A. Fraile

发表

Water-trapping of unstable carbocations taking place into the inverted region of the Marcus equation. First experimental and computational evidence

E. T. Vilar, A. Martínez, S. D. L. M. Cerero, 2012 .

On the mechanism of the reaction between ketones and trifluoromethanesulfonic anhydride. An improved and convenient method for the preparation of pyrimidines and condensed pyrimidines

M. Hanack, L. R. Subramanian, F. Jiménez, 1992 .

The role of the C(2) configuration and methyl substitution on the catalytic activity of novel 2,3,3‐ and 2,7,7‐trimethyl‐substituted γ‐aminonorbornan‐2‐ols

A. Martínez, E. T. Vilar, S. D. L. M. Cerero, 2010 .

The role of conformational flexibility on the catalytic activity of norbornane-derived β-, γ- and δ-amino alcohols

E. T. Vilar, A. Martínez, S. D. L. M. Cerero, 2007 .

Understanding the catalytic role of flexible chiral δ-amino alcohols: the 1-(2-aminoethyl)norbornan-2-ol model

E. T. Vilar, B. L. Maroto, A. Martínez, 2005 .

2-exo- versus 2-endo-Hydroxyl in δ-amino norbornan-2-ol-based catalysts: investigating the role of the C(2) configuration in the asymmetric induction

E. T. Vilar, B. L. Maroto, A. Martínez, 2004 .

The role of the substitution pattern on the catalytic activity of chiral bridgehead norbornane-derived β-amino alcohols

P. Martínez-Ruiz, E. T. Vilar, A. Martínez, 2002 .

Bridgehead-norbornane-derived β-amino alcohol catalysts: structural factors influencing the chirality transfer

P. Martínez-Ruiz, E. T. Vilar, A. Martínez, 2002 .

Electron impact fragmentation patterns of 3,3-dimethyl-1, 2-norbornane derivatives

E. T. Vilar, A. Martínez, S. D. L. M. Cerero, 1999 .

Synthesis of enantiopure norbornane derivatives. Effect of bridgehead substituent on the π-facial selectivity of the reduction of 2-norbornanones and their oximes

E. T. Vilar, A. Martínez, S. D. L. M. Cerero, 1998 .

A facile synthesis of new homochiral β-amino alcohols with norbornane framework

L. R. Subramanian, E. T. Vilar, S. D. L. M. Cerero, 1996 .

Surprising obtention of an enantiopure eight-membered cyclic ether from camphor

E. T. Vilar, A. Martínez, S. D. L. M. Cerero, 2007 .

Intramolecular-activation evidence for the unexpected Beckmann fragmentation of C(1)-substituted-7-bromonorbornane-2-ones

E. T. Vilar, B. L. Maroto, A. Martínez, 2004 .

On the mechanism of the Leuckart reaction. Enantiospecific preparation of (1R,2R)- and (1S,2S)-N-(3,3-dimethyl-2-formylamino-1-norbornyl)acetamide

E. T. Vilar, A. Fraile, P. M. Ruiz, 1999 .

Synthesis of homochiral 1,2-diols from (−)-fenchone and (+)-camphor

L. R. Subramanian, E. T. Vilar, S. D. L. M. Cerero, 1994 .

Electron ionization-induced fragmentation of bridgehead-substituted norbornan-2-ones derived from fenchone

P. Martínez-Ruiz, E. T. Vilar, F. Jiménez, 2013 .

Stereocontrolled synthesis of conformationally restricted enantiopure triols and dihydroxy acids based on the norbornane framework

P. Martínez-Ruiz, E. T. Vilar, A. Martínez, 2005 .

Electron ionization mass spectral studies of bridgehead 7,7‐dimethylnorbornane‐based β‐amino alcohols

R. Martínez‐Álvarez, P. Martínez-Ruiz, E. T. Vilar, 2005 .

About the Leuckart reaction of chiral 2-norbornanones bearing electron-withdrawing groups: reaction of bridgehead triflates and triflamides

P. Martínez-Ruiz, E. T. Vilar, A. Martínez, 2003 .

Synthesis of homochiral 3-substituted cyclopentanones from 2-norbornanones

L. R. Subramanian, E. T. Vilar, S. D. L. M. Cerero, 1996 .

Synthesis of Homochiral 1,2-Diols from (-)-Fenchone and (+)-Camphor.

L. R. Subramanian, E. T. Vilar, S. D. L. M. Cerero, 1994 .

Enantiospecific access to 10-N-substituted camphors

E. T. Vilar, A. Martínez, S. D. L. M. Cerero, 2005 .

Enantioselective synthesis of both enantiomers of vicinal norbornanediamines through the Leuckart reaction of 2-norbornanones

P. Martínez-Ruiz, E. T. Vilar, A. Martínez, 2001 .

Influence of the Bridgehead Substituent on the Stereoselective Leuckart Reaction of 2-Norbornanones − Skeletal Rearrangement versus Structural Retention

P. Martínez-Ruiz, E. T. Vilar, A. Martínez, 2001 .

Synthesis of homochiral cyclopentane derivatives by Beckmann fragmentation of 1-substituted 2-norbornanones

L. R. Subramanian, E. T. Vilar, S. D. L. M. Cerero, 1994 .

Unexpected reactivity of 1 -amine -2 -methylenenorbornane hydrochlorides with m-CPBA

E. T. Vilar, B. L. Maroto, A. Martínez, 2007 .

A new type of anomalous ozonolysis in strained allylic bicycloalkan-1-ols

E. T. Vilar, B. L. Maroto, A. Martínez, 2005 .

Unexpected Bromine-Assisted Beckmann Fragmentation of a C1-Electron-Acceptor Substituted 7-Bromonorbornan-2-one Upon Hydroxylamine Treatment

E. T. Vilar, B. L. Maroto, A. Martínez, 2002 .

From natural camphor to (1 R ,2 S )-2-chloromethyl-3-oxocyclopentanecarboxylic acid: a stereocontrolled approach to enantiopure sarkomycin

E. T. Vilar, B. L. Maroto, A. Martínez, 2001 .

About the timing of Wagner-Meerwein and Nametkin rearrangements, 6,2-hydride shift, proton elimination and cation trapping in 2-norbornyl carbocations

E. T. Vilar, F. Jiménez, A. Martínez, 1998 .

Synthesis of methyl (1R,2S)-α,α-dimethyl-3-oxo-2-pentylcyclopentaneacetate. A model procedure for the preparation of chiral jasmonoids and prostaglandins

E. T. Vilar, P. Alvarez, S. D. L. M. Cerero, 1997 .

Synthesis of Homochiral 3-Substituted Cyclopentanones from 2- Norbornanones.

L. R. Subramanian, E. T. Vilar, S. D. L. M. Cerero, 1997 .

Unusual reactivity of norbornane bridgehead derivatives

M. Hanack, L. R. Subramanian, J. Barcina, 1989 .

An improved modification of ritter reaction

M. Hanack, L. R. Subramanian, E. T. Vilar, 1989 .

Synthesis and catalytic activity of 10-(aminomethyl)isoborneol-based catalysts : the role of the c(2)-group on the asymmetric induction

E. T. Vilar, B. L. Maroto, A. Martínez, 2003 .

First efficient preparation of enantiopure 10-bromofenchone: the key intermediate to C10-substituted fenchone-derived chiral sources

E. T. Vilar, B. L. Maroto, A. Martínez, 2001 .

A facile synthesis of homochiral 1-norbornanecarboxylic acids and 1-norbornanecarbonitriles

L. R. Subramanian, E. T. Vilar, S. D. L. M. Cerero, 1994 .

A Computational and Experimental Study on the Relative Stabilities of Cis and Trans Isomers of N-Alkylamides in Gas Phase and in Solution

P. Martínez-Ruiz, E. T. Vilar, A. Martínez, 2002 .

Straightforward synthesis of (1 S )-10-dimethylaminomethylcamphor: an enantiospecific model procedure to C10 C-substituted camphor-derived chiral sources

E. T. Vilar, B. L. Maroto, A. Martínez, 2002 .

Fragmentation of vinyl triflates by electron impact. Mechanism of an unusual double hydrogen atom transfer reaction

M. Hanack, L. R. Subramanian, J. Barcina, 1994 .

Reduktive Arylierung von Vinyl-trifluoromethansulfonaten durch Friedel-Crafts-Reaktion

M. Hanack, L. R. Subramanian, A. Fraile, 1987 .

A new procedure for formylation of less active aromatics

M. Hanack, L. R. Subramanian, J. Barcina, 1990 .

Chemoselective reaction of spiro[oxirane-2,2′-norborn]-1′-yl triflates with nucleophiles: a new case of HSAB-principle dependence

E. T. Vilar, B. L. Maroto, A. Martínez, 2001 .

Synthesis of gem-Bistriflates: Reaction of Aliphatic Aldehydes with Trifluoromethanesulfonic Acid Anhydride

M. Hanack, L. R. Subramanian, A. Martínez, 1987 .

Preparation of alkyl- and phenyl-substituted pyrimidines

J. Barcina, E. T. Vilar, A. Fernández, 1987 .

Palladium(II)-catalyzed ring expansion of a 1-alkenyl cyclopentanol

E. T. Vilar, B. L. Maroto, A. Martínez, 2005 .

C(10)-Substituted Camphors and Fenchones by Electrophilic Treatment of 2-Methylenenorbornan-1-ols: Enantiospecificity, Scope, and Limitations

A. Martínez, E. T. Vilar, B. L. Maroto, 2003 .

A novel enantiospecific route to 10-hydroxyfenchone: a convenient intermediate for C(10)-O-substituted fenchones

E. T. Vilar, B. L. Maroto, A. Martínez, 2002 .

Corrigendum to “A new highly efficient synthetic route to enantiopure 10-bromocamphor”

E. T. Vilar, B. L. Maroto, A. Martínez, 2000 .

A new highly efficient synthetic route to enantiopure 10-bromocamphor

E. T. Vilar, B. L. Maroto, A. Martínez, 2000 .

Enantiospecific synthesis of 9,10-dihalocamphors

E. T. Vilar, A. Martínez, S. D. L. M. Cerero, 2004 .

Stereoelectronic control in the solvolysis of spiroepoxidic 1-norbornyl triflates: unexpected reactivity in 3-bromomethyl derivatives

E. T. Vilar, A. Martínez, S. D. L. M. Cerero, 2011 .

First access to enantiopure C(7)-substituted fenchones: new norbornane-based chiral materials from the chiral pool

E. T. Vilar, B. L. Maroto, A. Martínez, 2003 .

A new convenient procedure for the preparation of enantiopure C10-S- and C10-Se-substituted camphor-derived sulfides and selenides

E. T. Vilar, B. L. Maroto, A. Martínez, 2001 .

A new straightforward preparation of enantiopure 10-hydroxycamphor

E. T. Vilar, B. L. Maroto, A. Martínez, 2000 .

ChemInform Abstract: First Efficient Preparation of Enantiopure 10-Bromofenchone: The Key Intermediate to C10-Substituted Fenchone-Derived Chiral Sources.

E. T. Vilar, B. L. Maroto, A. Martínez, 2002 .

A novel route to enantiopure cyclopentene carboxylic acids based on 3-endo-bromocamphor

E. T. Vilar, B. L. Maroto, A. Martínez, 2001 .

Solvent and stereoelectronic effects on the solvolysis rates of oxaspirocyclopropanated 1-norbornyl triflates and related bridgehead derivatives.

E. T. Vilar, B. L. Maroto, A. Martínez, 2008 .

Enantiospecific access to various C(9),C(10)-disubstituted camphors: scope and limitations.

S. de la Moya Cerero, A. Martínez, E. T. Vilar, 2004, The Journal of organic chemistry.

Synthesis of 7-anti-bromo-3,3-dimethyl-2-oxonorbornane-1-carboxylic acid: a new chiral source from the chiral pool

E. T. Vilar, B. L. Maroto, A. Martínez, 2002 .