M. Tomás

发表

Regioselective synthesis of 4,6,7-trisubstituted benzofurans from furfural imines and nonheteroatom stabilized alkynylcarbene complexes.

J. Barluenga, J. Santamaría, Aránzazu Gómez, 2009, Journal of the American Chemical Society.

Rhodium(I) catalyzed four-component reaction of Fischer alkenyl carbene complexes and 1,1-diphenylallene

J. Barluenga, L. López, R. Vicente, 2005 .

Formal alkyne insertion into alkoxycarbene complexes: simple access to enantiopure group 6 alkynyl(alkoxy)carbene complexes.

A. Ballesteros, J. Barluenga, M. Tomás, 2005, Angewandte Chemie.

Metal carbene dimerization: versatile approach to polyalkynylethenes.

A. Ballesteros, J. Barluenga, J. Santamaría, 2008, Angewandte Chemie.

Synthesis of new chiral alkenyl Fischer carbene complexes

J. Barluenga, J. Santamaría, M. Tomás, 2003 .

Asymmetric C2-C3 cyclopentannulation of the indole ring.

A. Ballesteros, J. Barluenga, M. Tomás, 2009, Journal of the American Chemical Society.

Gold-catalyzed rearrangements: reaction pathways using 1-alkenyl-2-alkynylcyclopropane substrates.

A. Ballesteros, J. Barluenga, R. Vicente, 2011, Angewandte Chemie.

Alkynylcyclopropanes from terminal alkynes through consecutive coupling to Fischer carbene complexes and selective propargylene transfer.

A. Ballesteros, J. Barluenga, R. Vicente, 2011, Chemistry.

1,4-Cycloaddition of 1,3-diazabutadienes with enamines: an efficient route to the pyrimidine ring

A. Ballesteros, J. Barluenga, M. Tomás, 1989 .

Gold-catalyzed functionalization of unactivated C(sp3)-H bonds by hydride transfer facilitated by alkynylspirocyclopropanes.

Miguel A. Rodríguez, R. Sigüeiro, A. Ballesteros, 2012, Angewandte Chemie.

Discrimination of diazo compounds toward carbenoids: copper(I)-catalyzed synthesis of substituted cyclobutenes.

J. Barluenga, L. López, M. Tomás, 2009, Angewandte Chemie.

Cu(I)-catalyzed regioselective synthesis of polysubstituted furans from propargylic esters via postulated (2-furyl)carbene complexes.

J. Barluenga, R. Vicente, M. Tomás, 2008, Journal of the American Chemical Society.

Rearrangement of propargylic esters: metal-based stereospecific synthesis of (E)- and (Z)-knoevenagel derivatives.

J. Barluenga, L. López, R. Vicente, 2007, Journal of the American Chemical Society.

A Very Efficient, Short Synthesis of 6,7,8,8a-Tetrahydropyrrolo[1,2-a]pyrimidines from lmines via 4-Amino-1-aza-butadienes

J. Jardón, V. Gotor, J. Barluenga, 1989 .

Synthesis of heterocycles from Azadienes

J. Barluenga, M. Tomás, 1994 .

New perspectives of carbo- and hetero-l,3-dienes in organic synthesis

S. Fustero, J. Barluenga, M. Tomás, 1990 .

Cycloaddition reactions of 3,4-bismethoxycarbonyl-2-aza-1,3-dienes. The first example of an intramolecular [4 + 2] cycloaddition of simple 2-azadienes

V. Gotor, A. Ballesteros, J. Barluenga, 1989 .

An easy synthesis of electron-withdrawing substituted 2-aza-1,3-dienes and their 1,4-cycloaddition with enamines

V. Gotor, A. Ballesteros, J. Barluenga, 1987 .

Fischer Carbene Complexes in Heterocyclic Synthesis. Selective Cycloaddition Reactions to 2-Aza-1,3-butadienes

A. Ballesteros, J. Barluenga, J. Santamaría, 1997 .

First [4+2] cycloaddition of alkynyl Fischer carbene complexes with heterodienes. Facile synthesis of 1,4-dihydropyridines from 1-azadienes

J. Barluenga, M. Tomás, E. Rubio, 1997 .

REACTIVITY OF DIHYDRODIAZAPHOSPHININES TOWARDS UNSATURATED SUBSTRATES: ADDITION, 5 + 2 CYCLOADDITION AND REARRANGEMENT PROCESSES

S. García‐Granda, J. Barluenga, K. Bieger, 1997 .

[5+2]Cycloaddition of Cyclic N‐Phosphino‐1‐azadienes: Synthesis, Structure, and Reactivity of the First Seven‐Membered Iminophosphorane

S. García‐Granda, J. Barluenga, K. Bieger, 1996 .

Simple synthesis of 2H-1,3-oxazines and their stereoselective transformation into 1,3-aminoalcohols and azetidines

A. Ballesteros, J. Barluenga, M. Tomás, 1996 .

Alkenyl Fischer Carbene Complexes and α,β‐Unsaturated Imine Derivatives: Synthesis of Azepines and Mechanistic NMR Studies

S. García‐Granda, A. Ballesteros, F. López-Ortiz, 1996 .

An Efficient, One-Pot Synthesis of 1,3-Thiazines and 1,2,3,5-Thiatriazines from N-(Trimethylsilyl)imines via [4+2] Cycloaddition of 1-Thia-3-azadienes

A. Ballesteros, J. Barluenga, M. Tomás, 1995 .

Stereoselective cyclopropanation of 1-azadienes with Fischer carbene complexes

J. Barluenga, M. Tomás, E. Rubio, 1995 .

The first [4 + 3] annulation of Fischer carbene complexes with azadienes: facile synthesis of azepines

F. López-Ortiz, J. Barluenga, J. Santamaría, 1994 .

A facile and stereoselective approach to substituted polyamines

J. Barluenga, M. Tomás, E. Rubio, 1993 .

Synthesis, structure, and reactivity of the first diazagermocines

A. Ballesteros, J. Barluenga, P. Pertierra, 1992 .

Reactivity of the Nitrogen-Silicon Bond. Pyridines and Furo[2,3-b][1,4]diazepines from 4-Amino-1-azabutadienes via 1,2-Dihydro-1,3,2-diazasilines

A. Ballesteros, J. Barluenga, M. Tomás, 1992 .

A facile and versatile synthesis of heteropolycyclic compounds from 4-amino-1-azabutadienes via friedel-crafts cyclization of their heterocyclic derivatives.

J. Barluenga, M. Tomás, E. Rubio, 1990 .

Cycloaddition reactions of heteroazadienes: [4+2] cycloaddition of 1-thia-3-azabutadienes with electron-poor dienophiles

A. Ballesteros, J. Barluenga, M. Tomás, 1989 .

Direct access to β-oxodiazo compounds by copper(II)-catalyzed oxidative rearrangement of stabilized vinyl diazo derivatives.

J. Barluenga, M. Tomás, L. A. López, 2011, Journal of the American Chemical Society.

1,2-Heteroannulation of Lactams: A Facile Entry to Fused Pyrimidines

J. Barluenga, M. Tomás, E. Rubio, 1992 .

Bis(pyridine)iodonium(I) Tetrafluoroborate

A. Ballesteros, J. Barluenga, M. Tomás, 2006 .

An Efficient Approach to Pyrroles and N-Bridgehead Pyrroles by Propargylation/Cycloamination of 4-Amino-1-azabutadiene Derivatives

J. Barluenga, M. Tomás, E. Rubio, 1996 .

Simple and regioselective synthesis of N-substituted pyrimidine-2(1H)-ones and -thiones

V. Gotor, J. Barluenga, M. Tomás, 1979 .

Chromium–Copper Exchange of Fischer Carbene Complexes: X-Ray Crystal Structure of a [Cu{=CR1(OR2)}(MeCN)(Et2O)][PF6] Complex

C. Alvarez-Rúa, J. Borge, S. García‐Granda, 2001 .

Sequential five-component construction of the cyclopenta[e][1,3]oxazine skeleton using stable 2-azetine derivatives.

J. Barluenga, J. Santamaría, Aránzazu Gómez, 2010, Angewandte Chemie.

The Reaction of Chromium Alkenyl Carbene Complexes with Alkenyl Oxazolines: A Diastereoselective [3 + 2] Annulation Route to Cyclopentanones

J. Barluenga, M. Tomás, Á. Suárez‐Sobrino, 2000 .

Synthesis of heterocycles via group VI Fischer carbene complexes.

J. Barluenga, J. Santamaría, M. Tomás, 2004, Chemical reviews.

[4+2] Cyclization reactions of chiral Cβ-substituted Fischer alkenyl carbene complexes: efficient synthesis of enantiopure cyclohexenone and norbornene derivatives

J. Barluenga, J. Santamaría, Aránzazu Gómez, 2007 .

Unusual [1,2]- and [1,3]-M(CO)5 Shifts in Fischer Carbene Complexes: [4 + 3] and [3 + 3] Annulation Reactions of Furan and Pyrrole Rings.

S. García‐Granda, J. Barluenga, M. Tomás, 1999 .

UNUSUAL 1,2- AND 1,3-M(CO)5 SHIFTS IN FISCHER CARBENE COMPLEXES : 4 + 3 AND 3 + 3 ANNULATION REACTIONS OF FURAN AND PYRROLE RINGS

J. Barluenga, M. Tomás, E. Rubio, 1999 .

Pyridine activation via copper(I)-catalyzed annulation toward indolizines.

J. Barluenga, L. López, M. Tomás, 2010, Journal of the American Chemical Society.

Copper(I)-catalyzed [3+1] cycloaddition of alkenyldiazoacetates and iminoiodinanes: easy access to substituted 2-azetines.

J. Barluenga, L. López, M. Tomás, 2012, Chemistry.

1,4-Cycloaddition of 1,3-Diazabutadienes with Enamines: An Efficient Route to the Pyrimidine Ring.

A. Ballesteros, J. Barluenga, M. Tomás, 1990 .

6.18 – Functions Containing a Thiocarbonyl Group Bearing Two Heteroatoms Other Than a Halogen or Chalcogen

J. Barluenga, M. Tomás, E. Rubio, 2005 .

One-pot, two-step synthesis of substituted anthraquinones from chromium(0) alkynyl carbenes and isobenzofurans.

J. Barluenga, M. Tomás, Á. Suárez‐Sobrino, 2008, Organic letters.

Rhodium(I)-catalyzed[3+2+2]-cyclization of alkenyl Fischer carbene complexes with methyl buta-2,3-dienoate

J. Barluenga, L. López, R. Vicente, 2010 .

Nickel(0)-mediated [2+2+1] cyclization reaction of chromium carbene complexes and internal alkynes

J. Barluenga, L. López, M. Tomás, 2006 .

Copper-catalyzed dimerization of chromium Fischer carbene complexes: synthesis of dialkoxytrienes and their Nazarov-type cyclization to 2-alkoxy-2-cyclopentenones

J. Barluenga, L. López, R. Vicente, 2004 .

Intramolecular Diels-Alder reactions of 1-thia-3-azabutadienes. One-pot synthesis of annulated thiazines from N-(trimethylsilyl)imines and isothiocyanates

A. Ballesteros, J. Barluenga, M. Tomás, 1991 .

Diastereo- and enantioselective cyclopropanation with chromium fischer carbene complexes: alkenyl oxazolines as useful achiral and chiral substrates.

S. García‐Granda, J. Barluenga, M. Tomás, 2001, Journal of the American Chemical Society.

New reaction pathways for Fischer carbene complexes: [6 + 3] cycloaddition of chromium alkenyl carbene complexes with fulvenes.

J. Barluenga, M. Tomás, Á. Suárez‐Sobrino, 2001, Journal of the American Chemical Society.

A useful synthesis of 3-halogeno-1-azabutadiene derivatives, and their applicability in the preparation of heterocycles

V. Gotor, J. Barluenga, M. Tomás, 1983 .

[8+2] and [8+3] cyclization reactions of alkenyl carbenes and 8-azaheptafulvenes: direct access to tetrahydro-1-azaazulene and cyclohepta[b]pyridinone derivatives.

J. Barluenga, M. Tomás, Jaime García-Rodríguez, 2008, Chemistry, an Asian journal.

Regio- and stereoselective synthesis of cyclopentenones: intermolecular pseudo-Pauson-Khand cyclization.

J. Barluenga, M. Tomás, Á. Suárez‐Sobrino, 2012, Angewandte Chemie.

A general and regioselective synthesis of cyclopentenone derivatives through nickel(0)-mediated [3 + 2] cyclization of alkenyl Fischer carbene complexes and internal alkynes.

J. Barluenga, M. Tomás, Pablo Barrio, 2007, Journal of the American Chemical Society.

One-pot, two-step synthesis of substituted anthraquinones from chromium(0) alkynyl carbenes and isobenzofurans.

J. Barluenga, M. Tomás, Á. Suárez‐Sobrino, 2008, Organic letters.

A general and regioselective synthesis of cyclopentenone derivatives through nickel(0)-mediated [3 + 2] cyclization of alkenyl Fischer carbene complexes and internal alkynes.

J. Barluenga, M. Tomás, Pablo Barrio, 2007, Journal of the American Chemical Society.

New Fischer carbene complexes of rhodium(i): preparation and 2-cyclopentenone ring synthesis by annelation to alkynes.

C. Alvarez-Rúa, J. Barluenga, R. Vicente, 2004, Journal of the American Chemical Society.

Single and consecutive cyclization reactions of alkynyl carbene complexes and 8-azaheptafulvenes: direct access to polycyclic pyrrole and indole derivatives.

J. Barluenga, M. Tomás, Jaime García-Rodríguez, 2009, Chemistry.

Facile and versatile annulation of the imidazole ring: Single and sequential cyclization reactions of Fischer carbene complexes with 1,4-diazafulvenes.

J. Barluenga, M. Tomás, Jaime García-Rodríguez, 2006, Chemistry.

Single and consecutive cyclization reactions of alkynyl carbene complexes and 8-azaheptafulvenes: direct access to polycyclic pyrrole and indole derivatives.

J. Barluenga, M. Tomás, Jaime García-Rodríguez, 2009, Chemistry.

Reaction of Fischer alkynylcarbene complexes with 1-azadiene derivatives: unexpected formation of 3,4-dihydropyridines

S. García‐Granda, A. Ballesteros, J. Barluenga, 2001 .

Uncatalyzed Mukaiyama-Michael reaction: rapid access to simple and complex enantiopure gamma-butenolides.

J. Barluenga, J. Santamaría, A. de Prado, 2005, Angewandte Chemie.

Generation of azomethine ylides via the desilylation reaction of immonium salts

A. Padwa, M. Tomás, G. Haffmanns, 1984 .

Benzannulation and Cyclopentannulation Reactions of Electron-Poor Amino-Stabilized Alkenyl Fischer Carbene Complexes

J. Barluenga, L. López, M. Tomás, 2000 .

Highly chemo-, regio-, and stereoselective [3+2]-cyclization of activated and deactivated allenes with alkenyl Fischer carbene complexes: a straightforward access to alkylidenecyclopentanone derivatives.

J. Barluenga, R. Vicente, M. Tomás, 2006, Journal of the American Chemical Society.

Reaction of Diimines with Carbonyl Compounds. Synthesis of Dihydropyrimidines

V. Gotor, S. Fustero, J. Barluenga, 1979 .

A simple metal-promoted three-step access to n/5/m angular carbocyclic systems.

J. Barluenga, M. Tomás, Á. Suárez‐Sobrino, 2013, Organic letters.

A NEW ELECTRON-POOR FISCHER CARBENE COMPLEX : UNUSUALLY EFFICIENT AND GENERAL BENZANNULATION OF AMINO-STABILIZED ALKENYL FISCHER CARBENE COMPLEXES

J. Barluenga, M. Tomás, L. A. López, 1998 .

New Applications of Dipolar Cycloaddition Chemistry Toward the Synthesis of Heterocycles

K. Koehler, A. Padwa, Yon-Yih Chen, 1984 .

Cyclopropanation of enantiopure metal alkenyl carbenes with 2-methoxyfuran: a practical route to carboxycyclopropylglycine precursors.

J. Barluenga, J. Santamaría, A. de Prado, 2007, Chemistry.

Chiral 2-alkoxy-1,3-butadienes: synthesis and face-selectivity in Diels–Alder reactions

J. Barluenga, M. Tomás, L. A. López, 1995 .

Cesium fluoride induced desilylation reaction of immonium salts derived from vinylogous amides

A. Padwa, M. Tomás, G. Haffmanns, 1983 .

Bis(dichlorotrimethylsilylmethyl)mercury

J. Barluenga, M. Tomás, J. González, 2001 .

Carbene and silicon routes as methods for the generation and dipolar cycloaddition reactions of methyl nitrile ylide

I. Gould, N. Turro, J. Gasdaska, 1986 .

Carbene and silicon routes toward a simple nitrile ylide. Spectroscopic, kinetic, and chemical characterization

I. Gould, N. Turro, J. Gasdaska, 1985 .

An Extremely Short, Stereoselective Synthesis of (.+-.)-Tetraponerine-8

J. Barluenga, M. Tomás, E. Rubio, 1994 .

A facile synthesis of N-bridgehead pyrroles

J. Barluenga, M. Tomás, E. Rubio, 1992 .

The [2 + 1] and [4 + 3] cyclization reactions of fulvenes with Fischer carbene complexes: new access to annulated cyclopentanones.

J. Barluenga, M. Tomás, Á. Suárez‐Sobrino, 2002, Journal of the American Chemical Society.

Metal-controlled selective [3+2] cyclization reactions of alkenyl Fischer carbene complexes and allenes.

J. Barluenga, L. López, R. Vicente, 2004, Journal of the American Chemical Society.

Chromium(0) alkynylcarbene complexes as Cbeta-electrophilic carbene equivalents: regioselective access to dienynes and dienediynes.

A. Ballesteros, J. Barluenga, E. Aguilar, 2007, Angewandte Chemie.

Kinetics of polycondensation of urea with formaldehyde. Molecular weight distribution, average molecular weight, and polydispersity parameters

S. Katuščák, M. Tomás, O. Schiessl, 1981 .

Phenyl(trichloromethyl)mercury

J. Barluenga, M. Tomás, J. González, 2001 .

[6 + 3] Cycloaddition of Fischer aminocarbene complexes: An efficient annulation of fulvenes to indene derivatives

J. Barluenga, M. Tomás, Á. Suárez‐Sobrino, 2005 .

A new, simple method for the preparation of substituted 2H-1,2-thiazine-1,1-dioxides from aminoazabutadienes

J. Barluenga, M. Tomás, Á. Suárez‐Sobrino, 1989 .

A facile and diastereoselective access to substituted cyclopentanones from Fischer alkenyl carbene complexes and 1-amino-1-azadienes

A. Ballesteros, J. Barluenga, J. Santamaría, 2002 .

Nickel(0)-mediated [3+2+2] and [2+2+2+1] cyclization reactions of chromium Fischer carbene complexes and alkynes.

C. Alvarez-Rúa, S. García‐Granda, J. Barluenga, 2003, Angewandte Chemie.

Polymer-Bound Fischer Tungsten Carbene Complexes: Synthesis and Reactivity

J. Barluenga, J. Santamaría, M. Tomás, 2005 .

1-Bromo-1,2,2,2-tetrafluoroethyl(phenyl)mercury†

J. Barluenga, M. Tomás, J. González, 2001 .

An unambiguous synthesis of pyrazoles by sulphur extrusion from 1,2,6-thiadiazines

V. Gotor, J. Barluenga, M. Tomás, 1981 .

Group 6 Heteroatom- and Non-Heteroatom-Stabilized Carbene Complexes. β,β‘- and α,β,β‘-Annulation Reactions of Cyclic Enamines

A. Ballesteros, J. Barluenga, J. Santamaría, 2003 .

A simple approach toward enantiomerically pure Fischer carbene complexes of chromium and molybdenum: Chiral modification of the metal fragment

S. García‐Granda, A. Ballesteros, J. Barluenga, 2003 .

Cyclopropanation of alkenes mediated by novel chiral Fischer carbene complexes

A. Ballesteros, J. Barluenga, K. Muñiz, 2002 .

Versatile Reactivity of Alkynyl Fischer Carbene Complexes toward Pentafulvenes: Carbocyclization and C-H Insertion Reactions

J. Barluenga, M. Tomás, Á. Suárez‐Sobrino, 2006 .

Efficient Approaches to the Stereoselective Synthesis of Chiral 2-Alkoxydienes and Heterodienes

J. Barluenga, M. Tomás, L. A. López, 1997 .

Reduction of the Pyrimidine Ring: Regio- and Stereoselective Synthesis of 1,3-Diamine Derivatives

J. Jardón, J. Barluenga, M. Tomás, 1991 .

Specific synthesis of 1,2- and 1,3-dialkylidenecycloheptanes by [3+2+2] cyclization of alkenyl Fischer carbene complexes and allenes.

J. Borge, J. Barluenga, L. López, 2004, Journal of the American Chemical Society.

Cu(I)-catalyzed regioselective synthesis of polysubstituted furans from propargylic esters via postulated (2-furyl)carbene complexes.

J. Barluenga, L. López, R. Vicente, 2008, Journal of the American Chemical Society.

Chromium (0)-rhodium (I) metal exchange : Synthesis and X-ray structure of new Fischer (NHC)carbene complexes of rhodium(I)

J. Barluenga, L. López, R. Vicente, 2006 .

Specific Synthesis of 1,2‐ and 1,3‐Dialkylidenecycloheptanes by [3 + 2 + 2] Cyclization of Alkenyl Fischer Carbene Complexes and Allenes.

J. Borge, J. Barluenga, L. López, 2005 .

Efficient synthesis of 2-alkoxy-1,3-butadienes by methylenation of alkenyl Fischer carbene complexes

J. Barluenga, L. López, R. Vicente, 2006 .