David J. H. Emslie

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Cyclic and Non-Cyclic Pi Complexes of Manganese

J. S. Price, David J. H. Emslie, 2021, Reference Module in Chemistry, Molecular Sciences and Chemical Engineering.

Cyclometalation and coupling of a rigid 4,5-bis(imino)acridanide pincer ligand on yttrium.

E. W. Wong, David J. H. Emslie, 2015, Dalton transactions.

Reactions of Manganese Silyl and Silylene Complexes with CO2 and C(NiPr)2: Synthesis of Mn(I) Formate and Amidinylsilyl Complexes

J. S. Price, David J. H. Emslie, 2020 .

Potassium-alkane interactions within a rigid hydrophobic pocket.

David J. H. Emslie, Nicholas R. Andreychuk, 2013, Angewandte Chemie.

Uranium(iv) alkyl cations: synthesis, structures, comparison with thorium(iv) analogues, and the influence of arene-coordination on thermal stability and ethylene polymerization activity

P. Ayers, G. Schreckenbach, J. Britten, 2022, Chemical science.

A New Chelating Anilido-Imine Donor Related to β-Diketiminato Ligands for Stabilization of Organoyttrium Cations

Paul G. Hayes, G. Welch, W. Piers, 2003 .

Triphenylene analogues with B2N2C2 cores: synthesis, structure, redox behavior, and photophysical properties.

T. S. Sorensen, W. Piers, M. Parvez, 2006, Journal of the American Chemical Society.

Interconversion and reactivity of manganese silyl, silylene, and silene complexes

J. S. Price, David J. H. Emslie, 2019, Chemical science.

Actinides: Amido Complexes

David J. H. Emslie, 2018, Encyclopedia of Inorganic and Bioinorganic Chemistry.

Yttrium and Aluminum Alkyl Complexes of a Rigid Bis-Anilido NON-Donor Ligand: Synthesis and Hydroamination Catalysis

H. Jenkins, David J. H. Emslie, Kelly S. A. Motolko, 2017 .

[(dmpe)2MnH(C2H4)] as a Source of a Low-Coordinate Ethyl Manganese(I) Species: Reactions with Primary Silanes, H2, and Isonitriles

J. Britten, I. Vargas-Baca, J. S. Price, 2018, Organometallics.

Alkyl yttrium complexes of doubly cyclometallated xanthene- and naphthalene-backbone bis(phosphinimine) ligands

J. Britten, David J. H. Emslie, Aathith Vasanthakumar, 2019 .

Thorium(iv) alkyl and allyl complexes of a rigid NON-donor pincer ligand with flanking 1-adamantyl substituents.

H. Jenkins, David J. H. Emslie, Nicholas R. Andreychuk, 2018, Dalton transactions.

Organo-scandium and -yttrium complexes supported by a salicylaldiminato ligand

W. Piers, David J. H. Emslie, Robert W. MacDonald, 2002 .

Organometallic complexes of scandium and yttrium supported by a bulky salicylaldimine ligand

R. McDonald, W. Piers, and Masood Parvez, 2002 .

Synthesis and thermal reactivity of organoscandium and yttrium complexes of sterically less bulky salicylaldiminato ligands

W. Piers, M. Parvez, David J. H. Emslie, 2003 .

Zirconium Complexes of a Rigid, Dianionic Pincer Ligand: Alkyl Cations, Arene Coordination, and Ethylene Polymerization

J. Britten, J. S. Price, H. Jenkins, 2017 .

M–H–BR3 and M–Br–BR3 interactions in rhodium and nickel complexes of an ambiphilic phosphine–thioether–borane ligand

David J. H. Emslie, B. Cowie, 2018 .

Potassium and Yttrium Complexes of a Rigid Bis‐Phosphido POP‐Donor Ligand

J. Britten, H. Jenkins, David J. H. Emslie, 2017 .

Synthesis, Structures, and Thermal Stability of Dialkyl and Bis(amido) Zirconium(IV) Acen Complexes

David J. H. Emslie, M. Al Hareri, 2022, European Journal of Inorganic Chemistry.

Homoleptic 1-norbornyl complexes of group 4 and manganese: synthesis, structures, volatility, and thermal stability

Patricio E. Romero, J. S. Price, David J. H. Emslie, 2022, Canadian Journal of Chemistry.

Acyclic boron-containing π-ligand complexes: η2- and η3-coordination modes.

David J. H. Emslie, B. Cowie, Kristopher B Kolpin, 2012, Dalton transactions.

Eta3-vinylborane complexes of platinum and nickel: borataallyl- and alkyl/borataalkene-like coordination modes.

David J. H. Emslie, Kristopher B Kolpin, 2010, Angewandte Chemie.

Uranium(IV) Alkyl Complexes of a Rigid Dianionic NON-Donor Ligand: Synthesis and Quantitative Alkyl Exchange Reactions with Alkyllithium Reagents

H. Jenkins, David J. H. Emslie, B. Vidjayacoumar, 2013 .

Rigid NON-donor pincer ligand complexes of lutetium and lanthanum: synthesis and hydroamination catalysis

J. Britten, David J. H. Emslie, Kelly S. A. Motolko, 2017 .

Coordination Chemistry of Lewis Acidic Ligands

David J. H. Emslie, B. Cowie, Katarina M. Paskaruk, 2021 .

Nickel and Palladium Complexes of Ferrocene-Backbone Bisphosphine-Borane and Trisphosphine Ligands

David J. H. Emslie, B. Cowie, 2015 .

Synthesis and platinum complexes of an alane-appended 1,1'-bis(phosphino)ferrocene ligand.

David J. H. Emslie, Fu An Tsao, B. Cowie, 2015, Angewandte Chemie.

Platinum complexes of a borane-appended analogue of 1,1'-bis(diphenylphosphino)ferrocene: flexible borane coordination modes and in situ vinylborane formation.

David J. H. Emslie, B. Cowie, 2014, Chemistry.

Bridging Rhodium–Iron Borataaminocarbyne Complexes Formed by Intramolecular Isonitrile–Borane Coordination

David J. H. Emslie, B. Cowie, 2013 .

Synthesis of a Heterobimetallic Rhodium−Iron Complex Containing an η3-Interaction between Rhodium and the B−Cipso−Cortho Unit of a Triarylborane

J. Britten, I. Vargas-Baca, C. Robertson, 2006 .

Manganese(II) Alkyl/π-Allyl Complexes Resistant to Ligand Redistribution

H. Jenkins, David J. H. Emslie, P. Chadha, 2014 .

Rigid NON- and NSN-ligand complexes of tetravalent and trivalent uranium: comparison of U-OAr2 and U-SAr2 bonding.

J. Britten, Terry Chu, H. Jenkins, 2012, Dalton transactions.

Divergent reactivity of [(κ3-L)ThCl2(dme)] with Grignard reagents: Alkylation, ancillary ligand transfer to magnesium, and halide exchange caught in the act

J. Britten, Terry Chu, H. Jenkins, 2010 .

Group 10 Transition-Metal Complexes of an Ambiphilic PSB-Ligand: Investigations into η3(BCC)-Triarylborane Coordination

J. Britten, C. Robertson, H. Jenkins, 2008 .

2,2'-diborabiphenyl: a Lewis acid analogue of 2,2'-bipyridine.

W. Piers, M. Parvez, David J. H. Emslie, 2003, Angewandte Chemie.

Cyclometallation following coordination of anionic and neutral Lewis bases to a uranium(IV) dialkyl complex

J. Britten, H. Jenkins, David J. H. Emslie, 2017 .

A thermally robust di-n-butyl thorium complex with an unstable dimethyl analogue.

J. Britten, H. Jenkins, David J. H. Emslie, 2010, Dalton transactions.

Cationic Thorium Alkyl Complexes of Rigid NON- and NNN-Donor Ligands: π-Arene Coordination as a Persistent Structural Motif

J. Britten, C. Robertson, H. Jenkins, 2009 .

Single and Double Alkyl Abstraction from a Bis(anilido)xanthene Thorium(IV) Dibenzyl Complex: Isolation of an Organothorium Cation and a Thorium Dication

J. Britten, David J. H. Emslie, Laura E. Harrington, 2008 .

Extremely Stable Thorium(IV) Dialkyl Complexes Supported by Rigid Tridentate 4,5-Bis(anilido)xanthene and 2,6-Bis(anilidomethyl)pyridine Ligands

J. Britten, C. Robertson, David J. H. Emslie, 2007 .

Base-Free and Bisphosphine Ligand Dialkylmanganese(II) Complexes as Precursors for Manganese Metal Deposition

J. S. Price, David J. H. Emslie, P. Chadha, 2016 .

The substitution chemistry of the tris(3,5-dimethylpyrazolyl)methanerhodium complex [Rh(CO)2{HC(pz′)3}]+

A. Orpen, C. Adams, N. Connelly, 2003 .

Redox-induced κ2–κ3 isomerisation in hydrotris(pyrazolyl)boratorhodium complexes: synthesis, structure and ESR spectroscopy of stabilised rhodium(II) species

A. Orpen, M. J. Quayle, N. Connelly, 2001 .

Redox-induced κ 2 -κ 3 isomerisation in rhodium hydrotris(3,5-dimethylpyrazolyl)borate chemistry: the stabilisation of square-pyramidal rhodium(II)

A. Orpen, M. J. Quayle, Bernhard Metz, 1996 .

Metal ALD and pulsed CVD: Fundamental reactions and links with solution chemistry

J. S. Price, David J. H. Emslie, P. Chadha, 2013 .

Bis-hydrocarbyl Platinum(II) Ambiphilic Ligand Complexes: Alkyl–Aryl Exchange between Platinum and Boron

David J. H. Emslie, B. Cowie, 2015 .

Manganese Silyl Dihydride Complexes: A Spectroscopic, Crystallographic, and Computational Study of Nonclassical Silicate and Hydrosilane Hydride Isomers

B. Berno, J. S. Price, David J. H. Emslie, 2019, Organometallics.

Coordination chemistry and structural rearrangements of the Me2PCH2AlMe2 ambiphilic ligand.

J. Britten, David J. H. Emslie, Katarina M. Paskaruk, 2022, Dalton transactions.

Uranium(IV) Thio- and Selenoether Complexes: Syntheses, Structures, and Computational Investigation of U-ER2 Interactions.

J. S. Price, David J. H. Emslie, Novan A. G. Gray, 2021, Chemistry.

Reactions of [(dmpe)2MnH(C2H4)]: synthesis and characterization of manganese(i) borohydride and hydride complexes.

J. Britten, J. S. Price, David J. H. Emslie, 2020, Dalton transactions.

Manganese Silylene Hydride Complexes: Synthesis and Reactivity with Ethylene to Afford Silene Hydride Complexes.

J. Britten, J. S. Price, David J. H. Emslie, 2017, Angewandte Chemie.

Reactions of Manganese Silyl Dihydride Complexes with CO2

J. S. Price, David J. H. Emslie, 2021 .

Investigation of AlMe3, BEt3, and ZnEt2 as Co-Reagents for Low-Temperature Copper Metal ALD/Pulsed-CVD

J. Britten, A. Rheingold, S. Clendenning, 2010 .

Reversible sequence of intramolecular associative and dissociative electron-transfer reactions in hydrotris(pyrazolylborate) complexes of rhodium.

N. Connelly, W. Geiger, David J. H. Emslie, 2003, Journal of the American Chemical Society.

A study of M-X-BR3 (M = Pt, Pd or Rh; X = Cl or I) interactions in square planar ambiphilic ligand complexes: structural, spectroscopic, electrochemical and computational comparisons with borane-free analogues.

J. Britten, H. Jenkins, David J. H. Emslie, 2012, Dalton transactions.

Group 3 dialkyl complexes of a rigid monoanionic NNN-donor pincer ligand: synthesis, structures, unexpected reactivity with CPh3+, and hydroamination catalysis.

David J. H. Emslie, Christopher J. Franko, Aathith Vasanthakumar, 2023, Dalton transactions.

Trans Ligand Determines the Stability of Paramagnetic Manganese(II) Hydrides of the Type trans-[MnH(L)(dmpe)2]+ Where L is PMe3, C2H4, or CO.

R. Morris, J. S. Price, David J. H. Emslie, 2023, Inorganic chemistry.

Room-Temperature Atomic Layer Deposition of Elemental Antimony

David J. H. Emslie, M. Al Hareri, 2022, Chemistry of Materials.

Silicon nitride subwavelength grating metamaterial waveguides functionalized with atomic layer deposited Al2O3 cladding

J. Bradley, P. Cheben, J. Schmid, 2023, 2023 Photonics North (PN).

Analysis of Electron Paramagnetic Resonance Spectra with Very Large Quadrupole Couplings

N. Connelly, P. Rieger, David J. H. Emslie, 2002 .

A Synthetic, Structural, Spectroscopic, and Computational Study of Alkali Metal-Thioether, -Selenoether, and -Telluroether Interactions.

I. Vargas-Baca, David J. H. Emslie, Novan A G Gray, 2023, Inorganic chemistry.

J. Britten, H. Jenkins, David J. H. Emslie, 2012, Dalton transactions.

A comparison of the coordination behaviour of R2PCH2BMe2 (R = Me vs. Ph) ambiphilic ligands with late transition metals.

David J. H. Emslie, Katia M Paskaruk, James F Britten, 2023, Dalton transactions.

Synthesis and platinum complexes of an alane-appended 1,1'-bis(phosphino)ferrocene ligand.

David J. H. Emslie, Fu An Tsao, B. Cowie, 2015, Angewandte Chemie.

A Zwitterionic Palladium(II) η3-Boratoxypentadienyl Complex: Cooperative Activation of Dibenzylideneacetone between Palladium and a Phosphine/Thioether/Borane Ligand

J. Britten, J. Blackwell, David J. H. Emslie, 2006 .

Cyclometalation and coupling of a rigid 4,5-bis(imino)acridanide pincer ligand on yttrium.

David J. H. Emslie, Edwin W. Y. Wong, 2015, Dalton transactions.

Reactions of [(dmpe)2MnH(C2H4)] with hydrogermanes to form germylene, germyl, hydrogermane, and germanide complexes.

I. Vargas-Baca, J. S. Price, David J. H. Emslie, 2023, Dalton transactions.

Acyclic boron-containing π-ligand complexes: η2- and η3-coordination modes.

David J. H. Emslie, B. Cowie, Kristopher B Kolpin, 2012, Dalton transactions.