Takashi Komuro

发表

Synthesis and characterisation of hydrido molybdenum and tungsten complexes having a hemilabile tridentate Si,Si,O-ligand: observation of stepwise hydrosilylation of a nitrile to form an N-silylimine on the metal centre.

H. Tobita, R. Begum, Takashi Komuro, 2011, Dalton transactions.

Synthesis and structural characterization of silanethiolato complexes having tert-butyldimethylsilyl and trimethylsilyl groups.

K. Tatsumi, Tsukasa Matsuo, H. Kawaguchi, 2004, Dalton transactions.

[MoFe3S4]3+ and [MoFe3S4]2+ cubane clusters containing a pentamethylcyclopentadienyl molybdenum moiety

J. Lang, K. Tatsumi, H. Kawaguchi, 2007 .

Iridium Complexes with a Naphthyridine-Based Si,N-Ligand: Synthesis and Catalytic Activity toward Olefin Hydrogenation

H. Tobita, Tomo Osawa, H. Hashimoto, 2022, Organometallics.

Synthesis of Ruthenium Complexes with a Nonspectator Si,O,P-Chelate Ligand: Interconversion between a Hydrido(η2-silane) Complex and a Silyl Complex Leading to Catalytic Alkene Hydrogenation

H. Tobita, K. Kikuchi, Takashi Komuro, 2015 .

Recent progress in transition metal complexes supported by multidentate ligands featuring group 13 and 14 elements as coordinating atoms

Y. Nakajima, J. Takaya, H. Hashimoto, 2022, Coordination Chemistry Reviews.

Synthesis, Structure, and Reactions of a (η3-α-silabenzyl)molybdenum Complex: A Synthetic Equivalent of a Coordinatively Unsaturated Silyl Complex

H. Tobita, Takashi Komuro, Yuto Kanno, 2013 .

Synthesis of ruthenium–bis(silyl) chelate complexes without carbonyl ligands by reactions of a bis(allyl)ruthenium(II) complex with bis(hydrosilyl)xanthene and phosphines

H. Tobita, Takashi Komuro, Keita Sato, 2020 .

Tandem Hydrosilylation/o-C–H Silylation of Arylalkynes Catalyzed by Ruthenium Bis(silyl) Aminophosphine Complexes

H. Tobita, Takashi Komuro, Rikima Ono, 2017 .

Double and Single Hydroboration of Nitriles Catalyzed by a Ruthenium–Bis(silyl)xanthene Complex: Application to One-Pot Synthesis of Diarylamines and N-Arylimines

H. Tobita, Takashi Komuro, Takeo Kitano, 2019, Organometallics.

Coordination chemistry of silanedithiolato ligands derived from cyclotrisilathiane: synthesis and structures of complexes of iron(II), cobalt(II), palladium(II), copper(I), and silver(I).

K. Tatsumi, Tsukasa Matsuo, H. Kawaguchi, 2003, Inorganic chemistry.

Directed ortho-C–H Silylation Coupled with trans-Selective Hydrogenation of Arylalkynes Catalyzed by Ruthenium Complexes of a Xanthene-Based Si,O,Si-Chelate Ligand, “Xantsil”

M. Okazaki, H. Tobita, Keisuke Ohta, 2016 .

Synthesis of a 14-electron iridium(III) complex with a xanthene-based bis(silyl) chelate ligand (xantsil): A distorted seesaw-shaped four-coordinate geometry and reactions leading to 16-electron complexes

H. Tobita, Takashi Komuro, Takeo Kitano, 2014 .

Insertion of carbon monoxide into an aldehyde CO double bond induced by an (η3-α-silabenzyl)carbonylmolybdenum complex

H. Tobita, Takashi Komuro, Yuto Kanno, 2014 .

Three- and five-membered W/C/N metallacycles formed by incorporation of acetonitrile molecules into silyltungsten intermediates

M. Okazaki, H. Tobita, E. Suzuki, 2007 .

(η3-α-Silabenzyl)tungsten Complexes: An Isolable Intermediate for Interconversion between a Silylene Complex and a Silyl Complex through 1,2-Aryl Migration

H. Tobita, E. Suzuki, Takashi Komuro, 2013 .

Facile 1,2-Migration of a Methyl Group on a {Dimethoxy(methyl)silyl}tungsten Complex: Formation of a Base-Stabilized (Dimethoxysilylene)(methyl) Complex†

M. Okazaki, H. Tobita, E. Suzuki, 2010 .

Synthesis and Characterization of κ2C,N-N-Silyliminoacyl Tungsten Complexes Cp*(CO)2W{κ2C,N-C(R)═NSiR′3} [R = Me, Et,i-Pr,t-Bu; R′3= (p-Tol)2Me, (p-Tol)3, Et3; Cp* = η5-C5Me5]: Thermally Induced Carbon−Carbon Bond Cleavage of Their Iminoacyl Ligands

M. Okazaki, H. Tobita, E. Suzuki, 2010 .

Synthesis and Characterization of DMAP-Stabilized Aryl(silylene) Complexes and (Arylsilyl)(DMAP) Complexes of Tungsten: Mechanistic Study on the Interconversion between These Complexes via 1,2-Aryl Migration

M. Okazaki, H. Tobita, E. Suzuki, 2009 .

The First Resonance Hybrid of Silyl–Carbene and Pyridyl–Silylene Complexes: Formation by Aryl C–H Bond Activation of DMAP [4-(Dimethylamino)pyridine] on a Silylene Complex

H. Tobita, R. Begum, Takashi Komuro, 2007 .

Group 6 metal complexes with a hemilabile tridentate xantsil ligand and facile insertion of tBuCN into a W-Si bond [xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)].

H. Tobita, R. Begum, Takashi Komuro, 2006, Chemical Communications.

Synthesis and Structures of Alkynylchlorocyclotriphosphazenes and Their Cluster-Forming Reactions with Octacarbonyldicobalt

H. Tobita, K. Mori, Takashi Komuro, 2009 .

Direct Conversion of a Si–C(aryl) Bond to Si–Heteroatom Bonds in the Reactions of η3-α-Silabenzyl Molybdenum and Tungsten Complexes with 2-Substituted Pyridines

H. Tobita, Takashi Komuro, Yuto Kanno, 2015 .

Palladium dimethylsilanedithiolato complex: a precursor for Ti-Pd and Ti-Pd2 heterometallic complexes.

K. Tatsumi, Tsukasa Matsuo, H. Kawaguchi, 2002, Chemical communications.

Synthesis, Structure, and Properties of Three- and Six-Membered Metallacycles Composed of Iron, Germanium, and Sulfur Atoms

M. Okazaki, H. Tobita, H. Okada, 2007 .

Catalysts for Regio- and Stereoselective C(sp3)–H Deuteration of Tricyclohexylphosphine with Benzene-d6 Generated via Dehydrochlorination of Chlorido(dihydrido)iridium Complexes Containing a Xanthene-Based Bis(silyl) Chelate Ligand

H. Tobita, H. Hashimoto, Takashi Komuro, 2021, Organometallics.

[Ru(xantsil)(CO)(η6-toluene)]: Synthon for a Highly Unsaturated Ruthenium(II) Complex through Facile Dissociation of the Toluene Ligand [xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]

M. Okazaki, H. Tobita, H. Ogino, 2008 .

New hydrosilylation reaction of arylacetylene accompanied by C-H bond activation catalyzed by a xantsil ruthenium complex

M. Okazaki, H. Tobita, Keisuke Ohta, 2008 .

Synthesis and reactions of triphenylsilanethiolato complexes of manganese(II), iron(II), cobalt(II), and nickel(II).

K. Tatsumi, H. Kawaguchi, Takashi Komuro, 2002, Inorganic chemistry.

Preparation of endohedral fullerene containing lithium (Li@C60) and isolation as pure hexafluorophosphate salt ([Li+@C60][PF6−])

T. Kaneko, R. Hatakeyama, Y. Matsuo, 2012 .

A layered ionic crystal of polar Li@C(60) superatoms.

E. Nishibori, M. Takata, R. Kitaura, 2010, Nature chemistry.

Silyl-pyridine-amine pincer-ligated iridium complexes for catalytic silane deuteration via room temperature C-D bond activation of benzene-d6.

H. Tobita, Tomo Osawa, Ryuju Suzuki, 2019, Chemical communications.

Iridium and Platinum Complexes of Li+@C60

H. Tobita, H. Okada, Y. Kasama, 2014 .

Bifunctional Rhodium Complex Featuring a Silyl–1,8-naphthyridine Si,N-Chelate Ligand: Cooperation of Metal and Pendant Base for Capture and Bond-weakening of BH3

H. Tobita, H. Hashimoto, Takashi Komuro, 2020 .

Thermal reaction of a ruthenium bis(silyl) complex having a lutidine-based Si,N,Si ligand: formation of a mu-silyl(mu-silylene) diruthenium complex involving a 3c-2e Ru-Si-C interaction.

H. Tobita, Takashi Komuro, 2010, Chemical communications.