T. Harada

发表

Recent developments in asymmetric reduction of ketones with biocatalysts

T. Matsuda, Rio Yamanaka, Kaoru Nakamura, 2003 .

Transformation of benzonitrile into benzyl alcohol and benzoate esters in supercritical alcohols

Kenji Yamamoto, T. Matsuda, T. Harada, 2008 .

Chiral synthesis of secondary alcohols using Geotrichum candidum.

T. Matsuda, Kaoru Nakamura, T. Harada, 2002, Chirality.

Two classes of enzymes of opposite stereochemistry in an organism: one for fluorinated and another for nonfluorinated substrates.

T. Itoh, T. Matsuda, T. Harada, 2000, The Journal of organic chemistry.

Asymmetric Reduction of Ketones by Geotrichum candidum: Immobilization and Application to Reactions Using Supercritical Carbon Dioxide.

T. Matsuda, Kaoru Nakamura, T. Harada, 2009 .

Alcohol dehydrogenase is active in supercritical carbon dioxide

T. Matsuda, Kaoru Nakamura, T. Harada, 2000 .

Recent Developments in Asymmetric Reduction of Ketones with Biocatalysts

T. Matsuda, Rio Yamanaka, Kaoru Nakamura, 2003 .

High-efficiency and minimum-waste continuous kinetic resolution of racemic alcohols by using lipase in supercritical carbon dioxide.

Kazunori Watanabe, T. Ikariya, T. Matsuda, 2004, Chemical communications.

Novel continuous carboxylation using pressurized carbon dioxide by immobilized decarboxylase

T. Matsuda, Kaoru Nakamura, T. Nagasawa, 2008 .

Asymmetric synthesis using hydrolytic enzymes in supercritical carbon dioxide

T. Ikariya, T. Matsuda, Kaoru Nakamura, 2005 .

Rate Enhancement of Lipase-catalyzed Reaction in Supercritical Carbon Dioxide

T. Ikariya, T. Matsuda, Kaoru Nakamura, 2005 .

Reactions of supercritical alcohols with unsaturated hydrocarbons

T. Matsuda, H. Ozaki, T. Harada, 2003 .

Reduction of acetophenone using supercritical 2-propanol: the substituent effect and the deuterium kinetic isotope effect

T. Matsuda, T. Harada, Takashi Kamitanaka, 2003 .

Mechanism for the reduction of ketones to the corresponding alcohols using supercritical 2-propanol

T. Matsuda, T. Harada, Takashi Kamitanaka, 2007 .

Asymmetric synthesis of (R)-2-chloro-1-(m-chlorophenyl)ethanol using acetone powder of Geotrichum candidum

T. Miura, T. Matsuda, Kaoru Nakamura, 2001, Biotechnology Letters.

Enzymatic Reactions in Supercritical CO2: Carboxylation, Asymmetric Reduction and Esterification

Kazunori Watanabe, T. Matsuda, Kaoru Nakamura, 2004 .

Organic synthesis using enzymes in supercritical carbon dioxide

T. Matsuda, Kaoru Nakamura, T. Harada, 2004 .

Conversion of pyrrole to pyrrole-2-carboxylate by cells of Bacillus megaterium in supercritical CO2.

T. Matsuda, T. Nagasawa, T. Harada, 2001, Chemical communications.

Solvent-free reactions of solid substances using solid catalysts: estimation of physical states of substrate–product mixtures by the BET method and the SEM observation

T. Harada, Toshiyuki Kitamura, 2001 .

Non-solvent hydrogenation of solid alkenes and alkynes with supported palladium catalysts

T. Osawa, T. Harada, Toshiyuki Kitamura, 2001 .

Control of enantioselectivity of lipase-catalyzed esterification in supercritical carbon dioxide by tuning the pressure and temperature

Kazunori Watanabe, T. Matsuda, Kaoru Nakamura, 2003 .

Control on enantioselectivity with pressure for lipase-catalyzed esterification in supercritical carbon dioxide

Kazunori Watanabe, T. Matsuda, Kaoru Nakamura, 2001 .

Hydrogenolysis of disodium trans-epoxysuccinate in the solid-to-solid state with palladium catalysts

T. Harada, Toshiyuki Kitamura, 1999 .

Supercritical carbon dioxide as a reaction medium for enzymatic kinetic resolution of P-chiral hydroxymethanephosphinates

T. Matsuda, Kaoru Nakamura, J. Drabowicz, 2005 .

Atropisomerism in polymers. Screw-sense selective polymerization of isocyanides by inhibiting the growth of one enantiomer of a racemic pair of helices

R. Nolte, P. Kamer, W. Drenth, 1988 .

Stereochemical Studies of the Hydrogenation with an Asymmetrically Modified Raney Nickel Catalyst. The Hydrogenation of Acetylacetone

A. Tai, T. Harada, K. Ito, 1981 .

The Stereo-differentiating (Asymmetric) Hydrogenation of the C=O Double Bond with a Modified Nickel Catalyst. XXXV. A Facile Method for the Preparation of Optically Pure β-Diols

A. Tai, T. Harada, K. Ito, 1980 .

The Preparation of Optically Pure 3-Hydeoxybutanoic Acid and Its Homologues as the Dibenzylammonium Salt

T. Sugimura, A. Tai, T. Harada, 1987 .

Stereochemical Investigation on Asymmetrically Modified Raney Nickel Catalyst. Mode of Interaction between Modifying Reagent and Substrate in the Enantioface-differentiating Process

A. Tai, T. Harada, Yuji Hiraki, 1983 .

The enantioface-differentiating (asymmetric) hydrogenation of the C=O double bond with modified raney nickel. XXXVI. The development of modified nickel catalysts with high enantioface-differentiating abilities.

A. Tai, Y. Izumi, H. Ozaki, 1981 .

Ring-methylation of pyrrole and indole using supercritical methanol

T. Matsuda, T. Osawa, T. Harada, 2010 .

Selective reduction of unsaturated aldehydes to unsaturated alcohols using supercritical 2-propanol

T. Matsuda, T. Harada, Takashi Kamitanaka, 2006 .

The Meerwein-Ponndorf-Verley-Oppenauer type reaction in supercritical or high-temperature alcohols or acetone without catalyst: Effect of oxidation enthalpy and solvent concentrations on yield

T. Matsuda, H. Morishima, T. Harada, 2009 .

Enantio-differentiating hydrogenation of methyl acetoacetate over tartaric acid-NaBr-modified Raney nickel catalyst under a low hydrogen pressure

T. Osawa, I.‐Yin Sandy Lee, T. Harada, 2011 .

Studies of the effects of the modification conditions on the hydrogenation rate for the enantio-differentiating hydrogenation of methyl acetoacetate over a tartaric acid–NaBr-modified nickel catalyst

T. Osawa, T. Harada, O. Takayasu, 2006 .

Asymmetrically Modified Nickel Catalyst for the Enantio-Differentiating Hydrogenation of Prochiral Ketones

T. Osawa, T. Harada, O. Takayasu, 2006 .

Enantio-differentiating hydrogenation of methyl acetoacetate over tartaric acid-NaBr-modified supported nickel catalyst prepared from nickel acetylacetonate

T. Osawa, I. Matsuura, T. Harada, 2000 .

Acceleration of the Hydrogenation of 2-Octanone with an Alkali Salt of an Organic Acid

T. Osawa, T. Harada, 1991 .

Enantio-differentiating Hydrogenation of 2-Alkanones over asymmetrically modified nickel catalyst and its application to the preparation of optically pure 2-alkanols

T. Osawa, A. Tai, T. Harada, 1990 .

The enantioface-differentiating hydrogenation of the C=O double bond with asymmetrically modified Raney nickel. XXXVIII: The hydrogenation of methyl ketones to optically active secondary alcohols

T. Osawa, T. Harada, 1984 .

IMPROVED MODIFIED RANEY NICKEL CATALYST FOR ENANTIOFACE-DIFFERENTIATING (ASYMMETRIC) HYDROGENATION OF METHYL ACETOACETATE

Y. Izumi, T. Harada, 1978 .

Direct addition of supercritical alcohols, acetone or acetonitrile to the alkenes without catalysts

T. Matsuda, S. Hayashi, T. Harada, 2007 .

Solid-phase hydrogenolysis of trans-epoxysuccinic acid with Pd catalysts

T. Osawa, T. Harada, Toshiyuki Kitamura, 1997 .

Asymmetrically Modified Nickel Catalysts

A. Tai, T. Harada, 1986 .

An Improved Asymmetrically-Modified Nickel Catalyst Prepared from Ultrasonicated Raney Nickel.

T. Sugimura, Y. Inoue, T. Osawa, 1994 .

Enantio-Differentiating Hydrogenation of Methyl acetoacetate over Asymmetrically Modified Reduced Nickel Catalysts: The Effects of the Coverage of the Modifiers on the Enantio-Differentiating Ability

T. Osawa, T. Harada, O. Takayasu, 2009 .

Progress of enantio-differentiating hydrogenation of prochiral ketones over asymmetrically modified nickel catalysts and a newly proposed enantio-differentiation model

T. Osawa, T. Harada, O. Takayasu, 2000 .

Enantio-differentiating hydrogenation of prochiral ketones over modified nickel

A. Tai, T. Harada, Tsutomu Osaw, 1997 .

ENANTIOFACE-DIFFERENTIATING HYDROGENATION OF 2-OCTANONE OVER MODIFIED RANEY NICKEL IN THE REACTION MEDIA CONTAINING ORGANIC ACID

T. Osawa, T. Harada, 1982 .

Modification of Nickel Surface With Optically Active Substrate: The Method and Mechanism

A. Tai, Y. Izumi, T. Harada, 1982 .

The enantioface-differentiating hydrogenation of the C=O double bond with asymmetrically modified raney nickel. XXXIII. The preparation of (R)- and (S)-1,3-butanediol from 4-hydroxy-2-butanone.

A. Tai, T. Harada, S. Murakami, 1980 .

Enantioface-differentiating (Asymmetric) Hydrogenation of Keto Ester with Modified Nickel Catalyst. XXXII. Structural Requirements of Modifying Reagent and Substrate

S. Okamoto, A. Tai, T. Harada, 1979 .

Stereochemical Studies of the Hydrogenation with Asymmetrically Modified Nickel Catalysts; The Hydrogenation of Methyl 2-Alkyl-3-oxobutyrate

A. Tai, T. Harada, Hiroshi Watanabe, 1979 .

Asymmetric Hydrogenation of C=O Double Bond with Modified Raney Nickel. XIX

Y. Izumi, T. Harada, M. Imaida, 1971 .

Asymmetric Hydrogenation of C=O Double Bond with Modified Raney Nickel. XVII

K. Okuda, Y. Izumi, T. Harada, 1971 .

Asymmetric Hydrogenation of C=O Double Bond with Modified Raney Nickel. XI

S. Yajima, Y. Izumi, T. Ninomiya, 1969 .

Synthesis and molecular structure of [7]circulene

Y. Kai, N. Kasai, Koji Yamamoto, 1988 .

Synthesis and characterization of [7]circulene

Y. Kai, N. Kasai, Koji Yamamoto, 1983 .

Biocatalytic reduction of ketones by a semi-continuous flow process using supercritical carbon dioxide.

Kazunori Watanabe, T. Matsuda, Kaoru Nakamura, 2003, Chemical communications.

Asymmetric reduction of simple aliphatic ketones with dried cells of Geotrichum candidum

T. Matsuda, Kaoru Nakamura, T. Harada, 2002 .

Mechanism for improving stereoselectivity for asymmetric reduction using acetone powder of microorganism

T. Matsuda, Kaoru Nakamura, T. Harada, 2000 .

The Preparation of Optically Pure 3-Hydroxyalkanoic Acid. The Enantioface-differentiating Hydrogenation of the C=O Double Bond with Modified Raney Nickel. XXXVII.

A. Tai, H. Ozaki, T. Harada, 1982 .

A FACILE METHOD FOR PREPARATION OF THE OPTICALLY PURE 3-HYDROXYTETRADECANOIC ACID BY AN APPLICATION OF ASYMMETRICALLY MODIFIED NICKEL CATALYST

S. Kusumoto, A. Tai, T. Shiba, 1980 .

Asymmetric reduction of ketones by Geotrichum candidum: immobilization and application to reactions using supercritical carbon dioxide

T. Matsuda, Kaoru Nakamura, T. Harada, 2008 .

Enantio-differentiating hydrogenation of methyl acetoacetate over modified Raney nickel catalysts prepared by two-step modifications

K. Yoshino, T. Osawa, T. Harada, 2006 .

Screw Sense Differentiating Polymerization of Achiral Isocyanides

R. Nolte, W. Drenth, T. Harada, 1984 .

Study of the parameters controlling the enantio-differentiating ability of asymmetrically modified solid catalysts for the hydrogenation of γ-ketoesters

T. Osawa, T. Harada, Eri Mieno, 2003 .

Studies of co-modifier and carboxylic acid for the enantio-differentiating hydrogenation of 2-octanone over a tartaric acid in situ modified nickel catalyst

T. Osawa, Y. Nakagawa, T. Harada, 2009 .

Transesterification of supercritical ethyl acetate by higher alcohol

T. Matsuda, T. Osawa, T. Harada, 2010 .

Crystallization Condition of Glassy Syndiotactic Polystyrene in Supercritical CO2

T. Matsuda, T. Harada, T. Nakaoki, 2003 .

Study of the properties of nickel oxide and nickel as precursors for the tartaric acid-NaBr-modified nickel catalyst

T. Osawa, T. Harada, O. Takayasu, 2005 .

Enantio-differentiating hydrogenation of methyl acetoacetate over asymmetrically modified reduced nickel catalysts: The effects of the nickel sources on the enantio-differentiating ability

T. Osawa, T. Harada, O. Takayasu, 2004 .

Modification Method Studies for the Preparation of Tartaric acid-NaBr-Modified Nickel Catalyst for the Enantio-differentiating Hydrogenation of Methyl Acetoacetate

T. Osawa, T. Harada, O. Takayasu, 2006 .

Application of an in situ modification of nickel catalysts to the enantio-differentiating hydrogenation of methyl acetoacetate

T. Osawa, T. Harada, O. Takayasu, 2001 .

Enantio-differentiating hydrogenation of methyl acetoacetate over fine nickel powder with in situ modification

T. Osawa, T. Harada, O. Takayasu, 2000 .

New Preparation Method of Asymmetrically Modified Supported Nickel Catalysts for the Enantio-differentiating Hydrogenation of Methyl Acetoacetate

T. Osawa, I. Matsuura, T. Harada, 1998 .

A novel method for enzymatic asymmetric reduction of ketones in a supercritical carbon dioxide/water biphasic system

T. Matsuda, Kaoru Nakamura, T. Harada, 2009 .

High‐Efficiency and Minimum‐Waste Continuous Kinetic Resolution of Racemic Alcohols by Using Lipase in Supercritical Carbon Dioxide.

Kazunori Watanabe, T. Ikariya, T. Matsuda, 2005 .

Enantio-differentiating hydrogenation of 3-alkanones with asymmetrically modified fine nickel powder

T. Osawa, I. Matsuura, A. Tai, 1997 .

Stereochemical studies of the enantio-differentiating hydrogenation of various prochiral ketones over tartaric acid-modified nickel catalyst

T. Sugimura, T. Osawa, S. Nakagawa, 1996 .

Synthesis and Molecular Structure of (7)Circulene.

Y. Kai, N. Kasai, Koji Yamamoto, 1988 .

Biocatalysis in Supercritical CO2

T. Matsuda, Kaoru Nakamura, T. Harada, 2005 .

Characterization of the Surface of Asymmetrically Modified Nickel Catalyst; An Approach for the Development of Highly Effective Enantioface-Differentiating (Asymmetric) Hydrogenation Catalyst

A. Tai, Y. Izumi, H. Ozaki, 1981 .

The Durability of the Enantio-Differentiating Ability of a Tartaric Acid–NaBr-Modified Reduced Nickel Catalyst Pre-Modified in Tetrahydrofuran

T. Osawa, T. Harada, O. Takayasu, 2006 .

Enantio-differentiating hydrogenation of methyl acetoacetate over reduced nickel catalysts pre-modified in methanol

T. Osawa, T. Harada, O. Takayasu, 2005 .

Highly Durable Enantio-Differentiating Nickel Catalyst for Repeated Use for the Hydrogenation of Methyl Acetoacetate

T. Osawa, T. Harada, O. Takayasu, 2001 .

Repeated use of the in-situ modified nickel catalyst for the enantio-differentiating hydrogenation of 2-octanone

T. Osawa, T. Harada, O. Takayasu, 2004 .

A FACILE METHOD FOR THE PREPARATION OF OPTICALLY PURE 2,4-PENTANEDIOL; AN APPLICATION OF ASYMMETRICALLY MODIFIED NICKEL CATALYST FOR THE PREPARATION OF OPTICALLY ACTIVE COMPOUNDS

A. Tai, Y. Izumi, T. Harada, 1979 .

Mode of enantioface-differentiation in the hydrogenation of 2-alkanone over an asymmetrically modified nickel catalyst

T. Osawa, A. Tai, T. Harada, 1994 .