M. Midland

发表

Synthesis of alkyl 4-hydroxy-2-alkynoates

A. Tramontano, J. Cable, M. Midland, 1980 .

Vitamin D: Structure‐function analyses and the design of analogs

J. Palenzuela, W. Okamura, J. Plumet, 1992, Journal of cellular biochemistry.

REDUCTION OF α,β-ACETYLENIC KETONES WITH B-3-PINANYL-9-BORABICYCLO(3.3.1)NONANE. HIGH ASYMMETRIC INDUCTION IN ALIPHATIC SYSTEMS

R. Hatch, D. Mcdowell, A. Tramontano, 1980 .

Reduction of .alpha.,.beta.-acetylenic ketones with B-3-pinanyl-9-borabicyclo[3.3.1]nonane. High asymmetric induction in aliphatic systems

R. Hatch, D. Mcdowell, A. Tramontano, 1980 .

Effect of C2O stereochemistry on the conformational profile of the side chains of vitamin D analogs.

W. Okamura, J. Plumet, M. Midland, 1993 .

Biochemical Significance of the 6‐s‐cis Conformation of the Steroid Hormone lα,25‐Dihydroxyvitamin D3 Based on the Provitamin D Skeleton a

A. Norman, I. Nemere, W. Okamura, 1995, Annals of the New York Academy of Sciences.

Asymmetric Synthesis via Boranes: Chiral Allenic Boranes and Trialkylborane Reducing Agents

M. Midland, 1978 .

Enantioselective allylborane condensations

M. Midland, S. Preston, 1982 .

A rapid and efficient cycloaddition of simple imines with activated dienes leading to amino sugars; Unusually high “chelation-controlled” diastereoselectivity in the addition to an α,β-dihydroxy imine protected as a ketal.

M. Midland, J. I. Mcloughlin, 1988 .

The structures of syringolides 1 and 2, novel C-glycosidic elicitors from Pseudomonas syringae pv. tomato

Kate J. Graham, M. Stayton, J. Clardy, 1993 .

High threo diastereoselectivity via europium(III)-catalyzed cyclocondensation of a silyloxy diene with .alpha.-alkoxy aldehydes. Synthesis of (-)pestalotin

M. Midland, R. S. Graham, 1984 .

Stereospecific synthesis of (25)-26-hydroxycholesterol VIA [2, 3] sigmatropic rearrangement. A new stereoselective two-carbon homologation of 20-keto steroids to the 23-aldehyde.

M. Midland, Young C. Kwon, 1985 .

Reaction of dialkylchloroboranes with ethyl diazoacetate at low temperatures. Facile two-carbon homologation under exceptionally mild conditions

H. Brown, A. B. Levy, M. Midland, 1972 .

Chiral trialkylborane reducing agents. Preparation of 1-deuterio primary alcohols of high enantiomeric purity

S. Zderic, A. Tramontano, M. Midland, 1979 .

2 – Reductions with Chiral Boron Reagents

M. Midland, 1983 .

Asymmetric reductions with organoborane reagents

M. Midland, 1989 .

Asymmetric reductions of prochiral ketones with B-3-pinanyl-9-borabicyclo[3.3.1]nonane (Alpine-Borane) at elevated pressures

M. Midland, J. I. Mcloughlin, J. Gabriel, 1989 .

Efficient asymmetric reduction of acyl cyanides with B-3-pinanyl 9-BBN (Alpine-borane)

Penny E. Lee, M. Midland, 1985 .

Application of [2,3] sigmatropic (Wittig) rearrangements in synthesis. The synthesis of (+)-Prelog-Djerassi lactone

M. Midland, D. J. Tsai, 1985 .

Asymmetric reductions of propargyl ketones : An effective approach to the synthesis of optically-active compounds

D. Cardin, A. Tramontano, M. Midland, 1984 .

Kinetics of reductions of substituted benzaldehydes with B-alkyl-9-borabicyclo[3.3.1]nonane (9-BBN)

S. Zderic, M. Midland, 1982 .

Thermal reactions of B-alkyl-9-borabicyclo[3.3.1]nonane (9-BBN). Evidence for unusually facile dehydroboration with B-pinanyl-9-BBN

S. Zderic, M. Midland, A. Kazubski, 1982 .

Asymmetric synthesis of .gamma.-lactones. A facile synthesis of the sex pheromone of the Japanese beetle

N. Nguyen, M. Midland, 1981 .

The synthesis of naturally occurring 4-alkyl- and 4-alkenyl-γ-lactones using the asymmetric reducing agent B-3-pinanyl-9-borabicyclo[3.3.1]nonane

A. Tramontano, M. Midland, 1980 .

Facile reaction of alkyl- and aryldichloroboranes with organic azides. General stereospecific synthesis of secondary amines

H. Brown, A. B. Levy, M. Midland, 1973 .

Organoboranes for synthesis : Reaction of organoboranes with representative organic azides. A general stereospecific synthesis of secondary amines and N-substituted aziridines☆☆☆

R. B. Wetherill, H. Brown, A. Suzuki, 1987 .

Organoboranes for syntheses

H. Brown, M. Midland, 1986 .

Asymmetric reduction of ketones with B-(cis-10-pinanyl)-9-borabicyclo[3.3.1]nonane: observation of a change in enantioselection between similar organoborane and organoaluminum reagents

M. Midland, J. I. Mcloughlin, 1984 .

Reduction of .alpha.,.beta.-acetylenic ketones to (S)-propargyl alcohols of high enantiomeric purity

M. Midland, A. Kazubski, 1982 .

Asymmetric synthesis of hydroxycarboxylic acids

Penny E. Lee, M. Midland, 1981 .

Preparation of optically active benzyl-.alpha.-d alcohol via reduction by B-3.alpha.-pinanyl-9-borabicyclo[3.3.1]nonane. A new highly effective chiral reducing agent

S. Zderic, A. Tramontano, M. Midland, 1977 .

Two novel reactions of monomeric formaldehyde with trialkylboranes. Remarkably rapid elimination diverted by oxygen to a free-radical chain addition

N. Miyaura, H. Brown, A. Suzuki, 1972 .

Preparation of monolithium acetylide in tetrahydrofuran. Reaction with aldehydes and ketones

M. Midland, 1975 .

Organic Syntheses via Free‐Radical Displacement Reactions of Organoboranes

H. Brown, M. Midland, 1972 .

Convenient and general synthesis of acetylenes via the reaction of iodine with lithium l-alkynyltriorganoborates

N. Miyaura, H. Brown, A. Suzuki, 1973 .

Reaction of alkyl- and aryldichloroboranes with ethyl diazoacetate at low temperature

J. Bridson, H. Brown, A. B. Levy, 1973 .

The facile reaction of B-alkyl-9-borabicyclo[3.3.1]nonanes with benzaldehyde

S. Zderic, A. Tramontano, M. Midland, 1977 .

Preparation of allenes and acetylenes from ethynylalkanol acetates via organoboranes

M. Midland, 1977 .

Reaction of lithium ethynyl- and ethenyltrialkylborates with acid. Valuable route to the Markovnikov alkenyl- and alkylboranes

H. Brown, A. B. Levy, M. Midland, 1975 .

Convenient general synthesis of alkyl hydroperoxides via autoxidation of organoboranes

H. Brown, M. Midland, 1971 .

Stoichiometrically controlled reaction of organoboranes with oxygen under very mild conditions to achieve essentially quantitative conversion into alcohols

G. Kabalka, H. Brown, M. Midland, 1971 .

Initiation rates for autoxidation of trialkylboranes. Effect of a steric factor on the initiation rate

H. Brown, M. Midland, 1971 .

Stereochemistry at the migration terminus of organoborane rearrangements. Stereoselective and enantioselective formation of allylic alcohols

M. Midland, S. Preston, 1980 .

HIGH THREO DIASTEREOSELECTIVITY VIA EUROPIUM(III)‐CATALYZED CYCLOCONDENSATION OF A SILYLOXY DIENE WITH α‐ALKOXY ALDEHYDES. SYNTHESIS OF (‐)PESTALOTIN

M. Midland, R. S. Graham, 1984 .

Vinylic organoboranes. 1. A convenient synthesis of acetylenes via the reaction of lithium (1-alkynyl) organoborates with iodine

N. Miyaura, H. Brown, A. Suzuki, 1986 .

Convenient stereospecific synthesis of terminal acetylenes via the treatment of lithium ethynyltrialkylborates with iodine

H. Brown, J. A. Sinclair, M. Midland, 1974 .

Stereocontrolled synthesis of 22-hydroxy-23-acetylenic steroids, key intermediates in steroid side chain construction. Observation of a directive effect by an α-chiral site during asymmetric reduction with -B-3-pinanyl-9-BBN (Alpine-Borane)

M. Midland, Young C. Kwon, 1984 .

Stereochemistry of hydroboration of .alpha.-chiral olefins and reduction of .alpha.-chiral ketones. An unusual anti-Cram selectivity with dialkylboranes

M. Midland, Young C. Kwon, 1983 .

Asymmetric reductions with organoborane reagents

M. Midland, 1989 .

A new class of enantioselective organoboron reducing agents. Borane complexes with chiral terpenic 1,2-azaboracyclohexanes

M. Midland, A. Kazubski, 1992 .

NB-Enantride, a new chiral trialkylborohydride for the asymmetric reduction of ketones

M. Midland, A. Kazubski, 1982 .

KINETICS OF REDUCTIONS OF SUBSTITUTED BENZALDEHYDES WITH B‐ALKYL‐9‐BORABICYCLO(3.3.1)NONANE (9‐BBN)

S. Zderic, M. Midland, 1982 .

APPLICATION OF (2,3) SIGMATROPIC (WITTIG) REARRANGEMENTS IN SYNTHESIS. THE SYNTHESIS OF (+)-PRELOG-DJERASSI LACTONE

M. Midland, D. J. Tsai, 1985 .

B‐3‐Pinanyl‐9‐borabicyclo[3.3.1]nonane

M. Midland, 2001 .

Stereospecific synthesis of hydroxylated steroid side chains. Synthesis of 25,28-dihydroxy-7,8-dihydroergosterol and its c-24 epimer via [2,3] sigmatropic rearrangement.

M. Midland, Young C. Kwon, 1986 .

Studies on Chirality Transfer in the [2,3] Sigmatropic Rearrangement of Anions Derived from Trialkylstannylmethyl Allylic Ethers. Stereospecific Synthesis of (2R)-3-Benzyloxy-2-methylpropanol.

M. Midland, Young C. Kwon, 1985 .

Asymmetric reduction of prochiral ketones with B-3-pinanyl-9-borabicyclo[3.3.1]nonane in efficiencies approaching 100%. Simultaneous rate enhancement and side reaction suppression via the use of elevated pressures

M. Midland, J. I. Mcloughlin, 1984 .

Controlled reaction of oxygen with alkyldichloroborane etherates. Synthesis of alkyl hydroperoxides in high yield

H. Brown, M. Midland, 1973 .

Facile photochemical or oxygen initiated free-radical chain reactions of trialkylboranes with organic disulfides. Convenient new synthesis of organic sulfides via hydroboration

H. Brown, M. Midland, 1971 .

THERMAL REACTIONS OF B-ALKYL-9-BORABICYCLO(3.3.1)NONANE (9-BBN). EVIDENCE FOR UNUSUALLY FACILE DEHYDROBORATION WITH B-PINANYL-9-BBN

S. Zderic, M. Midland, A. Kazubski, 1982 .

Asymmetric Reductions of Prochiral Ketones with B‐3‐Pinanyl‐9‐borabicyclo(3.3.1)nonane (Alpine‐Borane) at Elevated Pressures.

M. Midland, J. I. Mcloughlin, J. Gabriel, 1989 .

2‐[2‐[(Benzyloxy)ethyl]‐6,6‐dimethylbicyclo[3.3.1]‐3‐nonyl]‐9‐borabicyclo[3.3.1]nonane

M. Midland, 2001 .

The reaction of B-alkyl-9-borabicyclo[3.3.1]nonanes with aldehydes and ketones. A facile elimination of the alkyl group by aldehydes

S. Zderic, A. Tramontano, M. Midland, 1978 .

The isomerization of optically-active propargyl alcohols to terminal acetylenes.

C. Brown, R. L. Halterman, M. Midland, 1981 .

Olefin-alkyl group exchange of B-alkyl-9-borabicyclo-[3.3.1]nonanes. Evidence for a dehydroboration-hydroboration process

S. Zderic, M. Midland, J. Petre, 1979 .

B-alkyl-9-borabicyclo[3.3.1]nonanes as mild, chemoselective reducing agents for aldehydes

A. Tramontano, M. Midland, 1978 .

Stereocontrolled synthesis of steroid side chains via organoboranes. Stereospecific synthesis of 20R- and 20S-25-hydroxycholesterol.

M. Midland, Young C. Kwon, 1982 .

Synthesis of (-)-talaromycin A

M. Midland, J. Gabriel, 1985 .

Asymmetric Reduction of α,β‐Acetylenic Ketones with B‐3‐Pinanyl‐9‐Borabicyclo[3.3.1]Nonane: (R)‐( + )‐1‐Octyn‐3‐Ol

M. Midland, R. S. Graham, 2003 .

The Preparation of 9-Borabicyclo[3.3.1]nonane-9-d

M. Midland, S. Greer, 1978 .

Facile reaction of dialkylchloroboranes with organic azides. Remarkable enhancement of reactivity relative to trialkylboranes

H. Brown, A. B. Levy, M. Midland, 1972 .

Reaction of representative organic azides with triethylborane. New route to secondary amines

H. Brown, M. Midland, M. Itoh, 1971 .

Organoboranes for synthesis. 5: Stoichiometrically controlled reaction of organoboranes with oxygen under mild conditions to achieve quantitative conversion to alcohols1

G. Kabalka, H. Brown, M. Midland, 1986 .

Iodine as an exceptionally favorable inhibitor for the reaction of oxygen with trialkylboranes. Evidence for a very slow initiation step in the autoxidation of organoboranes

H. Brown, M. Midland, 1971 .

Organoboranes for Synthesis. Part 8. Reaction of Organoboranes with Representative Organic Azides. A General Stereospecific Synthesis of Secondary Amines and N-Substituted Aziridines.

H. Brown, A. Suzuki, A. B. Levy, 1988 .

ASYMMETRIC REDUCTION OF KETONES WITH B‐(CIS‐10‐PINANYL)‐9‐BORABICYCLO(3.3.1)NONANE. OBSERVATION OF A CHANGE IN ENANTIOSELECTION BETWEEN SIMILAR ORGANOBORANE AND ORGANOALUMINUM REAGENTS

M. Midland, J. I. Mcloughlin, 1985 .

Investigation of cyclization reactions of dicyclohexyl-6-iodo- and -6-tosylhexenylborane. A facile radical cyclization diverted to a rearrangement-cyclization with base.

Diane M. Hinkens, M. Midland, 2009, The Journal of organic chemistry.

Stereoselective bromination of allylic alcohols. A facile synthesis of (E)- or (Z)-bromo epoxides from a common starting material

R. L. Halterman, M. Midland, 1981 .

Preparation of monolithium acetylide in tetrahydrofuran. Reaction with aldehydes and ketones

M. Mark Midland, M. Midland, 1975 .

Optically active ketones as chiral auxiliaries in the [2,3]-Wittig rearrangement

M. Midland, J. I. Mcloughlin, D. S. Keegan, 1991 .

Acyclic stereocontrol through diastereo- and enantioselective [2,3]-sigmatropic Wittig rearrangements

M. Mark Midland, David J.S. tsai, M. Midland, 1984 .

Stereochemistry at the migration terminus in the base-induced rearrangement of .alpha.-haloorganoboranes

A. Zolopa, R. L. Halterman, M. Midland, 1979 .

Stereochemistry of the allene in the conversion of ethynylalkanol acetates into allenes via organoboranes

D. Mcdowell, M. Midland, 1978 .

Ab Initio Investigation of the Transition State for Asymmetric Synthesis with Boronic Esters

M. Midland, 1998 .

The stable pentamethylcyclopentadienyl cation remains unknown.

Guy Bertrand, G. Bertrand, J. B. Lambert, 2002, Angewandte Chemie.

Synthesis of (-)-talaromycin A

M. Midland, J. Gabriel, 1985 .

Synthesis and Conformational Analysis of(6R)-[6-2H1]-1,2:3,4-Di-O-isopropylidene-.alpha.-D-galactopyranose. NMR and Molecular Modeling Studies

M. Midland, L. Morell, John C. S. Cheng, 1994 .

Is Protonated Ammonium Fluoride an Ion-Neutral Complex in the Gas Phase?

T. Morton, M. Midland, 1993 .

Facile double migration in the protonation of lithium alkynyltrialkylborates with acid

H. Brown, M. Midland, 1975 .

Chemistry and conformation of vitamin D molecules

A. Norman, I. Nemere, W. Okamura, 1995, The Journal of Steroid Biochemistry and Molecular Biology.

Hydrophobic ion probe studies of membrane dipole potentials.

W. B. Kleijn, L. Bruner, M. Midland, 1983, Biochimica et biophysica acta.

Stereoselective syntheses of erythro- and threo-.beta.-amino alcohol derivatives via hetero-Diels-Alder reactions

M. Afonso, M. Midland, 1989 .

Diastereoselection in the Lewis acid catalyzed cycloaddition reaction of .alpha.-alkoxy imines

M. Midland, R. Koops, 1992 .

Diastereoselection in the Lewis Acid Catalyzed Cycloaddition Reaction of α‐Alkoxy Imines.

M. Midland, R. Koops, 1992 .

Oxygen-induced reaction of trialkylboranes with alkyl iodides. Facile coupling of benzylic and allylic iodides via triethylborane

H. Brown, A. Suzuki, M. Harada, 1971 .

Stereocontrolled synthesis of a steroid side chain

M. Midland, Young C. Kwon, 1981 .

Asymmetric hetero Diels-Alder reaction of .alpha.-alkoxy aldehydes with activated dienes. The scope of Lewis acid chelation-controlled cycloadditions

M. Midland, R. Koops, 1990 .