C. Grapperhaus

发表

Density functional theory investigations of NiN2S2 reactivity as a function of nitrogen donor type and N–H···S hydrogen bonding inspired by nickel-containing superoxide dismutase

P. Kozlowski, C. Mullins, C. Grapperhaus, 2006, JBIC Journal of Biological Inorganic Chemistry.

Alkylation-Induced O-Atom Rearrangement in Nickel S-Oxygenates.

M. Darensbourg, J. Reibenspies, C. Grapperhaus, 1998 .

Photocatalytic hydrogen evolution on Si photocathodes modified with bis(thiosemicarbazonato)nickel(ii)/Nafion.

Joshua M. Spurgeon, J. Spurgeon, Sahar Pishgar, 2019, Chemical communications.

Active uptake of hydrophilic copper complex Cu(ii)-TETA in primary cultures of neonatal rat cardiomyocytes.

Zhenghui Luo, Y. J. Kang, Tao Wang, 2019, Metallomics : integrated biometal science.

Metal-centered oxidation decreases nitrile hydration activity of bioinspired (N 2 S 3 )Ru-PPh 3 precatalysts

M. S. Mashuta, Davinder Kumar, C. Grapperhaus, 2015 .

Kinetic effects of sulfur oxidation on catalytic nitrile hydration: nitrile hydratase insights from bioinspired ruthenium(II) complexes.

Davinder Kumar, C. Grapperhaus, Tho N. Nguyen, 2014, Inorganic chemistry.

Sulfur‐Oxygenation and FunctionalModels of Nitrile Hydratase

Davinder Kumar, C. Grapperhaus, 2014 .

Reinvestigation of the first structurally characterized metal-coordinated sulfenic acid complex

Rajat Chauhan, M. S. Mashuta, C. Grapperhaus, 2013 .

Bioinspired catalytic nitrile hydration by dithiolato, sulfinato/thiolato, and sulfenato/sulfinato ruthenium complexes.

César A. Masitas, Davinder Kumar, C. Grapperhaus, 2013, Chemical communications.

Sulfur Oxygenation Enhances Ligand Exchange in Nitrile-Hydratase-Inspired Ruthenium(II) Complexes

César A. Masitas, M. S. Mashuta, C. Grapperhaus, 2013 .

The effect of flue gas contaminants on electrochemical reduction of CO2 to methyl formate in a dual methanol/water electrolysis system

Joshua M. Spurgeon, J. Spurgeon, Manu Gautam, 2022, Chem Catalysis.

Synthesis and sulfur oxygenation of a (N3S)Ni complex related to nickel-containing superoxide dismutase.

Brian C. Frye, C. Mullins, L. Wood, 2009, Inorganic chemistry.

An experimental and computational study of sulfur-modified nucleophilicity in a dianionic NiN2S2 complex.

Roxanne M. Jenkins, M. Darensbourg, K. Green, 2007, Inorganic chemistry.

Oxygen Capture by Sulfur in Nickel Thiolates

M. Darensbourg, C. Grapperhaus, 1998 .

Facet-selective asymmetric functionalization of anisotropic gold nanoprisms for Janus particle synthesis

M. O’Toole, C. Grapperhaus, Emtias Chowdhury, 2020, Journal of Nanoparticle Research.

Reversible methanol addition to copper Schiff base complexes: a kinetic, structural and spectroscopic study of reactions at azomethine C[double bond, length as m-dash]N bonds.

Wuyu Zhang, M. S. Mashuta, R. M. Buchanan, 2016, Dalton transactions.

Rapid scalable fabrication of roll-to-roll slot-die coated flexible perovskite solar cells using intense pulse light annealing

T. Druffel, P. Chandrasekhar, Sashil Chapagain, 2022, Sustainable Energy & Fuels.

Structural, spectroscopic, and computational study of an octahedral, non-heme [Fe-NO](6-8) Series: [Fe(NO)(cyclam-ac)]2+/+/0.

F. Neese, K. Wieghardt, E. Bill, 2004, Journal of the American Chemical Society.

Metal-Assisted Ligand-Centered Electrocatalytic Hydrogen Evolution upon Reduction of a Bis(thiosemicarbazonato)Cu(II) Complex.

Mark S. Mashuta, Craig A. Grapperhaus, Robert M. Buchanan, 2017, Inorganic chemistry.

Metal-stabilized thiyl radicals as scaffolds for reversible alkene addition via C-S bond formation/cleavage.

M. S. Mashuta, C. Grapperhaus, K. Ouch, 2011, Inorganic chemistry.

Singlet diradical character of an oxidized ruthenium trithiolate: electronic structure and reactivity.

Devesh Kumar, P. Kozlowski, C. Grapperhaus, 2007, Angewandte Chemie.

Influence of sequential thiolate oxidation on a nitrile hydratase mimic probed by multiedge X-ray absorption spectroscopy.

J. Shearer, César A. Masitas, C. Grapperhaus, 2012, Inorganic chemistry.

Redox-regulated ethylene binding to a rhenium-thiolate complex.

M. S. Mashuta, C. Grapperhaus, K. Ouch, 2009, Journal of the American Chemical Society.

Carbon-sulfur bond formation between a ruthenium-coordinated thiyl radical and methyl ketones.

M. S. Mashuta, C. Grapperhaus, Selma Poturovic, 2005, Angewandte Chemie.

Antifungal activity of thiosemicarbazones, bis(thiosemicarbazones), and their metal complexes.

R. M. Buchanan, C. Grapperhaus, Kritika Bajaj, 2021, Journal of inorganic biochemistry.

Mononuclear (nitrido)iron(V) and (oxo)iron(IV) complexes via photolysis of [(cyclam-acetato)FeIII(N3)]+ and ozonolysis of [(cyclam-acetato)FeIII(O3SCF3)]+ in water/acetone mixtures.

K Wieghardt, K. Wieghardt, E. Bill, 2000, Inorganic chemistry.

Selective and reversible base-induced elimination of a ruthenium dithioether yields a vinyl metallosulfonium complex.

Rajat Chauhan, M. S. Mashuta, C. Grapperhaus, 2012, Inorganic chemistry.

First [Fe-NO](6) complex with an N(2)S(3)Fe-NO core as a model of NO-inactivated iron-containing nitrile hydratase. Are thiolates and thioethers equivalent donors in low-spin iron complexes?

A. Patra, M. S. Mashuta, C. Grapperhaus, 2002, Inorganic chemistry.

Synthesis and Dimer Cleavage Reactions of the N(2)S Thiolate Bridged Dimer [(mmp-dach)(2)Ni(2)]Cl(2).

M. Darensbourg, J. Reibenspies, C. Grapperhaus, 1999, Inorganic chemistry.

Investigations of Bis(alkylthiocarbamato)copper Linkage Isomers.

B. Narayanan, P. Bates, S. A. Andres, 2022, Inorganic chemistry.

Synthesis and characterization of N2S3X-Fe models of iron-containing nitrile hydratase.

P. Kozlowski, M. Zgierski, A. Patra, 2003, Inorganic chemistry.

Copper catalysed aerobic oxidation of benzylic alcohols in an imidazole containing N4 ligand framework.

M. S. Mashuta, R. Jain, R. M. Buchanan, 2016, Dalton transactions.

Template synthesis of N2S and N3S chelates via alkylation of bis(2-aminoethanethiolato)Ni: sulfur- and nitrogen-centered alkylations

M. S. Mashuta, J. Roddy, C. Grapperhaus, 2005 .

N-(2-formyl-1-methylimidazol-4-yl)-2,2-dimethylpropanamide: a versatile reagent for preparing imidazole-amine ligands with variable second-coordination spheres

M. S. Mashuta, R. M. Buchanan, Lionel Cheruzel, 2011 .

Molecular and Electronic Structure of [MnVN(cyclam−acetato)]PF6. A Combined Experimental and DFT Study

F. Neese, K. Wieghardt, E. Bill, 2001 .

Metal-Ligand Cooperativity Promotes Reversible Capture of Dilute CO2 as a Zn(II)-Methylcarbonate.

M. S. Mashuta, R. M. Buchanan, Dillon T. Hofsommer, 2023, Inorganic chemistry.

Probing the Reactivity and Radical Nature of Oxidized Transition Metal-Thiolate Complexes by Mass Spectrometry

J. Campbell, Rajat Chauhan, Hao Chen, 2013, Journal of The American Society for Mass Spectrometry.

Copper bis(thiosemicarbazone) Complexes with Pendent Polyamines: Effects of Proton Relays and Charged Moieties on Electrocatalytic HER

J. Spurgeon, M. S. Mashuta, R. M. Buchanan, 2020, European Journal of Inorganic Chemistry.

Syntheses, structures, and electrochemical studies of N , N ′-bis(alkylthiocarbamate)butane-2,3-diimine Cu(II) complexes as pendent alkoxy derivatives of Cu(ATSM)

M. S. Mashuta, R. M. Buchanan, N. Vishnosky, 2017 .

Dichloromethane alkylates a trithiolato-ruthenium complex to yield a methylene-bridged thioether core. Synthesis and structural comparison to the thiolato-ruthenium precursor.

M. S. Mashuta, C. Grapperhaus, Selma Poturovic, 2002, Inorganic chemistry.

Alkyne Addition to a Metal‐Stabilized Thiyl Radical: Carbon–Sulfur Bond Formation between 1‐Octyne and [Ru(SP)3]+

M. S. Mashuta, C. Grapperhaus, K. Ouch, 2012 .

Supramolecular assembly of a dinuclear Ag(I) complex with discreet Ag2S2 centers

M. S. Mashuta, R. M. Buchanan, C. Grapperhaus, 2009 .

Chemiresistive metal-stabilized thiyl radical films as highly selective ethylene sensors

F. Zamborini, D. Banda, Rajat Chauhan, 2014 .

Addition of polysubstituted alkenes, aromatic alkynes, and dienes to a metal-stabilized thiyl radical via carbon–sulfur bond formation: Electrochemical, chemical, and computational investigations

M. S. Mashuta, Davinder Kumar, C. Grapperhaus, 2013 .

Carbon-sulfur bond formation via alkene addition to an oxidized ruthenium thiolate.

M. S. Mashuta, C. Grapperhaus, K. Venna, 2007, Inorganic chemistry.

Electrochemical investigations of the [tris(2-(diphenylphosphino)thiaphenolato)ruthenate(II)] monoanion reveal metal- and ligand-centered events: radical, reactivity, and rate.

C. Grapperhaus, Selma Poturovic, 2004, Inorganic chemistry.

Electrocatalytic Hydrogen Evolution and Oxidation with Rhenium Tris(thiolate) Complexes: A Competition between Rhenium and Sulfur for Electrons and Protons

E. Brothers, Hao Tang, M. Hall, 2020, ACS Catalysis.

Controlled sulfur oxygenation of the ruthenium dithiolate (4,7-bis-(2'-methyl-2'-mercaptopropyl)-1-thia-4,7-diazacyclononane)RuPPh(3) under limiting O(2) conditions yields thiolato/sulfinato, sulfenato/sulfinato, and bis-sulfinato derivatives.

Manoj Kumar, P. Kozlowski, César A. Masitas, 2010, Inorganic chemistry.

Asymmetric oxygenation of a ruthenium dithiolate mimics the mixed sulfenato/sulfinato donor sets of nitrile hydratase and thiocyanate hydrolase.

César A. Masitas, M. S. Mashuta, C. Grapperhaus, 2010, Inorganic chemistry.

Spin-state-dependent oxygen sensitivity of iron dithiolates: sulfur oxygenation or disulfide formation

P. Kozlowski, M. S. Mashuta, M. O’Toole, 2008, JBIC Journal of Biological Inorganic Chemistry.

Oxygenation of a ruthenium(II) thiolate to a ruthenium(II) sulfinate proceeds via ruthenium(III).

M. S. Mashuta, C. Grapperhaus, Selma Poturovic, 2005, Inorganic chemistry.

Synthesis and oxygenation of a nickel(II) and zinc(II) dithiolate: an experimental and theoretical comparison.

P. Kozlowski, C. Mullins, M. S. Mashuta, 2004, Inorganic chemistry.

Singlet Oxygen and the Production of Sulfur Oxygenates of Nickel(II) and Palladium(II) Thiolates.

M. Darensbourg, Thawatchai Tuntulani, M. Maguire, 1997, Inorganic chemistry.

Template Effect for O2 Addition across cis-Sulfur Sites in Nickel Dithiolates

L. Sumner, D. Russell, M. Darensbourg, 1996 .

Hg(II) and Cd(II) complexes with mixed donor macrocyclic thioethers: The oxophobicity of mercury(II)

G. J. Grant, D. Janzen, D. Vanderveer, 2008 .

Ligand-Assisted Metal-Centered Electrocatalytic Hydrogen Evolution upon Reduction of a Bis(thiosemicarbazonato)Ni(II) Complex.

P. Kozlowski, A. Mamun, C. A. Grapperhaus, 2018, Inorganic chemistry.

Methylation of Tethered Thiolates in [(bme-daco)Zn](2) and [(bme-daco)Cd](2) as a Model of Zinc Sulfur-Methylation Proteins.

M. Darensbourg, J. Reibenspies, Thawatchai Tuntulani, 1998, Inorganic chemistry.

Subtle bite-angle influences on N(2)S(2)Ni complexes.

M. Miller, M. Darensbourg, J. Reibenspies, 2001, Inorganic Chemistry.

Structural comparison of alkylated derivatives of (bmmp-dmed)Ni and (bmmp-dmed)Zn

C. Mullins, M. S. Mashuta, C. Grapperhaus, 2005 .

{3,3′‐[Ethane‐1,2‐diylbis(methylimino)]bis(propane‐1‐thiolato)}nickel(II)

M. S. Mashuta, M. O’Toole, C. Grapperhaus, 2007 .

Ligand-Centered Hydrogen Evolution with Ni(II) and Pd(II)DMTH.

Joshua M. Spurgeon, J. Spurgeon, P. Kozlowski, 2022, Inorganic chemistry.

1,5-diazacyclooctane, pendant arm thiolato derivatives and [N,N′-Bis(2-mercaptoethyl)-1,5-diazacyclooctanato]nickel(II)

R. Hancock, A. Martell, M. Darensbourg, 2007 .

1,5-Bis(benzothiazolyl)-3-thiapentane and its asymmetric dinuclear Ag(I) complex with three distinct intermolecular-stacking interactions.

Ming Li, M. S. Mashuta, C. Grapperhaus, 2002, Chemical communications.

Correlation of electrochemistry, nucleophilicity and density functional calculations of the cis -dithiolate (bme*-daco)Ni

M. Darensbourg, A. Derecskei-Kovacs, J. Reibenspies, 2000 .

Synthesis, Characterization, and Biological Activity of Hybrid Thiosemicarbazone-Alkylthiocarbamate Metal Complexes.

P. Bates, S. A. Andres, M. S. Mashuta, 2020, Inorganic chemistry.

Comparative Technoeconomic Analysis of Pathways for Electrochemical Reduction of CO2 with Methanol to Produce Methyl Formate

Joshua M. Spurgeon, J. Spurgeon, C. Grapperhaus, 2022, ACS Sustainable Chemistry & Engineering.

Direct Deposition of Nonaqueous SnO2 Dispersion by Blade Coating on Perovskites for the Scalable Fabrication of p–i–n Perovskite Solar Cells

M. Reese, T. Druffel, M. Van Hest, 2021, ACS Applied Energy Materials.

Utilizing Charge Effects and Minimizing Intramolecular Proton Rearrangement to Improve the Overpotential of a Thiosemicarbazonato Zinc HER Catalyst.

P. Kozlowski, Y. Losovyj, A. Mamun, 2019, Inorganic chemistry.

Streams, cascades, and pools: various water cluster motifs in structurally similar Ni(II) complexes

Brian C. Frye, C. Mullins, M. S. Mashuta, 2018 .

Translation of Ligand-Centered Hydrogen Evolution Reaction Activity and Mechanism of a Rhenium-Thiolate from Solution to Modified Electrodes: A Combined Experimental and Density Functional Theory Study.

P. Kozlowski, Andrew Z. Haddad, Wuyu Zhang, 2017, Inorganic chemistry.

Beyond Metal-Hydrides: Non-Transition-Metal and Metal-Free Ligand-Centered Electrocatalytic Hydrogen Evolution and Hydrogen Oxidation.

Pawel M. Kozlowski, Craig A. Grapperhaus, Robert M. Buchanan, 2016, Journal of the American Chemical Society.

Proposed Ligand-Centered Electrocatalytic Hydrogen Evolution and Hydrogen Oxidation at a Noninnocent Mononuclear Metal-Thiolate.

Andrew Z. Haddad, C. A. Grapperhaus, M. S. Mashuta, 2015, Journal of the American Chemical Society.

DNA-induced assembly of gold nanoprisms and polystyrene beads into 3D plasmonic SERS substrates

N. Sathitsuksanoh, Mohammad Shahinur Rahaman, M. O’Toole, 2020, Nanotechnology.

Synthesis, Characterization, and HER Activity of Pendant Diamine Derivatives of NiATSM

J. Spurgeon, M. S. Mashuta, R. M. Buchanan, 2019, European Journal of Inorganic Chemistry.

Prolonged Stability of Pb-Catalyzed CO2 Electroreduction to Methyl Formate in Acidic Methanol

Joshua M. Spurgeon, J. Spurgeon, Manu Gautam, 2023, ACS Applied Energy Materials.

Effect of Stacking Interactions on the Translation of Structurally Related Bis(thiosemicarbazonato)nickel(II) HER Catalysts to Modified Electrode Surfaces.

Gautam Gupta, J. Spurgeon, Y. Losovyj, 2019, Inorganic chemistry.

Electrocatalytic Hydrogen Evolution and Hydrogen Oxidation with a Ni(PS)2 Complex

C. A. Grapperhaus, M. S. Mashuta, R. Jain, 2017 .

Water wire clusters in isostructural Cu(II) and Ni(II) complexes: Synthesis, characterization, and thermal analyses

Brian C. Frye, Gautam Gupta, M. S. Mashuta, 2019, Inorganica Chimica Acta.

Physical structure of constitutional isomers influences antiproliferation activity of thiosemicarbazone-alkylthiocarbamate copper complexes.

P. Bates, S. A. Andres, M. S. Mashuta, 2023, Journal of inorganic biochemistry.

Kinetic effects of sulfur oxidation on catalytic nitrile hydration: nitrile hydratase insights from bioinspired ruthenium(II) complexes.

Davinder Kumar, C. Grapperhaus, Tho N. Nguyen, 2014, Inorganic chemistry.

IPL-Annealed Mixed-Cation Perovskites with Robust Coating Window toward Scalable Manufacturing of Commercial Perovskite Solar Cells

M. Reese, T. Druffel, Sashil Chapagain, 2023, ACS Applied Energy Materials.