H. Klein

发表

The Crystal Structures of Trimethylphosphane supported Nickel- and Cobalt-Methyl Complexes: Octahedral mer-cis-[CoIIII(CH3)2(PMe3)3] and Square Planar trans-[NiIICl(CH3)(PMe3)2]

R. Beck, H. Klein, 2008 .

Methylnickel compounds containing 2-phosphinylethanolato ligands syntheses, properties, and ethene coupling reactions

D. Walther, G. Luft, H. Klein, 2005 .

NICKEL-MEDIATED SYNTHESIS OF DIALKYNYL AND TRIALKYNYL ETHENES : DEMETALLATION REACTIONS

H. Klein, A. Peterman, 1997 .

Studies on partial hydrogenation of 1,5,9-cyclo-dodecatriene towards cyclo-dodecene

J. Gaube, H. Klein, W. David, 2011 .

The promoter effect of alkali in Fischer-Tropsch iron and cobalt catalysts

J. Gaube, H. Klein, 2008 .

Reaction cascade: Ortho-C–H activation and C–C coupling of benzophenone leading to tetranuclear organoiron and mononuclear organocobalt complexes

U. Flörke, R. Beck, H. Klein, 2015 .

Regioselective ortho-Metallation of 2-Diphenylphosphanylpyridine and (2-(2-Diphenylphosphanyl)phenyl)-1-3-dioxalane with Methyltetrakis(trimethylphosphane)cobalt(I)

Xiaoyan Li, Hongjian Sun, R. Beck, 2009 .

C–H activation of diphenylphosphinoaryl-derivatives with dimethyltetrakis(trimethylphosphine)iron(II)

U. Flörke, Xiaoyan Li, Tingting Zheng, 2008 .

Four- and five-membered cobaltacycles by regioselective cyclometallation of benzyl sulfide derivatives via Co(v) intermediates.

R. Beck, H. Klein, M. Frey, 2008, Dalton transactions.

Cyclometalation of Thiobenzophenones with Mononuclear Methyliron and -cobalt Complexes

Xiaoyan Li, Hongjian Sun, R. Beck, 2008 .

ortho‐Metalation of Triarylphosphane at Cobalt and Template Synthesis of Chelating 2‐(Diarylphosphanyl)aroyl Ligands

S. Schneider, H. Haupt, U. Floerke, 2000 .

Kinetics and mechanism of butene isomerization/hydrogenation and of 1,3-butadiene hydrogenation on palladium

J. Gaube, H. Klein, 2014 .

Intramolecular rearrangement of the imine–amide ligand within the nickel coordination sphere affected by carbon monoxide

N. Schlörer, V. Bocharova, H. Klein, 2011 .

Conversion of imine ligands in allyl–nickel(II) complexes

R. Meusinger, I. Svoboda,, M. Pashchanka, 2009 .

C−F Bond Cleavage and Unexpected C−CN Activation by Cobalt Compounds Supported with Phosphine Ligands

U. Flörke, Xiaoyan Li, Feng‐Yang Yu, 2006 .

Reactivity Diversification – Synthesis and Exchange Reactions of Cobalt and Iron 2‐Alkenylpyridine/‐pyrazine Complexes Obtained by Vinylic C(sp2)–H Activation

U. Flörke, R. Beck, H. Klein, 2015 .

Cobalt induced tandem C-H activation/decarbonylation of various aromatic aldehydes and related benzylic alcohols forming mononuclear aryl monocarbonyl complexes.

U. Flörke, R. Beck, H. Klein, 2009, Inorganic chemistry.

First regioselective cyclometalation reactions of cobalt in arylketones: C-H versus C-F activation.

U. Flörke, R. Beck, H. Klein, 2008, Dalton transactions.

Cyclometalation of substrates containing imine and pyridyl anchoring groups by iron and cobalt complexes.

U. Flörke, R. Beck, H. Klein, 2005, Angewandte Chemie.

Five‐ and Six‐Membered Cobaltocycles with C,P‐Chelating Ligands through Regiospecific Cyclometalation of Mono(2‐Substituted) Triphenylphosphane

U. Flörke, H. Haupt, R. Beck, 2003 .

Regiospecific Cyclometalation of Diphenyl(2‐substituted phenyl)phosphane with Methyltetrakis(trimethylphosphane)cobalt(I)

Ulrich Flörke, U. Flörke, H. Haupt, 2003 .

Fluxional and Rigid (Trimethylphosphane)cobalt Complexes Containing Chelating (2‐Diphenylphosphanyl)anilido Ligands

U. Flörke, H. Haupt, R. Beck, 2003 .

Steric Control of Cyclometallation Reactions in Schiff‐Base Complexes of Cobalt(I) Containing an Anchoring Diphenylphosphanyl Group

U. Flörke, H. Haupt, R. Beck, 2002 .

2-DIPHENYLPHOSPHINOBENZALDEHYDE AS CHELATING LIGAND IN TRIMETHYLPHOSPHINE COMPLEXES OF COBALT AND NICKEL

Ute Lemke, H. Klein, Mathias Lemke, 1998 .

Coordination and Reactions of Diazenes in Trimethylphosphinecobalt(I). Complexes - Syntheses and Structures of Complexes Containing μ2-(N,N′)-Benzo[c]cinnoline and η2-Azobenzene Ligands

U. Flörke, H. Haupt, H. Klein, 1993 .

C−H Activation of Imines by Trimethylphosphine-Supported Iron Complexes and Their Reactivities

U. Flörke, R. Beck, H. Klein, 2009 .

Meridional bicyclometalation with iron: a novel way of forming dianionic [C,N,C]-ligands.

U. Flörke, R. Beck, H. Klein, 2005, Chemical communications.

The Dimethylphosphinomethanide Ion, (CH3)2PCH2⊖: A Novel Ligand for Transition Metals

H. Schmidbaur, H. Klein, H. Karsch, 1975 .

Trimethylphosphine Complexes of Diorganonickel(IV) Moieties

U. Flörke, H. Haupt, Hongjian Sun, 1997 .

Syntheses and Properties of the First Octahedral Diorganonickel(IV) Compounds

G. Cordier, H. Klein, A. Bickelhaupt, 1994 .

Oxidative Kupplung von Alkinylgruppen an Trimethylphosphan‐Nickel‐Komplexen

G. Cordier, H. Klein, H. Beck‐Hemetsberger, 1989 .

Methyl(2-phosphanylphenolato[P,O])nickel(II) Complexes – Synthesis, Structure, and Activity as Ethene Oligomerization Catalysts

U. Flörke, W. Keim, H. Haupt, 2000 .

Syntheses and properties of molecular nickel(II) hydride, methyl, and nickel(I) complexes supported by trimethylphosphane and (2-diphenylphosphanyl)thiophenolato and -naphtholato ligands

H. Fuess,, I. Svoboda,, R. Hauptmann, 2009 .

Methyl(2‐phosphanylphenolato[P,O])nickel(II) Complexes — Synthesis, Structure, and Activity as Ethene Oligomerization Catalysts.

W. Keim, H. Haupt, U. Floerke, 2000 .

Formation of η1-P-(2-Phosphinophenol)Ni(0)(PMe3)3 and Oxidation to cis/trans-Bis(2-phosphinophenolato)nickel(II) Complexes

U. Flörke, H. Haupt, H. Klein, 1999 .

Coordination of ortho and para quinones and oxidation reduction processes in trimethylphosphine complexes of cobalt and nickel

U. Flörke, E. Auer, H. Haupt, 1999 .

Syntheses and Structures of Molecular Diphenolatonickel Compounds Containing Trimethylphosphane Ligands

U. Flörke, S. Braun, H. Haupt, 1998 .

Synthesis and Reactions with CO and C2H4 of Cobalt(I) Complexes Containing Trimethylphosphine and Chelating o-Diphenylphosphanyl- phenolate Ligands

G. Cordier, H. Klein, A. Brand, 1998 .

Ligand-induced fragmentation of methylnickel phenolates containing a 2-aldehyde function : structure of (3-tert-butyl-5-methyl-2-oxobenzoyl)-tris(trimethylphosphine)nickel

H. Haupt, U. Floerke, H. Klein, 1994 .

Cycloisomerization and [2 + 2]cyclodimerization of 1,5-cyclooctadiene catalyzed with the Ni(COD)2/BF3·OEt2 system

S. Petrovskii, V. Bocharova, H. Klein, 2010 .

Stabilization of dimethyliron(II) and methylcobalt(I) complexes bearing a hemilabile 2-benzoylpyridine ligand in octahedral and square-pyramidal coordination

U. Flörke, R. Beck, H. Klein, 2009 .

Methylnickel compounds containing trimethylphosphine and salicylaldiminato(N:O) ligands

H. Klein, A. Bickelhaupt, 1996 .

Ligand-induced C,C-coupling and C,C-bond breaking in diarylfulvene complexes of cobalt(0)

E. Auer, H. Klein, C. Roehr, 1995 .

Olefin-Insertion into Cobalt(d8) Complexes—Structure of Ethylene(phenyl)tris(trimethylphosphane)cobalt†

U. Schubert, H. Klein, R. Hammer, 1980 .

Cobalt-Promoted Tandem C(sp2)–H Activation and C–C Coupling of Vinyldiphenylphosphine: σ- vs π-Coordination Modes within Cyclometalation

U. Flörke, R. Beck, H. Klein, 2015 .

Pd6(.mu.3-CO)4(PMe3)7: the first octahedral hexapalladium cluster core

H. Haupt, U. Floerke, H. Klein, 1992 .

Unexpected formation of a molecular tetraalkyl nickel complex from an olefin/nickel(0) system.

H. Klein, P. Kraikivskii, 2009, Angewandte Chemie.

Novel imido- and phosphorane-imido-nickel(II) complexes. Crystal and molecular structure of (.mu.3-NH)(.mu.3-NPMe3)(NiClPMe3)3

S. Haller, M. Menu, M. Dartiguenave, 1991 .

Trimethylphosphane Complexes of Nickel, Cobalt, and Iron—Model Compounds for Homogeneous Catalysis

H. Klein, 1980 .

Chelating Coordination of Di- and Triallylamines: Syntheses and NMR Studies of Trimethylphosphane Nickel and Cobalt Complexes†

S. Braun, H. Klein, Michael Helwig, 1994 .

Steering of Configuration by (2-Phosphanyl)phenolato Ligands in Trimethylphosphane Iron Complexes

H. Klein, M. Frey, Shi-zhen Mao, 2005 .

Spontaneous formation of trinickel clusters containing μ3-imido bridges from 2-nitrophenols and Ni(PMe3)4

U. Flörke, H. Haupt, H. Klein, 1999 .

Acetylnickelhalogenide durch CO‐Einschiebung in NiC‐σ‐Bindungen

H. Klein, 1973 .

Reduction of 2-nitrophenols by low-valent trimethylphosphine complexes of cobalt

U. Flörke, H. Haupt, A. Schmidt, 2003 .

Oxidation–reduction exchange of 2-acylenolato and trimethylphosphane ligands between d8 complexes of nickel and cobalt

U. Flörke, Xiaoyan Li, H. Haupt, 2000 .

P,O-ligands: 2-hydroxyarylphosphines, nickel complexes and use in homogenous catalysis

W. Keim, M. Köhler, H. Klein, 1999 .

Four-membered and five-membered metallocycles of methylnickel compounds

H. Klein, Thomas Wiemer, 1991 .

Methylnickel compounds with chelating anionic ligands. Crystal and molecular structures of methyl(trimethylphosphine)nickel oxinate and oxalate dimer

M. Menu, M. Dartiguenave, Y. Dartiguenave, 1988 .

Stabile Methylnickelverbindungen, V. Das Methyltetrakis(trimethylphosphin)nickel‐Kation

H. Klein, W. Buchner, H. Karsch, 1974 .

Acetylnickel Halides by Insertion of CO into NiC σ‐Bonds

H. Klein, 1973 .

Nuclear magnetic resonance spectra and ligand substitution reactions of methylgold and trimethylgold complexes

H. Schmidbaur, H. Klein, Akinori Shiotani, 1971 .

INTERMEDIATES AND SIDE-REACTIONS IN THE SYNTHESIS OF MOLECULAR DIPHENOLATONICKEL COMPOUNDS CONTAINING TRIMETHYLPHOSPHANE LIGANDS

U. Flörke, H. Haupt, H. Klein, 1998 .

Spontaneous Bicyclometalation of a Single Cobalt(I) Complex Stabilized by a δ‐C–H Agostic Interaction

R. Beck, H. Klein, Sebnem Camadanli, 2018 .

Synthesis and Structure of Octahedral Nickel(IV) Complexes Containing Two Chelating Acylphenolato Ligands

H. Klein, C. Röhr, Mathias Lemke, 1995 .

Catalytic Graphite-Intercalation with Alkali Metals in Solution†

J. Besenhard, H. Klein, J. Gross, 1980 .

Cobalt diazenides of Main Group 1-3 metals: X-ray structure of a Grignard compound containing (dinitrogen)(trimethylphosphine)cobaltate anions

Herbert Koenig, H. Klein, J. Riede, 1987 .

Insertion of alkynes into Ni-H bonds : Synthesis of novel vinyl nickel(II) and dinuclear vinyl nickel(II) complexes containing a [P, S]-ligand

Xiaoyan Li, Hongjian Sun, H. Klein, 2007 .

Synthesis and Catalytic Application in Hydrosilylation of the Complex mer-Hydrido(2-mercaptobenzoyl)tris(trimethylphosphine)cobalt(III)

U. Flörke, Xiaoyan Li, Qingfen Niu, 2013 .

A Novel Hetero‐Bimetallic Dinitrogen Complex

U. Schubert, G. Huttner, H. Klein, 1976 .

Nickel phosphine complexes. Crystal and molecular structure of a new nickel(I) complex: [Ni(P(CH3)3)4]B(C6H5)4

J. Galy, A. Gleizes, M. Dartiguenave, 1977 .

Dioxobenzene dianions - unusual ligands in methylnickel compounds

M. Menu, M. Dartiguenave, Y. Dartiguenave, 1991 .

Methylnickel compounds containing bridging and monodentate carboxylate ligands

M. Dartiguenave, Y. Dartiguenave, H. Klein, 1991 .

Ambient-temperature preparation of LiCn by lithium transfer in hydrocarbon solutions

J. D. Besenhard, H. Klein, H. Witty, 1984 .

Steric Control of Oxidative Trimerization of Alkynyl Ligands in Trimethylphosphane Palladium Complexes

H. Klein, B. Zettel, 1995 .

Oxidative Coupling of Alkynyl Groups on Trimethylphosphane Nickel Complexes.

G. Cordier, H. Klein, H. Beck‐Hemetsberger, 1989 .

Silyl-, stannyl- and plumbyl-copper compounds containing chelating and monodentate phosphine ligands

U. Flörke, H. Haupt, H. Klein, 1990 .

Tris(trimethylphosphine)cobalt(I) halides. Preparation and properties

H. Klein, H. Karsch, 1975 .

Nickel-trimethylphosphine complexes: crystal and molecular structure and decomposition reaction of methyltetrakis(trimethylphosphine)nickel(II) tetraphenylborate

A. Gleizes, M. Dartiguenave, Y. Dartiguenave, 1981 .

Das Dimethylphosphanomethanid-Ion als Brückenligand - Struktur von μ-Dimethylphosphido, μ-Dimethylphosphanomethanidotetrakis(trimethylphosphan)dicobalt / The Dimethylphosphanomethanide Ion as a Bridging Ligand - Structure of μ-Dimethylphosphido, μ-Dimethylphosphanomethanidotetrakis(trimethylphosphan

U. Schubert, H. Klein, J. Wenninger, 1979 .

Synthese von Phosphor‐yliden am Cobalt‐Komplexzentrum

H. Klein, R. Hammer, 1976 .

Synthesis of Phosphorus Ylides at a Cobalt‐Complex Center

H. Klein, R. Hammer, 1976 .

Tetrakis(trimethylphosphane)cobalt(0): Preparation and Reactions

H. Klein, 1971 .

Synthesis, Properties, and Structure of a Dinitrogen Bridged Dinuclear Hydridocobalt Complex and its Reactions with 1-Alkynes

H. Paulus, G. Cordier, H. Klein, 1991 .

Hexameric KN2Co [P(CH3)3]3—A Novel Potassium‐Dinitrogen Cluster

P. Friedrich, G. Huttner, H. Klein, 1977 .

The reactivity of cyanogen towards compounds containing active hydrogens at carbon atoms. Part 4. The cyanation of [Mn(acac)2], [Mn(acac)3 and [Zn(acac)2]

A. Marcomini, B. Corain, M. Basato, 1983 .

Simple Metal-Catalyzed Synthesis of Functionalized Pyrimidines from Dicyanogen and 1,3-Dicarbonyl Compounds†

B. Corain, M. Basato, H. Klein, 1981 .

SIMPLE METAL‐CATALYZED SYNTHESIS OF FUNCTIONAL PYRIMIDINES FROM DICYAN AND 1,3‐DICARBONYL COMPOUNDS

B. Corain, M. Basato, H. Klein, 1982 .

Studies on the reaction mechanism of the Fischer-Tropsch synthesis on iron and cobalt catalysts

J. Gaube, H. Klein, 2008 .

Conductivity of carbon fibres intercalated with potassium at room temperature. Binary compounds, solvated compounds, large spacing residual compounds

H. Möhwald, J. Besenhard, H. Klein, 1981 .

Synthesis of novel polyfunctional nickel(II)-nickel(II) dimer Ni2Cl2[C(SiMe3)(PMe3)]2 by photolysis of the first [(trimethylsilyl)diazomethyl]nickel(II) complex Ni[C(N2)SiMe3]Cl(PMe3)2

M. Menu, M. Dartiguenave, Y. Dartiguenave, 1990 .

The Tetrakis(trimethylphosphine)cobalt Anion

H. Klein, R. Hammer, 1977 .

The Tetrakis(trimethylphosphine)cobalt Anion.

H. Klein, R. Hammer, 1977 .

Ambient Temperature Alkali Metal Transfer in Hydrocarbons - A New Route to Intercalation Compounds and Alloys

J. Besenhard, H. Möhwald, H. Klein, 1982 .

α,β-Unsaturated Carbonyl Compounds as Hard/Soft Chelating Ligands in Methyl Nickel Phenolates and the Structure of trans-Methyl-2-(3-phenyl-2,3-η2- propenoyl)phenolatobis(trimethylphosphine)nickel(II)

U. Flörke, Xiaoyan Li, Hongjian Sun, 2005 .

An Organometallic Compound with Two‐coordinated Fluorine Atoms

H. Schmidbaur, H. Klein, 1966 .

Di(μ-phosphido)cobalt-und -nickel-Verbindungen mit Trimethylphosphanliganden/ Di(μ-phosphido)cobalt and Nickel Compounds with Trimethylphosphine Ligands

H. Klein, B. Eisenmann, U. Zucha, 1988 .

Further support for the two-mechanisms hypothesis of Fischer–Tropsch synthesis

J. Gaube, H. Klein, 2010 .

Preparation and crystal structure of anti-(η3:η3-azulene)pentakis(trimethylphosphine)dicobalt. Reactions with carbon monoxide and solution dynamics

U. Flörke, H. Haupt, H. Klein, 1994 .

Formation and Crystal Structure of Stable Five-coordinate Diorgano Cobalt(III) Complexes

U. Flörke, Xiaoyan Li, Hongjian Sun, 2005 .

Linear trimerization of phenylethyne: homogeneous catalysis with triangulo-Co3(.mu.3-H)(.mu.2-CO)3(PMe3)6

H. Klein, M. Mager, 1992 .

Single and double π-alkyne coordination in oxidation-reduction equilibria of low-valent trimethylphosphinecobalt complexes: spontaneous formation of a mixed valence dicobaltatetrahedrane core in the structure of Co2Cl(μ2-Me3ECCCCEMe3)(PMe3)4 (ESi, C)

U. Flörke, H. Haupt, M. Schwind, 1993 .

Triangulo cluster molecules of cobalt(0) and nickel(0) containing trimethylphosphine and carbonyl ligands: syntheses, properties, and x-ray structures

R. Boča, M. Breza, H. Haupt, 1992 .

Magnetic properties of triangulo cobalt–hydride cluster [H3Co3(μ2-CO)3(PMe3)6]

R. Boča, M. Valko, W. Linert, 2000 .

Transition metal complexes of tetraphosphorus trisulphide, P4S3

H. Klein, R. Jefferson, J. Nixon, 1969 .