A. Fraile

发表

Asymmetric [2+2] photocycloaddition via charge transfer complex for the synthesis of tricyclic chiral ethers.

T. Rigotti, S. Díaz-Tendero, Pablo Domingo-Legarda, 2021, Chemical communications.

Chromoselective access to Z- or E- allylated amines and heterocycles by a photocatalytic allylation reaction

R. Pérez-Ruíz, Leyre Marzo, R. Mas‐Ballesté, 2019, Nature Communications.

Boron Dipyrromethene (BODIPY) as Electron‐Withdrawing Group in Asymmetric Copper‐Catalyzed [3+2] Cycloadditions for the Synthesis of Pyrrolidine‐Based Biological Sensors

T. Rigotti, Á. Somoza, S. Díaz-Tendero, 2020, Advanced Synthesis & Catalysis.

BODIPY as electron withdrawing group for the activation of double bonds in asymmetric cycloaddition reactions† †Electronic supplementary information (ESI) available. CCDC 1880124. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc00959k

S. Díaz-Tendero, J. Alemán, E. Peña‐Cabrera, 2019, Chemical science.

Oxidized Multiwalled Nanotubes as Efficient Carbocatalyst for the General Synthesis of Azines

S. Agnoli, J. Alemán, M. Blanco, 2022, Journal of Catalysis.

Intramolecular hydrogen-bond activation for the addition of nucleophilic imines: 2-hydroxybenzophenone as a chemical auxiliary.

S. Díaz-Tendero, Alberto F. Garrido-Castro, J. Alemán, 2018, Chemical communications.

C-〔o-(p-TOLYL)SULFINYL〕PHENYLNITRONES : SYNTHESIS AND REACTIVITY IN 〔3+2〕 DIPOLAR CYCLOADDITIONS (Dedicated to Dr. Albert Padwa on his 75th birthday)

A. Nuñez, I. Alonso, J. G. Ruano, 2012 .

Expanding the scope of arylsulfonylacetylenes as alkynylating reagents and mechanistic insights in the formation of Csp2-Csp and Csp3-Csp bonds from organolithiums.

S. Díaz-Tendero, Leyre Marzo, J. Alemán, 2012, Chemistry.

Methyl sulfinates as electrophiles in Friedel-Crafts reactions. Synthesis of aryl sulfoxides.

B. Ortíz, J. G. Ruano, A. Fraile, 2011, The Journal of organic chemistry.

Enantioselective Synthesis of 4‐Isoxazolines by 1,3‐Dipolar Cycloadditions of Nitrones to Alkynals Catalyzed by Fluorodiphenylmethylpyrrolidines

S. Díaz-Tendero, Leyre Marzo, J. Alemán, 2012 .

Thiol–ene/oxidation tandem reaction under visible light photocatalysis: synthesis of alkyl sulfoxides† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7cc05672a

J. Alemán, A. Fraile, Fereshteh Ahmadi, 2017, Chemical communications.

Control of the dual reactivity (iminium-dienamine) of β-arylmethyl α,β-unsaturated aldehydes in organocatalytic 1,3-dipolar cycloadditions with N-benzoyl C,N-cyclic azomethine imines.

J. Alemán, A. Fraile, A. Parra, 2014, The Journal of organic chemistry.

Asymmetric synthesis of hexahydropyrrolo-isoquinolines by an organocatalytic three-component reaction.

Rebecca L. Davis, K. Jørgensen, A. Albrecht, 2012, Chemistry.

"Anti-Michael addition" of Grignard reagents to sulfonylacetylenes: synthesis of alkynes.

J. Alemán, J. L. García Ruano, A. Fraile, 2017, Organic & biomolecular chemistry.

High-entropy Fe-Cr-Ni-Co-(Cu) coatings produced by vacuum electro-spark deposition for marine and coastal applications

T. Polcar, D. Shtansky, S. G. Ignatov, 2023, Surface and Coatings Technology.

Arylsulfonylacetylenes as alkynylating reagents of Csp2-H bonds activated with lithium bases.

Leyre Marzo, J. Alemán, Cuauhtémoc Alvarado, 2012, Angewandte Chemie.

2‐Hydroxybenzophenone as a Chemical Auxiliary for the Activation of Ketiminoesters for Highly Enantioselective Addition to Nitroalkenes under Bifunctional Catalysis

J. Alemán, Ana Martín-Sómer, A. Fraile, 2018, Angewandte Chemie.

Asymmetric synthesis of pyrrolo[2,1-a]isoquinoline derivatives by 1,3-dipolar cycloadditions of stabilized isoquinolinium N-ylides with sulfinyl dipolarophiles.

A. Fraile, J. L. Ruano, A. M. Martín-Castro, 2011, The Journal of organic chemistry.

Efficient synthesis of new 3-heteroaryl-1-functionalized 1H-indazoles

J. G. Ruano, A. Fraile, M. R. Martín, 2011 .

Asymmetric Synthesis of 1,2-Diamines bearing Tetrasubstituted Centers from Nonstabilized Azomethine Ylides and N-Sulfinylketimines under Brønsted Acid Catalysis.

J. Alemán, A. Fraile, J. L. Ruano, 2016, Organic letters.

Organocatalytic Transformations of Alkynals, Alkynones, Propriolates, and Related Electron-Deficient Alkynes

J. Alemán, A. Fraile, A. Parra, 2014 .

Abnormal behaviour of allenylsulfones under Lu's reaction conditions: synthesis of enantiopure polyfunctionalised cyclopentenes.

A. Nuñez, J. L. García Ruano, A. Fraile, 2010, Chemistry.

Totally regio- and stereoselective behavior of mono- and diactivated cyclic alkenes in the Lu reaction: synthesis of enantiopure functionalized cyclopentanes.

A. Nuñez, J. L. García Ruano, A. Fraile, 2008, The Journal of organic chemistry.

Development and Application of Asymmetric Organocatalytic Mukaiyama and Vinylogous Mukaiyama-Type Reactions.

Alberto F. Garrido-Castro, J. Alemán, A. Fraile, 2018, Chemistry.

Enantioselective H-bond-directing approach for trienamine-mediated reactions in asymmetric synthesis.

K. Jørgensen, Ł. Albrecht, A. Albrecht, 2012, Angewandte Chemie.

Regio- and stereoselective synthesis of pyrrolo or azepine-fused cyclopenta[d]isoxazolines from 2-p-tolylsulfinylcyclopent-2-en-1-one

J. F. Soriano, A. Nuñez, J. L. García Ruano, 2013 .

Pyrrolo[2,1-b]thiazole derivatives by asymmetric 1,3-dipolar reactions of thiazolium azomethine ylides to activated vinyl sulfoxides.

J. L. García Ruano, A. Fraile, M. R. Martín, 2008, The Journal of organic chemistry.

Organophosphorus reagents in organocatalysis: synthesis of optically active α-methylene-δ-lactones and δ-lactams.

Fabio Morana, K. Jørgensen, A. Albrecht, 2012, Chemistry.

A General Asymmetric Formal Synthesis of Aza-Baylis-Hillman Type Products under Bifunctional Catalysis.

J. Alemán, A. Fraile, Ana C. Carrasco, 2017, Chemistry.

Synthesis of bicyclo[3.1.0]hexanones via 1,3-dipolar cycloaddition of diazoalkanes to homochiral α-sulfinyl-2-cyclopentenones

J. G. Ruano, A. Fraile, F. Yuste, 2008 .

Intramolecular Hydrogen Bond Activation: Thiourea-Organocatalyzed Enantioselective 1,3-Dipolar Cycloaddition of Salicylaldehyde-Derived Azomethine Ylides with Nitroalkenes

J. Alemán, E. Arpa, A. Fraile, 2018, ACS catalysis.

Intramolecular Hydrogen-Bond Activation: Strategies, Benefits, and Influence in Catalysis

J. Alemán, A. Fraile, Andrea Guerrero-Corella, 2022, ACS organic & inorganic Au.

1,3-cycloaddition of nitrile oxides to cyclic and open-chain 4-oxo-2-sulfinylbut-2-enoic acid derivatives

J. G. Ruano, A. Fraile, M. R. Martín, 1999 .

The role of steric and electronic interactions in the stereocontrol of the asymmetric 1,3-dipolar reactions of 5-ethoxy-3-p-(S)-tolylsulfinylfuran-2(5H)-ones with diazoalkanes: theoretical calculations and experimental evidences.

J. L. García Ruano, A. Fraile, R. Gordillo, 2003, The Journal of organic chemistry.

Asymmetric synthesis of 4-ethoxy-1-p-tolylsulfonyl-3,6-dioxabicyclo[3.1.0]hexan-2-ones

J. G. Ruano, A. Fraile, M. R. Martín, 2010 .

Enantioselective Organocatalyzed aza ‐Michael Addition Reaction of 2‐Hydroxybenzophenone Imines to Nitroolefins under Batch and Flow Conditions

J. Alemán, A. Fraile, Andrea Guerrero-Corella, 2021, Advanced Synthesis & Catalysis.

Stereoselectivity control in Diels–Alder reactions of 4-thiosubstituted 5-alkoxyfuranones: synthesis and reactivity of enantiopure 4-sulfinyl and sulfonyl 5-(l-menthyloxy)furan-2(5H)-ones

J. G. Ruano, A. Fraile, A. M. Castro, 2000 .

(Ss)-5-ethoxy-3-p-tolylsulfinylfuran-2(5H)-ones as chiral dipolarophiles: First asymmetric cycloaddition of diazomethane to vinyl sulfoxides

J. G. Ruano, A. Fraile, M. R. Martín, 1996 .

Asymmetric 1,3-dipolar reactions of 3-sulfinylfuran-2(5H)-ones with 11H-dibenzo[b,e]azepine 5-oxide. Synthesis of pyrroloazepines via isoxazoloazepines

J. G. Ruano, A. Fraile, A. M. Castro, 2004 .

First asymmetric cycloaddition of carbonyl ylides to vinyl sulfoxides and furan-2(5H)-ones.

A. Nuñez, J. L. García Ruano, A. Fraile, 2006, The Journal of organic chemistry.

1,4-Michael additions of cyclic-β-ketoesters catalyzed by DNA in aqueous media

J. Alemán, Javier Luis‐Barrera, A. Fraile, 2014 .

Enantioselective H-bond-directing approach for trienamine-mediated reactions in asymmetric synthesis.

Ł. Albrecht, A. Albrecht, A. Fraile, 2012, Angewandte Chemie.