R. Mulvey

发表

Structural Studies of Donor‐Free and Donor‐Solvated Sodium Carboxylates

Richard M. Gauld, A. Kennedy, J. Reid, 2021 .

Lithium, sodium and potassium picolyl complexes: syntheses, structures and bonding.

A. Kennedy, R. Mulvey, Robert I Urquhart, 2014, Dalton transactions.

Synthesis and structure of the novel heptalithiumtetrarubidium mixed alkoxide peroxide [{((BuOLi)-O-t)(5)((BuORb)-O-t)(4)(Li2O2)center dot 2tmeda}(infinity)]: twenty-two vertex cage molecules linked by Rb-TMEDA-Rb bridges

S. Liddle, W. Clegg, R. Mulvey, 1998 .

X-ray crystallographic studies and comparative reactivity studies of a sodium diisopropylamide (NDA) complex and related hindered amides

P. Andrews, W. Clegg, B. Wakefield, 1996 .

An unexpected transamination of bis[bis(trimethylsilyl)amido]zinc with dibenzylamine to form bis(dibenzylamido)zinc: structural studies by NMR spectroscopy, X-ray crystallography and theoretical calculations

Duncan M. Tooke, D. Armstrong, W. Clegg, 2002 .

Direct C–H Metalation with Chromium(II) and Iron(II): Transition-Metal Host / Benzenediide Guest Magnetic Inverse-Crown Complexes

J. Klett, E. Rentschler, W. Clegg, 2009, Angewandte Chemie.

X-ray crystallographic and solution studies of the pentamethyldiethylenetriamine and tetramethylethylenediamine adducts of lithium diphenylphosphide

D. Armstrong, W. Clegg, K. Wade, 1987 .

Contrasting Synergistic Heterobimetallic (Na-Mg) and Homometallic (Na or Mg) Bases in Metallation Reactions of Dialkylphenylphosphines and Dialkylanilines: Lateral versus Ring Selectivities.

E. Izgorodina, V. Blair, Eunice S. H. Gwee, 2018, Chemistry.

A mechanistic study of the C-P bond cleavage reaction of 1,2-(PH2)2-C6H4 with nBuLi/Sb(NMe2)3.

D. Wright, E. McInnes, R. Edge, 2008, Dalton transactions.

TEMPO: a novel chameleonic ligand for s-block metal amide chemistry

A. Kennedy, R. Mulvey, Glenn C. Forbes, 2001 .

A monomeric three-coordinate magnesium bis(amide).

A. Kennedy, R. Mulvey, J. Schulte, 2001, Acta crystallographica. Section C, Crystal structure communications.

Formation of the Unprecedented Trilithio-Capped Heteroadamantanyl Iminoalane Anion [(HAl)4 (NPh)6 {Li(OEt2 )}3 ]- : An Open Cage Derived from a Rhombododecahedron.

K. Henderson, A. Kennedy, R. Mulvey, 2000, Angewandte Chemie.

Bis[(μ-cyclopentylamino-N:N)dimethylaluminium(III)]

A. Kennedy, R. Mulvey, F. Craig, 2000 .

Synthesis and crystal structure of trimeric sodium 2,2,6,6- tetramethylpiperidide (NaTMP)

M. Lappert, A. Kennedy, R. Mulvey, 1999 .

Exposing elusive cationic magnesium-chloro aggregates in aluminate complexes through donor control.

Etienne V. Brouillet, K. Koszinowski, A. Kennedy, 2016, Dalton transactions.

Closer Insight into the Reactivity of TMP−Dialkyl Zincates in Directed ortho-Zincation of Anisole: Experimental Evidence of Amido Basicity and Structural Elucidation of Key Reaction Intermediates

W. Clegg, Eva Hevia, Matthew D. McCall, 2009, Journal of the American Chemical Society.

Pre-inverse-crowns: synthetic, structural and reactivity studies of alkali metal magnesiates primed for inverse crown formation

D. Armstrong, J. Klett, A. Martı́nez-Martı́nez, 2014 .

Alkali-metal-mediated zincation of polycyclic aromatic hydrocarbons: synthesis and structures of mono- and dizincated naphthalenes.

W. Clegg, Eva Hevia, C. T. O'Hara, 2006, Angewandte Chemie.

Dis-assembling lithium amide ladder structures: new insight through the structure of [{[PhCH2N(H)Li](2)center dot thf}(infinity)], a polymer of (NLi)(2) planar rings connected by thf-bridged (NLi)(2) butterfly junctions

S. Liddle, W. Clegg, A. Robertson, 1999 .

Structurally Defined Potassium-Mediated Zincation of Pyridine and 4-R-Substituted Pyridines (R=Et, iPr, tBu, Ph, and Me2N) by Using Dialkyl–TMP–Zincate Bases

D. Wright, W. Clegg, A. Kennedy, 2009, Chemistry.

Structurally Defined Ring‐Opening and Insertion of Pinacolborane into Aluminium‐Nitrogen Bonds of Sterically Demanding Dialkylaluminium Amides

T. Tuttle, A. Kennedy, R. McLellan, 2020 .

Developing lithium chemistry of 1,2-dihydropyridines: from kinetic intermediates to isolable characterized compounds.

D. Armstrong, A. Kennedy, J. Liggat, 2015, Chemistry.

TMP (2,2,6,6-tetramethylpiperidide)-aluminate bases : lithium-mediated alumination or lithiation-alkylaluminium-trapping reagents?

D. Armstrong, Eva Hevia, Donna L. Ramsay, 2014 .

Comparing Neutral (Monometallic) and Anionic (Bimetallic) Aluminum Complexes in Hydroboration Catalysis: Influences of Lithium Cooperation and Ligand Set

A. Kennedy, R. McLellan, R. Mulvey, 2018, Angewandte Chemie.

Donor‐influenced Structure–Activity Correlations in Stoichiometric and Catalytic Reactions of Lithium Monoamido‐Monohydrido‐Dialkylaluminates

J. Okuda, A. Kennedy, Eva Hevia, 2018, Chemistry.

Deprotonative metalation using ate compounds: synergy, synthesis, and structure building.

Y. Kondo, M. Uchiyama, F. Mongin, 2007, Angewandte Chemie.

Split personality of lithium chloride: recent salt effects in organometallic recipes.

Eva Hevia, R. Mulvey, 2011, Angewandte Chemie.

Catalytic hydrophosphination of alkynes using structurally diverse sodium diphenylphosphide donor complexes

T. Tuttle, A. Kennedy, Sumanta Banerjee, 2022, Cell Reports Physical Science.

Backbone reactivity of lithium β-diketiminate (NacNac) complexes with CO2, t-BuNCO and i-PrNCO.

Richard M. Gauld, A. Kennedy, J. Reid, 2019, Chemistry.

Structural Basis for Regioisomerization in the Alkali-Metal-Mediated Zincation (AMMZn) of Trifluoromethyl Benzene by Isolation of Kinetic and Thermodynamic Intermediates

D. Armstrong, V. Blair, Joaquín García‐Álvarez, 2010, Journal of the American Chemical Society.

Sodium-mediated manganation: direct mono- and dimanganation of benzene and synthesis of a transition-metal inverse-crown complex.

J. Klett, E. Rentschler, W. Clegg, 2007, Angewandte Chemie.

Manganese(II)-lithium and -sodium inverse crown ether (ICE) complexes.

D. Wright, J. Klett, A. Kennedy, 2008, Chemical communications.

Modern Ate Chemistry: Applications of Synergic Mixed Alkali-Metal−Magnesium or −Zinc Reagents in Synthesis and Structure Building

R. Mulvey, 2006 .

Inverse crown ether complexes: extension to potassium through the synthesis of [{[(Me3Si)(2)N](4)K2Mg2(O-2)}(infinity)], a peroxo- centred macrocycle linked into infinite chains by intermolecular K center dot center dot center dot CH3(SiMe2) interac

C. Raston, B. A. Roberts, A. Kennedy, 1999 .

Reactivity studies and structural outcomes of a bulky dialkylaluminium amide in the presence of the N-heterocyclic carbene, ItBu

A. Kennedy, Catherine Weetman, R. Mulvey, 2021, Polyhedron.

Cleave and capture chemistry illustrated through bimetallic-induced fragmentation of tetrahydrofuran.

J. Klett, V. Blair, W. Clegg, 2010, Nature chemistry.

Isolation, characterisation, and solution structures of the bis(pyridine) complex of the n-butyllithium-pyridine adduct, Bun(C5H5N)Li·2C5H5N, its mode of decomposition, and ab initio calculations on model systems

D. Armstrong, D. Reed, R. Mulvey, 1988 .

Neutral zinc, lower-order zincate and higher-order zincate derivatives of pyrrole: synthesis and structural characterisation of zinc complexes with one, two, three or four pyrrolyl ligands.

A. Kennedy, J. A. Garden, R. Mulvey, 2011, Dalton transactions.

Evaluating cis-2,6-Dimethylpiperidide (cis-DMP) as a Base Component in Lithium-Mediated Zincation Chemistry

D. Armstrong, A. Steven, A. Kennedy, 2013, Chemistry.

Alkali-Metal-Mediated Magnesiations of an N-Heterocyclic Carbene: Normal, Abnormal, and "Paranormal" Reactivity in a Single Tritopic Molecule.

A. Martı́nez-Martı́nez, A. Kennedy, Eva Hevia, 2015, Angewandte Chemie.

Lithium diamidodihydridoaluminates: bimetallic cooperativity in catalytic hydroboration and metallation applications.

A. Kennedy, Eva Hevia, R. McLellan, 2018, Chemical communications.

Alkali-Metal-Mediated Synergistic Effects in Polar Main Group Organometallic Chemistry.

M. Uzelac, R. Mulvey, S. Robertson, 2019, Chemical reviews.

Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations.

J. Klett, W. Clegg, A. Kennedy, 2010, Dalton transactions.

Synthesis, Structure, and DFT Analysis of the THF Solvate of 2‐Picolyllithium: A 2‐Picolyllithium Solvate with Significant Carbanionic Character

Etienne V. Brouillet, T. Krämer, A. Kennedy, 2020, Zeitschrift für anorganische und allgemeine Chemie.

Expected and Unexpected Reactivities of Homoleptic LiNacNac and Heteroleptic NacNacMg(TMP) β-Diketiminates toward Various Small Unsaturated Organic Molecules

Richard M. Gauld, A. Kennedy, J. Reid, 2021, Inorganic chemistry.

N-Heterocyclic-Carbene-Induced Monomerization of Sterically Encumbered Dialkylmagnesium and Dialkylmanganese Polymers

J. Klett, A. Kennedy, R. Mulvey, 2011 .

A record-breaking magnesium hydride molecular cluster: implications for hydrogen storage.

Eva Hevia, R. Mulvey, 2011, Angewandte Chemie.

N-Heterocyclic carbene stabilized adducts of alkyl magnesium amide, bisalkyl magnesium and Grignard reagents: trapping oligomeric organo s-block fragments with NHCs.

A. Kennedy, R. Mulvey, S. Robertson, 2010, Dalton transactions.

Structural Tracking of the Potassium-Mediated Magnesiation of Anisole

T. Tuttle, W. Clegg, A. Kennedy, 2009, Chemistry.

Avant-garde metalating agents: structural basis of alkali-metal-mediated metalation.

R. Mulvey, 2009, Accounts of chemical research.

Unmasking representative structures of TMP-active Hauser and turbo-Hauser bases.

J. Klett, S. Weatherstone, A. Kennedy, 2008, Angewandte Chemie.

Tuning the Basicity of Synergic Bimetallic Reagents: Switching the Regioselectivity of the Direct Dimetalation of Toluene from 2,5- to 3,5-Positions**

J. Klett, V. Blair, R. Harrington, 2008, Angewandte Chemie.

Structurally-defined direct C-magnesiation and C-zincation of N-heterocyclic aromatic compounds using alkali-metal-mediated metallation.

A. Kennedy, Eva Hevia, R. Mulvey, 2007, Chemical communications.

Dizincation and dimagnesiation of benzene using alkali-metal-mediated metallation.

D. Armstrong, W. Clegg, A. Kennedy, 2007, Chemical communications.

Alkali-metal-mediated zincation of anisole: synthesis and structures of three instructive ortho-zincated complexes.

W. Clegg, Eva Hevia, R. Mulvey, 2006, Journal of the American Chemical Society.

Pre-metalation structural insights into the use of alkali-metal-mediated zincation for directed ortho-metalation of a tertiary aromatic amide.

W. Clegg, Eva Hevia, R. Mulvey, 2006, Angewandte Chemie.

Selective meta-deprotonation of toluene by using alkali-metal-mediated magnesiation.

D. Armstrong, P. Andrikopoulos, A. Kennedy, 2005, Angewandte Chemie.

Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse crowns.

A. Kennedy, Eva Hevia, Christine Talmard, 2004, Chemical communications.

Trimagnesium-bridged trinuclear ferrocenophanes cocomplexed with solvated mononuclear alkali metal amide molecules.

K. Henderson, C. T. O'Hara, R. Mulvey, 2001, Chemical communications.

Synthesis of the mixed lithium-magnesium, mixed amide (R,R/S,S)-[{LiMg(TMP)[CH2Si(Me)(2)N(SiMe3)]}(2)]: a conformationally-locked structure of five fused rings inducing two stereogenic nitrogen centres

Jonathan G Maclellan, A. Kennedy, R. Mulvey, 2000 .

An alternative picture of alkali-metal-mediated metallation: cleave and capture chemistry.

R. Mulvey, 2013, Dalton transactions.

Opening the black box of mixed-metal TMP metallating reagents: direct cadmation or lithium–cadmium transmetallation?

D. Armstrong, J. Parkinson, A. Kennedy, 2012 .

"LiZn(TMP)3", a zincate or a turbo-lithium amide reagent? DOSY NMR spectroscopic evidence.

J. Parkinson, P. García‐Álvarez, R. Mulvey, 2011, Angewandte Chemie.

A regioselectively 1,1′,3,3′-tetrazincated ferrocene complex displaying core and peripheral reactivity†

D. Armstrong, J. Parkinson, W. Clegg, 2020, Chemical science.

Structurally-defined potassium-mediated regioselective zincation of amino- and alkoxy-substituted pyridines.

J. Klett, A. Kennedy, Eva Hevia, 2008, Chemical communications.

Transforming LiTMP Lithiation of Challenging Diazines through Gallium Alkyl Trans‐Metal‐Trapping

A. Kennedy, Eva Hevia, M. Uzelac, 2016, Angewandte Chemie.

Directed meta-metalation using alkali-metal-mediated zincation.

D. Armstrong, W. Clegg, Eva Hevia, 2006, Angewandte Chemie.

Contacted Ion-Pair Lithium Alkylamidoaluminates: Intramolecular Alumination (Al−H Exchange) Traps for TMEDA and PMDETA

Joaquín García‐Álvarez, A. Kennedy, Eva Hevia, 2009 .

Structurally Defined Zincated and Aluminated Complexes of Ferrocene Made by Alkali-Metal-Synergistic Syntheses

W. Clegg, A. Kennedy, Eva Hevia, 2015 .

Alkali metal cation-pi interactions stabilized solely by [M{N(SiMe3)(2)}(3)](-) anions (M = Mg or Zn): The competing influence of alkali metal center dot center dot center dot C(Me) agostic interactions

B. A. Roberts, A. Kennedy, R. Mulvey, 2002 .

Synthesis and Structures of [(Trimethylsilyl)methyl]sodium and ‐potassium with Bi‐ and Tridentate N‐Donor Ligands

J. Klett, W. Clegg, A. Kennedy, 2011 .

s-Block metal inverse crowns: synthetic and structural synergism in mixed alkali metal–magnesium (or zinc) amide chemistry

R. Mulvey, 2001 .

Directed ortho-meta′- and meta-meta′-dimetalations: A template base approach to deprotonation

A. Martı́nez-Martı́nez, A. Kennedy, C. T. O'Hara, 2014, Science.

Sodium-mediated magnesiation of thiophene and tetrahydrothiophene: structural contrasts with furan and tetrahydrofuran.

V. Blair, A. Kennedy, C. T. O'Hara, 2010, Chemistry.

Monomerizing alkali-metal 3,5-dimethylbenzyl salts with tris(N, N-dimethyl-2-aminoethyl)amine (Me6TREN): structural and bonding implications.

D. Armstrong, M. Davidson, A. Kennedy, 2013, Inorganic chemistry.

Synthetically important alkali-metal utility amides: lithium, sodium, and potassium hexamethyldisilazides, diisopropylamides, and tetramethylpiperidides.

R. Mulvey, S. Robertson, Stuart D. Robertson, 2013, Angewandte Chemie.

Concerning the structures of alkali-metal-mediated ortho zincation of benzamides and phenyl o-carbamate

V. Snieckus, T. Rantanen, A. Kennedy, 2011 .

Structurally Stimulated Deprotonation/Alumination of the TMP Anion**

A. Kennedy, R. Mulvey, S. Robertson, 2010, Angewandte Chemie.

CRYSTAL STRUCTURE OF A HEAVIER ALKALI METAL DIISOPROPYLAMIDE COMPLEX : A DISCRETE (KN)2 RING DIMER WITH TMEDA CHELATION AND SHORT INTRAMOLECULAR K...H (C) CONTACTS

W. Clegg, R. Mulvey, P. O'Shaughnessy, 1998 .

A remarkable isostructural homologous series of mixed lithium-heavier alkali metal tert-butoxides [(t-BuO)(8)Li4M4] (M = Na, K, Rb or Cs)

D. Armstrong, S. Liddle, W. Clegg, 2000 .

The isolation and crystal structure of [Ph(2-Pyr)NLi]·(HMPA)·[Ph(2-Pyr)NH]; a model monomeric orgenonitrogen–lithium species containing co-ordination of lithium by both an anchimeric pyridyl N-atom and by a potentially reactive amine ligand

W. Clegg, R. Mulvey, R. Snaith, 1984 .

Solvent induced disproportionation of alkyl(amido)magnesium species containing a (2-pyridyl)amido unit: Synthetic, theoretical and NMR spectroscopic studies of bis(amido)magnesium compounds

K. Henderson, A. Dorigo, R. Mulvey, 1996 .

Reactions of chelating alkali metal amides with the Grignard reagent nBuMgCl: crystal structures and solution 1H NMR spectroscopic studies of the expected mono(amido)-product [PhCH2(Me2NCH2CH2)NMgnBu]2 and the unexpected bis(amido)-product {[Ph(2-Pyr)N]2M9 · (THF)2}

W. Clegg, K. Henderson, R. Mulvey, 1992 .

The structural isomers of {[ph(2-pyridyl)NLi]·[OP(NMe2)3]}2: dimeric species with alternative central (LiN)2 and (LiO)2 rings, the latter involving unprecedented neutral bridging oxygen ligands

W. Clegg, R. Mulvey, R. Snaith, 1984 .

Synthesis of zirconocene amides and ketimides and an investigation into their ethylene polymerization activity

K. Henderson, A. Kennedy, R. Mulvey, 2002 .

Synthesis, Characterization, and Structural Analysis of AM[Al(NONDipp)(H)(SiH2Ph)] (AM = Li, Na, K, Rb, Cs) Compounds, Made Via Oxidative Addition of Phenylsilane to Alkali Metal Aluminyls

J. R. Fulton, G. Ballmann, A. Kennedy, 2022, Inorganic chemistry.

A. Kennedy, R. Mulvey, Michael T. Whitelaw, 2020 .

A novel heterometallic alkoxide: lithium–potassium tert-butoxide [(ButO)8Li4K4]

S. Liddle, W. Clegg, A. Robertson, 1999 .

Lithiated amidines: syntheses and structural characterisations

J. Howard, P. Raithby, M. Davidson, 1997 .

Synthetic and theoretical MO calculational studies of lithiotriazine intermediates produced during alkyllithium-induced cyclotrimerisation reactions of organic nitriles, and comparison of their structures with that of a methylmagnesiotriazine derivative

D. Armstrong, W. Clegg, K. Henderson, 1995 .

Model structural types for rationalising stoichiometries and coordination numbers in lithium amidomagnesiates: syntheses and X-ray diffraction studies of [{Mg(NR2)2}2], [Li2Mg(NR2)4] and [LiMg(NR2)3·py](R = benzyl, py = pyridine)

W. Clegg, K. Henderson, R. Mulvey, 1994 .

Butyllithium-induced cyclotrimerisation reactions of organic nitriles: solvent dependency, crystal and solution structures of lithio triazine intermediates and an unexpected rearrangement of dihydrotriazino anions

D. Armstrong, W. Clegg, R. Mulvey, 1993 .

An infinite ladder structure of alternating, fused K2N2 rhomboids and KN2 triangles: synthesis and crystallographic characterisation of benzotriazolatopotassium·HMPA (HMPA = hexamethylphosphoric triamide)

P. Andrews, W. Clegg, R. Mulvey, 1993 .

A new type of structure in sodium amide ring chemistry: crystal structure of [PhCH2(Me)NNa(tmeda)]2 showing a buckled, rather than the normal planar, (NNa)2 cyclic ring, with a cisoid, rather than the normal transoid, arrangement of amido-substituents (tmeda = tetramethylethylenediamine)

D. Armstrong, P. Andrews, W. Clegg, 1991 .

Structurally defined reactions of sodium TMP-zincate with nitrile compounds: synthesis of a salt-like sodium sodiumdizincate and other unexpected ion-pair products.

W. Clegg, Eva Hevia, C. T. O'Hara, 2008, Angewandte Chemie.

Main Group Multiple C–H/N–H Bond Activation of a Diamine and Isolation of A Molecular Dilithium Zincate Hydride: Experimental and DFT Evidence for Alkali Metal–Zinc Synergistic Effects

T. Tuttle, A. Kennedy, J. Saßmannshausen, 2011, Journal of the American Chemical Society.

Organometallic Polymers Assembled from Cation–π Interactions: Use of Ferrocene as a Ditopic Linker Within the Homologous Series [{(Me3Si)2NM}2⋅(Cp2Fe)]∞ (M=Na, K, Rb, Cs; Cp=cyclopentadienyl)

B. Noll, K. Henderson, A. Kennedy, 2007 .

Adding a Structural Context to the Deprotometalation and Trans-Metal Trapping Chemistry of Phenyl-Substituted Benzotriazole.

V. Snieckus, J. Parkinson, T. Rantanen, 2015, Chemistry.

Structural Elucidation of tmeda-Solvated Alkali Metal Diphenylamide Complexes

J. Klett, A. Kennedy, C. T. O'Hara, 2009 .

Bond indices, enthalpies and relative stabilities of real and hypothetical closo-BnHc−n clusters (n = 5–12; c = 0, 2 or 4) as revealed by the molecular-orbital bond index method

K. Wade, R. Mulvey, R. Snaith, 1986 .

Cluster bonding and energetics of the borane anions, BnHn2− (n = 5–12): A comparative study using bond length—bond enthal

C. Housecroft, K. Wade, R. Mulvey, 1985 .

Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate.

D. Armstrong, Joaquín García‐Álvarez, R. Harrington, 2008, Chemical communications.

Synthesis and characterisation of a series of alkylmagnesium amide and related oxygen-contaminated "alkoxy" compounds.

S. Weatherstone, A. Kennedy, Eva Hevia, 2005, Dalton transactions.

Crystallographic characterisation of binary alkali metal alkoxide-magnesium bis(alkyl) mixtures: differential binding of Na+ and K+ to a common dinuclear diorganomagnesiate.

S. Weatherstone, W. Clegg, A. Kennedy, 2005, Chemical communications.

Sodium congener of the classical lithium methylchromate dimer: synthetic, X-ray crystallographic, and magnetic studies of Me8Cr2[Na(OEt2)]4.

E. Rentschler, W. Clegg, Luca M. Carrella, 2011, Inorganic chemistry.

Contrasting the group 6 metal-metal bonding in sodium dichromate(ii) and sodium dimolybdate(ii) polymethyl complexes: synthetic, X-ray crystallographic and theoretical studies.

S. Sproules, A. Kennedy, R. McLellan, 2017, Dalton transactions.

Synergic monodeprotonation of bis(benzene)chromium by using mixed alkali metal-magnesium amide bases and structural characterization of the heterotrimetallic products.

D. Sherrington, A. Kennedy, Eva Hevia, 2004, Angewandte Chemie.

Meldola Medal Lecture. Ring-stacking and ring-laddering in organonitrogenlithium compounds: the development of concepts with wide applicability throughout lithium structural chemistry

R. Mulvey, 1991 .

Crystal structures of (Ph2CNLi·NC5H5)4 and [CILi·OP(NMe2)3]4; discrete tetrameric pseudo-cubane clusters with bridging of Li3 triangles by nitrogen and by chlorine atoms

W. Clegg, R. Mulvey, R. Snaith, 1984 .

LiTMP Trans‐Metal‐Trapping of Fluorinated Aromatic Molecules: A Comparative Study of Aluminum and Gallium Carbanion Traps

A. Kennedy, Eva Hevia, M. Uzelac, 2017, Angewandte Chemie.

A structural and computational study of synthetically important alkali-metal/tetramethylpiperidide (TMP) amine solvates.

D. Armstrong, A. Kennedy, David V. Graham, 2008, Chemistry.

Concealed cyclotrimeric polymorph of lithium 2,2,6,6-tetramethylpiperidide unconcealed: X-ray crystallographic and NMR spectroscopic studies.

A. Kennedy, Eva Hevia, Donna L. Ramsay, 2013, Chemistry.

Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire.

A. Kennedy, Eva Hevia, T. Cadenbach, 2012, Dalton transactions.

Meta-metallation of N,N-dimethylaniline: Contrasting direct sodium-mediated zincation with indirect sodiation-dialkylzinc co-complexation

D. Armstrong, A. Kennedy, Eva Hevia, 2011, Beilstein journal of organic chemistry.

A unique lithium halide complex, [(LiBr)2·3HMPA·toluene]: synthesis from reaction of solid NH4Br with BunLi in HMPA (hexamethylphosphoramide)/toluene media, crystal structure showing two Li–Br units linked by three µ2-HMPA ligands, and detection of 7Li ⋯31P coupling in solutions of the complex

D. Wright, P. Raithby, D. Reed, 1989 .

Reactions of ammonium salts with butyllithium and with lithium hydride: new routes to fully anhydrous inorganic lithium complexes

D. Wright, K. Wade, R. Mulvey, 1987 .

Synthesis, Structural Authentication, and Structurally Defined Metalation Reactions of Lithium and Sodium DA-Zincate Bases (DA = diisopropylamide) with Phenylacetylene†

Joaquín García‐Álvarez, R. Harrington, W. Clegg, 2008 .

Structures of the potassium aluminates [{K-2(Me(3)AlOBu(t))(2)center dot pmdeta}(infinity)] and [{K(pmdeta)(2)}(+)(AlMe(4))(-)]: how the nature of the alane reagent determines which of these products form from alkoxide-containing reaction mixtures

A. Kennedy, R. Mulvey, M. Spicer, 1996 .

Modern Developments in Magnesium Reagent Chemistry for Synthesis

R. Mulvey, S. Robertson, 2013 .

Synthesis and characterisation of new bimetallic alkali metal-magnesium mixed diisopropylamide-acetylides: structural variations in bimetallic lithium- and sodium-heteroleptic magnesiates.

Joaquín García‐Álvarez, A. Kennedy, Eva Hevia, 2008, Dalton transactions.

Magnesium aryloxides: synthesis, structure, solution behavior and magnesiate ion formation

D. Sherrington, J. Parkinson, K. Henderson, 2003 .

Diisopropylamide and TMP turbo-Grignard reagents: a structural rationale for their contrasting reactivities.

D. Armstrong, J. Parkinson, A. Kennedy, 2010, Angewandte Chemie.

Structural chemistry of monodentate donor-solvated mixed lithium–magnesium secondary amide complexes

A. Kennedy, R. Mulvey, Glenn C. Forbes, 2001 .

Butyllithium cubane tetramers linked by Li-TMEDA-Li bridges in an infinite, zig-zag chain arrangement: first crystallographic study of a simple butyl compound of an early main group element

W. Clegg, R. Mulvey, P. A. O'neil, 1993 .

Synthetic and structural insights into the zincation of toluene: direct synergic ring metallation versus indirect nonsynergic lateral metallation.

D. Armstrong, Joaquín García‐Álvarez, A. Kennedy, 2009, Chemistry.

Organozinc pivalate reagents: segregation, solubility, stabilization, and structural insights.

P. Knochel, K. Koszinowski, A. Kennedy, 2014, Angewandte Chemie.

Accessible heavier s-block dihydropyridines: structural elucidation and reactivity of isolable molecular hydride sources.

A. Kennedy, J. Liggat, R. McLellan, 2016, Dalton transactions.

Mixed Lithium Complexes: Structure and Applicationin Synthesis

C. T. O'Hara, R. Mulvey, 2014 .

Developing a Hetero-Alkali-Metal Chemistry of 2,2,6,6-Tetramethyl-piperidide (TMP): Stoichiometric and Structural Diversity within a Series of Lithium/Sodium, Lithium/Potassium and Sodium/Potassium TMP Compounds

D. Armstrong, A. Kennedy, R. Mulvey, 2011, Chemistry.

Exploiting σ/π coordination isomerism to prepare homologous organoalkali metal (Li, Na, K) monomers with identical ligand sets.

M. Davidson, A. Kennedy, Daniel García-Vivó, 2011, Chemistry.

A triclinic polymorph of octa-tert-butoxy-tetralithiumtetrasodium

S. Liddle, W. Clegg, R. Mulvey, 2003 .

Alkali metal–1-azaallyl complexes: X-ray crystallographic, NMR spectroscopic and ab initio calculational studies

D. Armstrong, S. Liddle, W. Clegg, 1998 .

Lithium Dihydropyridine Dehydrogenation Catalysis: A Group 1 Approach to the Cyclization of Diamine Boranes

A. Kennedy, R. McLellan, R. Mulvey, 2016, Angewandte Chemie.

Alkali‐Metal Mediation: Diversity of Applications in Main‐Group Organometallic Chemistry

R. Mulvey, T. X. Gentner, 2020, Angewandte Chemie.

Di‐tert‐butylzinc

J. A. Garden, R. Mulvey, 2014 .

Dis-assembling lithium amide ladder structures: structural elucidation of the lithium anilide solvate [{PhN(H)Li}6·8THF], a model intermediate En route to forming tetra-solvated ring dimers

W. Clegg, Fiona M. Mackenzie, R. Mulvey, 1995 .

Synthesis and structural characterisation of the mixed lithium–magnesium amide, [{PhCH2(Me2NCH2CH2)N}4Li2Mg]: a new type of magnesiate complex free of a donor solvent as ligand

W. Clegg, K. Henderson, R. Mulvey, 1993 .

After-effects of lithium-mediated alumination of 3-iodoanisole: isolation of molecular salt elimination and trapped-benzyne products.

A. Kennedy, R. Mulvey, S. Robertson, 2012, Dalton transactions.

Structurally powered synergic 2,2,6,6-tetramethylpiperidine bimetallics: new reflections through lithium-mediated ortho aluminations.

D. Armstrong, A. Kennedy, R. Mulvey, 2011, Inorganic chemistry.

Structural insights into mono-amido tris-alkyl potassium aluminates

J. Klett, A. Kennedy, P. García‐Álvarez, 2010 .

Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines.

M. Mcpartlin, D. Wright, R. Less, 2010, Chemical communications.

Lewis base stabilized lithium TMP-aluminates: an unexpected fragmentation and capture reaction involving cyclic ether 1,4-dioxane.

J. Klett, Joaquín García‐Álvarez, A. Kennedy, 2007, Chemical communications.

New reactivity and structural insights of alkali-metal-mediated alumination in directed ortho-alumination of a tertiary aromatic amide.

S. Weatherstone, Joaquín García‐Álvarez, A. Kennedy, 2006, Chemical communications.

Synthetic and structural developments in hetero-s-block-metal chemistry: new ring-laddering, ring-stacking and other architectures

R. Mulvey, 2010 .

Lithium‐Aluminate‐Catalyzed Hydrophosphination Applications

T. Tuttle, A. Kennedy, R. McLellan, 2019, Angewandte Chemie.

Solid-state and dynamic solution equilibria of bis(dibenzylamido) magnesium complexes: aggregation dependence on stoichiometry and denticity of donor solvent

W. Clegg, K. Henderson, A. Kennedy, 1997 .

Synthesis and solid-state structures of three magnesium diamide complexes derived from RN(H)CH2CH2N(H)R diamine precursors (R = Ph or PHCH2)

V. Wilson, W. Clegg, R. Mulvey, 1998 .

Synthesis and X-ray crystallographic characterisation of o-phenylenediamidomagnesium·tetrahydrofuran: the first octahedral Mg6 cluster

W. Clegg, M. Frank, R. Mulvey, 1994 .

Synthesis of heteroleptic bis(amides) : crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]

W. Clegg, K. Henderson, R. Mulvey, 1993 .

Isostructural potassium and sodium di-nitrogen functionalized amides: Syntheses and crystal structures of [Ph(2-Pyr)NK·TMEDA]2 and [Me(2-Pyr)NNa·TMEDA]2

D. Baker, P. Andrews, W. Clegg, 1991 .

Lewis‐Base‐Dictated Structural Variations in Sodium Amide Chemistry: X‐Ray Crystal Structures of Phenyl(2‐pyridyl)amidosodium with Hexamethylphosphoric Triamide (HMPA) and with Pentamethyldiethylenetriamine (PMDETA)

P. Andrews, W. Clegg, R. Mulvey, 1990 .

Crystal structure of lithium diisopropylamide (LDA): an infinite helical arrangement composed of near-linear nitrogen-lithium-nitrogen units with four units per turn of helix

W. Clegg, R. Mulvey, P. A. O'neil, 1991 .

Regioselective heterohalogenation of 4-halo-anisoles via a series of sequential ortho-aluminations and electrophilic halogenations.

A. Kennedy, R. Mulvey, S. Robertson, 2012, Chemical communications.

Isolation and structural elucidation of a key aluminoaromatic intermediate and evidence for dismutation phenomena in TMP-alumination chemistry.

Joaquín García‐Álvarez, A. Kennedy, Eva Hevia, 2007, Chemical communications.

SYNTHESIS, CHARACTERISATION AND A THEORETICAL INVESTIGATION OF THE FORMATION OF LITHIUM DIALKYLALUMINIUM AMIDES

S. Liddle, W. Clegg, K. Henderson, 1999 .

Donor-activated alkali metal dipyridylamides: co-complexation reactions with zinc alkyls and reactivity studies with benzophenone.

Etienne V. Brouillet, D. Armstrong, A. Kennedy, 2014, Dalton transactions.

Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)·Na(μ-TMP)(μ-tBu)Zn(tBu)] towards TEMPO and chalcone.

D. Armstrong, J. Klett, J. Crawford, 2012, Chemical communications.

Synthesis, Structure and Theoretical Studies of the Hydrido Inverse Crown [K2Mg2(NiPr2)4(μ-H)2·(toluene)2]: a Rare Example of a Molecular Magnesium Hydride with a Mg-(μ-H)2-Mg Double Bridge

D. Armstrong, P. Andrikopoulos, A. Kennedy, 2003 .

Lithium and aluminium carbamato derivatives of the utility amide 2,2,6,6-tetramethylpiperidide.

A. Kennedy, R. Mulvey, S. Robertson, 2010, Dalton transactions.

Modifying Alkylzinc Reactivity with 2,2′-Dipyridylamide: Activation of tBu=Zn Bonds for para-Alkylation of Benzophenone**

D. Armstrong, A. Kennedy, J. A. Garden, 2013, Angewandte Chemie.

catena-Poly[sodium-μ2-(N,N,N′,N′-tetramethylethane-1,2-diamine)-κ2 N:N′-sodium-bis[μ2-bis(trimethylsilyl)azanido-κ2 N:N]]

A. Kennedy, C. T. O'Hara, R. Mulvey, 2012, Acta crystallographica. Section E, Structure reports online.

Molecular structures of THF-solvated alkali-metal 2,2,6,6-tetramethylpiperidides finally revealed: X-ray crystallographic, DFT, and NMR (including DOSY) spectroscopic studies.

D. Armstrong, A. Kennedy, P. García‐Álvarez, 2011, Chemistry.

Synthesis and structural characterisation of mixed alkalimetal-magnesium mixed ligand alkyl-amido ate complexes

D. Armstrong, P. Andrikopoulos, S. Weatherstone, 2007 .

Trapping, stabilization, and characterization of an enolate anion of a 1,6-adduct of benzophenone chelated by a sodium alkylamidozincate cation.

A. Kennedy, Eva Hevia, R. Mulvey, 2005, Journal of the American Chemical Society.

Sodium dialkyl-amidozincates: alkyl or amido bases? An experimental and theoretical case study.

D. Armstrong, P. Andrikopoulos, W. Clegg, 2005, Journal of the American Chemical Society.

Synthesis and structural characterisation of 'solvent-free' lithium-calcium hexamethyldisilazide, [Li{mu-N(SiMe3)(2)}(2)Ca{N(SiMe3)(2)}], exhibiting a double ration of agostic H3C center dot center dot center dot Li and H3C center dot center dot center dot Ca intramolecular interactions

A. Kennedy, R. Mulvey, R. Rowlings, 2002 .

Inverse crown ether complexes extended to group 12 through the syntheses of [Na2Zn2(HMDS)(4)(O)] and [{K2Zn2(HMDS)(4)(O-2)(x)(O)(y)}(infinity)]

Chick C. Wilson, S. Liddle, W. Clegg, 2000 .

Revealing the remarkable structural diversity of the alkali metal transfer agents of the trans-calix[2]benzene[2]pyrrolide ligand.

A. Martı́nez-Martı́nez, A. Kennedy, R. Mulvey, 2016, Chemical communications.

Zirconocene ketimides: Synthesis, structural characterization, ethylene polymerization activity, and ab initio computational studies

D. Armstrong, K. Henderson, A. Kennedy, 2000 .

Hydride encapsulation in s-block metal inverse crown chemistry.

K. Henderson, A. Kennedy, C. T. O'Hara, 2002, Chemical communications.

Selective crystallization of di-sec-butylmagnesium. N,N,N',N'-tetramethylethylenediamine from solutions containing mixtures of normal-butyl and secondary-butyl isomers

W. Clegg, D. Reed, R. Mulvey, 1996 .

Hexameric Mg-O stacks with six THF-solvated sodium amide appendages: "super" variants of inverse crown ethers generated by cleavage of THF.

L. Gibson, A. Kennedy, C. T. O'Hara, 2002, Angewandte Chemie.

Heterobimetallic metallation studies of N,N-dimethylphenylethylamine (DMPEA): benzylic C-H bond cleavage/dimethylamino capture or intact DMPEA complex.

A. Kennedy, Donna L. Ramsay, R. Mulvey, 2015, Dalton transactions.

Solvation Effects on the Structure and Stability of Alkali Metal Carbenoids

V. Gessner, R. Mulvey, Kai‐Stephan Feichtner, 2020, Angewandte Chemie.

Alkali-Metal-Mediated Manganation(II) of Functionalized Arenes and Applications of ortho-Manganated Products in Pd-Catalyzed Cross-Coupling Reactions with Iodobenzene

J. Klett, V. Blair, W. Clegg, 2007, Chemistry.

Adding rubidium and cesium to the homologous series of alkali metal compounds of (Trimethylsilyl)methanides and 2,2,6,6-Tetramethylpiperidides

J. Klett, W. Clegg, A. Kennedy, 2012 .

A homologous series of regioselectively tetradeprotonated group 8 metallocenes: new inverse crown ring compounds synthesized via a mixed sodium-magnesium tris(diisopropylamide) synergic base.

Duncan M. Tooke, D. Armstrong, P. Andrikopoulos, 2004, Journal of the American Chemical Society.

Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: structural characterization of potassium, calcium, and mixed potassium-calcium enolates.

A. Beatty, B. Noll, K. Henderson, 2004, Journal of the American Chemical Society.

Solvent-free and TMEDA-solvated mixed alkali metal-magnesium tris-diisopropylamides

A. Kennedy, Eva Hevia, R. Mulvey, 2003 .

Synthesis of the mixed lithium-potassium-(bis)magnesium N-metallated/N, C-dimetallated amide [Li2K2Mg4[But(Me3Si)N]4[But[Me2(H2C)Si]N]4]: an inverse crown molecule with an atomless cavity.

J. Parkinson, A. Kennedy, C. T. O'Hara, 2003, Chemical communications.

Potassium-zinc induced synergic enhancement of the basicity of hexamethyldisilazide (HMDS) towards methylbenzene molecules.

S. Liddle, W. Clegg, A. Kennedy, 2003, Chemical communications.

New homo- and hetero-alkali metal alkoxide cages; crystal structures of [Me2N(CH2)2OLi]8 and [{Me2N(CH2)2O}12Li8K6]O

P. Andrews, Jonathan G Maclellan, Peter J. Nichols, 2002 .

Regioselective Tetrametalation of Ferrocene in a Single Reaction: Extension of s-Block Inverse Crown Chemistry to the d-Block.

Duncan M. Tooke, W. Clegg, K. Henderson, 2001, Angewandte Chemie.

Landmark Crystal Structure of an Experimentally Utilized Tetralithium-Tetrapotassium Amide-Alkoxide Superbase.

Jonathan G Maclellan, A. Kennedy, R. Mulvey, 2001, Angewandte Chemie.

An Unprecedented Hexapotassium-Hexamagnesium 24-Membered Macrocyclic Amide: A Polymetallic Cationic Host to Six Monodeprotonated Arene Anions

C. Raston, P. Andrews, B. A. Roberts, 2000 .

Pentanuclear asymmetrical ladder structure of the 1,4-dimethylpiperazine solvate of lithium anilide and its implication for the unknown structure of amorphous lithium anilide

S. Liddle, W. Clegg, A. Robertson, 2000 .

A new approach to lithium–heavier alkali metal interchange reactions: synthesis of a tetralithium pentasodium mixed alkoxide–amide dome-shaped cage compound with an encapsulated hydroxide molecule

Jonathan G Maclellan, A. Kennedy, A. Robertson, 2000 .

The changing structural chemistry of lithium anilide on solvation by pyridine, 4-methylpyridine or 4-tert-butylpyridine

S. Liddle, W. Clegg, Fiona M. Mackenzie, 2000 .

Mixed-metal sodium-magnesium macrocyclic amide chemistry: A template reaction for the site selective dideprotonation of arene molecules

D. Armstrong, A. Kennedy, R. Mulvey, 1999 .

NEW ALKALI METAL PRIMARY AMIDE LADDER STRUCTURES DERIVED FROM TBUNH2 : BUILDING CISOID AND TRANSOID RING CONFORMATIONS INTO LADDER FRAMEWORKS

W. Clegg, K. Henderson, Fiona M. Mackenzie, 1998 .

Regioselective solvation in a polymeric lithium amide: remarkable twisted ladder structure of [{[PhCH2N(H)Li]2·H2NCH2Ph}∞]

A. Kennedy, A. Robertson, R. Mulvey, 1998 .

The first trimetallic lithium-sodium-potassium complex : Synthesis and crystal structure of a twelve-vertex Li2Na2K2N4O2 cage molecule containing an amide-alkoxide combination

W. Clegg, Fiona M. Mackenzie, R. Mulvey, 1996 .

Novel octameric structure of the lithium primary amide [{Bu(t)N(H)Li}(8)] and its implication for the directed synthesis of heterometallic imide cages

P. Williard, W. Clegg, D. Lindsay, 1996 .

Lithium anilide complexed by pmdeta: expectation of a simple monomer, but in reality an odd trinuclear composition combining three-, four- and five-coordinate lithium

W. Clegg, Fiona M. Mackenzie, R. Mulvey, 1995 .

Expanding the Scope of Lithium Coordination Chemistry by Placing Sodium Nearby: A Mixed Lithium-Sodium Benzyl Compound Having TMEDA-Chelated Li+ Cations in an Unprecedented Tetrameric Environment

D. Baker, W. Clegg, R. Mulvey, 1994 .

Ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes, [cyclic] {[H2C(CH2)3NLi]3.cntdot.PMDETA}2 and [cyclic] {[H2C(CH2)3NLi]2.cntdot.TMEDA}2, and ab initio MO calculations probing ring vs ladder vs stack struct

D. Wright, D. Armstrong, W. Clegg, 1989 .

Bonding implications of interatomic distances and ligand orientations in the iminolithium hexamers [LiNC(Ph)But]6 and [LiNC(Ph)NMe2]6: a stacked-ring approach to these and related oligomeric organolithium systems

W. Clegg, K. Wade, R. Mulvey, 1986 .

The laddering principle in lithium amide chemistry: the crystal and molecular structure of the pyrrolididolithium adduct [H2C(CH2)3NLi]3·MeN(CH2CH2NMe2)2

D. Armstrong, W. Clegg, K. Wade, 1986 .

Crystal and Solution Structures of [tBu2CNLi·OP(NMe2)3]n

W. Clegg, D. Reed, R. Mulvey, 1985 .

Donor-activated lithiation and sodiation of trifluoromethylbenzene: structural, spectroscopic and theoretical insights

D. Armstrong, W. Clegg, A. Kennedy, 2013 .

Structural Diversity in Alkali Metal and Alkali Metal Magnesiate Chemistry of the Bulky 2,6‐Diisopropyl‐N‐(trimethylsilyl)anilino Ligand

A. Kennedy, R. Mulvey, M. Fuentes, 2016, Chemistry.

Benzyl(trimethylsilyl)amidolithium: structural studies by ab initio mo and X-RAY crystallographic methods, and comparison with the known structures of dibenzyl and bis(trimethylsilyl) analogues

D. Armstrong, D. Baker, W. Clegg, 1996 .

Alkali Metal Effects in Trans-Metal-Trapping (TMT): Comparing LiTMP with NaTMP in Cooperative MTMP/Ga(CH2SiMe3)3 Metalation Reactions

D. Armstrong, A. Kennedy, Eva Hevia, 2019, Synthesis.

A hetero-alkali-metal version of the utility amide LDA: lithium-potassium diisopropylamide.

D. Armstrong, A. Kennedy, R. Mulvey, 2013, Dalton transactions.

FascinATES: Mixed-Metal Ate Compounds That Function Synergistically

R. Mulvey, S. Robertson, 2013 .

Structural elaboration of the surprising ortho-zincation of benzyl methyl ether.

J. Klett, A. Kennedy, C. T. O'Hara, 2010, Chemical communications.

Structural and magnetic insights into the trinuclear ferrocenophane and unexpected hydrido inverse crown products of alkali-metal-mediated manganation(II) of ferrocene.

J. Klett, V. Blair, E. Rentschler, 2009, Chemistry.

Trans-Metal-Trapping: Concealed Crossover Complexes En Route to Transmetallation?

M. Uzelac, R. Mulvey, 2018, Chemistry.

Tetraamine Me6TREN induced monomerization of alkali metal borohydrides and aluminohydrides

A. Kennedy, R. McLellan, R. Mulvey, 2016 .

Dehydromethylation of alkali metal salts of the utility amide 2,2,6,6-tetramethylpiperidide (TMP).

A. Martı́nez-Martı́nez, A. Steven, A. Kennedy, 2014, Chemical communications.

Synthesis of an alkylmagnesium amide and interception of a ring-opened isomer of the important utility amide 2,2,6,6-tetramethylpiperidide (TMP)

J. Klett, A. Kennedy, C. T. O'Hara, 2014 .

Contrasting reactivity of mono- versus Bis-2,2,6,6-tetramethylpiperidide lithium aluminates towards polydentate lewis bases: co-complexation versus deprotonation

A. Kennedy, R. Mulvey, S. Robertson, 2013 .

Structurally engineered deprotonation/alumination of THF and THTP with retention of their cycloanionic structures.

J. Klett, A. Kennedy, P. García‐Álvarez, 2010, Angewandte Chemie.

Alkali-metal-mediated manganation: a method for directly attaching manganese(II) centers to aromatic frameworks.

J. Klett, Joaquín García‐Álvarez, A. Kennedy, 2007, Angewandte Chemie.

Dizincation of a 2-substituted thiophene: constructing a cage with a [16]crown-4 zincocyclic core.

V. Snieckus, T. Rantanen, A. Kennedy, 2012, Angewandte Chemie.

1‐Alkali‐metal‐2‐alkyl‐1,2‐dihydropyridines: Soluble Hydride Surrogates for Catalytic Dehydrogenative Coupling and Hydroboration Applications

A. Kennedy, R. McLellan, R. Mulvey, 2017, Chemistry.

Stoichiometric dependence of the long-established reaction of butyllithium with pyridine : A hidden secondary reaction that produces a pyridine adduct of a lithiodihydropyridine

W. Clegg, R. Mulvey, Lynne Horsburgh, 1996 .

Crystal structure of sodium iodide•(diglyme): an unprecedented bridging role for diglyme

W. Clegg, R. Mulvey, R. Snaith, 1986 .

Dichlorobis(dibenzylamino)bis(tetrahydrofuran)zirconium(IV) toluene hemisolvate.

K. Henderson, A. Kennedy, R. Mulvey, 2001, Acta crystallographica. Section C, Crystal structure communications.

Synthesis and crystal structure of the mixed lithium sodium guanidide [Li4Na2{NC(NMe2)2}6]: A stack of three (metal-nitrogen)2 dimeric rings with additional intramolecular (tertiary amine) nitrogen-lithium coordinations

W. Clegg, R. Mulvey, P. A. O'neil, 1992 .

Trimeric dibenzylamidolithium and its dimeric diethyl ether and hexamethylphosphoramide complexes: structural and theoretical studies of reactive organonitrogen–lithium oligomers

W. Clegg, R. Mulvey, R. Snaith, 1984 .

Synthesis and structure of the novel octalithium-dipotassium mixed oxide-alkoxide cage complex [Li8K2(O)(ButO)8·2TMEDA]

W. Clegg, Fiona M. Mackenzie, R. Mulvey, 1998 .

A new architecture in lithium amide chemistry : Synthesis of [{(c-C5H9)N(H)}(12)(O)Li-14], a cage molecule containing a salt-like, distorted, face-centred cube of lithium cations

W. Clegg, P. Dennison, Fiona M. Mackenzie, 1996 .

Synthetic, structural, mechanistic, and theoretical MO studies of the alkali-metal chemistry of dibenzylamine and its transformation to 1,3-diphenyl-2-azaallyl derivatives

D. Armstrong, D. Baker, P. Andrews, 1995 .

Unexpected structure of 1,3-diphenyl-2-azaallylpotassium–N,N,N′,N″ ,N″-pentamethyldiethylenetriamine: infinite, zigzag chains of alternating cations and two distinct types of anion, one azaallyl bonded, the other allyl bonded

D. Armstrong, P. Andrews, W. Clegg, 1997 .

Exploiting a substituted dihydrotriazinide as a novel bulky ligand: synthesis and crystal structure of a rubidium complex with an unprecedented tetrameric cyclic core

W. Clegg, R. Mulvey, P. O'Shaughnessy, 1997 .

Synergic Transformation of an Ethylenediamine to a Lithium 1,3-Diaza-2-zincacyclopentene via an Alkyllithium/Bis(alkyl)zinc Mixture

A. Kennedy, P. García‐Álvarez, R. Mulvey, 2010, Chemistry.

Crystal Structure of a Representative Mixed Adduct of Trimethylaluminium and a Lithium Amide and a Theoretical MO Study on Model Systems

D. Armstrong, A. Kennedy, R. Mulvey, 1996 .

Synthesis and structure of the Li13 cage [[[O-P(mu-NtBu)]2Li2]3(LiCl)6Li(Cl/OnBu)0.5(thf)7], containing a [O-P(mu-NtBu)]2(2-) dianion.

M. Mcpartlin, D. Wright, S. Singh, 2008, Chemical communications.

Rubidium and caesium aluminyls: synthesis, structures and reactivity in C-H bond activation of benzene.

Samuel E. Neale, Claire L. McMullin, A. Kennedy, 2022, Chemical communications.

Structural variations within group 1 (Li-Cs)+ (2,2,6,6-tetramethyl-1-piperidinyloxy)- complexes made via metallic reduction of the nitroxyl radical.

J. Klett, A. Kennedy, David V. Graham, 2009, Inorganic chemistry.

Mixed Lithium Magnesium Aryl Oxides Derived from Cresol: Crystal Structures and Solution NMR Studies of an Unexpected, Magnesium-Rich Oxo Product with a Trigonal Bipyramidal LiMg4 Cage and an Expected Lithium-Rich Product with a More Familiar Li.cntdot..cntdot..cntdot.Mg.cntdot..cntdot..cntdot.Li Ch

W. Clegg, K. Henderson, Friedrich B M Reinhard, 1994 .

Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal-magnesium-alkoxide-diisopropylamides.

Katy J. Drewette, K. Henderson, A. Kennedy, 2002, Chemical communications.

Intermetallic Lithium−Magnesium Hexamethyldisilazide: Synthesis and Structure, Discovery of an Oxygen-Centered Variant, and a Reaction with Benzonitrile That Produces a Novel Amidinate Cage Compound with a Trigonal Bipyramidal Li4MgO Core

A. Kennedy, R. Mulvey, R. Rowlings, 1998 .

Three model structural types in lithium amide chemistry: the crystal and molecular structures of dimeric [Ph(Me)NLi·TMEDA]2(TMEDA = Me2NCH2CH2NMe2) and monomeric Ph(naphthyl)NLi·PMDETA [PMDETA = MeN(CH2CH2NMe2)2], and of [Ph(naphthyl)NLi·TMEDA]2, a ‘loose dimer’

D. Wright, W. Clegg, R. Mulvey, 1987 .

Characterization of the bis(pyridine) complex of the butyllithium-pyridine adduct, 2-Bun(C5H5N)Li·(C5H5N)2; its decomposition to 2-butylpyridine via a dihydropyridine

D. Reed, R. Mulvey, R. Snaith, 1988 .

Facile synthesis of a genuinely alkane-soluble but isolable lithium hydride transfer reagent.

A. Kennedy, J. Liggat, R. Mulvey, 2015, Chemical communications.

Synergic Sedation of Sensitive Anions: Alkali-Mediated Zincation of Cyclic Ethers and Ethene

D. Wright, J. Klett, A. Kennedy, 2009, Science.

Lithiations of mercaptoamines containing NC(S)NH–,–NHC(S)S– and –NHC(S)NH– units: syntheses, crystal structures and model molecular-orbital calculations

D. Wright, D. Armstrong, P. Raithby, 1991 .

Selective mono- and dimetallation of a group 3 sandwich complex.

Rian D. Dewhurst, F. Fantuzzi, A. Martı́nez-Martı́nez, 2019, Chemical communications.

cis-2,6-Dimethylpiperidide: a structural mimic for TMP (2,2,6,6-tetramethylpiperidide) or DA (diisopropylamide)?

J. Klett, A. Kennedy, P. García‐Álvarez, 2010, Dalton Transactions.

Structural complexity of the magnesiation of furan: an octadecanuclear product with a subporphyrin-like Mg3(2,5-fur-di-yl)3 substructure.

J. Klett, V. Blair, A. Kennedy, 2008, Chemical Communications.

Synergic para-directed-monometalation ofcby using alkali-metal-mediated magnesiation

D. Armstrong, A. Kennedy, Eva Hevia, 2006 .

Alkali-metal-mediated zincation of ferrocene: synthesis, structure, and reactivity of a lithium tmp/zincate reagent.

W. Clegg, A. Kennedy, Eva Hevia, 2005, Angewandte Chemie.

Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions.

D. Armstrong, P. Andrikopoulos, A. Kennedy, 2005, Chemical communications.

catena-Poly[[bis(mu-2,6-dimethylpiperidin-ido-N:N)dilithium]-mu-(N,N,N ',N '-tetra- methylethylenediamine-N : N'')]

W. Clegg, S. Couper, R. Mulvey, 1999 .

Lithium amides as initiators of anionic polymerisation of methyl methacrylate

D. Sherrington, S. Couper, R. Mulvey, 1998 .

Building an extended inverse crown motif via alkali-metal-mediated alpha-magnesiation of furan.

A. Kennedy, Eva Hevia, Christine Talmard, 2006, Chemical communications.

The ring-stacking principle in organolithium chemistry: its development through the isolation and crystal structures of hexameric iminolithium clusters (RR'C=NLi)6 (R'=Ph, R=But or Me2N; R=R'=Me2N or But)

D. Armstrong, W. Clegg, K. Wade, 1987 .

Diverse outcomes of CO2 fixation using alkali metal amides including formation of a heterobimetallic lithium-sodium carbamato-anhydride via lithium-sodium bis-hexamethyldisilazide.

Richard M. Gauld, A. Kennedy, J. Reid, 2019, Chemical communications.

The Ring-Stacking Principle in Organolithium Chemistry: Its Development Through the Isolation and Crystal Structures of Hexameric Iminolithium Clusters (RR′C=NLi)6 (R′: Ph, R: tBu or Me2N; R = R′: Me2N or tBu).

D. Armstrong, W. Clegg, K. Wade, 1987 .

Structural Characterization of the 1-Metallo-2-t-Butyl-1,2-Dihydropyridyl Rubidium and Caesium Complexes

Peter A. Macdonald, A. Kennedy, Sumanta Banerjee, 2023, Polyhedron.

Heavy Alkali Metal Manganate Complexes: Synthesis, Structures and Solvent‐Induced Dissociation Effects

G. Ballmann, A. Kennedy, Eva Hevia, 2022, Chemistry.

Alkali Metal (Li, Na, K, Rb, Cs) Mediation in Magnesium Hexamethyldisilazide [Mg(HMDS)2] Catalysed Transfer Hydrogenation of Alkenes

A. Kennedy, Eva Hevia, R. Mulvey, 2021, ChemCatChem.

Structural variations in bimetallic sodium-magnesium and sodium-zinc ketimides, and a sodium-zinc alkide-alkoxide-amide: connections to ring-stacking, ring-laddering, and inverse crown concepts.

R. Harrington, W. Clegg, A. Kennedy, 2007, Chemical communications.

''Potassium potassates'' based on dihydrotriazinide ligands: syntheses, crystal structures, and comparison with other alkali metal dihydrotriazinide compounds

W. Clegg, M. Elsegood, R. Mulvey, 1997 .

POTASSIUM POTASSIATE CONTACT ION PAIR POLYMER SYNTHESISED BY METALLATION OF A DIHYDROTRIAZINE

W. Clegg, R. Mulvey, Lynne Horsburgh, 1994 .

Remarkable Reaction of Hetero-S-Block-Metal Amides with Molecular Oxygen: Cationic (NMNMg)2 Ring Products (M=Li or Na) with Anionic Oxo or Peroxo Cores.

A. Kennedy, R. Mulvey, R. Rowlings, 1998, Angewandte Chemie.

A new Na/Mg inverse crown ether.

Jonathan G Maclellan, A. Kennedy, R. Mulvey, 2003, Acta crystallographica. Section C, Crystal structure communications.

Synthesis and crystal structure of the new heteroleptic magnesium bis(amide) [{Mg[mu-N(H)Ph][N(SiMe3)(2)]center dot THF}(2)], and density functional MO calculations on model systems

D. Armstrong, W. Clegg, R. Mulvey, 2001 .

Structural elucidation of homometallic anthracenolates synthesised via deprotonative metallation of anthrone.

J. Klett, W. Clegg, A. Kennedy, 2013, Dalton transactions.

Synthesis and Crystal Structure of [{nBuMg(μ‐TMP)}2] and of a Homometallic Inverse Crown in Tetranuclear [{nBuMg2[μ‐N(H)Dipp]2(μ3‐OnBu)}2]

S. Weatherstone, A. Kennedy, Eva Hevia, 2004 .

Crystallographic Characterisation of Organolithium and Organomagnesium Intermediates in Reactions of Aldehydes and Ketones

A. Kennedy, J. Reid, Jim Barker, 2022, Helvetica Chimica Acta.

Modern Developments in Magnesium Reagent Chemistry for Synthesis

R. Mulvey, S. Robertson, 2013 .

Mixed Lithium Amide–Lithium Halide Compounds: Unusual Halide-Deficient Amido Metal Anionic Crowns**

A. Kennedy, C. T. O'Hara, R. Mulvey, 2011, Angewandte Chemie.

Structure and bonding of the lithium tetrahydroborate–tetramethylethylenediamine adduct (TMEDA·LiBH4)2, a centrosymmetric dimer containing doubly and triply bridging hydrogen atoms

D. Armstrong, J. Daniels, W. Clegg, 1987 .

Isomerization Reactions in Anionic Mesoionic Carbene‐Borates and Control of Properties and Reactivities in the Resulting CoII Complexes through Agostic Interactions

Nicolás I. Neuman, B. Sarkar, J. Stubbe, 2020, Angewandte Chemie.

Synergic synthesis of benzannulated zincabicyclic complexes, alpha-zincated N ylides, through sodium-TMEDA-mediated zincation of a haloarene.

D. Armstrong, W. Clegg, A. Kennedy, 2009, Angewandte Chemie.

Synthesis, structure and methyl methacrylate polymerisation activity of a mixed pi-ferrocene pi-toluene complex of potassium tris(hexamethyldisilazide)magnesiate

D. Sherrington, A. Kennedy, R. Mulvey, 2004 .

When Electrons Step in: Polarizing Effects Explored with Triisobutylaluminum.

D. Stalke, R. Herbst‐Irmer, C. Strohmann, 2021, Inorganic chemistry.

A μ4-oxide-containing a dimeric variant of a sodium dialkyl(amido)zincate reagent.

A. Kennedy, R. Mulvey, S. Robertson, 2011, Acta crystallographica. Section C, Crystal structure communications.

Crossing organolithium compounds with organolithium compounds: molecular squares and a cage-encapsulating reaction.

J. Klett, A. Kennedy, R. Mulvey, 2011, Angewandte Chemie.

Lithium, sodium and potassium picolyl complexes: syntheses, structures and bonding.

A. Kennedy, R. Mulvey, Robert I Urquhart, 2014, Dalton transactions.

A hetero-alkali-metal version of the utility amide LDA: lithium-potassium diisopropylamide.

D. Armstrong, A. Kennedy, R. Mulvey, 2013, Dalton transactions.

High-field lithium-7 nuclear magnetic resonance spectroscopic and cryoscopic relative molecular mass studies on solutions of amido- and imido-lithium compounds

D. Reed, R. Mulvey, R. Snaith, 1986 .

Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines.

M. Mcpartlin, D. Wright, R. Less, 2010, Chemical communications.

Benzene submits to main-group power

R. Mulvey, 2017, Science.

Exposing elusive cationic magnesium-chloro aggregates in aluminate complexes through donor control.

K. Koszinowski, A. Kennedy, R. McLellan, 2016, Dalton transactions.