-polymetallic derivatives of palladium bearing pyridylthioether fragments incorporating a Fe2(CO)6 cluster core as ligand

P. Uguagliati, C. Santo, F. Visentin, 2005 .

Synthesis of novel heteroditopic carbene–pyridine palladium(II) chloro vinyl complexes. Comparative reactivity of different palladium vinyl derivatives toward transmetalation with alkynyl stannane

C. Levi, C. Santo, F. Visentin, 2013 .

Organometallic nucleophiles. A mechanistic study of halide displacement at saturated carbon by 2- and 4-pyridyl complexes of palladium(II) and platinum(II)

B. Crociani, P. Uguagliati, F. Visentin, 1996 .

Insertion of 1,1-Me2propadiene across the Pd–C bond of pyridyl–thioether methyl complexes. A mechanistic study

P. Uguagliati, C. Santo, F. Visentin, 2003 .

The marked influence of steric and electronic properties of ancillary pyridylthioether ligands on the rate of allene insertion into the palladium–carbon bond

G. Bandoli, P. Uguagliati, C. Santo, 2002 .

Reactivity of palladium olefin complexes with heteroditopic NHC–pyridine as spectator ligand toward olefin exchange

C. Santo, F. Visentin, L. Canovese, 2014 .

Synthesis, stability and reactivity of palladium(0) olefin complexes bearing labile or hemi-labile ancillary ligands and electron-poor olefins

F. Visentin, L. Canovese, 2010 .

Transmetalation reactions. The role of the stabilizing olefin in determining the overall reaction rate

C. Levi, C. Santo, F. Visentin, 2008 .

Pyridine-based dendritic wedges with a specific metal ion coordination site and their palladium(II) complexes

A. Scrivanti, P. Uguagliati, F. Visentin, 1999 .

Unsymmetrical dendrimers with tridentate pyridylthioether coordination sites as repeating units: useful precursor for the synthesis of palladium-containing metallodendrimers

R. Seraglia, F. Visentin, L. Canovese, 2001 .

Isocyanide insertion across the Pd-C bond of allenyl and propargyl palladium complexes bearing phosphoquinoline as a spectator ligand. Synthesis of a palladium complex bearing a coordinated cyclobutenyl fragment.

V. Bertolasi, T. Scattolin, C. Santo, 2017, Dalton transactions.

Reactions of palladium(0) olefin complexes stabilized by some different hetero- and homo-ditopic spectator ligands with propargyl halides

T. Scattolin, C. Santo, F. Visentin, 2017 .

Attack of molecular iodine to novel palladacyclopentadienyl complexes bearing isocyanides as spectator ligands. A computational and mechanistic study

C. Santo, F. Visentin, L. Canovese, 2014 .

The role of the non-participating groups in substitution reactions at cationic Pt(II) complexes containing tridentate chelating nitrogen donors. Crystal structure of {Pt[bis(2-pyridylmethyl)amine](py)}(CF3SO3)2

V. Bertolasi, P. Gilli, F. Visentin, 2001 .

Catalytic transformations of diazo compounds promoted by platinum(0) and dicationic platinum(II) complexes

R. Bertani, M. Mozzon, R. Michelin, 2002 .

Measuring the Olefin‐to‐Pd(0) Bond Strength: A Kinetic Study Involving Olefin Exchange Reactions on Palladium(0) Complexes Bearing Isocyanide Ligands

T. Scattolin, C. Santo, F. Visentin, 2020 .

Synthesis, Stability Constant Determination, and Structural Study of Some Complexes of a Zinc Triad Containing Pyridyl-amine-quinoline and Pyridyl- thio-quinoline

C. Levi, A. Dolmella, F. Visentin, 2007 .

Allyl Amination of Phosphinoquinoline Allyl Complexes of Palladium. Influence of the Allyl Hapticity on the Reaction Rate and Regiochemistry

V. Bertolasi, C. Santo, F. Visentin, 2010 .

Mononuclear and dinuclear gold(i) complexes with a caffeine-based di(N-heterocyclic carbene) ligand: synthesis, reactivity and structural DFT analysis

A. Biffis, C. Graiff, L. Orian, 2021 .

Oxidative addition of organic halides on palladium(0) complexes stabilized by dimethylfumarate and quinoline-based N-P or N-S spectator ligands

V. Bertolasi, T. Scattolin, C. Santo, 2015 .

A study on the insertion of isocyanides into palladium allyl bond: Effect of their nature on the strategic steps of the process

F. Visentin, L. Canovese, G. Chessa, 2010 .

Migratory Insertion of Allyl Groups across the Pd−C Bond in Palladium(II) Isocyanide Complexes. The Fundamental Interplay between Temperature and Allyl Hapticity

C. Levi, C. Santo, F. Visentin, 2009 .

Insertion of Isocyanides across the Pd−C Bond in Alkyl or Aryl Palladium(II) Complexes Bearing Mixed Nitrogen−Sulfur and Nitrogen−Phosphorus Ancillary Ligands. The Mechanism of Reaction

C. Levi, A. Dolmella, C. Santo, 2007 .

Pyridylthioethers: a Promising Class of Polydentate Ligands in Palladium and Platinum Coordination

P. Uguagliati, F. Visentin, L. Canovese, 2004 .

Remarkable, Sterically Induced Rate Enhancement in the Insertion of Allenes into Palladium-Methyl Bonds

G. Bandoli, P. Uguagliati, F. Visentin, 2000 .

Equilibrium and kinetic studies of (2,2':6',2"-terpyridine)gold(III) complexes.Preparation and crystal structure of [Au(terpy)(OH)[ClO4]2

V. Bertolasi, P. Gilli, F. Visentin, 1999 .

The role of ancillary ligands and of electron poor alkenes and alkynes in stabilizing Pd(0) derivatives: A comparative study

A. Dolmella, C. Santo, F. Visentin, 2009 .

The formation of a metallacycloheptadienyl intermediate in the reaction of palladacyclopentadienyl derivatives with tetracyanoethylene

C. Santo, F. Visentin, L. Canovese, 2007 .

The synthesis of palladacyclopentadienyl derivatives from rigid bis-alkynes and their use as precursors in the synthesis of fluoroanthene-like cycles under mild conditions. A reactivity investigation

L. Maini, P. Uguagliati, C. Santo, 2007 .

Palladium(II)-η3-allyl complexes bearing N-trifluoromethyl N-heterocyclic carbenes:a new generation of anticancer agents which restrain the growth of high grade serous ovarian cancer tumoroids.

V. Canzonieri, T. Perin, N. Demitri, 2020, Chemistry.

Synthesis and in-depth studies on the anticancer activity of novel palladacyclopentadienyl complexes stabilized by N-Heterocyclic carbene ligands.

N. Demitri, F. Rizzolio, T. Scattolin, 2019, European journal of medicinal chemistry.

Crystal structure and fluxional behavior of novel Pd(II) allyl complexes containing a potentially tridentate S,N,S ligand: an example of selective syn-anti isomerism

V. Lucchini, G. Bandoli, P. Uguagliati, 1998 .

Mechanism of Nucleophilic Attack by Diethylamine on Cationic Palladium (II) Allyl Complexes containing α-Diimine Ligands"

S. Antonaroli, B. Crociani, P. Uguagliati, 1994 .

Transmetalation between Au(I) and Sn(IV) complexes. The reaction mechanism in non-coordinating and coordinating polar solvents

C. Levi, V. Bertolasi, C. Santo, 2013 .

Reactivity of cationic gold(I) carbene complexes toward oxidative addition of bromine

C. Levi, C. Santo, F. Visentin, 2012 .

Synthesis and Characterization of Palladium(II) π-Allyl Complexes with Chiral Phosphinocarbene Ligands. Kinetics and Mechanism of Allylic Amination

A. Togni, F. Visentin, 2007 .

Imidazo[1,5-a]pyridine-3-ylidenes and dipyridoimidazolinylidenes as ancillary ligands in Palladium allyl complexes with potent in vitro anticancer activity

V. Canzonieri, N. Demitri, F. Rizzolio, 2021 .

Highly active [Pd(ACO)2(dppp)] catalyst for the CO-C2H4 copolymerization in H2O-CH3COOH solvent [dppp = 1,3-bis(diphenylphosphino)propane]

A. Vavasori, G. Cavinato, F. Visentin, 2003 .

Synthesis of novel palladium allyl complexes bearing heteroditopic NHC–S ligands. Kinetic study on the carbene exchange between bis-carbene palladium allyl complexes

C. Levi, V. Bertolasi, C. Santo, 2013 .

Equilibrium studies of α-diimine displacement in cationic allylpalladium(II) complexes by monodentate N-donors and the mechanism of allyl amination by triethylamine and pyridine

S. Antonaroli, B. Crociani, P. Uguagliati, 1994 .

Palladium(0)-Catalyzed Cis−Trans Alkene Isomerizations

C. Santo, F. Visentin, L. Canovese, 2008 .

Equilibrium and kinetic studies on the displacement of pyridine by chloride ion in pyridine[2,6-bis(methylthiomethyl)pyridine]-palladium(II) perchlorate☆

P. Uguagliati, F. Visentin, L. Canovese, 1995 .

Synthesis and characterization of palladacyclopentadiene complexes with N-heterocyclic carbene ligands

V. Bertolasi, T. Scattolin, C. Santo, 2015 .

Reactivity of N-heterocyclic carbene-pyridine palladacyclopentadiene complexes toward halogen addition. The unpredictable course of the reaction.

N. Demitri, T. Scattolin, C. Santo, 2017, Dalton transactions.

Addition of halogens and interhalogens on palladacyclopentadienyl complexes stabilized by pyridyl−thioether N−S spectator ligands

V. Bertolasi, T. Scattolin, C. Santo, 2016 .

The anticancer activity of an air-stable Pd(I)-NHC (NHC = N-heterocyclic carbene) dimer.

V. Canzonieri, L. Cavallo, T. Perin, 2020, Chemical communications.

Synthesis, characterization, dynamics and reactivity toward amination of η3-allyl palladium complexes bearing mixed ancillary ligands. Evaluation of the electronic characteristics of the ligands from kinetic data.

C. Levi, A. Dolmella, F. Visentin, 2011, Dalton transactions.

Oxidative addition of allyl and propargyl halides on palladium(0)complexes bearing bidentate ligands with quinolinic structure

V. Bertolasi, T. Scattolin, C. Santo, 2015 .

Insertion of Isocyanides across the Pd–C Bond of Phosphinoquinoline Allyl Palladium Complexes Bearing η1- and η3-Coordinated Allyl Groups. A Synthetic and Mechanistic Study

V. Bertolasi, C. Santo, F. Visentin, 2014 .

Palladium(II) allyl complexes with potentially terdentate ancillary ligands. Mechanism of allyl amination by piperidine

P. Uguagliati, F. Visentin, L. Canovese, 1999 .

Mechanism of the reaction of allyl amination of Pd(II) allyl complexes containing chelating pyridine–chalcogen ligands. A surprisingly low influence of the chalcogen atom

P. Uguagliati, C. Santo, F. Visentin, 2001 .

Palladium(II) allyl complexes with nitrogen–sulfur bidentate ligands. Substituent effects in the mechanism of allyl amination

P. Uguagliati, F. Visentin, L. Canovese, 1998 .

Novel palladium(II) allyl complexes with nitrogen-sulfur donor bidentate ligands. Mechanism of allyl amination of [Pd(η3-allyl)-(N-SR)]ClO4 (allyl = C3H5; N-SR = C5H4N-2-CH2SR, R = C6H5, C2H5) in the presence of activated olefins. X-ray structure determination and fluxional behavior

V. Lucchini, G. Bandoli, P. Uguagliati, 1998 .

Low valent palladium benzoquinone complexes bearing different spectator ligands. The versatile coordinative capability of benzoquinone

V. Bertolasi, C. Santo, F. Visentin, 2014 .

The mechanism of olefin exchange in platinum(0) pyridyl–methanimine and pyridyl–thioether complexes. A kinetic study

M. Polito, L. Maini, P. Uguagliati, 2002 .

A novel mechanism for the fluxional behaviour of [Pd(η2-tetramethylethylenetetracarboxylate)(2-methylthiomethylpyridine)]

A. Zambon, V. Lucchini, C. Santo, 2002 .

Luminescent complexes of the zinc triad with N-substituted 8-amino-quinoline ligands: Synthesis and comparative study on the stability constants and related photophysical properties

C. Levi, P. Nikolov, F. Visentin, 2009 .

Palladium(II) and palladium(0) complexes of pyridylthioether-based metallodendrimers. Synthesis, characterization, and mechanistic study of the influence of wedge size on allyl amination

P. Uguagliati, C. Santo, F. Visentin, 2002 .

Solution Behavior and X-ray Structure of Cationic Allylpalladium(II) Complexes with Iminophosphine Ligands. Kinetics and Mechanism of Allyl Amination by Secondary Amines

G. Bandoli, S. Antonaroli, B. Crociani, 1999 .

The interaction between heteroditopic pyridine–nitrogen NHC with novel sulfur NHC ligands in palladium(0) derivatives: Synthesis and structural characterization of a bis-carbene palladium(0) olefin complex and formation in solution of an alkene–alkyne mixed intermediate as a consequence of the ligan

C. Levi, V. Bertolasi, C. Santo, 2012 .

Facile synthesis and reactivity study of mixed phosphane–isocyanide Pd(II) and Pd(0) complexes

C. Levi, V. Bertolasi, C. Santo, 2011 .

Kinetics and mechanism of regioselective amination of the 1-phenylallyl group in cationic palladium(II) complexes bearing bidentate ligands

S. Antonaroli, B. Crociani, P. Uguagliati, 2001 .

Binding ability of 2,6-bis(methylthiomethyl)pyridine with proton, palladium(II) and copper(II) in aqueous solutions

P. Uguagliati, F. Visentin, L. Canovese, 1991 .

Mechanism of aminocarbene formation by nucleophilic attack on isocyanide ligands in platinum(II) 2-pyrazyl and 4-pyridyl complexes

B. Crociani, P. Uguagliati, F. Visentin, 1997 .

Triphenylene based metal-pyridine cages

P. Sgarbossa, G. Borsato, A. Scarso, 2019, Tetrahedron Letters.

Synthesis, characterization and anticancer activity of palladium allyl complexes bearing benzimidazole-based N-heterocyclic carbene (NHC) ligands

V. Canzonieri, A. Piccin, N. Demitri, 2021 .

Oxidative coupling of activated alkynes with palladium(0) olefin complexes: Side production of the highly symmetric hexamethyl mellitate species under mild conditions at low alkyne/complex molar ratios

C. Levi, P. Uguagliati, C. Santo, 2006 .

Substitution reactions between bis-chelate ligands in palladium(II) alkenyl complexes: an unusual way to form unstable trans-P complexes. A study on the isomerization mechanism.

A. Dolmella, C. Santo, F. Visentin, 2009, Dalton transactions.

Heck self-condensation of polycyclic haloalkenes: the case of (1R)-2-iodobornene

F. Fabris, O. Lucchi, F. Visentin, 2001 .

Synthesis and characterization of novel olefin complexes of palladium(0) with chelating bis(N-heterocyclic carbenes) as spectator ligands

N. Demitri, T. Scattolin, C. Santo, 2018, Polyhedron.

Synthesis of novel olefin complexes of palladium(0) bearing monodentate NHC, phosphine and isocyanide spectator ligands

V. Bertolasi, T. Scattolin, C. Santo, 2018 .

Addition of protic molecules to coordinated 2-pyridinecarboxaldehyde in gold(III), palladium(II), and platinum(II) complexes

F. Visentin, Bruno Pitteri, G. Annibale, 2000 .

Chloride-Modulated Insertion Reactions of Dimethylallene across the Pd-C Bond in Palladium Methyl Complexes Bearing Potentially Terdentate Pyridylthioether Ligands

L. Maini, G. Bandoli, P. Uguagliati, 2003 .

Allyl palladium complexes bearing carbohydrate‐based N ‐heterocyclic carbenes: Anticancer agents for selective and potent in vitro cytotoxicity

N. Demitri, F. Rizzolio, T. Scattolin, 2020 .

Chemoselective oxidative addition of vinyl sulfones mediated by palladium complexes bearing picolyl-N-heterocyclic carbene ligands.

N. Demitri, T. Scattolin, C. Santo, 2020, Dalton transactions.

Insertion of Substituted Alkynes into the Pd−C Bond of Methyl and Vinyl Palladium(II) Complexes Bearing Pyridylthioethers as Ancillary Ligands. The Influence of Ligand Substituents at Pyridine and Sulfur on the Rate of Insertion

A. Dolmella, P. Uguagliati, C. Santo, 2005 .

Combined Treatment of Cancer Cells Using Allyl Palladium Complexes Bearing Purine-Based NHC Ligands and Molecules Targeting MicroRNAs miR-221-3p and miR-222-3p: Synergistic Effects on Apoptosis

R. Gambari, I. Lampronti, A. Finotti, 2023, Pharmaceutics.

Qualitative and quantitative discrimination of fake and true alkene rotation processes in pd(η2-olefin) complexes. A new bimolecular mechanism

A. Zambon, V. Lucchini, G. Borsato, 2009 .

Further crystallographic evidence of NH ? (system) and CO ? (system) interactions: The structures of bis(diarylhydrazonecarbonyl)methylene derivatives [{ArPhC?NNH?C(O)}2CH2] (Ar = Ph, 2-C5H4N, 2-C4H3S)

G. Valle, R. Bertani, L. Pandolfo, 1999 .

The importance of the electronic and steric features of the ancillary ligands on the rate of cis–trans isomerization of olefins coordinated to palladium(0) centre. A study involving (Z)-1,2-ditosylethene as olefin model

N. Demitri, T. Scattolin, C. Santo, 2019, Polyhedron.

Palladium (0) olefin complexes bearing purine-based N-heterocyclic carbenes and 1,3,5-triaza-7-phosphaadamantane (PTA): Synthesis, characterization and antiproliferative activity toward human ovarian cancer cell lines

R. Gambari, I. Lampronti, N. Demitri, 2019, Journal of Organometallic Chemistry.

Role of the Ligand and of the Size and Flexibility of the Palladium-Ancillary Ligand Cycle on the Reactivity of Substituted Alkynes toward Palladium(0) Complexes Bearing Potentially Terdentate Nitrogen-Sulfur-Nitrogen or Nitrogen-Nitrogen-Nitrogen Ligands: Kinetic and Structural Study

C. Levi, G. Bandoli, P. Uguagliati, 2006 .

Synthesis, characterization and X-ray structural determination of palladium(0)–olefin complexes containing pyridin-thioethers as ancillary ligands. Equilibria and rates of olefin and ligand exchange

A. Dolmella, P. Uguagliati, F. Visentin, 2000 .

Indenyl and allyl palladate complexes bearing N‐heterocyclic carbene ligands: an easily accessible class of new anticancer drug candidates

A. Casini, V. Canzonieri, S. Nolan, 2022, European Journal of Inorganic Chemistry.

Palladium(II)-Indenyl Complexes Bearing N-Heterocyclic Carbene (NHC) Ligands as Potent and Selective Metallodrugs toward High-Grade Serous Ovarian Cancer Models.

N. Demitri, U. Kamenšek, T. Scattolin, 2024, Journal of medicinal chemistry.

Halogen metathesis in Pd(II) σ-butadienyl complexes

T. Scattolin, C. Santo, F. Visentin, 2016 .

Antibody Drug Conjugates for Cancer Therapy: From Metallodrugs to Nature-Inspired Payloads

T. Scattolin, F. Visentin, Flavio Rizzolio, 2024, International Journal of Molecular Sciences.

Kinetic Studies of the Oxidative Addition and Transmetallation Steps Involved in the Cross‐Coupling of Alkynyl Stannanes with Aryl Iodides Catalysed by η2‐(Dimethyl fumarate)(iminophosphane)palladium(0) Complexes

S. Antonaroli, B. Crociani, P. Uguagliati, 2004 .

Mechanism of oxidative allyl transfer from allylic ammonium cations to palladium(0) α-diimine complexes

B. Crociani, P. Uguagliati, F. Visentin, 1996 .