C. T. O'Hara

发表

Structural Studies of Donor‐Free and Donor‐Solvated Sodium Carboxylates

Richard M. Gauld, A. Kennedy, J. Reid, 2021 .

Ultrafast amidation of esters using lithium amides under aerobic ambient temperature conditions in sustainable solvents

Joaquín García‐Álvarez, A. Kennedy, Eva Hevia, 2020, Chemical science.

The synthesis and characterisation of a magnesium amine bis(phenolate) complex as a potential initiator for the ring-opening polymerisation of cyclic esters

Matthew D. Jones, M. Davidson, D. Meng, 2006 .

Pre-inverse-crowns: synthetic, structural and reactivity studies of alkali metal magnesiates primed for inverse crown formation

D. Armstrong, J. Klett, A. Martı́nez-Martı́nez, 2014 .

Alkali-metal-mediated zincation of polycyclic aromatic hydrocarbons: synthesis and structures of mono- and dizincated naphthalenes.

W. Clegg, Eva Hevia, C. T. O'Hara, 2006, Angewandte Chemie.

Templated deprotonative metalation of polyaryl systems: Facile access to simple, previously inaccessible multi-iodoarenes

I. Oswald, A. Martı́nez-Martı́nez, A. Kennedy, 2017, Science Advances.

Optimisation of a lithium magnesiate for use in the non-cryogenic asymmetric deprotonation of prochiral ketones.

J. Francos, C. T. O'Hara, Silvia Zaragoza-Calero, 2014, Dalton transactions.

Evaluating cis-2,6-Dimethylpiperidide (cis-DMP) as a Base Component in Lithium-Mediated Zincation Chemistry

D. Armstrong, A. Steven, A. Kennedy, 2013, Chemistry.

Alkali-Metal-Mediated Magnesiations of an N-Heterocyclic Carbene: Normal, Abnormal, and "Paranormal" Reactivity in a Single Tritopic Molecule.

A. Martı́nez-Martı́nez, A. Kennedy, Eva Hevia, 2015, Angewandte Chemie.

Unmasking representative structures of TMP-active Hauser and turbo-Hauser bases.

J. Klett, S. Weatherstone, A. Kennedy, 2008, Angewandte Chemie.

Selective meta-deprotonation of toluene by using alkali-metal-mediated magnesiation.

D. Armstrong, P. Andrikopoulos, A. Kennedy, 2005, Angewandte Chemie.

Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse crowns.

A. Kennedy, Eva Hevia, Christine Talmard, 2004, Chemical communications.

Trimagnesium-bridged trinuclear ferrocenophanes cocomplexed with solvated mononuclear alkali metal amide molecules.

K. Henderson, C. T. O'Hara, R. Mulvey, 2001, Chemical communications.

Solid state and solution studies of lithium tris(n-butyl)magnesiates stabilised by Lewis donors.

A. Kennedy, J. Francos, C. T. O'Hara, 2015, Dalton transactions.

Remote functionalisation via sodium alkylamidozincate intermediates: access to unusual fluorenone and pyridyl ketone reactivity patterns.

J. Klett, J. Crawford, A. Kennedy, 2011, Chemical communications.

Directed ortho-meta′- and meta-meta′-dimetalations: A template base approach to deprotonation

A. Martı́nez-Martı́nez, A. Kennedy, C. T. O'Hara, 2014, Science.

Sodium-mediated magnesiation of thiophene and tetrahydrothiophene: structural contrasts with furan and tetrahydrofuran.

V. Blair, A. Kennedy, C. T. O'Hara, 2010, Chemistry.

Synthetic and structural investigations of alkali metal diamine bis(phenolate) complexes.

Matthew D. Jones, M. Davidson, W. Clegg, 2008, Dalton transactions.

Structurally defined reactions of sodium TMP-zincate with nitrile compounds: synthesis of a salt-like sodium sodiumdizincate and other unexpected ion-pair products.

W. Clegg, Eva Hevia, C. T. O'Hara, 2008, Angewandte Chemie.

Organometallic Polymers Assembled from Cation–π Interactions: Use of Ferrocene as a Ditopic Linker Within the Homologous Series [{(Me3Si)2NM}2⋅(Cp2Fe)]∞ (M=Na, K, Rb, Cs; Cp=cyclopentadienyl)

B. Noll, K. Henderson, A. Kennedy, 2007 .

Synthesis and structural chemistry of alkali metal tris(HMDS) magnesiates containing chiral diamine donor ligands.

A. Kennedy, P. García‐Álvarez, C. T. O'Hara, 2011, Dalton transactions.

Structural Elucidation of tmeda-Solvated Alkali Metal Diphenylamide Complexes

J. Klett, A. Kennedy, C. T. O'Hara, 2009 .

Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate.

D. Armstrong, Joaquín García‐Álvarez, R. Harrington, 2008, Chemical communications.

Synthetic and Structural Studies of Mixed Sodium Bis(trimethylsilyl)amide/Sodium Halide Aggregates in the Presence of η(2)-N,N-, η(3)-N,N,N/N,O,N-, and η(4)-N,N,N,N-Donor Ligands.

A. Martı́nez-Martı́nez, A. Kennedy, C. T. O'Hara, 2015, Inorganic chemistry.

A structural and computational study of synthetically important alkali-metal/tetramethylpiperidide (TMP) amine solvates.

D. Armstrong, A. Kennedy, David V. Graham, 2008, Chemistry.

Meta-metallation of N,N-dimethylaniline: Contrasting direct sodium-mediated zincation with indirect sodiation-dialkylzinc co-complexation

D. Armstrong, A. Kennedy, Eva Hevia, 2011, Beilstein journal of organic chemistry.

s-Block cooperative catalysis: alkali metal magnesiate-catalysed cyclisation of alkynols

Joaquín García‐Álvarez, Eva Hevia, C. T. O'Hara, 2019, Chemical science.

Mixed Lithium Complexes: Structure and Applicationin Synthesis

C. T. O'Hara, R. Mulvey, 2014 .

Synthesis and structure of a molecular barium Aminebis(phenolate) and its application as an initiator for ring-opening polymerization of cyclic esters.

Matthew D. Jones, G. Kociok‐Köhn, M. Mahon, 2007, Inorganic chemistry.

Structural studies of (rac)-BIPHEN organomagnesiates and intermediates in the halogen-metal exchange of 2-Bromopyridine

P. Gros, A. Kennedy, J. Francos, 2015 .

Introducing Glycerol as a Sustainable Solvent to Organolithium Chemistry: Ultrafast Chemoselective Addition of Aryllithium Reagents to Nitriles under Air and at Ambient Temperature.

Joaquín García‐Álvarez, Eva Hevia, M. Uzelac, 2018, Chemistry.

Complexity in seemingly simple sodium magnesiate systems.

A. Kennedy, P. García‐Álvarez, J. Francos, 2014, Dalton transactions.

Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)·Na(μ-TMP)(μ-tBu)Zn(tBu)] towards TEMPO and chalcone.

D. Armstrong, J. Klett, J. Crawford, 2012, Chemical communications.

Synthesis, Structure and Theoretical Studies of the Hydrido Inverse Crown [K2Mg2(NiPr2)4(μ-H)2·(toluene)2]: a Rare Example of a Molecular Magnesium Hydride with a Mg-(μ-H)2-Mg Double Bridge

D. Armstrong, P. Andrikopoulos, A. Kennedy, 2003 .

Monodentate coordination of the normally chelating chiral diamine (R,R)-TMCDA.

D. Armstrong, A. Martı́nez-Martı́nez, A. Kennedy, 2017, Chemical communications.

Structural Studies of Cesium, Lithium/Cesium, and Sodium/Cesium Bis(trimethylsilyl)amide (HMDS) Complexes.

A. Martı́nez-Martı́nez, A. Kennedy, C. T. O'Hara, 2016, Inorganic chemistry.

catena-Poly[sodium-μ2-(N,N,N′,N′-tetramethylethane-1,2-diamine)-κ2 N:N′-sodium-bis[μ2-bis(trimethylsilyl)azanido-κ2 N:N]]

A. Kennedy, C. T. O'Hara, R. Mulvey, 2012, Acta crystallographica. Section E, Structure reports online.

Synthesis and structural characterisation of mixed alkalimetal-magnesium mixed ligand alkyl-amido ate complexes

D. Armstrong, P. Andrikopoulos, S. Weatherstone, 2007 .

Reactions of (-)-sparteine with alkali metal HMDS complexes: conventional meets the unconventional.

A. Kennedy, P. García‐Álvarez, C. T. O'Hara, 2009, Chemical communications.

Hydride encapsulation in s-block metal inverse crown chemistry.

K. Henderson, A. Kennedy, C. T. O'Hara, 2002, Chemical communications.

Hexameric Mg-O stacks with six THF-solvated sodium amide appendages: "super" variants of inverse crown ethers generated by cleavage of THF.

L. Gibson, A. Kennedy, C. T. O'Hara, 2002, Angewandte Chemie.

A homologous series of regioselectively tetradeprotonated group 8 metallocenes: new inverse crown ring compounds synthesized via a mixed sodium-magnesium tris(diisopropylamide) synergic base.

Duncan M. Tooke, D. Armstrong, P. Andrikopoulos, 2004, Journal of the American Chemical Society.

Synthesis of the mixed lithium-potassium-(bis)magnesium N-metallated/N, C-dimetallated amide [Li2K2Mg4[But(Me3Si)N]4[But[Me2(H2C)Si]N]4]: an inverse crown molecule with an atomless cavity.

J. Parkinson, A. Kennedy, C. T. O'Hara, 2003, Chemical communications.

Regioselective Tetrametalation of Ferrocene in a Single Reaction: Extension of s-Block Inverse Crown Chemistry to the d-Block.

Duncan M. Tooke, W. Clegg, K. Henderson, 2001, Angewandte Chemie.

Lithium, sodium, and potassium magnesiate chemistry: a structural overview

A. Martı́nez-Martı́nez, C. T. O'Hara, A. Martínez‐Martínez, 2016 .

Structural elaboration of the surprising ortho-zincation of benzyl methyl ether.

J. Klett, A. Kennedy, C. T. O'Hara, 2010, Chemical communications.

Exploring the solid state and solution structural chemistry of the utility amide potassium hexamethyldisilazide (KHMDS).

A. Martı́nez-Martı́nez, A. Kennedy, C. T. O'Hara, 2017, Dalton transactions.

Dehydromethylation of alkali metal salts of the utility amide 2,2,6,6-tetramethylpiperidide (TMP).

A. Martı́nez-Martı́nez, A. Steven, A. Kennedy, 2014, Chemical communications.

Synthesis of an alkylmagnesium amide and interception of a ring-opened isomer of the important utility amide 2,2,6,6-tetramethylpiperidide (TMP)

J. Klett, A. Kennedy, C. T. O'Hara, 2014 .

Structural and metal-halogen exchange reactivity studies of sodium magnesiate biphenolate complexes.

P. Gros, A. Martı́nez-Martı́nez, S. Touchet, 2020, Dalton transactions.

Isolation and characterisation of a (-)-sparteine coordinated mixed alkyl/amido sodium magnesiate, a chiral variant of an important utility ate base.

A. Kennedy, C. T. O'Hara, 2008, Dalton transactions.

Synthetic and reactivity studies of hetero-tri-anionic sodium zincates.

A. Kennedy, J. Francos, C. T. O'Hara, 2016, Dalton transactions.

Structural variations within group 1 (Li-Cs)+ (2,2,6,6-tetramethyl-1-piperidinyloxy)- complexes made via metallic reduction of the nitroxyl radical.

J. Klett, A. Kennedy, David V. Graham, 2009, Inorganic chemistry.

Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal-magnesium-alkoxide-diisopropylamides.

Katy J. Drewette, K. Henderson, A. Kennedy, 2002, Chemical communications.

Selective mono- and dimetallation of a group 3 sandwich complex.

Rian D. Dewhurst, F. Fantuzzi, A. Martı́nez-Martı́nez, 2019, Chemical communications.

Synthesis and structural elucidation of a rare example of a tris(amido) potassium magnesiate

A. Kennedy, P. García‐Álvarez, B. Fleming, 2012 .

cis-2,6-Dimethylpiperidide: a structural mimic for TMP (2,2,6,6-tetramethylpiperidide) or DA (diisopropylamide)?

J. Klett, A. Kennedy, P. García‐Álvarez, 2010, Dalton Transactions.

Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions.

D. Armstrong, P. Andrikopoulos, A. Kennedy, 2005, Chemical communications.

Building an extended inverse crown motif via alkali-metal-mediated alpha-magnesiation of furan.

A. Kennedy, Eva Hevia, Christine Talmard, 2006, Chemical communications.

Structural elucidation of homometallic anthracenolates synthesised via deprotonative metallation of anthrone.

J. Klett, W. Clegg, A. Kennedy, 2013, Dalton transactions.

Mixed Lithium Amide–Lithium Halide Compounds: Unusual Halide-Deficient Amido Metal Anionic Crowns**

A. Kennedy, C. T. O'Hara, R. Mulvey, 2011, Angewandte Chemie.

Synergic synthesis of benzannulated zincabicyclic complexes, alpha-zincated N ylides, through sodium-TMEDA-mediated zincation of a haloarene.

D. Armstrong, W. Clegg, A. Kennedy, 2009, Angewandte Chemie.