S. Virgil

发表

Incorporation of a chiral gem-disubstituted nitrogen heterocycle yields an oxazolidinone antibiotic with reduced mitochondrial toxicity.

Alexander W. Sun, Jeff F. Miller, B. Stoltz, 2019, Bioorganic & medicinal chemistry letters.

Effects of NHC-backbone substitution on efficiency in ruthenium-based olefin metathesis.

R. Grubbs, Cheol K. Chung, S. Virgil, 2009, Journal of the American Chemical Society.

Low catalyst loadings in olefin metathesis: synthesis of nitrogen heterocycles by ring-closing metathesis.

Richard L. Pederson, R. Grubbs, Wentao Wei, 2010, Organic letters.

Rapid synthesis of an electron-deficient t-BuPHOX ligand: cross-coupling of aryl bromides with secondary phosphine oxides.

H. Mukherjee, B. Stoltz, S. Virgil, 2010, Tetrahedron letters.

Using decoys to expand the recognition specificity of a plant disease resistance protein

N. Schley, M. Shahgholi, D. VanderVelde, 2016 .

New Mechanistic and Stereochemical Insights on the Biosynthesis of Sterols from 2,3‐Oxidosqualene.

E. Corey, S. Sarshar, S. Virgil, 1992 .

Three Mutations Convert the Selectivity of a Protein Sensor from Nicotinic Agonists to S-Methadone for Use in Cells, Organelles, and Biofluids

Charlene H. Kim, J. Marvin, L. Looger, 2022, bioRxiv.

A Facile Method for Separation of the Cryptic Methionine Sulfoxide Diastereomers, Structural Assignment and DFT Analysis.

Hsiau-Wei Lee, Jevgenij A. Raskatov, L. M. Henling, 2019, Chemistry.

Enantioselective Pd-Catalyzed Decarboxylative Allylic Alkylation of Thiopyranones. Access to Acyclic, Stereogenic α-Quaternary Ketones.

B. Stoltz, M. Bartberger, S. Virgil, 2017, Organic letters.

Triphenylphosphine–N‐Bromosuccinimide

S. Virgil, 2001 .

The catalytic enantioselective total synthesis of (+)-liphagal.

B. Stoltz, R. McFadden, S. Virgil, 2011, Angewandte Chemie.

Cyclic alkyl amino carbene (CAAC) ruthenium complexes as remarkably active catalysts for ethenolysis.

R. Grubbs, V. Marx, G. Bertrand, 2015, Angewandte Chemie.

The total syntheses of basiliolide C, epi-basiliolide C, and protecting-group-free total syntheses of transtaganolides C and D.

B. Stoltz, H. Nelson, S. Virgil, 2014, The Journal of organic chemistry.

The Methyl Group at C(10) of 2,3-Oxidosqualene is Crucial to the Correct Folding of This Substrate in the Cyclization-Rearrangement Step of Sterol Biosynthesis

David R. Liu, E. Corey, S. Sarshar, 1992 .

Palladium-Catalyzed Decarbonylative Dehydration for the Synthesis of α-Vinyl Carbonyl Compounds and Total Synthesis of (-)-Aspewentins A, B, and C.

R. Grubbs, B. Stoltz, S. Virgil, 2015, Angewandte Chemie.

Investigations of an Unexpected [2+2] Photocycloaddition in the Synthesis of (-)-Scabrolide A from Quantum Mechanics Calculations.

W. Goddard, B. Stoltz, C. Reimann, 2022, The Journal of organic chemistry.

Stereochemical evaluation of bis(phosphine) copper catalysts for the asymmetric alkylation of 3-bromooxindoles with α-arylated malonate esters.

B. Stoltz, Seo-Jung Han, S. Virgil, 2015, Tetrahedron.

Enantioselective total synthesis of a protosterol, 3.beta.,20-dihydroxyprotost-24-ene

E. Corey, S. Virgil, 1990 .

Synthesis and Activity of Six-Membered Cyclic Alkyl Amino Carbene–Ruthenium Olefin Metathesis Catalysts

R. Grubbs, Ki-Young Yoon, Yan Xu, 2020 .

Enantioselective Construction of Quaternary N-Heterocycles by Palladium-Catalyzed Decarboxylative Allylic Alkylation of Lactams

B. Stoltz, D. Behenna, S. Virgil, 2011, Nature chemistry.

Total syntheses of cyanthiwigins B, F, and G.

B. Stoltz, S. Virgil, J. A. Enquist, 2011, Chemistry.

Catalytic enantioselective stereoablative alkylation of 3-halooxindoles: facile access to oxindoles with C3 all-carbon quaternary stereocenters.

B. Stoltz, Shyam Krishnan, S. Virgil, 2009, Angewandte Chemie.

Synthesis and Resolution of Quinazolinone Atropisomeric Phosphine Ligands(,).

X. Dai, S. Virgil, Audrey Wong, 1998, The Journal of organic chemistry.

Potassium tert-Butoxide-Catalyzed Dehydrogenative C-H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study.

R. Grubbs, K. Houk, R. Zare, 2017, Journal of the American Chemical Society.

Concise total syntheses of (–)-jorunnamycin A and (–)-jorumycin enabled by asymmetric catalysis

D. Slamon, K. Negoro, B. Stoltz, 2019, Science.

Highly Active Platinum Catalysts for Nitrile and Cyanohydrin Hydration: Catalyst Design and Ligand Screening via High-Throughput Techniques.

R. Grubbs, S. Virgil, Chen Xu, 2018, Journal of the American Chemical Society.

Total syntheses of (-)-transtaganolide A, (+)-transtaganolide B, (+)-transtaganolide C, and (-)-transtaganolide D and biosynthetic implications.

B. Stoltz, H. Nelson, S. Virgil, 2013, Angewandte Chemie.

Chemical Synthesis of (+)-Ryanodine and (+)-20-Deoxyspiganthine

S. Reisman, S. Virgil, Chen Xu, 2017, ACS central science.

Atroposelective Synthesis of PINAP via Dynamic Kinetic Asymmetric Transformation

B. Stoltz, Seo-Jung Han, S. Virgil, 2018, Advanced Synthesis & Catalysis.

Model Studies To Access the [6,7,5,5]-Core of Ineleganolide Using Tandem Translactonization-Cope or Cyclopropanation-Cope Rearrangements as Key Steps.

B. Stoltz, J. Roizen, Russell C. Smith, 2017, The Journal of organic chemistry.

Iridium-Catalyzed Enantioselective and Diastereoselective Hydrogenation of 1,3-Disubstituted Isoquinolines.

B. Stoltz, M. Bartberger, E. Welin, 2020, ACS catalysis.

Asymmetric synthesis of QUINAP via dynamic kinetic resolution.

B. Stoltz, S. Virgil, Vikram Bhat, 2013, Journal of the American Chemical Society.

Enantioselective vicinal hydroxylation of terminal and E-1,2-disubstituted olefins by a chiral complex of osmium tetraoxide. An effective controller system and a rational mechanistic model

R. D. Connell, E. Corey, P. Yuen, 1989 .

Control of Oligomerization and Oxidation Steps in the Synthesis of Tris(pentafluorophenyl)corrole

R. Grubbs, H. Gray, L. M. Henling, 2015 .

Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies.

Nathaniel H. Sherden, B. Stoltz, J. Roizen, 2011, Chemistry.

Regioselective reactions of highly substituted arynes.

B. Stoltz, S. Virgil, Pamela M. Tadross, 2010, Organic letters.

A palladium-catalysed enolate alkylation cascade for the formation of adjacent quaternary and tertiary stereocentres

B. Stoltz, S. Virgil, Jan Streuff, 2010, Nature Chemistry.

Asymmetric allylic alkylation catalyzed by palladium complexes with atropisomeric quinazolinone phosphine ligands

X. Dai, S. Virgil, 1999 .

Formal total syntheses of classic natural product target molecules via palladium-catalyzed enantioselective alkylation

B. Stoltz, J. Roizen, Jacquie Malette, 2014, Beilstein journal of organic chemistry.

Evolution of a Unified, Stereodivergent Approach to the Synthesis of Communesin F and Perophoramidine

B. Stoltz, Shyam Krishnan, J. A. May, 2014, The Journal of organic chemistry.

Aryne acyl-alkylation in the general and convergent synthesis of benzannulated macrolactone natural products: an enantioselective synthesis of (-)-curvularin.

B. Stoltz, S. Virgil, Pamela M. Tadross, 2010, Organic letters.

SYNTHESIS OF 2-HETEROSUBSTITUTED QUINAZOLINONE ATROPISOMERIC PHOSPHINE LIGANDS BY DIRECT LITHIATION OF A 2-UNSUBSTITUTED QUINAZOLINONE SYSTEM

X. Dai, S. Virgil, 1999 .

Expanding insight into asymmetric palladium-catalyzed allylic alkylation of N-heterocyclic molecules and cyclic ketones.

B. Stoltz, Nathan B. Bennett, Wen-Bo Liu, 2013, Chemistry.

A catalytic, asymmetric formal synthesis of (+)-hamigeran B.

H. Mukherjee, B. Stoltz, S. Virgil, 2011, Organic letters.

Unusual allylpalladium carboxylate complexes: identification of the resting state of catalytic enantioselective decarboxylative allylic alkylation reactions of ketones.

Nathaniel H. Sherden, B. Stoltz, D. Behenna, 2009, Angewandte Chemie.

Construction of vicinal tertiary and all-carbon quaternary stereocenters via Ir-catalyzed regio-, diastereo-, and enantioselective allylic alkylation and applications in sequential Pd catalysis.

B. Stoltz, Wen-Bo Liu, S. Virgil, 2013, Journal of the American Chemical Society.

A general approach to the basiliolide/transtaganolide natural products: total syntheses of basiliolide B, epi-8-basiliolide B, transtaganolide C, and transtaganolide D.

B. Stoltz, H. Nelson, K. Murakami, 2011, Angewandte Chemie.

The Total Synthesis of (-)-Scabrolide A.

B. Stoltz, C. Reimann, Beau P. Pritchett, 2020, Journal of the American Chemical Society.

New Insights Regarding the Cyclization Pathway for Sterol Biosynthesis from (S)-2,3-Oxidosqualene

E. Corey, S. Matsuda, S. Sarshar, 1995 .

A Diastereodivergent Synthetic Strategy for the Syntheses of Communesin F and Perophoramidine

B. Stoltz, Shyam Krishnan, J. A. May, 2014, Organic letters.

Catalytic Enantioselective Stereoablative Alkylation of 3‐Halooxindoles: Facile Access to Oxindoles with C3 All‐Carbon Quaternary Stereocenters.

B. Stoltz, Shyam Krishnan, S. Virgil, 2010 .

Unified Enantioselective, Convergent Synthetic Approach toward the Furanobutenolide-Derived Polycyclic Norcembranoid Diterpenes: Synthesis of a Series of Ineleganoloids by Oxidation-State Manipulation of the Carbocyclic Core.

B. Stoltz, J. Roizen, R. A. Craig, 2019, The Journal of organic chemistry.

Enantioselective Vicinal Hydroxylation of Terminal and E-1,2-Disubstituted Olefins by a Chiral Complex of Osmium Tetraoxide. An Effective Controller System and a Rational Mechanistic Model.

R. D. Connell, E. Corey, P. Yuen, 1990 .

Alkylidene transfer from phosphoranes to tungsten(IV) imido complexes

J. Ziller, R. Grubbs, S. Virgil, 1993 .

Structures and Spectroscopic Properties of Metallocorrole Nanoparticles.

H. Gray, J. Termini, Z. Gross, 2019, Inorganic chemistry.

Robotic Lepidoptery: Structural Characterization of (mostly) Unexpected Palladium Complexes Obtained from High-Throughput Catalyst Screening

J. Bercaw, N. Hazari, J. Labinger, 2009 .

Facile tungsten alkylidene synthesis: alkylidene transfer from a phosphorane to a tungsten imido complex

J. Ziller, R. Grubbs, S. Virgil, 1990 .

Asymmetric Total Synthesis of Havellockate.

B. Stoltz, S. Virgil, E. J. Alexy, 2022, Journal of the American Chemical Society.

Development of a Unified Enantioselective, Convergent Synthetic Approach Toward the Furanobutenolide-Derived Polycyclic Norcembranoid Diterpenes: Asymmetric Formation of the Polycyclic Norditerpenoid Carbocyclic Core by Tandem Annulation Cascade.

B. Stoltz, J. Roizen, R. A. Craig, 2018, Journal of Organic Chemistry.

1,3‐Dibromo‐5,5‐dimethylhydantoin

S. Virgil, 2001 .

Enantioselective, convergent synthesis of the ineleganolide core by a tandem annulation cascade

B. Stoltz, J. Roizen, Russell C. Smith, 2016, Chemical science.

Correction: Enantioselective, convergent synthesis of the ineleganolide core by a tandem annulation cascade† †Electronic supplementary information (ESI) available: X-ray crystal structure analysis of enone ent-12A. CCDC 1885720. For ESI and crystallographic data in CIF or other electronic format see

B. Stoltz, J. Roizen, R. A. Craig, 2019, Chemical science.

Pulsed-addition ring-opening metathesis polymerization: catalyst-economical syntheses of homopolymers and block copolymers.

R. Grubbs, John B. Matson, S. Virgil, 2009, Journal of the American Chemical Society.

An experimental demonstration of the stereochemistry of enzymic cyclization of 2,3-oxidosqualene to the protosterol system, forerunner of lanosterol and cholesterol

E. Corey, S. Virgil, 1991 .

1,3‐Diiodo‐5,5‐dimethylhydantoin

Todd A. Wenderski, S. Virgil, 2014 .

A covalent p97/VCP ATPase inhibitor can overcome resistance to CB-5083 and NMS-873 in colorectal cancer cells.

R. Deshaies, T. Chou, B. Stoltz, 2021, European journal of medicinal chemistry.

RAPID AND CONVERGENT SYNTHESIS OF A 2,4'-LINKED TRI-OXAZOLE IN AN APPROACH TO POLY-OXAZOLES (Dedicated to Professor Dr. Ei-ichi Negishi on the occasion of his 77th birthday)

S. Virgil, Haiming Zhang, Daniel D. Caspi, 2012 .

First‐Generation HIV‐1 Protease Inhibitors for the Treatment of HIV/AIDS

Scott C. Virgil, S. Virgil, 2011 .

New mechanistic and stereochemical insights on the biosynthesis of sterols from 2,3-oxidosqualene

E. Corey, S. Sarshar, S. Virgil, 1991 .

Nitrogen insertion into a corrole ring: iridium monoazaporphyrins.

H. Gray, A. Mahammed, Z. Gross, 2011, Angewandte Chemie.

Three Mutations Convert the Selectivity of a Protein Sensor from Nicotinic Agonists to S-Methadone for Use in Cells, Organelles, and Biofluids

Charlene H. Kim, J. Marvin, L. Looger, 2022, bioRxiv.

A Convergent Total Synthesis of (+)-Ineleganolide.

B. Stoltz, Seo-Jung Han, S. Virgil, 2023, Journal of the American Chemical Society.

Total Synthesis of Strempeliopidine and Non-Natural Stereoisomers through a Convergent Petasis Borono-Mannich Reaction.

B. Stoltz, A. W. Rand, S. Virgil, 2023, Journal of the American Chemical Society.

Enhanced Synthetic Access to Tris-CF3-Substituted Corroles.

H. Gray, Maryann Morales, A. Mahammed, 2020, Organic letters.

Enantioselective, convergent synthesis of the ineleganolide core by a tandem annulation cascade

B. Stoltz, Russell C. Smith, S. Virgil, 2016, Chemical science.

Pulsed-addition ring-opening metathesis polymerization: catalyst-economical syntheses of homopolymers and block copolymers.

R. Grubbs, John B. Matson, S. Virgil, 2009, Journal of the American Chemical Society.

Cyclic alkyl amino carbene (CAAC) ruthenium complexes as remarkably active catalysts for ethenolysis.

R. Grubbs, G. Bertrand, M. Melaimi, 2015, Angewandte Chemie.

A catalytic, asymmetric formal synthesis of (+)-hamigeran B.

B. Stoltz, S. Virgil, Nolan T. Mcdougal, 2011, Organic letters.

Total Synthesis of Aleutianamine

B. Stoltz, S. Virgil, Zachary P Sercel, 2023, Journal of the American Chemical Society.

Total Synthesis of Hypersampsone M

S. Virgil, Adrian E. Samkian, Brian M Stoltz, 2024, Journal of the American Chemical Society.