P. Spagnolo

发表

Radical allylations by reaction of azides with allylindium dichloride.

G. Zanardi, D. Nanni, Giorgio Bencivenni, 2010, Organic & biomolecular chemistry.

From azides to nitrogen-centered radicals: applications of azide radical chemistry to organic synthesis.

D. Nanni, M. Minozzi, P. Spagnolo, 2009, Chemistry.

A New Entry to Benzo(4,5)furo(3,2-b)pyridines via N-(Benzofuran-3-yl)iminophosphorane

M. Funicello, P. Spagnolo, Valeria Laboragine, 2010 .

DIAZO TRANSFER REACTION OF 2-(TRIMETHYLSILYL)-1,3-DITHIANE WITH TOSYL AZIDE. CARBENIC REACTIVITY OF TRANSIENT 2-DIAZO-1,3-DITHIANE

G. Calestani, D. Nanni, P. Spagnolo, 1997 .

Reactions of tosyl azide with 2-phenoxy- and 2-phenylsulfanyl-2,3-dihydro-1H-indane-1,3-dione. Unexpected reactivity of intermediate 4-acyl-5-hydroxy-1-tosyltriazolines

G. Calestani, P. Montevecchi, P. Spagnolo, 1995 .

Diazo transfer reaction of 2-(trimethylsilyl)-1,3-dithiane with tosyl azide. Reactivity of transient 2-diazo-1,3-dithiane

G. Calestani, P. Montevecchi, P. Spagnolo, 1995 .

One electron transfer reaction of phenyl vinyl sulfides with dioxygen. The fate of the intermediate vinyl sulfide radical cations.

D. Nanni, P. Montevecchi, P. Spagnolo, 1993 .

Intramolecular cyclization of acyl radicals onto the azido group: a new radical approach to cyclized lactams.

G. Zanardi, D. Nanni, M. Minozzi, 2002, Organic letters.

Approach to spirocyclohexadienimines and corresponding dienones through radical ipso cyclization onto aromatic azides.

G. Zanardi, D. Nanni, T. Lanza, 2008, Angewandte Chemie.

Metalation and halogen–metal exchange in 3-arylthiophens

M. Tiecco, P. Spagnolo, R. Leardini, 1970 .

Rotamers of 2,2′-dithienyl and 2-phenylthiophen radical anions

M. Tiecco, G. Pedulli, A. Mangini, 1969 .

A convenient synthesis of azidothiophenes and some of their reactions

P. Zanirato, P. Spagnolo, 1978 .

Cyclizations of N-stannylaminyl radicals onto nitriles.

G. Zanardi, C. Rizzoli, D. Nanni, 2004, Organic letters.

N-(3-Benzo[b]thienyl)iminophosphoranes toward the Synthesis of Benzo[b]thieno[3,2-b]pyridines: Reactivity and Alternative Regioselectivity with α,β-unsaturated Ketones and Aldehydes

M. Funicello, L. Chiummiento, C. Bonini, 2000 .

New entry to benzo[b]thieno[2,3-b]- and benzo[b]thieno-[3,2-b]-pyridines using 2- and 3-azidobenzo[b]thiophene as the nitrogen precursors

A. Degl'innocenti, P. Scafato, P. Zanirato, 1996 .

Reaction of heteroaromatic o-aminothioaldehydes with alkynes: a novel entry to b-fused pyridines

A. Degl'innocenti, P. Scafato, M. Funicello, 1997 .

Hexamethyldisilathiane: Its Use in the Conversion of Aromatic and Heteroaromatic Azides to Amines

A. Degl'innocenti, A. Capperucci, P. Scafato, 1995 .

Reaction of azides with dichloroindium hydride: very mild production of amines and pyrrolidin-2-imines through possible indium-aminyl radicals.

G. Zanardi, D. Nanni, Giorgio Bencivenni, 2006, Organic letters.

Reduction of azides to amines by samarium diiodide

D. Nanni, P. Montevecchi, P. Spagnolo, 1995 .

Conformational Studies by Dynamic NMR. 58.(1) Stereodynamics of C-C and C-N Rotation in Furan and Thiophene o-Amino Thioaldehydes and Aldehydes.

A. Mazzanti, A. Degl'innocenti, L. Lunazzi, 1997, The Journal of organic chemistry.

Novel Synthesis of Stable Furan and Thiophene o-Amino Thioaldehydes by Reaction of o-Azido Aldehydes with Hexamethyldisilathiane

A. Degl'innocenti, A. Capperucci, P. Scafato, 1996 .

Cascade radical reactions via alpha-(arylsulfanyl)imidoyl radicals: competitive [4 + 2] and [4 + 1] radical annulations of alkynyl isothiocyanates with aryl radicals.

G. Zanardi, G. Calestani, D. Nanni, 2003, The Journal of organic chemistry.

Diazo transfer reactions of tosyl azide with carbocyclic β-ketoesters: production and decomposition of ring-openedN-tosylcarbamoyl-substituted α-diazo esters

D. Nanni, P. Spagnolo, L. Benati, 1997 .

Tin-free generation of alkyl radicals from alkyl 4-pentynyl sulfides via homolytic substitution at the sulfur atom.

G. Zanardi, D. Nanni, Giorgio Bencivenni, 2008, Organic letters.

Generation and cyclization of unsaturated carbamoyl radicals derived from S-4-pentynyl carbamothioates under tin-free conditions.

G. Zanardi, D. Nanni, Giorgio Bencivenni, 2006, The Journal of organic chemistry.

Generation and intramolecular reactivity of acyl radicals from alkynylthiol esters under reducing tin-free conditions.

G. Calestani, D. Nanni, M. Minozzi, 2003, Organic letters.

PMR investigation of organic cations—I: Trithienyl methyl carbonium ions

F. Taddei, M. Tiecco, P. Spagnolo, 1970 .

Imidoyl Radicals in Organic Synthesis

D. Nanni, M. Minozzi, P. Spagnolo, 2007 .

A novel tin-free procedure for alkyl radical reactions.

G. Zanardi, D. Nanni, M. Minozzi, 2004, Angewandte Chemie.

Thermal reactions of tributyltin hydride with alpha-azido esters: unexpected intervention of tin triazene adducts under both nonradical and radical conditions.

G. Zanardi, D. Nanni, Giorgio Bencivenni, 2005, The Journal of organic chemistry.

Radical reduction of aromatic azides to amines with tributylgermanium hydride.

G. Zanardi, D. Nanni, Giorgio Bencivenni, 2006, The Journal of organic chemistry.

Radical reduction of aromatic azides to amines with triethylsilane.

G. Zanardi, D. Nanni, Giorgio Bencivenni, 2006, The Journal of organic chemistry.

A Study of Vinyl Radical Cyclization onto the Azido Group by Addition of Sulfanyl, Stannyl, and Silyl Radicals to Alkynyl Azides☆

M. L. Navacchia, P. Montevecchi, P. Spagnolo, 1998 .

Organosilanes-Mediated Synthesis and Reactivity of Thiocarbonyl-Containing Molecules

A. Degl'innocenti, A. Capperucci, P. Scafato, 1997 .

Hexamethyldisilathiane: Its Use in the Conversion of Aromatic and Heteroaromatic Azides to Amines.

A. Degl'innocenti, A. Capperucci, P. Scafato, 1995 .

Radical Chain Reactions of α-Azido-β-keto Esters with Tributyltin Hydride. A Novel Entry to Amides and Lactams through Regiospecific Nitrogen Insertion

D. Nanni, P. Spagnolo, L. Benati, 1999 .

Aliphatic CH, N-insertion versus aromatic N-substitution in the reaction of arylnitrenium-boron trifluoride complexes with methylated benzenes

P. Zanirato, P. Spagnolo, 1987 .

ATTEMPTS AT VINYL RADICAL CARBONYLATION THROUGH CYCLIZATION ONTO CARBONYL AND CYANO GROUPS

M. L. Navacchia, P. Montevecchi, P. Spagnolo, 1998 .

Ylide formation and rearrangement in the thermal reaction of 6H-dibenzo[b,d]thiopyran and its 6-phenyl derivative with diazoalkanes

P. Montevecchi, P. Spagnolo, L. Benati, 1982 .

Thermal reactivity of tricyclic 4,5-diacyltriazolines resulting from addition of aryl azides to 1,4-naphthoquinone and 2-methyl-1,4-naphthoquinone

P. Montevecchi, P. Spagnolo, L. Benati, 1991 .

Radical chain reactions of α-azido ketones with tributyltin hydride: Reduction vs nitrogen insertion and 1,2-hydrogen shift in the intermediate N-stannylaminyl radicals

G. Zanardi, G. Calestani, D. Nanni, 2002 .

Iminyl radicals from alpha-azido o-iodoanilides via 1,5-H transfer reactions of aryl radicals: new transformation of alpha-azido acids to decarboxylated nitriles.

G. Zanardi, D. Nanni, Giorgio Bencivenni, 2008, The Journal of organic chemistry.

Generation of Iminyl Radicals through Sulfanyl Radical Addition to Vinyl Azides

P. Montevecchi, P. Spagnolo, and Maria Luisa Navacchia, 1997 .

Structural effects on the reactivity of carbon radicals in homolytic aromatic substitutions. Part III. Reaction of the 1-adamantyl radical with benzene derivatives

M. Tiecco, P. Zanirato, L. Testaferri, 1976 .

Reactions of Benzocyclic β-Keto Esters with Sulfonyl Azides. 2.1 Further Insight into the Influence of Azide Structure and Solvent on the Reaction Course.

D. Nanni, P. Spagnolo, L. Benati, 1999, The Journal of organic chemistry.

Reactions of Benzocyclic β-Keto Esters with Tosyl and 4-Nitrophenyl Azide. Structural Influence of Dicarbonyl Substrate and Azide Reagent on Distribution of Diazo, Azide and Ring-Contraction Products†

G. Calestani, D. Nanni, P. Spagnolo, 1998 .

A Novel Synthesis of Fused Isothiazole Ring Systems

A. Degl'innocenti, A. Capperucci, P. Scafato, 1994 .

Unusual Radical Acceptors

D. Nanni, P. Spagnolo, 2012 .

Reaction of Azides with Dichloroindium Hydride: Very Mild Production of Amines and Pyrrolidin-2-imines Through Possible Indium—Aminyl Radicals.

G. Zanardi, D. Nanni, Giorgio Bencivenni, 2006 .

Cyclizations of N-stannylaminyl radicals onto nitriles.

G. Zanardi, C. Rizzoli, D. Nanni, 2004, Organic letters.

Synthetic utility of 4′-nitrobenzenesulfenanilide in the functionalization of carbon-carbon double and triple bonds : Its use in the bromosulfenylation of alkenes and alkynes

P. Montevecchi, P. Spagnolo, L. Benati, 1993 .

Radical chain reaction of benzenethiol with pentynylthiol esters-Production of aldehydes under stannane/silane free conditions

G. Zanardi, D. Nanni, M. Minozzi, 2004 .

Free-Radical Addition of Heteroarenethiols and Heteroarylmethanethiols to Hexyne and Phenylacetylene. Chemical Behavior of the Transient .beta.-Sulfanylvinyl Radicals

P. Montevecchi, P. Spagnolo, L. Capella, 1995 .

Free-Radical Addition of Alkanethiols to Alkynes. Rearrangements of the Intermediate .beta.-(Vinylthio) Radicals

P. Montevecchi, P. Spagnolo, L. Capella, 1994 .

Free-radical reactions of benzenethiol and diphenyl disulphide with alkynes. Chemical reactivity of intermediate 2-(phenylthio)vinyl radicals

P. Montevecchi, P. Spagnolo, L. Benati, 1991 .

General route for the facile transformation of ortho-substituted lithiobithienyls into amino derivatives

S. Gronowitz, P. Zanirato, P. Spagnolo, 1982 .

Thermal reactions of aryl azides with trans-1,2-dibenzoyl- and trans-1,2-diacetyl-ethylene. Reactivity of 4,5-dibenzoyl- and 4,5-diacetyl-1-aryltriazolines

P. Montevecchi, P. Spagnolo, L. Benati, 1989 .

Reduction of Azides to Amines by Samarium Diiodide.

D. Nanni, P. Montevecchi, P. Spagnolo, 1996 .

One-pot preparation of isomeric acetyl- and 2,2,2-trifluoroacetyl-azidothiophenes by selective bifunctionalization of dibromothiophenes via halogen–lithio exchange

P. Zanirato, P. Spagnolo, 1996 .

2-Cyano-iso-propyl radical addition to alkynes

M. L. Navacchia, P. Montevecchi, P. Spagnolo, 1997 .

Synthetic Applications of Bis(trimethylsilyl)sulfide: Part II. Synthesis of Aromatic and Heteroaromatic o-Azido-Thioaldehydes

A. Degl'innocenti, A. Capperucci, P. Scafato, 1995 .

Thermal reactivity of 2-azido- and 3-azido-benzo[b]thiophene with alkenes

P. Zanirato, M. Funicello, P. Spagnolo, 1990 .

Synthesis and thermal ring-cleavage fragmentation of 2-azido-1-methylindole and 2-azidobenzo[b]furan

E. Foresti, P. Zanirato, P. Spagnolo, 1989 .

Formation of thiochromans by cycloaddition reactions of the enethione resulting from thermal ring-cleavage fragmentation of 2-azidobenzo[b]thiophene with olefins

P. Zanirato, P. Spagnolo, 1985 .

Intramolecular cyclizations and ring-cleavage reactions of five-membered heteroarylnitrenes and their precursors

G. Consiglio, M. Chanon, P. Zanirato, 1993 .

Boron trifluoride-promoted reaction of 4′-nitrobenzenesulphenanilide with alkynes. Formal addition of benzenesulphenyl fluoride to carbon–carbon triple bonds

P. Montevecchi, P. Spagnolo, L. Benati, 1990 .

Nucleophilic character of bridgehead free radicals

M. Tiecco, P. Zanirato, A. Mangini, 1972 .

Photochemical production of the electrophilic cyano-radical: homolytic aromatic cyanation

M. Tiecco, L. Testaferri, P. Spagnolo, 1971 .

Homolytic aromatic substitution by phenylethynyl radicals

M. Tiecco, P. Spagnolo, G. Martelli, 1969 .

Vinyl radicals homolytic aromatic substitution with 1-cyclohex-1-enyl radicals

M. Tiecco, P. Spagnolo, 1968 .

Syntheses and properties of the 2-thienyl cyclopropenium ions

M. Tiecco, L. Testaferri, P. Spagnolo, 1979 .

The reactivity of thieno[3,2-b]thiophen and thieno[2,3-b]thiophen with phenyl radicals

M. Tiecco, L. Testaferri, P. Spagnolo, 1972 .

Homolytic aromatic substitution of heterocyclic compounds. Part V. The phenylation of benzo[b]thiophen and benzo[b]furan

M. Tiecco, A. Tundo, P. Spagnolo, 1972 .

Homolytic aromatic substitution by heterocyclic free radicals. Part II. 3-Thienyl radicals

M. Tiecco, P. Spagnolo, G. Martelli, 1968 .

Boron trifluoride promoted reaction of benzenesulphenanilides with alkenes-arylaminosulphenylation of alkenes.

P. Montevecchi, P. Spagnolo, L. Benati, 1984 .

Intramolecular addition of aryl azides to the azo group. 2. Synthesis and properties of benz[cd]indazole N-arylimines

P. Zanirato, A. Tundo, P. Spagnolo, 1978 .

Improved Radical Approach to N-Unsubstituted Indol-2-one and Dihydro-2-quinolinone Compounds Bearing Spirocyclic Cyclohexanone/Cyclohexadienone Rings

G. Zanardi, D. Nanni, A. Monesi, 2010 .

Radical reduction of aromatic azides to amines with tributylgermanium hydride.

G. Zanardi, D. Nanni, Giorgio Bencivenni, 2006, The Journal of organic chemistry.

Smiles rearrangement for the synthesis of 5-amino-substituted [1]benzothieno[2,3-b]pyridine

M. Funicello, C. Bonini, P. Spagnolo, 2003 .

Smiles Rearrangement for the Synthesis of 5‐Amino‐Substituted [1]Benzothieno[2,3‐b]pyridine.

M. Funicello, C. Bonini, P. Spagnolo, 2004 .

Boron trifluoride-promoted reaction of benzenesulphenanilides with alkenes in acetonitrile and benzonitrile: amidino- and amido-sulphenylation of alkenes

P. Montevecchi, P. Spagnolo, L. Benati, 1987 .

Reaction of diphenyl disulfide with alkynes promoted by di-tert-butyl and dibenzoyl peroxide: a useful synthetic route to 3-(and 2,3-) substituted benzo[b]thiophenes

P. Montevecchi, P. Spagnolo, L. Benati, 1992 .

GENERAL ROUTE FOR THE FACILE TRANSFORMATION OF ORTHO‐SUBSTITUTED LITHIOBITHIENYLS INTO AMINO DERIVATIVES

S. Gronowitz, P. Zanirato, P. Spagnolo, 2002 .

Thermal fragmentation of 2-azidobenzo[b]thiophene in the presence of alkenes: a new synthetic route to 1-(2-benzo[b]thienyl)aziridines and/or thiochroman-4-carbonitriles

P. Zanirato, P. Spagnolo, 1988 .

Thermal decomposition of o-azidobithienyls

G. Zanardi, P. Zanirato, P. Spagnolo, 1984 .

Thiophen-containing radicals. Anions of isomeric dithienylethylenes

M. Tiecco, G. Placucci, L. Lunazzi, 1972 .

Reaction of ortho-Azidohetarenecarbaldehydes with bis(Trimethylsilyl)sulfide. A Novel Route to Fused Isothiazoles

A. Degl'innocenti, P. Scafato, M. Funicello, 1994 .

DIAZO GROUP TRANSFER AND/OR TRIAZOLE FORMATION IN THE REACTION OF TOLUENE-4-SULPHONYL OR 4-NITROPHENYL AZIDE WITH ALPHA -METHYLENE BETA -DICARBONYL CO MPOUNDS IN HEXAMETHYLPHOSPHORIC TRIAMIDE

P. Montevecchi, P. Spagnolo, L. Benati, 1992 .

On the nature of the radical formed from tetraphenyl-p-xylene dichloride and zinc dust

M. Tiecco, G. Pedulli, A. Mangini, 1970 .

A useful method for configurational assignment of vinyl sulfides; stereochemical reassessment of the radical addition of benzenethiol to alkynes

P. Montevecchi, P. Spagnolo, L. Capella, 1995 .

o-N-tosylcarbamoyl-substituted α-diazoacetophenones: their preparation and decomposition

G. Calestani, P. Montevecchi, P. Spagnolo, 1994 .

o‐N‐Tosylcarbamoyl‐Substituted α‐Diazoacetophenones: Their Preparation and Decomposition.

G. Calestani, P. Montevecchi, P. Spagnolo, 1995 .

Synthesis and reactivity of 4-acyl-5-hydroxytriazolines resulting from thermal reaction of aryl and tosyl azides with 2-substituted indane-1,3-diones

E. Foresti, P. Montevecchi, P. Spagnolo, 1992 .

Cascade radical reaction of 2-alkynyl-substituted aryl radicals with aryl isothiocyanates: a novel entry to benzothieno[2,3-b]quinolines through alpha-(Arylsulfanyl)imidoyl radicals.

G. Zanardi, D. Nanni, M. Minozzi, 2000, The Journal of organic chemistry.

An insight into the radical thiol/yne coupling: the emergence of arylalkyne-tagged sugars for the direct photoinduced glycosylation of cysteine-containing peptides.

N. Marchetti, A. Massi, D. Nanni, 2011, The Journal of organic chemistry.