M. Hiersemann

发表

(4S,5S,6R,E)-3,5-Dimethyl-6-vinylhept-2-ene-1,4,7-triol

C. Golz, H. Preut, C. Strohmann, 2016 .

Crystal structure of N′-[(E)-(1S,3R)-(3-isopropyl-1-methyl-2-oxocyclopentyl)methylidene]-4-methylbenzenesulfonohydrazide

C. Golz, H. Preut, C. Strohmann, 2015, Acta crystallographica. Section E, Crystallographic communications.

Functions Bearing Two Nitrogens

M. Hiersemann, 2005 .

(4R)-4-Benzyl-3-{(4S)-4-chloro-4-[(S)-2,2-dimethyl-1,3-dioxolan-4-yl]butanoyl}-1,3-oxazolidin-2-one

H. Preut, C. Strohmann, M. Hiersemann, 2011, Acta crystallographica. Section E, Structure reports online.

{2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate)

M. Schürmann, H. Preut, J. Rehbein, 2009, Acta crystallographica. Section E, Structure reports online.

2.21 Selected Diastereoselective Reactions: Diastereoface-Differentiating Claisen, Cope, and [2,3]-Wittig Rearrangements in Contemporary Natural Product Synthesis

M. Hiersemann, Tobias Jaschinski, 2012 .

Synthesis of Homoverrucosanoid-Derived Esters and Evaluation as MDR Modulators.

M. Wiese, A. Schäfer, Sebastian C Köhler, 2017, The Journal of organic chemistry.

Synthesis and Lewis acid catalyzed Claisen rearrangement of 2-(1,3-oxazolin-2-yl)-substituted allyl vinyl ethers

M. Hiersemann, Hannes Helmboldt, 2003 .

Catalysis of the Claisen Rearrangement of Aliphatic Allyl Vinyl Ethers

M. Hiersemann, L. Abraham, Lars Abraham, 2002 .

Catalytic asymmetric Claisen rearrangement of Gosteli-type allyl vinyl ethers: total synthesis of (-)-9,10-dihydroecklonialactone B.

Valeska von Kiedrowski, F. Quentin, M. Hiersemann, 2014, The Journal of organic chemistry.

Total synthesis of (-)-ecklonialactone B.

Valeska von Kiedrowski, F. Quentin, M. Hiersemann, 2013, Organic letters.

Total Synthesis and Structural Assignment of Curvicollide C.

Valeska von Kiedrowski, F. Quentin, M. Hiersemann, 2017, Organic letters.

(-)-Lytophilippine A: synthesis of a C1-C18 building block.

M. Hiersemann, Annika Gille, 2010, Organic letters.

Catalytic Asymmetric Gosteli–Claisen Rearrangement (CAGC)

J. Rehbein, M. Hiersemann, 2013 .

Synthesis of a Diastereomer of the Marine Macrolide Lytophilippine A.

A. Klüppel, M. Hiersemann, Annika Gille, 2019, Organic letters.

{1,6}-Transannular catalytic asymmetric Gosteli-Claisen rearrangement.

M. Hiersemann, Tobias Jaschinski, 2012, Organic letters.

Integration of catalysis and analysis is the key: rapid and precise investigation of the catalytic asymmetric Gosteli-Claisen rearrangement.

O. Trapp, Johannes Troendlin, J. Rehbein, 2011, Journal of the American Chemical Society.

Gosteli-Claisen rearrangement of propargyl vinyl ethers: cascading molecular rearrangements.

J. Rehbein, M. Hiersemann, Annika Gille, 2011, Organic letters.

Enantioselective synthesis of the C-14 to C-5 cyclopentane segment of jatrophane diterpenes

J. Rehbein, M. Hiersemann, Hannes Helmboldt, 2004 .

Photochemical Approach to the Cyclohepta[b]indole Scaffold by Annulative Two‐Carbon Ring‐Expansion

Sebastian Henke, M. Hiersemann, David Tymann, 2020, Chemistry.

Synthesis of the Cyclohepta[e]hydrindane Core of the Marine Homoverrucosane Diterpenoid Gagunin E.

A. Schäfer, M. Hiersemann, 2017, Organic letters.

The Catalytic Enantioselective Claisen Rearrangement of an Allyl Vinyl Ether.

M. Hiersemann, R. Czerwonka, L. Abraham, 2010 .

Organocatalytic claisen rearrangement: theory and experiment.

T. Strassner, J. Rehbein, M. Kirsten, 2007, The Journal of organic chemistry.

The Claisen Rearrangement

M. Hiersemann, U. Nubbemeyer, 2007 .

The Cu(OTf)2- and Yb(OTf)3-catalyzed Claisen rearrangement of 2-alkoxycarbonyl-substituted allyl vinyl ethers.

M. Hiersemann, L. Abraham, 2001, Organic letters.

Sequencing Pericyclic Reactions: The Ester Dienolate [2,3]‐Wittig/Oxy‐Cope Rearrangement/Carbonyl Ene Reaction, a New Access to Substituted Carbocycles

M. Hiersemann, 2001 .

The Catalytic Diastereo‐ and Enantioselective Claisen Rearrangement of 2‐Alkoxycarbonyl‐Substituted Allyl Vinyl Ether

M. Hiersemann, Pia Schwab, L. Abraham, 2004 .

Claisen Rearrangement of Aliphatic Allyl Vinyl Ethers from 1912 to 2012: 100 Years of Electrophilic Catalysis

J. Rehbein, M. Hiersemann, 2013 .

The Sequential Ester Dienolate [2,3]-Wittig/3-oxy-Cope Rearrangement. New Access to Substituted α-Keto Esters

M. Hiersemann, 2000 .

Palladium(II)-catalyzed cycloisomerization of substituted 1,5-hexadienes: a combined experimental and computational study on an open and an interrupted hydropalladation/carbopalladation/β-hydride elimination (HCHe) catalytic cycle.

S. Herres‐Pawlis, H. Preut, C. Strohmann, 2012, The Journal of organic chemistry.

Highly enantioselective catalytic asymmetric Claisen rearrangement of 2-alkoxycarbonyl-substituted allyl vinyl ethers

M. Hiersemann, L. Abraham, M. Körner, 2004 .

THE DIENOLATE 2,3-WITTIG REARRANGEMENT -DIASTEREOSELECTIVE SYNTHESIS OF HIGHLY FUNCTIONALIZED TERTIARY ALCOHOLS

A. Pollex, C. Lauterbach, M. Hiersemann, 1999 .

The claisen rearrangement : methods and applications

M. Hiersemann, U. Nubbemeyer, 2007 .

The Pd(II)-Catalyzed and the Thermal Claisen Rearrangement of 2-Alkoxycarbonyl-Substituted Allyl Vinyl Ethers

M. Hiersemann, 1999 .

Catalytic asymmetric claisen rearrangement in natural product synthesis: synthetic studies toward (-)-xeniolide F.

A. Pollex, M. Hiersemann, 2005, Organic letters.

Gosteli-Claisen rearrangement: substrate synthesis, simple diastereoselectivity, and kinetic studies.

S. Leick, J. Rehbein, M. Hiersemann, 2009, The Journal of organic chemistry.

Highly Enantioselective Catalytic Asymmetric Claisen Rearrangement of 2-Alkoxycarbonyl-Substituted Allyl Vinyl Ethers.

M. Hiersemann, L. Abraham, M. Körner, 2004 .

Development of an Alkyne Analogue of the de Mayo Reaction: Synthesis of Medium-Sized Carbacycles and Cyclohepta[b]indoles.

J. Rehbein, M. Hiersemann, David Tymann, 2018, Angewandte Chemie.

Development of an Alkyne Analogue of the de Mayo Reaction: Synthesis of Medium‐Sized Carbacycles and Cyclohepta[ b ]indoles

J. Rehbein, M. Hiersemann, David Tymann, 2018, Angewandte Chemie.

Gosteli-Claisen rearrangement: DFT study of substituent-rate effects.

Julia Rehbein, Martin Hiersemann, J. Rehbein, 2009, The Journal of organic chemistry.

Enantioselective synthesis of the C8-C20 segment of curvicollide C.

M. Hiersemann, M. Körner, 2007, Organic letters.

Synthesis of α-Allyloxy-Substituted α,β-Unsaturated Esters via Aldol Condensation. Convenient Access of Highly Substituted Allyl Vinyl Ethers

M. Hiersemann, 2000 .

Mechanistic Aspects of the Aliphatic Claisen Rearrangement

J. Rehbein, M. Hiersemann, 2007 .

Intramolecular 1,3-dipolar cycloaddition as a tool for the preparation of azaspirocyclic keto aziridines. Synthesis of intermediates for the total synthesis of (±)-cephalotaxine

G. Molander, M. Hiersemann, 1997 .

1,2:5,6‐Di‐O‐isopropylidene‐α‐D‐gulofuranose as a Chiral Auxiliary in the Diastereoselective C Methylation of Ester Enolates. The Influence of the Base on the Stereochemistry of Enolate Formation and Alkylation

J. Mulzer, P. Luger, M. Hiersemann, 2006 .

Cyclopentanoids by uncatalyzed intramolecular carbonyl ene (ICE) reaction of α-keto esters.

A. Klüppel, W. Hiller, M. Hiersemann, 2014, Organic letters.

The ester dienolate [2,3]-Wittig rearrangement. Diastereoselective synthesis of 2,3-dialkenyl-substituted 2-hydroxy-γ-lactones

M. Hiersemann, 1999 .

Total synthesis of jatrophane diterpenes from Euphorbia characias.

C. Schnabel, M. Hiersemann, 2009, Organic letters.

Synthetic studies toward jatrophane diterpenes from Euphorbia characias. Enantioselective synthesis of (-)-15-O-acetyl-3-O-propionyl-17-norcharaciol.

M. Hiersemann, Hannes Helmboldt, 2009, The Journal of organic chemistry.

Total synthesis of natural and non-natural Δ(5,6)Δ(12,13)-jatrophane diterpenes and their evaluation as MDR modulators.

C. Schnabel, M. Wiese, J. Rehbein, 2011, The Journal of organic chemistry.

Progress toward the Total Synthesis of Gukulenin A: Photochemically Triggered Two-Carbon Ring Expansion Key to α-Tropolonic Ether Synthesis.

M. Hiersemann, David Tymann, Ljuba Iovkova-Berends, 2018, Organic letters.

An Update on Cyclohepta[ b ]indoles

M. Hiersemann, Lars Benedix, Jan Gierok, 2021, European Journal of Organic Chemistry.

Total synthesis of (3S,4S,2′S)- and (3R,4R,2′S)-viridiofungin A triester

A. Pollex, M. Hiersemann, L. Abraham, 2004 .

Synthesis of the norjatrophane diterpene (-)-15-acetyl-3-propionyl- 17-norcharaciol.

D. Köhler, M. Hiersemann, Hannes Helmboldt, 2006, Organic letters.

Ester dienolate [2,3]-Wittig rearrangement in natural product synthesis: diastereoselective total synthesis of the triester of viridiofungin A, A2, and A4.

A. Pollex, M. Hiersemann, A. Millet, 2005, The Journal of organic chemistry.

Palladium(II)-catalyzed cycloisomerization of functionalized 1,5-hexadienes.

A. Pollex, W. Hiller, M. Hiersemann, 2011, Organic letters.

(2R,4S,5S)-5-Hydroxy-4-methyl-3-oxohept-6-en-2-yl benzoate

H. Preut, C. Strohmann, Valeska von Kiedrowski, 2017 .

Crystal structure of 4-(4-methoxyphenoxy)benzaldehyde

H. Preut, A. Schäfer, M. Hiersemann, 2015, Acta crystallographica. Section E, Crystallographic communications.

Crystal structure of rac-(3aR,4S,5aR,6S,9R,10aS,10bR)-3a,5a,9-trimethyltetradecahydro-6,9-epoxycyclohepta[e]inden-4-ol monohydrate

C. Golz, H. Preut, C. Strohmann, 2015, Acta crystallographica. Section E, Crystallographic communications.

Triphenyl(prop-2-yn-1-yl)silane

H. Preut, C. Strohmann, M. Hiersemann, 2012, Acta crystallographica. Section E, Structure reports online.

1-Phenyl-5-{[2-(trimethylsilyl)ethyl]sulfonyl}-1H-tetrazole

H. Preut, C. Strohmann, M. Hiersemann, 2011, Acta crystallographica. Section E, Structure reports online.

(2SR,3SR)-Isopropyl 3-{[dimethyl(phenyl)silyl]methyl}-2-hydroxy-2-vinylpent-4-enoate

Hans Preut, Bjoern Nelson, Markus Schürmann, 2010, Acta crystallographica. Section E, Structure reports online.

Crystal structure of 4-(4-methoxyphenoxy)benzaldehyde

H. Preut, A. Schäfer, M. Hiersemann, 2015, Acta crystallographica. Section E, Crystallographic communications.

(3S,4S,5R)-4-Hydroxy-3-methyl-5-[(2S,3R)-3-methylpent-4-en-2-yl]-4,5-dihydrofuran-2(3H)-one

H. Preut, R. Boese, D. Bläser, 2008, Acta crystallographica. Section E, Structure reports online.

(3R,4S,5S)-4-Hydroxy-3-methyl-5-[(2S,3R)-3-methylpent-4-en-2-yl]tetrahydrofuran-2-one

Annika Becker, Hans Preut, Markus Schürmann, 2008, Acta crystallographica. Section E, Structure reports online.

Gosteli-Claisen rearrangement of propargyl vinyl ethers: cascading molecular rearrangements.

J. Rehbein, M. Hiersemann, Annika Gille, 2011, Organic letters.

Total Synthesis and Structural Assignment of (−)‐Fusaequisin A

M. Hiersemann, A. Schmidt, 2021, Chemistry.