G. Hillhouse

发表

Oxygen-atom transfer from nitrous oxide to a nickel metallacycle. Synthesis, structure, and reactions of [cyclic] (2,2'-bipyridine)Ni(OCH2CH2CH2CH2)

A. Rheingold, P. Matsunaga, G. Hillhouse, 1993 .

Oxygen-atom transfer from nitrous oxide (NNO) to nickel alkyls. Syntheses and reactions of nickel(II) alkoxides

John C. Mavropoulos, P. Matsunaga, G. Hillhouse, 1995 .

Carbon−Oxygen Reductive-Elimination from Nickel(II) Oxametallacycles and Factors That Control Formation of Ether, Aldehyde, Alcohol, or Ester Products

G. Hillhouse, Runyu Han and, 1997 .

Hydrogen-atom abstraction from Ni(I) phosphido and amido complexes gives phosphinidene and imide ligands.

V. Iluc, G. Hillhouse, Vlad M. Iluc, 2010, Journal of the American Chemical Society.

Arrested 1,2-hydrogen migration from silicon to nickel upon oxidation of a three-coordinate Ni(I) silyl complex.

V. Iluc, G. Hillhouse, Vlad M. Iluc, 2010, Journal of the American Chemical Society.

Three-coordinate nickel carbene complexes and their one-electron oxidation products.

V. Iluc, G. Hillhouse, Vlad M. Iluc, 2014, Journal of the American Chemical Society.

Heterolytic H-H and H-B Bond Cleavage Reactions of {(IPr)Ni(μ-S)}2.

T. Cundari, G. Hillhouse, R. F. Jordan, 2017, Inorganic chemistry.

Reactions of water and ammonia with bis(pentamethylcyclopentadienyl) complexes of zirconium and hafnium

J. Bercaw, G. Hillhouse, 1984 .

Syntheses, structures, and reactivities of unusual four-membered metallacycles formed in insertion reactions of N:N:O, N:N:NR, and N:N:CR2 with (.eta.5-C5Me5)2Zr(C2Ph2)

A. Rheingold, G. Hillhouse, G. Vaughan, 1990 .

Leveraging artificial intelligence to optimize COVID-19 robust spread and vaccination roll-out strategies in Southern Africa

M. Mafu, G. Hillhouse, Bruce Mellado, 2022, Frontiers in Artificial Intelligence.

Synthesis and characterization of side-bound aryldiazo and end-bound nitrosyl complexes of nickel.

Alexander J. M. Miller, V. Iluc, G. Hillhouse, 2005, Chemical communications.

Synthesis and structure of a terminal dinitrogen complex of nickel

R. Waterman, G. Hillhouse, 2005 .

Stacked schiff base complexes. The structural characterization of M,N′-ethylenebis(1,1,1-triflouro-2,4-pentanedioneiminato)copper(II0 and N,N′-ethylenebis(1,1,1-triflouro-2,4-hexanedioneiminato)nickel(II), Cu[en(tfpd)2] and Ni[en(tfhd)2]

H. Allen, D. Hodgson, G. Hillhouse, 1979 .

Syntheses and reactions of hydrazine and diazene complexes of tungsten. The first example of monodentate coordination of diazene

Milton R. Smith, G. Hillhouse, T. Cheng, 1993 .

Terminal amido and imido complexes of three-coordinate nickel.

D. Mindiola, G. Hillhouse, 2001, Journal of the American Chemical Society.

A two-coordinate nickel imido complex that effects C−H amination.

T. Cundari, Alexander J. M. Miller, G. Hillhouse, 2011, Journal of the American Chemical Society.

Interactions of aziridines with nickel complexes: oxidative-addition and reductive-elimination reactions that break and make C-N bonds.

G. Hillhouse, Christopher R. Clough, B. L. Lin, 2002, Journal of the American Chemical Society.

Single-electron oxidation of N-heterocyclic carbene-supported nickel amides yielding benzylic C–H activation

T. Cundari, Glenn R. Morello, G. Hillhouse, 2013 .

Monomeric phosphido and phosphinidene complexes of nickel.

D. Mindiola, G. Hillhouse, R. Melenkivitz, 2002, Journal of the American Chemical Society.

Oxygen-atom transfer from nitrous oxide. Identification of intermediates in the oxidation of diphenylacetylene at Group 4 metal centers and the structural characterization of (.eta.-C5Me5)2Ti{N(O)NCPh:CPh}.cntdot.1/2C7H8

A. Rheingold, G. Hillhouse, C. D. Sofield, 1989 .

Synthesis, structures, and catalytic reactivity of bis(N-heterocyclic carbene) supported diphenyldiazomethane and 1-azidoadamantane complexes of nickel

Amanda R. Corcos, G. Hillhouse, Nicole D. Harrold, 2016 .

Protonolysis and amide exchange reactions of a three-coordinate cobalt amide complex supported by an N-heterocyclic carbene ligand.

G. Hillhouse, R. F. Jordan, Christopher Hansen, 2015, Inorganic chemistry.

Eta2-organoazide complexes of nickel and their conversion to terminal imido complexes via dinitrogen extrusion.

R. Waterman, G. Hillhouse, 2008, Journal of the American Chemical Society.

Diazoalkane complexes of molybdenum and tungsten

B. Haymore, G. Hillhouse, 1982 .

Carbon–Hydrogen Bond Activation, C–N Bond Coupling, and Cycloaddition Reactivity of a Three-Coordinate Nickel Complex Featuring a Terminal Imido Ligand

T. Cundari, D. Mindiola, R. Waterman, 2014, Inorganic chemistry.

Synthesis, structure, and reactivity of platinum compounds featuring terminal amido and phosphido ligands

D. Mindiola, R. Waterman, G. Hillhouse, 2014 .

Synthesis and reactivity of NHC-supported Ni2(μ(2)-η(2),η(2)-S2)-bridging disulfide and Ni2(μ-S)2-bridging sulfide complexes.

G. Hillhouse, R. F. Jordan, Frank Olechnowicz, 2015, Inorganic chemistry.

Redox-Neutral Transformations of Carbon Dioxide Using Coordinatively Unsaturated Late Metal Silyl Amide Complexes.

M. Pink, Jeremy M. Smith, K. G. Caulton, 2022, Inorganic chemistry.

Functionalization of Complexed N2O in Bis(pentamethylcyclopentadienyl) Systems of Zirconium and Titanium

D. Mindiola, K. Meyer, G. Hillhouse, 2014, Organometallics.

Oxygen-atom transfer from nitrous oxide. Synthesis and structure of a zirconocene oxametallacyclobutene complex

S. Buchwald, R. Lum, A. Rheingold, 1988 .

Diazoalkane complexes of molybdenum and tungsten

B. Haymore, G. Hillhouse, 1982 .

Preparation of stable alkyl complexes of Ni(I) and their one-electron oxidation to Ni(II) complex cations.

D. Mindiola, G. Hillhouse, Kristina D. Kitiachvili, 2004, Journal of the American Chemical Society.

Synthesis and reactivity of a neutral tungsten(0) alkyl complex. Insertion of CO2 into the W-CH3 bond of trans,trans-W(CH3)(CO)2(NO)(PPh3)2 and the structural characterization of trans-W(.eta.2-O2CCH3)(CO)(NO)(PPh3)2

K. Folting, J. Huffman, M. Holl, 1987 .

Synthesis and characterization of three-coordinate Ni(III)-imide complexes.

Marisa J. Monreal, Alexander J. M. Miller, M. Monreal, 2011, Journal of the American Chemical Society.

Synthesis of 1,2-bis(di-tert-butylphosphino)ethane (dtbpe) complexes of nickel: radical coupling and reduction reactions promoted by the nickel(I) dimer [(dtbpe)NiCl]2

D. Mindiola, R. Waterman, David M. Jenkins, 2003 .

Reactions of CO(2) and CS(2) with 1,2-bis(di-tert-butylphosphino)ethane complexes of nickel(0) and nickel(I).

John S. Anderson, V. Iluc, G. Hillhouse, 2010, Inorganic chemistry.

Formation of Phosphirenes by Phosphinidene Group-Transfer Reactions from (dtbpe)Ni=P(dmp) to Alkynes

R. Waterman, G. Hillhouse, 2003 .

Monomeric and dimeric disulfide complexes of nickel(II).

C. Brozek, V. Iluc, G. Hillhouse, 2010, Inorganic chemistry.

Snapshots of the oxidative-addition process of silanes to nickel(0)

V. Iluc, G. Hillhouse, Vlad M. Iluc, 2006 .

STABILIZATION OF RN:NN:PR3. PREPARATION AND STRUCTURAL CHARACTERIZATION OF STABLE TETRAARYLPHOSPHAZIDE COMPLEXES CONTAINING MOLYBDENUM AND TUNGSTEN

B. Haymore, G. Hillhouse, G. V. Goeden, 1982 .

Synthesis, structure, and reactions of a copper–sulfido cluster comprised of the parent Cu2S unit: {(NHC)Cu}2(μ-S)

M. D. Hopkins, A. Filatov, G. Hillhouse, 2015, Chemical science.

Strongly bent nickel imides supported by a chelating bis(N-heterocyclic carbene) ligand

G. Hillhouse, Nicole D. Harrold, 2013 .

Synthesis and reactivity of two-coordinate Ni(I) alkyl and aryl complexes.

V. Iluc, G. Hillhouse, Steven M. Baldwin, 2013, Journal of the American Chemical Society.

Carbon-Nitrogen Bond Formation by Reductive Elimination from Nickel(II) Amido Alkyl Complexes

G. Hillhouse, Kwangmo Koo, 1995 .

Stereoselective synthesis of monosubstituted cis-aryldiazenes, NH=NR

Milton R. Smith, G. Hillhouse, 1988 .

Halide, hydride, alkyl, and dinitrogen complexes of bis(pentamethylcyclopentadienyl)hafnium

D. Roddick, J. Bercaw, P. Seidler, 1985 .

Structure of a methyldiazo complex of tungsten, (.eta.5-C5H5)W(CO)2(N2CH3), at low temperature

W. Herrmann, B. Haymore, G. Hillhouse, 1979 .

Synthesis and molecular structure of (η5-C5Me5)2Hf(H)(NHMe). Structural evidence for nitrogen-to-hafnium π-donation

B. Santarsiero, J. Bercaw, G. Hillhouse, 1988 .

Formation of a Substituted Tetrahydrofuran by Formal [2 + 2 + 1] Coupling of an Oxygen Atom with Two Olefins at a Nickel Center

G. Hillhouse, Kwangmo Koo, 1998 .

Synthesis and Structure of a CuI3S Cluster Unsupported by Other Bridging Ligands

M. D. Hopkins, G. Hillhouse, Jun Zhai, 2015 .

Carbon suboxide as a C1 reagent. Sequential cleavage of CO from C3O2 at a metal center to give WCl2(CO)(PMePh2)2[C,C':.eta.2-C(O)CPMePh2] and WCl2(CO)(PMePh2)2(.tplbond.CPMePh2)

A. Rheingold, G. Hillhouse, A. List, 1989 .

A carbon-carbon bond cleavage reaction of carbon suboxide at a metal center. Synthesis and structural characterization of WCl2(CO)(PMePh2)2{C,C':.eta.2-C(O)CPMePh2}

A. Rheingold, G. Hillhouse, A. List, 1988 .

Metalloketene formation by insertion of carbon suboxide into tungsten and rhenium metal-hydride bonds

G. Hillhouse, 1985 .

Synthesis and carbene -transfer reactivity of dimeric nickel carbene cations supported by N-heterocyclic carbene ligands

G. Hillhouse, Carl A. Laskowski, 2011 .

Photoionization mass spectrometric study and ab initio calculations of ionization and bonding in P–H compounds; heats of formation, bond energies, and the 3B1–1A1 separation in PH+2

L. Curtiss, J. Pople, S. Gibson, 1986 .

Synthesis and characterization of a carbon suboxide complex of nickel, (PPh3)2Ni(C,C':.eta.2-C3O2)

Milton R. Smith, G. Hillhouse, A. List, 1991 .

Chemistry of coordinated nitroxyl. Reagent-specific protonations of trans-Re(CO)(2)(NO)(PR(3))(2) (R = Ph, Cy) that give the neutral nitroxyl complexes cis,trans-ReCl(CO)(2)(NH=O)(PR(3))(2) or the cationic hydride complex [trans,trans-ReH(CO)(2)(NO)(PPh(3))(2)(+)][SO(3)CF(3)(-)].

I. Guzei, A. Rheingold, M. T. Green, 2001, Inorganic chemistry.

Group-Transfer Reactions of Ni(II)−Ni(II) Bridging Imido Complexes. Catalytic Formation of Carbodiimides and Isocyanates via Nitrene Transfer from Organoazides

G. Hillhouse, Carl A. Laskowski, 2009 .

Isocyanate and carbodiimide synthesis by nitrene-group-transfer from a nickel(II) imido complex.

D. Mindiola, G. Hillhouse, 2002, Chemical communications.

Complex chemistry of reactive organic compounds. 46. Conformation of metal carbene complexes: synthesis and structure of carbonyl(.eta.5-cyclopentadienyl)(diphenylcarbene)nitrosylchromium and its relationship to the isoelectronic compound dicarbonyl(.eta.5-cyclopentadienyl)(diphenylcarbene)manganese

W. Herrmann, B. Haymore, I. Bernal, 1984 .

Carbon Suboxide as a C1 Reagent. Sequential Cleavage of CO from C3O2 at a Metal Center to Give WCl2(CO)(PMePh2)2(C,C′:η2-C(O)CPMePh2) and WCl2(CO)(PMePh2)2(CPMePh2).

A. Rheingold, G. Hillhouse, A. List, 1989 .

Metalloketene Formation by Insertion of Carbon Suboxide into Tungsten and Rhenium Metal

G. Hillhouse, 1986 .

A Carbon-Carbon Bond Cleavage Reaction of Carbon Suboxide at a Metal Center. Synthesis and Structural Characterization of WCl2(CO)(PMePh2)2(C,C′:η2-C(O)CPMePh2).

A. Rheingold, G. Hillhouse, A. List, 1988 .

Group-transfer reactions of nickel-carbene and -nitrene complexes with organoazides and nitrous oxide that form new C=N, C=O, and N=N bonds.

T. Cundari, R. Waterman, G. Hillhouse, 2009, Journal of the American Chemical Society.

Selective O-atom transfer from nitrous oxide to hydride and aryl ligands of bis(pentamethylcyclopentadienyl)hafnium derivatives

P. Rupert, G. Hillhouse, G. Vaughan, 1987 .

A carbon-carbon bond cleavage reaction of carbon suboxide at a metal center. Synthesis and structural characterization of WCl2(CO)(PMePh2)2{C,C':.eta.2-C(O)CPMePh2} [Erratum to document cited in CA109(9):73587a]

A. Rheingold, G. Hillhouse, A. List, 1988 .

Phosphido derivatives of bis(pentamethylcyclopentadienyl)zirconium and -hafnium complexes and the molecular structure of (.eta.-C5Me5)2Hf(HI)(PHPh)

A. Rheingold, G. Hillhouse, G. Vaughan, 1989 .

Group transfer from nickel imido, phosphinidene, and carbene complexes to ethylene with formation of aziridine, phosphirane, and cyclopropane products.

R. Waterman, G. Hillhouse, 2003, Journal of the American Chemical Society.

Synthesis, Structure, and Reactions of a Three-Coordinate Nickel-Carbene Complex, {1,2-Bis(di-tert-butylphosphino)ethane}NiCPh2

D. Mindiola, G. Hillhouse, 2002 .

Interaction of aryl azides with tungsten complexes. Three new types of reactions yielding coordinated RN3PR3, RN3H, and RN.

B. Haymore, G. Hillhouse, 1978 .

Monosubstituted triazenido complexes as intermediates in the formation of amido complexes from hafnium hydrides and aryl azides

J. Bercaw, G. Hillhouse, 1982 .

Crystal structure of the inverse crown ether tetrakis[μ2-bis(trimethylsilyl)amido]-μ4-oxido-dicobalt(II)disodium, [Co2Na2{μ2-N(SiMe3)2}4](μ4-O)

A. Filatov, G. Hillhouse, Christopher Hansen, 2016, Acta crystallographica. Section E, Crystallographic communications.

Syntheses and reactions of WH(CO)2(NO)(P(C6H5)3)2 and related tungsten nitrosyl complexes

B. Haymore, G. Hillhouse, 1987 .

Preparation of trimethylsilyl alkyne complexes of bis(pentamethylcyclopentadienyl)zirconium, (η5-C5Me5)2Zr(RC≡CSiMe3), and their regioselective reactions with nitrous oxide

A. Rheingold, G. Hillhouse, Kwangmo Koo, 1998 .

Two-coordinate d9 complexes. synthesis and oxidation of NHC nickel(I) amides.

G. Hillhouse, Carl A. Laskowski, 2008, Journal of the American Chemical Society.

Oxygen-Atom Transfer from Nitrous Oxide to an Organonickel(II) Phosphine Complex. Syntheses and Reactions of New Nickel(II) Aryloxides and the Crystal Structure of [cyclic] (Me2PCH2CH2PMe2)Ni(O-o-C6H4CMe2CH2)

A. Rheingold, G. Hillhouse, Kwangmo Koo, 1995 .

Thianickelacycles by Ring‐Opening Reactions of Cyclic Thioethers and Their Subsequent Carbonylation to Thioesters

P. Matsunaga, G. Hillhouse, 1994 .

Indoline Synthesis via Coupling of Phenethyl Grignard Reagents with Organoazides Mediated by (Alkylphosphine)nickel(II) Complexes

G. Hillhouse, Kwangmo Koo, 1996 .

Synthesis, structure, and reactions of a nitroxyl complex of iridium(III), cis,trans-IrHCl2(NH=O)(PPh3)2.

G. Hillhouse, R. Melenkivitz, 2002, Chemical communications.

Hydroxylamine, Hydrazine, and Diazene as Unidentate Ligands in Osmium and Ruthenium Complexes

A. Ponce, A. Rheingold, G. Hillhouse, 1994 .

Reactions of coordinated diazene in rhenium and tungsten complexes. Deprotonation of ligated NH:NH and subsequent hydrogen-migration to carbonyl ligands to give metal formyls

J. Peters, G. Hillhouse, T. Cheng, 1994 .

The Ruthenostannylene Complex [Cp*(IXy)H2 Ru-Sn-Trip]: Providing Access to Unusual Ru-Sn Bonded Stanna-imine, Stannene, and Ketenylstannyl Complexes.

Micah S. Ziegler, T. Tilley, G. Hillhouse, 2015, Angewandte Chemie.

Arrested 1,2-hydrogen migration from silicon to nickel upon oxidation of a three-coordinate Ni(I) silyl complex.

G. Hillhouse, Vlad M. Iluc, 2010, Journal of the American Chemical Society.

Synthesis and characterization of three-coordinate Ni(III)-imide complexes.

Marisa J. Monreal, Alexander J. M. Miller, M. Mehn, 2011, Journal of the American Chemical Society.

Sequential Insertion Reactions of Carbon Monoxide and Ethylene into the Ni−C Bond of a Cationic Nickel(II) Alkyl Complex

R. Waterman, J. Curley, G. Hillhouse, 2009 .

Synthesis, structure, and reactions of a copper–sulfido cluster comprised of the parent Cu2S unit: {(NHC)Cu}2(μ-S)

M. D. Hopkins, A. Filatov, G. Hillhouse, 2015, Chemical science.

Sulfur-Atom Transfer from Elemental Sulfur to Nickel−Carbon Bonds as a New Route to Reactive Nickel(II) Thiolates

G. Hillhouse, R. Han, 1998 .