S. Robertson

发表

Lithium, sodium and potassium picolyl complexes: syntheses, structures and bonding.

A. Kennedy, R. Mulvey, Robert I Urquhart, 2014, Dalton transactions.

Exposing elusive cationic magnesium-chloro aggregates in aluminate complexes through donor control.

Etienne V. Brouillet, K. Koszinowski, A. Kennedy, 2016, Dalton transactions.

Pre-inverse-crowns: synthetic, structural and reactivity studies of alkali metal magnesiates primed for inverse crown formation

D. Armstrong, J. Klett, A. Martı́nez-Martı́nez, 2014 .

Developing lithium chemistry of 1,2-dihydropyridines: from kinetic intermediates to isolable characterized compounds.

D. Armstrong, A. Kennedy, J. Liggat, 2015, Chemistry.

TMP (2,2,6,6-tetramethylpiperidide)-aluminate bases : lithium-mediated alumination or lithiation-alkylaluminium-trapping reagents?

D. Armstrong, Eva Hevia, Donna L. Ramsay, 2014 .

Donor‐influenced Structure–Activity Correlations in Stoichiometric and Catalytic Reactions of Lithium Monoamido‐Monohydrido‐Dialkylaluminates

J. Okuda, A. Kennedy, Eva Hevia, 2018, Chemistry.

Structurally Mapping Alkyl and Amide Basicity in Zincate Chemistry: Diversity in the Synthesis of Mixed Sodium–Zinc Complexes and Their Applications in Enolate Formation

A. Kennedy, Eva Hevia, S. Robertson, 2020 .

Alkali-metal-mediated zincation (AMMZn) meets N-heterocyclic carbene (NHC) chemistry: Zn–H exchange reactions and structural authentication of a dinuclear Au(I) complex with a NHC anion

D. Armstrong, V. Blair, Joaquín García‐Álvarez, 2013 .

Reactivity studies and structural outcomes of a bulky dialkylaluminium amide in the presence of the N-heterocyclic carbene, ItBu

A. Kennedy, Catherine Weetman, R. Mulvey, 2021, Polyhedron.

Neutral zinc, lower-order zincate and higher-order zincate derivatives of pyrrole: synthesis and structural characterisation of zinc complexes with one, two, three or four pyrrolyl ligands.

A. Kennedy, J. A. Garden, R. Mulvey, 2011, Dalton transactions.

Alkali-Metal-Mediated Synergistic Effects in Polar Main Group Organometallic Chemistry.

M. Uzelac, R. Mulvey, S. Robertson, 2019, Chemical reviews.

Synthesis, Structure, and DFT Analysis of the THF Solvate of 2‐Picolyllithium: A 2‐Picolyllithium Solvate with Significant Carbanionic Character

Etienne V. Brouillet, T. Krämer, A. Kennedy, 2020, Zeitschrift für anorganische und allgemeine Chemie.

Probing the metallating ability of a polybasic sodium alkylmagnesiate supported by a bulky bis(amido) ligand: deprotomagnesiation reactions of nitrogen-based aromatic substrates.

D. Armstrong, W. Clegg, A. Kennedy, 2014, Dalton transactions.

N-Heterocyclic-Carbene-Induced Monomerization of Sterically Encumbered Dialkylmagnesium and Dialkylmanganese Polymers

J. Klett, A. Kennedy, R. Mulvey, 2011 .

N-Heterocyclic carbene stabilized adducts of alkyl magnesium amide, bisalkyl magnesium and Grignard reagents: trapping oligomeric organo s-block fragments with NHCs.

A. Kennedy, R. Mulvey, S. Robertson, 2010, Dalton transactions.

Opening the black box of mixed-metal TMP metallating reagents: direct cadmation or lithium–cadmium transmetallation?

D. Armstrong, J. Parkinson, A. Kennedy, 2012 .

A regioselectively 1,1′,3,3′-tetrazincated ferrocene complex displaying core and peripheral reactivity†

D. Armstrong, J. Parkinson, W. Clegg, 2020, Chemical science.

Contacted Ion-Pair Lithium Alkylamidoaluminates: Intramolecular Alumination (Al−H Exchange) Traps for TMEDA and PMDETA

Joaquín García‐Álvarez, A. Kennedy, Eva Hevia, 2009 .

Structurally Defined Zincated and Aluminated Complexes of Ferrocene Made by Alkali-Metal-Synergistic Syntheses

W. Clegg, A. Kennedy, Eva Hevia, 2015 .

Developing catalytic applications of cooperative bimetallics: competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates.

A. Kennedy, Eva Hevia, Alberto Hernán‐Gómez, 2013, Chemical communications.

Monomerizing alkali-metal 3,5-dimethylbenzyl salts with tris(N, N-dimethyl-2-aminoethyl)amine (Me6TREN): structural and bonding implications.

D. Armstrong, M. Davidson, A. Kennedy, 2013, Inorganic chemistry.

NMR spectroscopic study of the adduct formation and reactivity of homoleptic rare earth amides with alkali metal benzyl compounds, and the crystal structures of [Li(TMEDA)2][Nd{N(SiMe3)2}3(CH2Ph)] and [{Li(TMP)}2{Li(Ph)}]2.

S. M. Mansell, S. Robertson, Simon G. Rachor, 2017 .

Synthetically important alkali-metal utility amides: lithium, sodium, and potassium hexamethyldisilazides, diisopropylamides, and tetramethylpiperidides.

R. Mulvey, S. Robertson, Stuart D. Robertson, 2013, Angewandte Chemie.

Concerning the structures of alkali-metal-mediated ortho zincation of benzamides and phenyl o-carbamate

V. Snieckus, T. Rantanen, A. Kennedy, 2011 .

Structurally Stimulated Deprotonation/Alumination of the TMP Anion**

A. Kennedy, R. Mulvey, S. Robertson, 2010, Angewandte Chemie.

Gold complexes of ditelluridoimidodiphosphinate ligands - reversible oxidation of Au(I) to Au(III) via insertion of gold into a phosphorus-tellurium bond

T. Chivers, Dana J. Eisler, S. Robertson, 2009 .

Main Group Multiple C–H/N–H Bond Activation of a Diamine and Isolation of A Molecular Dilithium Zincate Hydride: Experimental and DFT Evidence for Alkali Metal–Zinc Synergistic Effects

T. Tuttle, A. Kennedy, J. Saßmannshausen, 2011, Journal of the American Chemical Society.

Adding a Structural Context to the Deprotometalation and Trans-Metal Trapping Chemistry of Phenyl-Substituted Benzotriazole.

V. Snieckus, J. Parkinson, T. Rantanen, 2015, Chemistry.

Sodium congener of the classical lithium methylchromate dimer: synthetic, X-ray crystallographic, and magnetic studies of Me8Cr2[Na(OEt2)]4.

E. Rentschler, W. Clegg, Luca M. Carrella, 2011, Inorganic chemistry.

Contrasting the group 6 metal-metal bonding in sodium dichromate(ii) and sodium dimolybdate(ii) polymethyl complexes: synthetic, X-ray crystallographic and theoretical studies.

S. Sproules, A. Kennedy, R. McLellan, 2017, Dalton transactions.

Palladium and platinum complexes of tellurium-containing imidodiphosphinate ligands: nucleophilic attack of Li[(P(i)Pr2)(TeP(i)Pr2)N] on coordinated 1,5-cyclooctadiene.

T. Chivers, Jamie S Ritch, S. Robertson, 2009, Dalton transactions.

New insights into the chemistry of imidodiphosphinates from investigations of tellurium-centered systems.

H. Tuononen, T. Chivers, J. Konu, 2010, Accounts of chemical research.

Organo-aluminum, zinc and magnesium derivatives of the imidotris(amido)phosphate Me3SiNP((NHBu)-Bu-t)(3)

T. Chivers, J. Konu, S. Robertson, 2007 .

Concealed cyclotrimeric polymorph of lithium 2,2,6,6-tetramethylpiperidide unconcealed: X-ray crystallographic and NMR spectroscopic studies.

A. Kennedy, Eva Hevia, Donna L. Ramsay, 2013, Chemistry.

Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire.

A. Kennedy, Eva Hevia, T. Cadenbach, 2012, Dalton transactions.

Meta-metallation of N,N-dimethylaniline: Contrasting direct sodium-mediated zincation with indirect sodiation-dialkylzinc co-complexation

D. Armstrong, A. Kennedy, Eva Hevia, 2011, Beilstein journal of organic chemistry.

Modern Developments in Magnesium Reagent Chemistry for Synthesis

R. Mulvey, S. Robertson, 2013 .

Accessible heavier s-block dihydropyridines: structural elucidation and reactivity of isolable molecular hydride sources.

A. Kennedy, J. Liggat, R. McLellan, 2016, Dalton transactions.

Developing a Hetero-Alkali-Metal Chemistry of 2,2,6,6-Tetramethyl-piperidide (TMP): Stoichiometric and Structural Diversity within a Series of Lithium/Sodium, Lithium/Potassium and Sodium/Potassium TMP Compounds

D. Armstrong, A. Kennedy, R. Mulvey, 2011, Chemistry.

Exploiting σ/π coordination isomerism to prepare homologous organoalkali metal (Li, Na, K) monomers with identical ligand sets.

M. Davidson, A. Kennedy, Daniel García-Vivó, 2011, Chemistry.

Lithium Dihydropyridine Dehydrogenation Catalysis: A Group 1 Approach to the Cyclization of Diamine Boranes

A. Kennedy, R. McLellan, R. Mulvey, 2016, Angewandte Chemie.

Synthesis, Structure and Solution Studies on Mixed Aryl/Alkyl Lithium Zincates

A. Kennedy, Eva Hevia, R. McLellan, 2016 .

After-effects of lithium-mediated alumination of 3-iodoanisole: isolation of molecular salt elimination and trapped-benzyne products.

A. Kennedy, R. Mulvey, S. Robertson, 2012, Dalton transactions.

Structurally powered synergic 2,2,6,6-tetramethylpiperidine bimetallics: new reflections through lithium-mediated ortho aluminations.

D. Armstrong, A. Kennedy, R. Mulvey, 2011, Inorganic chemistry.

Structural insights into mono-amido tris-alkyl potassium aluminates

J. Klett, A. Kennedy, P. García‐Álvarez, 2010 .

Complexity in seemingly simple sodium magnesiate systems.

A. Kennedy, P. García‐Álvarez, J. Francos, 2014, Dalton transactions.

Regioselective heterohalogenation of 4-halo-anisoles via a series of sequential ortho-aluminations and electrophilic halogenations.

A. Kennedy, R. Mulvey, S. Robertson, 2012, Chemical communications.

Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)·Na(μ-TMP)(μ-tBu)Zn(tBu)] towards TEMPO and chalcone.

D. Armstrong, J. Klett, J. Crawford, 2012, Chemical communications.

Lithium and aluminium carbamato derivatives of the utility amide 2,2,6,6-tetramethylpiperidide.

A. Kennedy, R. Mulvey, S. Robertson, 2010, Dalton transactions.

Modifying Alkylzinc Reactivity with 2,2′-Dipyridylamide: Activation of tBu=Zn Bonds for para-Alkylation of Benzophenone**

D. Armstrong, A. Kennedy, J. A. Garden, 2013, Angewandte Chemie.

catena-Poly[sodium-μ2-(N,N,N′,N′-tetramethylethane-1,2-diamine)-κ2 N:N′-sodium-bis[μ2-bis(trimethylsilyl)azanido-κ2 N:N]]

A. Kennedy, C. T. O'Hara, R. Mulvey, 2012, Acta crystallographica. Section E, Structure reports online.

Molecular structures of THF-solvated alkali-metal 2,2,6,6-tetramethylpiperidides finally revealed: X-ray crystallographic, DFT, and NMR (including DOSY) spectroscopic studies.

D. Armstrong, A. Kennedy, P. García‐Álvarez, 2011, Chemistry.

Synthesis, NMR characterisation and X-ray structures of mixed chalcogenido PNP ligands containing tellurium: crystal structures of SeiPr2PNP(H)iPr2 and [NaN(EPiPr2)2]infinity (E = Se, Te).

T. Chivers, S. Robertson, 2008, Dalton transactions.

Heterobimetallic metallation studies of N,N-dimethylphenylethylamine (DMPEA): benzylic C-H bond cleavage/dimethylamino capture or intact DMPEA complex.

A. Kennedy, Donna L. Ramsay, R. Mulvey, 2015, Dalton transactions.

Donor-activated lithiation and sodiation of trifluoromethylbenzene: structural, spectroscopic and theoretical insights

D. Armstrong, W. Clegg, A. Kennedy, 2013 .

A hetero-alkali-metal version of the utility amide LDA: lithium-potassium diisopropylamide.

D. Armstrong, A. Kennedy, R. Mulvey, 2013, Dalton transactions.

FascinATES: Mixed-Metal Ate Compounds That Function Synergistically

R. Mulvey, S. Robertson, 2013 .

Exploring the solid state and solution structural chemistry of the utility amide potassium hexamethyldisilazide (KHMDS).

A. Martı́nez-Martı́nez, A. Kennedy, C. T. O'Hara, 2017, Dalton transactions.

Tetraamine Me6TREN induced monomerization of alkali metal borohydrides and aluminohydrides

A. Kennedy, R. McLellan, R. Mulvey, 2016 .

Synthesis of an alkylmagnesium amide and interception of a ring-opened isomer of the important utility amide 2,2,6,6-tetramethylpiperidide (TMP)

J. Klett, A. Kennedy, C. T. O'Hara, 2014 .

Contrasting reactivity of mono- versus Bis-2,2,6,6-tetramethylpiperidide lithium aluminates towards polydentate lewis bases: co-complexation versus deprotonation

A. Kennedy, R. Mulvey, S. Robertson, 2013 .

Structurally engineered deprotonation/alumination of THF and THTP with retention of their cycloanionic structures.

J. Klett, A. Kennedy, P. García‐Álvarez, 2010, Angewandte Chemie.

Dizincation of a 2-substituted thiophene: constructing a cage with a [16]crown-4 zincocyclic core.

V. Snieckus, T. Rantanen, A. Kennedy, 2012, Angewandte Chemie.

1‐Alkali‐metal‐2‐alkyl‐1,2‐dihydropyridines: Soluble Hydride Surrogates for Catalytic Dehydrogenative Coupling and Hydroboration Applications

A. Kennedy, R. McLellan, R. Mulvey, 2017, Chemistry.

Platinum complexes of dibenzo[1,2]dithiin, dibenzo[1,2]dithiin oxides and related polyaromatic hydrocarbon ligands.

A. Slawin, J. Woollins, P. Kilian, 2006, Chemistry.

Constructing Multimetallic Systems with the Naphthalene‐1,8‐bis(thiolato) Ligand

A. Slawin, J. Woollins, S. Robertson, 2007 .

The preparation and characterisation of bimetallic iridium(II) complexes containing derivatised bridging naphthalene-1,8-disulfur or 4,5-dithiolato acephenanthrylene ligands.

A. Slawin, J. Woollins, S. Robertson, 2004, Dalton transactions.

Synthesis, multinuclear NMR spectra, and X-ray structures of tBu2PNP(I)tBu2 and EPR2NP(I)R2 (E = Se, Te; R = iPr, tBu).

T. Chivers, Jamie S Ritch, S. Robertson, 2010, Inorganic Chemistry.

Experimental and theoretical investigations of the contact ion pairs formed by reactions of the anions [(EPR2)2N]- (R = (i)Pr, (t)Bu; E = S, Se) with the cations [(TePR2)2N]+ (R = (i)Pr, (t)Bu).

H. Tuononen, T. Chivers, S. Robertson, 2009, Inorganic Chemistry.

Experimental and theoretical investigations of the redox behavior of the heterodichalcogenido ligands [(EP(i)Pr2)(TeP(i)Pr2)N](-) (E = S, Se): cyclic cations and acyclic dichalcogenide dimers.

H. Tuononen, T. Chivers, S. Robertson, 2008, Inorganic chemistry.

Ni[(EPiPr2)2N]2 complexes: stereoisomers (E = Se) and square-planar coordination (E = Te).

A. Terzis, C. Raptopoulou, P. Kyritsis, 2008, Inorganic chemistry.

The preparation and characterisation of a series of group IV metallocene dithiolato complexes containing a naphthalene backbone

A. Slawin, J. Woollins, S. Robertson, 2006 .

Nickel(II) complexes of heterodichalcogenido and monochalcogenido imidodiphosphinate ligands: AACVD synthesis of nickel ditelluride.

P. O’Brien, Javeed Akhtar, M. Afzaal, 2008, Dalton transactions.

Platinum complexes of naphthalene-1,8-dichalcogen and related polyaromatic hydrocarbon ligands.

A. Slawin, J. Woollins, S. Robertson, 2004, Chemistry.

Bis(cyclopentadienyl)titanium complexes of naphthalene-1,8-dithiolates, biphenyl 2,2'-dithiolates, and related ligands.

A. Slawin, J. Woollins, P. Kilian, 2005, Inorganic chemistry.

Facile synthesis of a genuinely alkane-soluble but isolable lithium hydride transfer reagent.

A. Kennedy, J. Liggat, R. Mulvey, 2015, Chemical communications.

Exploiting cation aggregation in new magnesium amidohaloaluminate electrolytes for magnesium batteries

Etienne V. Brouillet, S. Corr, Marco Amores, 2020, Inorganic Chemistry Frontiers.

Structural Characterization of the 1-Metallo-2-t-Butyl-1,2-Dihydropyridyl Rubidium and Caesium Complexes

Peter A. Macdonald, A. Kennedy, Sumanta Banerjee, 2023, Polyhedron.

Two alternative approaches to access mixed hydride-amido zinc complexes: synthetic, structural and solution implications.

M. Probert, W. Clegg, A. Kennedy, 2015, Dalton transactions.

Methodologies for Operando ATR-IR Spectroscopy of Magnesium Battery Electrolytes.

S. K. Kairy, S. Robertson, A. Wain, 2022, Analytical Chemistry.

Differentiating between Ion Transport and Plating–Stripping Phenomena in Magnesium Battery Electrolytes Using Operando Raman Spectroscopy

A. Pollard, Sofia Marchesini, K. Paton, 2023, ACS Energy Letters.

Atom-efficient synthesis of a benchmark electrolyte for magnesium battery applications.

Rhiannon M. Kennard, Sofia Marchesini, S. Robertson, 2022, Chemical communications.

THE CHEMISTRY OF (ECN)2 (E = S, Se) AND RELATED COMPOUNDS

A. Slawin, J. Woollins, S. Robertson, 2004 .

Modern Developments in Magnesium Reagent Chemistry for Synthesis

R. Mulvey, S. Robertson, 2013 .

Mixed Lithium Amide–Lithium Halide Compounds: Unusual Halide-Deficient Amido Metal Anionic Crowns**

A. Kennedy, C. T. O'Hara, R. Mulvey, 2011, Angewandte Chemie.

Crystal structures of dibenzo[ce]‐1,2‐dithiine and its related oxides

A. Slawin, J. Woollins, S. Robertson, 2005 .

Crystal structures and molecular modeling of 1,8 chalcogenide-substituted naphthalenes

A. Slawin, J. Woollins, S. Robertson, 2004 .

A μ4-oxide-containing a dimeric variant of a sodium dialkyl(amido)zincate reagent.

A. Kennedy, R. Mulvey, S. Robertson, 2011, Acta crystallographica. Section C, Crystal structure communications.