M. E. García

发表

N-O Bond Activation and Cleavage Reactions of the Nitrosyl-Bridged Complexes [M2Cp2(μ-PCy2)(μ-NO)(NO)2] (M = Mo, W).

Miguel A. Ruiz, Daniel García-Vivó, Alberto Ramos, 2018, Inorganic chemistry.

Heterometallic Phosphinidene-Bridged Complexes Derived from the Phosphanyl Complexes syn-[MCp(PHR*)(CO)2] (M = Mo, W; R* = 2,4,6-C6H2Bu3).

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2022, Journal of Organometallic Chemistry.

Insertion and C-C coupling processes in reactions of the unsaturated hydride [W2Cp2(H)(μ-PCy2)(CO)2] with alkynes.

Miguel A. Ruiz, M. Vega, Daniel García-Vivó, 2016, Dalton transactions.

Reactions of the Carbyne-Bridged Radical Complex [Mo2(η5-C5H5)2(μ-CPh)(μ-PCy2)(μ-CO)]+ with Bidentate Ligands Having E–H Bonds (E = O, S, N)

Miguel A. Ruiz, M. Alvarez, Sonia Menéndez, 2014 .

Reactions of the phosphinidene-bridged complexes [Fe2(η5-C5H5)2(μ-PR)(μ-CO)(CO)2] (R = Cy, Ph) with electrophiles based on p-block elements.

Miguel A. Ruiz, M. Alvarez, Rocío González, 2012, Dalton transactions.

Synthesis and decarbonylation reactions of the triiron phosphinidene complex [Fe3Cp3(μ-H)(μ3-PPh)(CO)4]: easy cleavage and formation of P-H and Fe-Fe bonds.

Miguel A. Ruiz, C. Álvarez, Alberto Ramos, 2011, Inorganic chemistry.

Heterometallic derivatives of the unsaturated ditungsten hydride [W2(η(5)-C5H5)2(H)(μ-PCy2)(CO)2].

Miguel A. Ruiz, M. Vega, M. Alvarez, 2013, Inorganic chemistry.

P-C and C-H bond cleavages in the photochemical reactions of [Fe2(η5-C5H5)2(CO)4] with bis(diphenylphosphino)methane

Miguel A. Ruiz, J. Vaissermann, C. Álvarez, 2003 .

Phosphinidene-bridged binuclear complexes

Miguel A. Ruiz, Daniel García-Vivó, Alberto Ramos, 2017 .

P–C and C–C Coupling Processes in the Reactions of the Phosphinidene-Bridged Complex [Fe2(η5-C5H5)2(μ-PCy)(μ-CO)(CO)2] with Alkynes

Miguel A. Ruiz, M. Alvarez, Rocío González, 2013 .

P-S bond cleavage in reactions of thiophosphinidene-bridged dimolybdenum complexes with [Co2(CO)8] to give phosphinidene-bridged heterometallic derivatives.

Miguel A. Ruiz, M. Alvarez, M. E. García, 2016, Dalton transactions.

Electronic Structure and Multisite Basicity of the Pyramidal Phosphinidene-Bridged Dimolybdenum Complex [Mo2(η(5)-C5H5)(μ-κ(1):κ(1),η(5)-PC5H4)(η(6)-C6H3(t)Bu3)(CO)2(PMe3)].

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2015, Inorganic chemistry.

Activity of Mo–Mo and Mo–P multiple bonds at the phosphinidene complex [Mo2Cp2{μ-P(2,4,6-C6H2tBu3)}(μ-CO)2] in reactions with isocyanides and phosphine ligands

Miguel A. Ruiz, J. Jeffery, Daniel García-Vivó, 2015 .

Novel Dimerization of Maleic Anhydride at a Mo2 Complex: Phase-Driven Keto/Enol Tautomerism in a Phosphinidenium–Ylide Complex

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2013 .

Enhanced nucleophilic behavior of a dimolybdenum phosphinidene complex: multicomponent reactions with activated alkenes and alkynes in the presence of CO or CNXyl.

Miguel A. Ruiz, M. Alvarez, M. E. García, 2011, Angewandte Chemie.

Proton induced P-H and Mo-H bond activation at the phosphide bridged dimolybdenum complexes [Mo2Cp2(mu-H)(mu-PHR)(CO)4](R = Cy, 2,4,6-C6H2R'3; R'= H, Me, tBu).

Miguel A. Ruiz, L. Falvello, P. Herson, 2004, Dalton Transactions.

Gold( I )-induced chelate ring-opening of palladium( II ) and platinum( II ) triphos complexes

P. Sadler, A. Habtemariam, S. Parsons, 1999 .

Reactions of the unsaturated hydroxo complex [W2Cp2(OH)(μ-PPh2)2(CO)]BF4 with mono- and bidentate ligands having E-H bonds (E = O, S, N).

Miguel A. Ruiz, C. Graiff, Daniel García-Vivó, 2012, Inorganic chemistry.

Organotin compounds with 2,2′-biimidazole derivatives. The crystal structure of dibromo(N,N′-dimethyl-2,2′-biimidazole)dimethyltin(IV)

U. Casellato, R. Graziani, J. Casas, 1992 .

Complexes of diorganotin(IV) dihalides with N,N'-dimethyl-2,2'-bisimidazole

M. Leal, J. Casas, J. Sordo, 1993 .

Chelate ring-opening of Pd(II) triphos complexes:

P. Sadler, A. Habtemariam, A. Castiñeiras, 1998 .

One-step synthesis and P-H bond cleavage reactions of the phosphanyl complex syn-[MoCp{PH(2,4,6-C6H2tBu3)}(CO)2] to give heterometallic phosphinidene-bridged derivatives.

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2019, Dalton transactions.

Hydride, alkyl and carbyne derivatives of the unsaturated heterometallic anion [MoWCp2(μ-PCy2)(μ-CO)2]−

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2019, Journal of Organometallic Chemistry.

Terminal vs. bridging coordination of CO and NO ligands after decarbonylation of [W2Cp2(μ-PR2)(CO)3(NO)] complexes (R = Ph, Cy). An experimental and computational study.

Miguel A. Ruiz, M. Vega, Daniel García-Vivó, 2017, Dalton transactions.

Insertion, coupling and elimination processes in the reactions of the unsaturated alkyl-bridged complexes [Mo₂(η⁵-C₅H₅)₂(μ-CH₂R)(μ-PCy₂)(CO)₂] (R = H, Ph) with isocyanides and secondary phosphines.

Miguel A. Ruiz, Daniel García-Vivó, Alberto Ramos, 2014, Dalton transactions.

Reversible P–C Coupling Reactions at the Unsaturated Dimolybdenum Carbyne Complex [Mo2(η5-C5H5)2(CPh)(μ-PCy2)(μ-SPh)(CO)]+

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2012 .

Reactions of the tetrafluoroborate complex [Mo2Cp2(κ(2)-F2BF2)(μ-PPh2)2(CO)]BF4 with mono- and bidentate ligands having E-H bonds (E = O, S, Se, N, P).

Miguel A. Ruiz, C. Graiff, Daniel García-Vivó, 2012, Inorganic chemistry.

Protonation reactions of the oxo complex cis-[Mo2(η5-C5H5)2(O)(μ-PPh2)2(CO)]. Hydroxo and tetrafluoroborate derivatives

Miguel A. Ruiz, Daniel García-Vivó, S. Halut, 2012 .

Synthesis of the triply-bonded dimolybdenum anions [Mo(2)(eta(5)-C(5)H(5))(2)(mu-PA(2))(mu-CO)(2)](-) (A = Cy, Et, Ph, OEt): unsaturated hydride and carbyne derivatives.

Miguel A. Ruiz, Alberto Ramos, M. E. García, 2009, Dalton transactions.

Chemistry of Highly Electrophilic Binuclear Cations. 3. Reactivity of [W~2(eta^5-C~5H~5)~2(mu-CO)(CO)~2(mu-Ph~2PCH~2PPh~2)] [B-{3,5-C~6H~3(CF~3)~2}~4]~2 toward Small Donor Molecules

Miguel A. Ruiz, V. Riera, M. Alvarez, 2004 .

Ten-electron coordination and reactivity of an arylphosphinidene ligand.

Miguel A. Ruiz, T. Riis-Johannessen, J. Jeffery, 2003, Journal of the American Chemical Society.

Chemistry of Highly Electrophilic Binuclear Cations. 2. Oxidation Reactions of [W2(η5-C5H5)2(CO)4(μ-Ph2PCH2PPh2)] with [FeCp2][B{3,5-C6H3(CF3)2}4]

Miguel A. Ruiz, J. Vaissermann, M. Alvarez, 2003 .

High yield synthesis and reactivity of a phosphinidene bridged dimolybdenum complex.

Miguel A. Ruiz, J. Vaissermann, J. Jeffery, 2002, Journal of the American Chemical Society.

CHEMISTRY OF HIGHLY ELECTROPHILIC BINUCLEAR CATIONS. 1. OXIDATION REACTIONS OF M2(ETA 5-C5H5)2(CO)4(MU -PH2PCH2PPH2) (M = MO, W) WITH FECP2X (X = BF4, PF6)

Miguel A. Ruiz, M. Lanfranchi, V. Riera, 1999 .

A Highly Electrophilic Unsaturated Ditungsten Dication

Miguel A. Ruiz, V. Riera, C. Bois, 1993 .

C-C and C-N Couplings Following Hydride Addition on Isocyanide Cyclopolyenyl Dimolybdenum Complexes to Give Tethered Aldimine and Aminocarbene Derivatives.

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2017, Chemistry.

Stepwise hydrogenation of an arylthiophosphinidene isocyanide complex to give tethered aldimine and aminocarbene functions.

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2013, Dalton transactions.

Symmetrization in a phosphinidene-bridged complex to give a diphosphanediyl derivative with metal-centered reactivity.

Miguel A. Ruiz, Daniel García-Vivó, Alberto Ramos, 2012, Inorganic chemistry.

A thiophosphinidene complex as a vehicle in phosphinidene transmetalation: easy formation and cleavage of a P-S bond.

Miguel A. Ruiz, M. Alvarez, M. E. García, 2011, Inorganic chemistry.

High-Yield Synthesis and Reactivity of Stable Diiron Complexes with Bent-Phosphinidene Bridges

Miguel A. Ruiz, J. Jeffery, C. Álvarez, 2005 .

Heterometallic clusters derived from the unsaturated carbyne-bridged dimolybdenum complexes [Mo2(η5-C5H5)2(μ-CPh) (μ-PCy2) (CO)x] (x = 1, 2)

Miguel A. Ruiz, M. Alvarez, Sonia Menéndez, 2015 .

Binuclear Carbyne and Ketenyl Derivatives of the Alkyl-Bridged Complexes [Mo2(η5-C5H5)2(μ-CH2R)(μ-PCy2)(CO)2] (R = H, Ph)

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2011 .

Reactions of the Unsaturated Ditungsten Anion [W2Cp2(μ-PCy2)(μ-CO)2]− with C- and P-Based Electrophiles

Miguel A. Ruiz, M. Vega, Daniel García-Vivó, 2015 .

O‐Protonation at a Neutral Ditungsten Carbonyl Dimer to Give a Stable Hydroxycarbyne Complex

Miguel A. Ruiz, V. Riera, C. Bois, 1996 .

Reactivity of the 30-electron dimolybdenum anion [Mo2(η5-C5H5)2(μ-PCy2)(μ-CO)2]− towards β,γ-unsaturated organic halides: Alkenyl, allenyl and alkoxycarbyne derivatives

Miguel A. Ruiz, Alberto Ramos, M. Alvarez, 2009 .

Chemistry of highly electrophilic binuclear cations. 6. Synthesis of the alkyne-bridged complexes [Mo2(η5-C5H5)2{μ-η2:η2-HC2(p-tol)}(CO)2(μ-L2)][B{3,5-C6H3(CF3)2}4]2 and their isocyanide derivatives (L2 = Ph2PCH2PPh2, Me2PCH2PMe2)

Miguel A. Ruiz, M. Alvarez, M. E. García, 2007 .

Electronic Structure and Reactivity of the Carbyne-Bridged Dimolybdenum Radical [Mo2(η5-C5H5)2(μ-CPh)(μ-PCy2)(μ-CO)]+

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2013 .

Heterometallic derivatives of [Fe2Cp2(μ-PCy)(μ-CO)(CO)2]: rational synthesis of polynuclear complexes from neutral precursors having pyramidal-phosphinidene bridges.

Miguel A. Ruiz, Alberto Ramos, M. Alvarez, 2011, Inorganic chemistry.

Reactions of the unsaturated ditungsten complexes [W2Cp2(μ-PPh2)2(CO)x] (x = 1, 2) with nitric oxide: stereoselective carbonyl displacement and oxygen-transfer reactions of a nitrite ligand.

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2014, Inorganic chemistry.

Dimolybdenum cyclopentadienyl complexes with bridging chalcogenophosphinidene ligands.

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2012, Inorganic chemistry.

A glimpse into the chemical reactivity of the unsaturated hydride [MoWCp2(H)(μ-PCy2)(CO)2]

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2021 .

Reactivity of the unsaturated dimolybdenum anion [Mo2(η5-C5H5)2(μ-PCy2)(μ-CO)2]― towards electrophiles based on p- and d-block elements

Miguel A. Ruiz, Alberto Ramos, M. Alvarez, 2010 .

Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 6. C−E Bond Formation and C−O Bond Cleavage Processes in the Reactions of [Mo2(η5-C5H5)2(μ-COMe)(μ-PCy2)(μ-CO)] with Several p-Block Elements (E) and Their Hydride Derivatives

Miguel A. Ruiz, Daniel García-Vivó, M. García, 2010 .

Chemistry of CS2- and SCNPh-adducts of the pyramidal phosphinidene-bridged complex [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(CO)2(η6-HMes*)(PMe3)].

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2017, Dalton transactions.

Insertion, Rearrangement, and Coupling Processes in the Reactions of the Unsaturated Hydride Complex [W2(η5-C5H5)2(H)(μ-PCy2)(CO)2] with Isocyanides

Miguel A. Ruiz, M. Vega, Daniel García-Vivó, 2013 .

P–C, P–N, and M–N Bond Formation Processes in Reactions of Heterometallic Phosphinidene-Bridged MoMn and MoRe Complexes with Diazoalkanes and Organic Azides to Build Three- to Five-Membered Phosphametallacycles

Miguel A. Ruiz, M. Alvarez, M. E. García, 2022, Inorganic chemistry.

Efficient Synthesis and Multisite Reactivity of a Phosphinidene-Bridged Mo-Re Complex. A Platform Combining Nucleophilic and Electrophilic Features.

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2020, Inorganic chemistry.

Coordination and Dehydrogenation of Diphosphine-Borane Ph2PCH2PPh2·BH3 at a Heterometallic MoRe Center to Give an Agostic Boryl-Bridged Derivative.

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2019, Inorganic chemistry.

C–C and C–N Couplings in Reactions of the Benzylidyne-Bridged Complex [Mo2Cp2(μ-CPh)(μ-PCy2)(CO)2] with Small Unsaturated Organics

Miguel A. Ruiz, Daniel García-Vivó, Sonia Menéndez, 2016 .

Multisite Reactivity of the Central Mo2CP Core in the Unsaturated Carbyne-Bridged Complex [Mo2(η5-C5H5)2(μ-CPh)(μ-PCy2)(CO)2]

Miguel A. Ruiz, M. Alvarez, M. García, 2011 .

Hydride, gold(i) and related derivatives of the unsaturated ditungsten anion [W2Cp2(μ-PCy2)(μ-CO)2](-).

Miguel A. Ruiz, M. Vega, Daniel García-Vivó, 2014, Dalton transactions.

Site-Selectivity in the Protonation and Related Reactions of Chalcogenophosphinidene-Bridged Dimolybdenum Cyclopentadienyl Complexes

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2014 .

Nitrosyl derivatives of the unsaturated dihydrides [Mn2(μ-H)2(CO)6(μ-L2)] (L2 = Ph2PCH2PPh2, (EtO)2POP(OEt)2)

Miguel A. Ruiz, L. Marchiò, A. Tiripicchio, 2011 .

Activation of H-H and H-O bonds at phosphorus with diiron complexes bearing pyramidal phosphinidene ligands.

Miguel A. Ruiz, Daniel García-Vivó, Alberto Ramos, 2012, Inorganic chemistry.

Thermally Stable Diazoalkane Derivatives of the Unsaturated Ditungsten Hydride [W2Cp2(H)(μ-PCy2)(CO)2]

Miguel A. Ruiz, M. Vega, Daniel García-Vivó, 2015 .

Structural and Chemical Effects of the PtBu2 Bridge at Unsaturated Dimolybdenum Complexes Having Hydride and Hydrocarbyl Ligands.

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2017, Inorganic chemistry.

Structure and Bonding in the Unsaturated Hydride- and Hydrocarbyl-Bridged Complexes [Mo2(η5-C5H5)2(μ-X)(μ-PCy2)(CO)2] (X = H, CH3, CH2Ph, Ph). Evidence for the Presence of α-Agostic and π-Bonding Interactions†

Miguel A. Ruiz, M. Lanfranchi, L. Marchiò, 2007 .

Synthesis and DFT Study of a Diphenylsilanone-Bridged Dimolybdenum Complex.

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2016, Chemistry.

E-H Bond Activation and Insertion Processes in the Reactions of the Unsaturated Hydride [W2Cp2(μ-H)(μ-PPh2)(NO)2].

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2018, Inorganic chemistry.

Hydrogen Atom Transfer Reactions of the Unsaturated Hydroxycarbyne Complex [W2Cp2(μ-COH)(μ-PPh2)2]BF4

Miguel A. Ruiz, C. Graiff, Daniel García-Vivó, 2013 .

Low-temperature N-O bond cleavage and reversible N-P bond formation processes in the reactions of the unsaturated anions [M2(η5-C5H5)2(μ-PCy2)(μ-CO)2]- (M = Mo, W) with the nitrosyl complex [Re(η5-C5H4Me)(CO)2(NO)]+.

Miguel A. Ruiz, M. Vega, M. Alvarez, 2013, Inorganic chemistry.

C-X bond formation and cleavage in the reactions of the ditungsten hydride complex [W2(η5-C5H5)2(H)(μ-PCy2)(CO)2] with small molecules having multiple C-X bonds (X = C, N, O).

Miguel A. Ruiz, M. Vega, M. Alvarez, 2011, Dalton transactions.

Chemistry of the oxophosphinidene ligand. 2. Reactivity of the anionic complexes [MCp{P(O)R*}(CO)(2)](-) (M = Mo, W; R* = 2,4,6-C(6)H(2)(t)Bu(3)) toward electrophiles based on elements different from carbon.

Miguel A. Ruiz, J. Jeffery, M. Alvarez, 2010, Inorganic Chemistry.

Chemistry of the oxophosphinidene ligand. 1. Electronic structure of the anionic complexes [MCp{P(O)R*}(CO)(2)](-) (M = Mo, W; R* = 2,4,6-C(6)H(2)(t)Bu(3)) and their reactions with H(+) and C-based electrophiles.

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2010, Inorganic chemistry.

Synthesis and Reactivity of the Triply Bonded Binuclear Anion [W2(η5-C5H5)2(μ-PCy2)(μ-CO)2]−: Tungsten Makes a Difference

Miguel A. Ruiz, M. Vega, Daniel García-Vivó, 2010 .

Low-temperature N-O bond cleavage of nitrogen monoxide in heterometallic carbonyl complexes. An experimental and theoretical study.

Miguel A. Ruiz, R. López, L. Marchiò, 2008, Inorganic Chemistry.

Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 4. Carbonyl, Isocyanide, and Diphosphine Derivatives of the Complexes [M2(η5-C5H5)2(μ-COMe)(μ-PR2)2]BF4 (M = W, R = Ph; M = Mo, R = Et)

Miguel A. Ruiz, P. Herson, Daniel García-Vivó, 2008 .

Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 1. Synthesis, Structure, and Bonding of 30-Electron Complexes

Miguel A. Ruiz, S. Alvarez, G. Aullón, 2007 .

M-P versus M=M bonds as protonation sites in the organophosphide-bridged complexes [M2Cp2(mu-PR2)(mu-PR'2)(CO)2], (M = Mo, W; R, R' = Ph, Et, Cy).

Miguel A. Ruiz, J. Vaissermann, Alberto Ramos, 2006, Inorganic Chemistry.

Miguel A. Ruiz, M. Alvarez, M. E. García, 2014, Inorganic chemistry.

Oxidative Additions of Coordinated Ligands at Unsaturated Molybdenum and Tungsten Diphosphine-Bridged Carbonyl Dimers. 1. Decarbonylation Reactions of [W2(η5-C5H5)2(CO)4(μ-R2PCH2PR2)] (R = Ph, Me)†

Miguel A. Ruiz, L. Falvello, C. Bois, 1997 .

Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 57. Reactions of iron–molybdenum complexes with oxygen and sulphur; crystal structure of [FeMo(µ-η2-SCC6H4Me-4)(CO)5(η-C5H5)]

P. Sherwood, J. Jeffery, F. Stone, 1987 .

Methylene, oxygen, and sulphur addition to a µ-alkylidyne ligand in an iron–molybdenum complex: X-ray crystal structures of [FeMo{µ-σ,η-C(C6H4Me-4)CH2}(µ-CH2)(CO)5(η-C5H5)], [FeMo{µ-η3-C(C6H4Me-4)C(OMe)C(H)}(CO)5(η-C5H5)], and [FeMo{µ-η-SC(C6H4Me-4)}(CO)5(η-C5H5)]

P. Sherwood, J. Jeffery, F. Stone, 1986 .

Fast and Reversible Intramolecular Cleavage of an Au−C Bond in the Spiked-Triangular Metal Complexes [Fe3Au(μ4,η2-C⋮CtBu)(CO)9(PR3)] (R = Ph, iPr)

Miguel A. Ruiz, F. Zamora, B. Donnadieu, 2002 .

Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 56. Synthesis of iron–molybdenum compounds; crystal structures of [FeMo(µ-CR)(CO)6(η-C5H5)] and [FeMo2(µ3-RC2R)(CO)6(η-C5H5)2](R = C6H4Me-4)

P. Sherwood, J. Jeffery, F. Stone, 1987 .

N O Bond Activation and Cleavage Reactions of the Nitrosyl-Bridged Complexes [ M 2 Cp 2 (-PCy 2 ) (-NO )

Daniel García-Vivó, Alberto Ramos, M. Alvarez, 2019 .

Mild N-O Bond Cleavage Reactions of a Pyramidalized Nitrosyl Ligand Bridging a Dimolybdenum Center.

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2015, Inorganic chemistry.

Low-temperature N-O bond cleavage in nitrosyl ligands induced by the unsaturated dimolybdenum anion [Mo2(eta(5)-C5H5)2(mu-PPh2)(mu-CO)2]-.

Miguel A. Ruiz, C. Graiff, Daniel García-Vivó, 2009, Inorganic chemistry.

Protonation Reactions on the Binuclear Complexes [W2Cp2(CO)n(μ-L2)] [L2= Ph2PCH2PPh2, Me2PCH2PMe2;n= 2, 4]. Chemical Behavior of Their Hydrido and Hydroxycarbyne Derivatives

Miguel A. Ruiz, M. Alvarez, M. E. García, 1999 .

Carbyne–Carbyne Coupling and H-Shifts in Reactions of the Unsaturated Methoxy- and Hydroxycarbyne Complexes [Mo2Cp2(μ-COR)(μ-CPh)(μ-PCy2)]+ with CO and Isocyanides

Miguel A. Ruiz, M. Alvarez, Sonia Menéndez, 2015 .

Chemical and Structural Effects of Bulkness on Bent-Phosphinidene Bridges: Synthesis and Reactivity of the Diiron Complex [Fe2Cp2{μ-P(2,4,6-C6H2tBu3)}(μ-CO)(CO)2]

Miguel A. Ruiz, Alberto Ramos, M. Alvarez, 2010 .

Migration and Insertion Processes in the Reactions of the Hydrocarbyl-Bridged Unsaturated Complexes [Mo2(η5-C5H5)2(μ-R)(μ-PCy2)(CO)2] (R = Me, CH2Ph, Ph) with CO and NO

Miguel A. Ruiz, Alberto Ramos, M. Alvarez, 2009 .

Alkenyl Derivatives of the Unsaturated Dimolybdenum Hydride Complex [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2]

Miguel A. Ruiz, A. Lanfranchi, A. Tiripicchio, 2007 .

Reactivity of the Unsaturated Hydride [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2] toward P-Donor Bidentate Ligands and Unsaturated N-Containing Organic Molecules

Miguel A. Ruiz, Alberto Ramos, M. Alvarez, 2007 .

Reactivity of the Unsaturated Hydride [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2] toward 17- and 16-Electron Metal Carbonyl Fragments: Rational Synthesis of Electron-Deficient Heterometallic Clusters

Miguel A. Ruiz, C. Graiff, C. Álvarez, 2007 .

A Triply Bonded Dimolybdenum Hydride Complex with Acid, Base and Radical Activity

Miguel A. Ruiz, M. Lanfranchi, C. Álvarez, 2005 .

Dehydrogenation, Methyl Elimination and Insertion Reactions of the Agostic Methyl-Bridged Complex [Mo2 Cp2 (μ-κ1 :η2 -CH3 )(μ-PtBu2 )(μ-CO)].

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2018, Chemistry.

Mild P-P bond cleavage in the methyldiphosphenyl complex [Mo2Cp2(μ-PCy2)(μ-κ(2):κ(2)-P2Me)(CO)2] to give novel phosphide-bridged trinuclear derivatives.

Miguel A. Ruiz, Daniel García-Vivó, Alberto Ramos, 2014, Inorganic chemistry.

Reactivity of the α-Agostic Methyl Bridge in the Unsaturated Complex [Mo2(η5-C5H5)2(μ-η1:η2-CH3)(μ-PCy2)(CO)2]: Migratory Behavior and Methylidyne Derivatives

Miguel A. Ruiz, Daniel García-Vivó, Alberto Ramos, 2008 .

Reactivity of the anionic diphosphorus complex [Mo2Cp2(μ-PCy2)(CO)2(μ-κ2:κ2-P2)]- toward ER3X electrophiles (E = C to Pb): insights into the multisite donor ability and dynamics of the P2 ligand.

Miguel A. Ruiz, Daniel García-Vivó, Alberto Ramos, 2012, Inorganic chemistry.

Divergent Reactivity of a Phosphinidene-Bridged Dimolybdenum Complex Toward 1-Alkynes: P–C, P–H, C–C, and C–H Couplings

Miguel A. Ruiz, Daniel García-Vivó, M. E. García, 2017 .

Tetranuclear phosphide- and phosphinidene-bridged derivatives of the diphosphenyl complex [Mo2Cp2(μ-PCy2)(μ-κ(2):κ(2)-P2Me)(CO)2].

Miguel A. Ruiz, Alberto Ramos, M. Alvarez, 2015, Inorganic chemistry.

Mild P4 activation to give an anionic diphosphorus complex with a dual binding ability at a single P site.

Miguel A. Ruiz, Daniel García-Vivó, Alberto Ramos, 2011, Inorganic chemistry.

Reactivity of the Phosphinidene-Bridged Complexes [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(η6-1,3,5-C6H3tBu3)(CO)2] and [Mo2Cp2(μ-PH)(η6-1,3,5-C6H3tBu3)(CO)2] toward Alkynes: Multicomponent Reactions in the Presence of Ligands

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2012 .

A Versatile and Unprecedented Triply Bonded Dimolybdenum Carbonyl Anion

Miguel A. Ruiz, C. Graiff, V. Riera, 2003 .

Reversible intramolecular carbon-hydrogen oxidative addition of cyclopentadienyl ligands at ditungsten(I) centers. A general intermediate step in the way to unsaturated dimetal cyclopentadienyl carbonyl complexes?

Miguel A. Ruiz, V. Riera, C. Bois, 1993 .

Reactivity of the anionic diphosphorus complex [Mo2Cp2(μ-PCy2)(μ-κ(2):κ(2)-P2)(CO)2]- toward phosphorus- and transition metal-based electrophiles.

Miguel A. Ruiz, Daniel García-Vivó, Alberto Ramos, 2013, Inorganic chemistry.

Synthesis of the Unsaturated [MMoCp(µ‐PR2)(CO)5]– Anions (M = Mn, R = Ph; M = Re, R = Cy): Versatile Precursors of Heterometallic Complexes

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2017 .

Chemistry of Highly Electrophilic Binuclear Cations. 5. Addition and C−C and C−P Coupling Processes in the Reactions of 1-Alkynes with the Dimolybdenum Radicals [Mo2(η5-C5H5)2(μ-CO)2(CO)2(μ-L2)][B{3,5-C6H3(CF3)2}4] (L2 = Ph2PCH2PPh2 or Me2PCH2PMe2)

Miguel A. Ruiz, J. Vaissermann, M. Alvarez, 2005 .

Reactivity of the Carbyne Complexes [W2(μ-COR)(η5-C5H5)2(CO)2(μ-Ph2PCH2PPh2)]+ (R = H, Me) toward Diazomethane

Miguel A. Ruiz, M. Alvarez, F. Robert, 2002 .

[Mo2(η5-C5H5)2(μ-PPh2)(CO)4], a Reactive 33-Electron Binuclear Radical

Miguel A. Ruiz, M. Lanfranchi, V. Riera, 1999 .

Chemistry of the phosphinidene oxide ligand.

Miguel A. Ruiz, J. Jeffery, M. E. García, 2004, Journal of the American Chemical Society.

Nucleophilic behaviour of dioxo- and thiooxophosphorane complexes [MoCp(CO)2{E,P-EP(O)(2,4,6-C6H2(t)Bu3)}](-) (E = O, S).

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2014, Dalton transactions.

Diphosphorus-bridged heterometallic anions and hydrides derived from reactions of complex [Mo2Cp2(μ-PCy2)(μ-κ2:κ2-P2)(CO)2]− with precursors of 16-electron metal carbonyl fragments

Miguel A. Ruiz, Alberto Ramos, M. Alvarez, 2015 .

Alkyne to carbyne coupling reactions of the unsaturated methoxycarbyne-bridged complex [Mo2(η5-C5H5)2(μ-COMe)(μ-PCy2)(CO)2]

Miguel A. Ruiz, Daniel García-Vivó, M. García, 2010 .

Electronic Structure and Donor Ability of an Unsaturated Triphosphorus-Bridged Dimolybdenum Complex

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2021, Inorganic chemistry.

Dimolybdenum−Tin Derivatives of the Unsaturated Hydride [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2] and HSnR3(R = Ph, Bu): Bridging versus Terminal Coordination of the Triorganostannyl Group

Miguel A. Ruiz, Alberto Ramos, M. Alvarez, 2006 .

Chemistry of a Nitrosyl Ligand κ:η-Bridging a Ditungsten Center: Rearrangement and N–O Bond Cleavage Reactions

Miguel A. Ruiz, L. Falvello, Daniel García-Vivó, 2022, Inorganic chemistry.

The doubly-bonded ditungsten anion [W2Cp2(μ-PPh2)(NO)2](-): an entry to the chemistry of unsaturated nitrosyl complexes.

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2016, Dalton transactions.

Synthesis and Decarbonylation Reactions of Diiron Cyclopentadienyl Complexes with Bent-Phosphinidene Bridges

Miguel A. Ruiz, Alberto Ramos, M. Alvarez, 2011 .

Structure, Bonding, and Reactivity of Binuclear Complexes Having Asymmetric Trigonal Phosphinidene Bridges: Addition of 16-Electron Metal Carbonyl Fragments to the Dimolybdenum Compounds [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(CO)2L] and [Mo2Cp2(μ-PH)(CO)2L] (L = η6-1,3,5-C6H3tBu3)§

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2010 .

Reactions of the Phosphinidene-Bridged Complexes [Fe2(η5-C5H5)2(μ-PR)(μ-CO)(CO)2] (R = Cy, Ph, 2,4,6-C6H2tBu3) with Diazoalkanes. Formation and Rearrangements of Phosphadiazadiene-Bridged Derivatives†

Miguel A. Ruiz, M. Alvarez, Rocío González, 2010 .

Aurophilic self-assembly of a Mo4Au2 phosphinidene complex with an unprecedented H-shaped planar metal core.

Miguel A. Ruiz, M. Alvarez, M. E. García, 2008, Inorganic chemistry.

Nucleophilic and Electrophilic Behavior of the Phosphinidene-Bridged Complex [Fe2(η5-C5H5)2(μ-PCy)(μ-CO)(CO)2]

Miguel A. Ruiz, M. Alvarez, Rocío González, 2008 .

Carbene- and carbyne-like behavior of the Mo-P multiple bond in a dimolybdenum complex inducing trigonal-pyramidal coordination of a phosphinidene ligand.

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2007, Inorganic chemistry.

Formation and Cleavage of P-C, Mo-C, and C-H Bonds Involving Arylphosphinidene and Cyclopentadienyl Ligands at Dimolybdenum Centers

Miguel A. Ruiz, J. Jeffery, M. E. García, 2006 .

Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 77. Reactions of iron–molybdenum compounds with alkynes; crystal structures of [MoFe{µ-C(C6H4Me-4)C(CHMe)CH2C(Me)C(Me)}(CO)4(η-C5H5)], [MoFe{µ-C(C6H4Me-4)C(CHMe)CH2}(CO)5(η-C5H5)], and [MoFe{µ-C(C6H4Me-4)C(CH2PMe

P. Sherwood, J. Jeffery, F. Stone, 1988 .

Cycloaddition Reactions of the Phosphinidene-Bridged Complex [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(CO)2(η6-HMes*)] with Diazoalkanes and Other Heterocumulenes.

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2016, Inorganic chemistry.

Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 69. Reactions of [MoW(CC6H4Me-4)(CO)7(η-C5H5)] with but-2-yne; crystal structures of [MoW{µ-C(C6H4Me-4)C(Me)C(Me)}(CO)3(η-MeC2Me)2(η-C5H5)] and [MoW{µ-C(C6H4Me-4)C(CH2)C(H)MeC(O)}(CO)6(η-C5H5)]·0.5CH2Cl2

P. Sherwood, J. Jeffery, F. Stone, 1988 .

Chalcogenoacyl-bridged derivatives of the unsaturated carbyne complex [Mo 2 ( η 5 -C 5 H 5 ) 2 ( μ -CPh)( μ -PCy 2 )(CO) 2 ]

Miguel A. Ruiz, M. Alvarez, Sonia Menéndez, 2017 .

Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 3. Formation and Cleavage of C−C and C−O Bonds in the Reactions of the Complexes [Mo2Cp2(µ-COMe)(µ-COR)(µ-PCy2)]BF4(R = Me, Et)

Miguel A. Ruiz, Daniel García-Vivó, M. E. García, 2008 .

Formation and Cleavage of C−C, C−O, and O−H Bonds Involving Methoxycarbyne and Hydroxycarbyne Ligands at Unsaturated Dimolybdenum Complexes

Miguel A. Ruiz, Daniel García-Vivó, C. Álvarez, 2005 .

Different Coordination Modes of a Tripod Phosphine in Gold(I) and Silver(I) Complexes

P. Sadler, A. Habtemariam, S. Parsons, 1999, Metal-based drugs.

Homonuclear PdII and PtII and heteronuclear PdII-AuI and PtII-AuI complexes of a tripod triphosphine ligand: synthesis, characterization and reactions with molecules of biological relevance

P. Sadler, A. Habtemariam, M. Seijo, 2000 .

Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 57. Reactions of Iron-Molybdenum Complexes with Oxygen and Sulfur; Crystal Structure of (FeMo(.mu±eta.2-SCC6H4Me-4)(CO)5(η-C5H5)).

P. Sherwood, J. Jeffery, F. Stone, 1987 .

Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 64. Addition of methylene groups to iron–molybdenum complexes; crystal structures of [FeMo(µ-CH2){µ-σ:η-C(C6H4Me-4)CH2}(CO)5(η-C5H5)] and [FeMo{µ-C(C6H4Me-4)C(OMe)C(H)}(CO)5(η-C5H5)]

P. Sherwood, J. Jeffery, F. Stone, 1987 .

Reactions of Heterometallic Phosphinidene-Bridged MoMn and MoRe Complexes with Sulfur and Selenium: From Chalcogenophosphinidene- to Trithiophosphonate-Bridged Derivatives

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2023, Inorganic chemistry.

Sn–H bond additions to asymmetric trigonal phosphinidene-bridged dimolybdenum complexes

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2017 .

Cycloaddition and C–S Bond Cleavage Processes in Reactions of Heterometallic Phosphinidene-Bridged MoRe and MoMn Complexes with Alkynes and Phenyl Isothiocyanate

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2023, Organometallics.

Phosphinidene-Bridged MoMn Derivatives of the Thiophosphinidene Complex [Mo2Cp2(μ-κ2:κ1,η6-SPMes*)(CO)2] (Mes* = 2,4,6-C6H2tBu3).

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2018, Inorganic chemistry.

Acetonitrile Adduct [MoReCp(μ-H)(μ-PCy2)(CO)5(NCMe)]: A Surrogate of an Unsaturated Heterometallic Hydride Complex.

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2018, Inorganic chemistry.

C-H Cleavages in the Photoreactions of [M2(.eta.5-C5H5)2(CO)6] (M = Mo, W): Isolation and Characterization of the V-Shaped Trinuclear Clusters [M2M'(.mu.-.eta.1,.eta.5-C5H4)(.eta.5-C5H5)2(CO)6] (M, M' = Mo or W)

Miguel A. Ruiz, V. Riera, C. Bois, 1995 .

P C coupling reactions of pyramidal phosphinidene-bridged dimolybdenum complexes with alkynes

Miguel A. Ruiz, M. Alvarez, M. E. García, 2020 .

P-N and N-Mo Bond Formation Processes in the Reactions of a Pyramidal Phosphinidene-Bridged Dimolybdenum Complex with Diazoalkanes and Organic Azides.

Miguel A. Ruiz, Daniel García-Vivó, M. Alvarez, 2020, Inorganic chemistry.

Methylmercury(II) complexes with 2-mercaptopyridinecarboxylic acids

J. Casas, L. Thunus, J. Sordo, 1992 .

Hydride, Gold(I) and Related Derivatives of the Unsaturated Ditungsten Anion [W 2 Cp 2 (  -PCy 2 )(  - CO) 2 ]  †

Miguel A. Ruiz, M. Vega, Daniel García-Vivó, 2016 .