Rafael Fernández-Galán

发表

New guanidine-borane adducts: An experimental and theoretical approach

A. Toro‐Labbé, K. Muñoz-Becerra, C. Daniliuc, 2021 .

Synthesis and characterization of new allyl palladium complexes with thionate ligands; X-ray molecular structures of [Pd3(η3-C4H7)3{pm(Me)2S}2](CF3SO3) and [Pd{pm(Me)2S}2], η3-C4H7=η3-2-MeC3H4, pm(Me)2S=Pyridine-4,6-dimethyl-2-thionate

A. Otero, B. Manzano, M. Kubicki, 1999 .

Mono- and Dinuclear Asymmetric Aluminum Guanidinates for the Catalytic CO2 Fixation into Cyclic Carbonates

A. Rodríguez‐Diéguez, C. Daniliuc, A. Antiñolo, 2021, Organometallics.

Aromatic guanidines as highly active binary catalytic systems for the fixation of CO2 into cyclic carbonates under mild conditions

Javier Martínez, A. Antiñolo, René S. Rojas, 2019, Catalysis Science & Technology.

Selective Three-Component Coupling for CO2 Chemical Fixation to Boron Guanidinato Compounds.

A. Rodríguez‐Diéguez, A. Antiñolo, Daniel García-Vivó, 2018, Inorganic chemistry.

Simple ZnEt2 as a catalyst in carbodiimide hydroalkynylation: structural and mechanistic studies.

A. Antiñolo, F. Carrillo-Hermosilla, Rafael Fernández-Galán, 2017, Dalton transactions.

Carbodiimides as catalysts for the reduction of CO2 with boranes.

A. Antiñolo, Daniel García-Vivó, F. Carrillo-Hermosilla, 2018, Chemical communications.

Neutral Dimethylzirconocene Complexes as Initiators for the Ring-Opening Polymerization of ϵ-Caprolactone

A. Antiñolo, F. Carrillo-Hermosilla, Rafael Fernández-Galán, 2013 .

ZnEt2 as a Precatalyst for the Addition of Alcohols to Carbodiimides

A. Antiñolo, Daniel García-Vivó, F. Carrillo-Hermosilla, 2022, Organometallics.

Ph2PCH2CH2B(C8H14) and Its Formaldehyde Adduct as Catalysts for the Reduction of CO2 with Hydroboranes.

A. Antiñolo, F. Carrillo-Hermosilla, Rafael Fernández-Galán, 2020, Inorganic chemistry.

The catalytic performance of metal complexes immobilized on SBA-15 in the ring opening polymerization of ε-caprolactone with different metals (Ti, Al, Zn and Mg) and immobilization procedures.

M. Fajardo, Yolanda Pérez, Rafael Fernández-Galán, 2015, Dalton transactions.

New alkenyl-substituted group 4 C-ansa-metallocene complexes. Reactivity of the substituent at the carbon ansa bridge

A. Otero, Ana M. Rodríguez, I. Rivilla, 2009 .

Synthesis and reactivity of asymmetrically substituted ansa-bridged zirconocene complexes: X-ray crystal structures of [Zr{R(H)C(η5-C5Me4)(η5-C5H4)}Cl2] (R = Bun, But) and [Zr{Bun(H)C(η5-C5Me4)(η5-C5H4)}(CH2Ph)2]

A. Otero, S. Prashar, Ana M. Rodríguez, 2006 .

Synthesis and Reactivity of Alkylzirconium Complexes Incorporating Asymmetrically Substituted ansa Ligands − X-ray Crystal Structure of [Zr{Me2Si(η5-C5Me4)(η5-C5H3Me)}(CH2Ph)Cl]

A. Otero, S. Prashar, A. Antiñolo, 2003 .

New zirconium and zirconocene guanidinate complexes

A. Otero, A. Antiñolo, F. Carrillo-Hermosilla, 2012 .

C-ansa-zirconocene complexes with O/S donor ligands: Novel homoleptic six coordinate 4-mercaptophenolate complex of Zr(IV)

A. Otero, Ana M. Rodríguez, I. Rivilla, 2010 .

New Group 4 Metallocene and Niobocene Complexes Containing Phosphane-Functionalizedansa-Ligands

A. Otero, S. Prashar, A. Antiñolo, 2002 .

Reactivity of N-Phosphinoguanidines of the Formula (HNR)(Ph2PNR)C(NAr) toward Main Group Metal Alkyls: Facile Ligand Rearrangement from N-Phosphinoguanidinates to Phosphinimine-Amidinates.

A. Antiñolo, Daniel García-Vivó, F. Carrillo-Hermosilla, 2020, Inorganic chemistry.

Reactivity of the Dimer [{RuCl(μ-Cl)(η3:η3-C10H16)}2] (C10H16 = 2,7-Dimethylocta-2,6-diene-1,8-diyl) toward Guanidines: Access to Ruthenium(IV) and Ruthenium(II) Guanidinate Complexes

V. Cadierno, A. Antiñolo, Eder Tomás‐Mendivil, 2015 .

Tris(pentafluorophenyl)borane as an efficient catalyst in the guanylation reaction of amines.

C. Alonso-Moreno, I. Bravo, J. Albaladejo, 2016, Dalton transactions.

Unusual ligand rearrangement: from N-phosphinoguanidinato to phosphinimine-amidinato compounds.

A. Antiñolo, Daniel García-Vivó, F. Carrillo-Hermosilla, 2019, Chemical communications.

Guanidinates as Alternative Ligands for Organometallic Complexes

F. Carrillo-Hermosilla, Rafael Fernández-Galán, Alberto Ramos, 2022, Molecules.

The Reactivity of Allyl and Olefin‐Hydride Niobocene Derivatives Towards Isocyanides. X‐ray Crystal Structure of [Nb(η5‐C5H4SiMe3)2{η3‐CH(R)CHCH(R)}] (R = SiMe2tBu)

I. Hierro, A. Otero, S. Prashar, 2003 .

19F and 31P NMR evidence for silver hexafluorophosphate hydrolysis in solution. New palladium difluorophosphate complexes and x-ray structure determination of [Pd(.eta.3-2-Me-C3H4)(PO2F2)(PCy3)]

A. Otero, M. Lanfranchi, M. Pellinghelli, 1994 .

Mixed amido-/imido-/guanidinato niobium complexes: synthesis and the effect of ligands on insertion reactions.

A. Antiñolo, F. Carrillo-Hermosilla, Rafael Fernández-Galán, 2014, Dalton transactions.

Preparation and Structural Studies of Non-Symmetric Guanidinate-Supported Zirconium Complexes

A. Antiñolo, F. Carrillo-Hermosilla, Rafael Fernández-Galán, 2014 .

Half‐Sandwich Guanidinate–Osmium(II) Complexes: Synthesis and Application in the Selective Dehydration of Aldoximes

J. Borge, V. Cadierno, A. Antiñolo, 2016 .

New studies on the reactivity of allyl difluorophosphate palladium complexes: synthesis of the first difluorophosphate metallocene derivatives

A. Otero, B. Manzano, Rafael Fernández-Galán, 1999 .

Synthesis and molecular structures of palladium and platinum complexes of PTFA: models of Grignard cross-coupling catalysts

N. Veldman, A. Spek, H. Kooijman, 1996 .

Unexpected mild C-N bond cleavage mediated by guanidine coordination to a niobium iminocarbamoyl complex.

A. Antiñolo, F. Carrillo-Hermosilla, Rafael Fernández-Galán, 2013, Chemical communications.

Ruthenium(II) Arene Complexes with Asymmetrical Guanidinate Ligands: Synthesis, Characterization, and Application in the Base-Free Catalytic Isomerization of Allylic Alcohols

V. Cadierno, A. Antiñolo, J. Díez, 2012 .

New Alkylimido Niobium Complexes Supported by Guanidinate Ligands: Synthesis, Characterization, and Migratory Insertion Reactions

A. Otero, A. Antiñolo, F. Carrillo-Hermosilla, 2012 .

New Chiral Palladium(0) and -(II) Complexes of (Aminoferrocenyl)phosphine Ligands PPFA and PTFA. X-ray Crystal Structure Analysis and Fluxional Behavior Involving Alkene Rotation, Pd−N Bond Rupture, and Selective η3−η1−η3 Allyl Isomerization

F. A. Jalón, G. Jogl, Rafael Fernández-Galán, 1997 .

Migratory Insertion Reactions in Asymmetrical Guanidinate-Supported Zirconium Complexes

A. Otero, A. Antiñolo, F. Carrillo-Hermosilla, 2012 .

Insertion reactions of small unsaturated molecules in the N-B bonds of boron guanidinates.

A. Antiñolo, María P. Montero‐Rama, Daniel García-Vivó, 2017, Dalton transactions.

Dialkylboron guanidinates: syntheses, structures and carbodiimide de-insertion reactions.

A. Antiñolo, María P. Montero‐Rama, René S. Rojas, 2016, Dalton transactions.

Synthesis, Characterization and Reactivity of New Dinuclear Guanidinate Diimidoniobium Complexes

A. Antiñolo, F. Carrillo-Hermosilla, Rafael Fernández-Galán, 2013 .

Asymmetric niobium guanidinates as intermediates in the catalytic guanylation of amines.

A. Antiñolo, F. Carrillo-Hermosilla, Rafael Fernández-Galán, 2013, Dalton transactions.

New Synthon in the Design of ansa-Cyclopentadienyl Ligands with Variable Substitution at the Bridging Atom

A. Otero, S. Prashar, I. Rivilla, 2004 .

Synthesis and structural characterisation of new ansa-bis(propene)s and {ansa-bis(allyl)}alkali metal and {ansa-bis(allyl)}transition metal complexes

P. Hitchcock, Ana M. Rodríguez, A. Antiñolo, 2000 .

9-Borabicyclo[3.3.1]nonane: a metal-free catalyst for the hydroboration of carbodiimides.

A. Antiñolo, Daniel García-Vivó, F. Carrillo-Hermosilla, 2019, Chemical communications.

ε-Caprolactone polymerization using titanium complexes immobilized onto silica based materials functionalized with ionic liquids: insights into steric, electronic and support effects

I. Hierro, M. Fajardo, Yolanda Pérez, 2016 .