M. Alajarín

发表

Iminophosphorane-substituted proton sponges. Part 2. Preparation and crystal structure of four phosphoranylideneammonionaphthalene derivatives

P. Molina, J. Elguero, A. Llamas-Saiz, 1991 .

Iminophosphorane-substituted proton sponges. Part 3. Preparation and crystal structure of three salts of protonated 1-dimethylamino-8-triphenylphosphoranylideneammonionaphthalene

P. Molina, J. Elguero, A. Llamas-Saiz, 1991 .

Mechanically interlocked molecules in metal-organic frameworks.

J. Berná, Aurelia Pastor, A. Martínez-Cuezva, 2022, Chemical Society reviews.

Modulating the propeller-like shape of a tripodal C(CH2PPh2)3 fragment by the size of the substituent at the pivotal carbon atom in macrobicyclic tri-λ5-phosphazenes

J. Berná, C. Lopez-Leonardo, M. Alajarín, 2007 .

Enhancing the selectivity of prolinamide organocatalysts using the mechanical bond in [2]rotaxanes†

J. Berná, A. Martínez-Cuezva, D. A. Alonso, 2020, Chemical science.

retro-Cheletropic ene reactions with 2-carbena-1,3-dioxolane as chelefuge

A. Vidal, Marta Marín‐Luna, P. Sánchez-Andrada, 2011 .

Center-to-propeller and propeller-to-propeller stereocontrol in a series of macrobicyclic tri-λ5-phosphazenes

P. Sánchez-Andrada, J. Berná, C. Lopez-Leonardo, 2007 .

From ketenimines to ketenes to quinolones: two consecutive pseudopericyclic events.

A. Vidal, P. Sánchez-Andrada, D. Bautista, 2005, Organic letters.

The consecutive [2+2] cycloaddition-ring expansion route to diastereomeric 1,4-diazepin-5-ones from imino-ketenimines. Alternative intramolecular transamidation of β-lactams

A. Vidal, Fulgencio Tovar, M. Alajarín, 2005 .

Copper-Linked Rotaxanes for the Building of Photoresponsive Metal Organic Frameworks with Controlled Cargo Delivery.

Mara R. B. Marzari, J. Berná, M. Martins, 2020, Journal of the American Chemical Society.

Enantioselective Formation of 2-Azetidinones by Ring-Assisted Cyclization of Interlocked N-(α-Methyl)benzyl Fumaramides.

J. Berná, A. Martínez-Cuezva, D. Bautista, 2018, Angewandte Chemie.

Density Functional Theory and Quantum Theory of Atoms in Molecules Analysis: Influence of Intramolecular Interactions on Pirouetting Movement in Tetraalkylsuccinamide[2]rotaxanes

N. Zanatta, M. Hörner, J. Berná, 2017 .

The Elusive 1,4‐Diazabutatrienes: Lurking in the Shadows

Marta Marín‐Luna, M. Alajarín, 2020, European Journal of Organic Chemistry.

Novel capsular aggregates from flexible tripodal triureas with C(s) symmetry.

J. Steed, J. Howard, E. C. Spencer, 2012, Chemistry.

Self-assembly of tris(2-ureidobenzyl)amines with C1 symmetry

Aurelia Pastor, Raúl-Ángel Orenes, M. Alajarín, 2011 .

Competition between the donor and acceptor hydrogen bonds of the threads in the formation of [2]rotaxanes by clipping reaction

N. Zanatta, J. Berná, C. Frizzo, 2017 .

Unmasking the elusive 1,4-diazabutatrienes: the stabilizing role of the N-substituents.

Marta Marín‐Luna, M. Alajarín, 2021, Physical chemistry chemical physics : PCCP.

In Search of 1,4-Diazabutatrienes, the Elusive Isocyanide Homodimers. The Superchameleonic F-NC.

Marta Marín‐Luna, M. Alajarín, 2020, The Journal of organic chemistry.

Insertion of benzynes into the P═N Bond of P-alkenyl(alkynyl)-λ5-phosphazenes.

Raúl-Ángel Orenes, C. Lopez-Leonardo, M. Alajarín, 2011, Organic letters.

The Molecular Structure and NMR Properties of P-Phosphinoylmethyl Aminophosphonium Salts

J. Elguero, I. Alkorta, M. Jimeno, 2003 .

Mechanically Interlocked Catalysts for Asymmetric Synthesis

J. Berná, A. Martínez-Cuezva, M. Alajarín, 2020, ACS Catalysis.

Persistent radical effect in the intramolecular addition of benzylic radicals onto ketenimines: selective cross-coupling of α-(indol-2-yl)benzyl radicals with the 1-cyano-1-methylethyl radical

A. Vidal, D. Bautista, M. Alajarín, 2004 .

Accessing polysubstituted oxazolidines, pyrrolidines and imidazolidines by regioselective [3 + 2] annulations of ketenimines with donor–acceptor oxiranes and aziridines

A. Vidal, Marta Marín‐Luna, Raúl-Ángel Orenes, 2018 .

1,4-Dioxepanes, 1,4-Oxathiepanes, and 1,4-Dithiepanes

P. Sánchez-Andrada, C. Lopez-Leonardo, M. Alajarín, 2021, Reference Module in Chemistry, Molecular Sciences and Chemical Engineering.

Versatile control of the submolecular motion of di(acylamino)pyridine-based [2]rotaxanes † ChemicalScience EDGE ARTICLE

J. Berná, Aurelia Pastor, A. Martínez-Cuezva, 2015 .

Thermally and Photochemically Induced Dethreading of Fumaramide-Based Kinetically Stable Pseudo[2]rotaxanes

J. Berná, A. Martínez-Cuezva, D. Bautista, 2019, European Journal of Organic Chemistry.

On the [2+2] cycloaddition of 2-aminothiazoles and dimethyl acetylenedicarboxylate. Experimental and computational evidence of a thermal disrotatory ring opening of fused cyclobutenes.

P. Sánchez-Andrada, Aurelia Pastor, D. Bautista, 2006, The Journal of organic chemistry.

New macrobicyclic triphosphazides and triphosphazenes formed by self-assembly of tripodal triazides with triphosphanes

J. Berná, C. Lopez-Leonardo, M. Alajarín, 2006 .

Synthesis of 6H -thieno [3,2 -b]pyridin -7 -ones from N-(2-X-carbonyl)-3-thienyl ketenimines (X = RS, ArO, R2N) via consecutive [1,5]-X sigmatropic rearrangement and 6π -electrocyclization

A. Vidal, M. Alajarín, María-Mar Ortín, 2007 .

New methodology for the preparation of quinazoline derivatives via tandem aza-Wittig/heterocumulene-mediated annulation. Synthesis of 4(3H)-quinazolinones, benzimidazo[1,2-c]quinazolines, quinazolino[3,2-a]quinazolines and benzothiazolo[3,2-c]quinazolines

P. Molina, A. Vidal, M. Alajarín, 1989 .

Recent Highlights in Ketenimine Chemistry

A. Vidal, Marta Marín‐Luna, M. Alajarín, 2012 .

Mode selectivity in the intramolecular cyclization of ketenimines bearing N-acylimino units: a computational and experimental study.

Angel Vidal, A. Vidal, P. Sánchez-Andrada, 2005, The Journal of organic chemistry.

Intramolecular addition of benzylic radicals onto ketenimines. Synthesis of 2-alkylindoles.

A. Vidal, M. Alajarín, María-Mar Ortín, 2003, Organic & biomolecular chemistry.

Intramolecular [4 + 2] cycloaddition reactions of ketenimines: A new synthesis of benz[b]acridines

A. Vidal, Fulgencio Tovar, M. Alajarín, 2002 .

Highly stereocontrolled [2+2] cycloaddition versus unprecedented imino-ene reactions of imino-ketenimines

A. Vidal, P. Sánchez-Andrada, Fulgencio Tovar, 2002 .

Periselective intramolecular [4+2] cycloadditions of ketenimines: synthesis of pyrido[1,2-a]benzimidazoles

A. Vidal, Fulgencio Tovar, M. Alajarín, 2000 .

Formal [4+2] intramolecular cycloaddition ketenimine-imine. Synthesis of benzimidazo[1,2-b]isoquinolines

A. Vidal, Fulgencio Tovar, M. Alajarín, 1999 .

Surpassing Torquoelectronic Effects in Conrotatory Ring Closures: Origins of Stereocontrol in Intramolecular Ketenimine–Imine [2+2] Cycloadditions

Mateo Alajarin, Fernando P. Cossío, Angel Vidal, 1999 .

Preparation and Intramolecular Cyclization of Bis(carbodiimides). Synthesis and X-ray Structure of 1,3-Diazetidine-2,4-diimine Derivatives

P. Sánchez-Andrada, M. C. Foces-Foces, M. Alajarín, 1999 .

The First Aza-Wittig Reaction of the β-Lactam Carbonyl Group

P. Molina, A. Vidal, Fulgencio Tovar, 1998 .

Intramolecular [2 + 2] cycloaddition of ketenimines with imines. Synthesis and chemical behaviour of azeto[2,1-b]quinazolines

P. Molina, A. Vidal, Fulgencio Tovar, 1997 .

Formal Total Synthesis of the Alkaloid Cryptotackieine (Neocryptolepine)

P. Molina, A. Vidal, M. Alajarín, 1997 .

INTRAMOLECULAR 2 + 2 CYCLOADDITION OF KETENIMINES WITH IMINES

P. Molina, A. Vidal, M. Alajarín, 1996 .

Iminophosphorane-mediated bispyrido annulation onto five-membered rings. X-ray crystal structure of 6,7-dibenzylamino-13-methoxymethyl-13H-diquino 4,3-b:3′,4′-dpyrrole. acetonitrile complex

P. Molina, A. Vidal, C. Foces-Foces, 1995 .

Preparation of [5,6,6] tricyclic guanidines from C,C-bis(iminophosphoranes)

P. Molina, A. Vidal, M. Alajarín, 1995 .

New synthetic applications of vinyliminophosphoranes based on the reactivity of the vinyl side chain

P. Molina, E. Aller, M. Alajarín, 1994 .

An Efficient One-Pot Synthesis of Pyrrolo[4,3,2-ij]isoquinoline Derivatives by a Consecutive Aza-Wittig/Electrocyclic Ring-Closure/Intramolecular Acylation Process

P. Molina, A. Vidal, M. Alajarín, 1992 .

Convenient Improved Syntheses of Isocyanates or Isothiocyanates from Amines

P. Molina, A. Arques, M. Alajarín, 1982 .

4‐Alkenyl‐2‐aminothiazoles: Smart Dienes for Polar [4 + 2] Cycloadditions

P. Sánchez-Andrada, Aurelia Pastor, Raúl-Ángel Orenes, 2013 .

FOUR-MEMBERED HETEROCYCLIC RINGS FROM IMINOPHOSPHORANES. PREPARATION AND REACTIVITY OF 2,4-DIIMINO-1,3-DIAZETIDINES AND RELATED COMPOUNDS

P. Molina, J. Elguero, C. Lopez-Leonardo, 1993 .

Reactivity and synthetic applications of bis(iminophosphoranes). One-pot preparation of pyrido[2,3,4-de]quinazolines and benzo[de][1,6]naphthyridines

P. Molina, A. Vidal, M. Alajarín, 1992 .

C=C-conjugated carbodiimides as 2-aza dienes in intramolecular [4+2] cycloadditions. One-pot preparation of quinoline, .alpha.-carboline, and quinindoline derivatives

P. Molina, A. Vidal, P. Sánchez-Andrada, 1992 .

2,4-Bisimino-1,3-diazetidines: iminophosphoranes, carbodiimides and related betaines

P. Molina, J. Elguero, A. Llamas-Saiz, 1992 .

One pot preparation of pyrido[2,3,4-de]quinazolines and benzo[de][1,6]naphthyridines by a consecutive process involving an aza-Wittig/electrocyclic ring-closure/heterocumulene-mediated annelation or intramolecular Diels-Alder cycloaddition sequence.

P. Molina, A. Vidal, M. Alajarín, 1991 .

Regioselective iminophosphorane-mediated annelation of a 1,3,4-thiadiazole ring into a 1,2,4-triazine ring: Preparation of novel mesoionic compounds derived from [1,3,4]thiadiazolo[2,3-c]- and [1,3,4]thiadiazolo[3,2-d][1,2,4]triazines.

P. Molina, M. Alajarín, Antonia López-Lázaro, 1991 .

New methodology for the preparation of pyrrole and indole derivatives via iminophosphoranes:synthesis of pyrrolo[1,2-a]quinoxalines, indolo[3,2-c]quinolines and indolo[1,2-c]quinazolines

P. Molina, A. Vidal, M. Alajarín, 1990 .

Iminophosphorane-mediated annelation of an imidazole ring into a benzimidazole ring: synthesis of imidazo[1,5-a-]benzimidazole derivatives. Crystal structure of 1-(4-methoxyphenylimino)-2-(4-methoxyphenylcarbamoyl)-2,3-dihydro-1-imidazo[1,5-a]benzimidazole

P. Molina, C. Foces-Foces, F. H. Cano, 1989 .

Ortho-pyrrolylphenyl heterocumulenes: preparation and cyclization to fused pyrroles

P. Molina, A. Vidal, M. Alajarín, 1989 .

Iminophosphorane‐mediated synthesis of mesoionic 1,3,4‐Oxadiazolo‐[3,2‐a]pyridinylium‐2‐aminides

P. Molina, F. H. Cano, M. C. Foces-Foces, 1988 .

Iminophosphorane-mediated synthesis of fused [1,2,4]triazines: preparation of the novel [1,2,4]triazino[4,3-b][1,2,4,5]tetrazine ring system

P. Molina, A. Vidal, J. Elguero, 1988 .

Heterocyclic synthesis via a tandem aza-Wittig reaction/heterocumulene-mediated annulation reaction. New methodology for the preparation of quinazoline derivatives.

P. Molina, A. Vidal, M. Alajarín, 1988 .

One-pot preparation of derivatives of the unknown 1,9-diazaphenalene ring by a consecutive electrocyclic ring-closure/Claisen rearrangement/intramolecular amination process

P. Molina, A. Vidal, M. Alajarín, 1990 .

Experimental and theoretical study of the R3P+−X− bond: case of betaines derived from N-iminophosphoranes and alkyl isocyanates

P. Molina, J. Catalán, J. Elguero, 1989 .

Iminophosphorane-mediated synthesis of 3,5-disubstituted 1,2,4-oxadiazoles

P. Molina, A. Ferao, M. Alajarín, 1986 .

An Efficient Method for the Preparation of N,N′,N″ - Trisubstituted Guanidines

P. Molina, M. Alajarín, J. Saez, 1983 .

Fused mesoionic heterocycles : synthesis of 1,3,4-triazolo(3,2-a)pyridine derivatives

P. Molina, A. Arques, M. Alajarín, 1983 .

A Mild and Efficient Synthesis of Symmetrical Diaryl Carbodiimides

P. Molina, A. Arques, M. Alajarín, 1982 .

[4 + 2] Cycloaddition reaction of C-aryl ketenimines with PTAD as a synthetic equivalent of dinitrogen. Synthesis of triazolocinnolines and cinnolines.

A. Vidal, Marta Marín‐Luna, Raúl-Ángel Orenes, 2009, The Journal of organic chemistry.

One pot conversion of alkyl halides into thiols under mild conditions

A. Katritzky, P. Molina, M. Alajarín, 1985 .

Transformation of Primary Amines to Thiols, Sulfides, or Arylmethyl Thiocyanates via Pyridinium Salts

P. Molina, P. M. Fresneda, A. Ferao, 1982 .

Synthesis of bridgehead nitrogen heterocycles from pyrylium salts and β‐functionalized amines

P. Molina, A. Tárraga, M. Alajarín, 1984 .

Preparation of [1,2,4]triazolo[5,1-c][1,2,4]triazine derivatives from 3,4-diamino[1,2,4]triazine

P. Molina, M. Alajarín, J. Vega, 1989 .

Stereocontrolled Synthesis of β-Lactams within [2]Rotaxanes: Showcasing the Chemical Consequences of the Mechanical Bond.

J. Berná, A. Martínez-Cuezva, C. Lopez-Leonardo, 2016, Journal of the American Chemical Society.

Ketenimine and imine functions linked by an ethylene group. Intramolecular [4+2] cycloadditions leading to imidazo[1,2-b]isoquinolines

A. Vidal, P. Sánchez-Andrada, D. Bautista, 2003 .

A Practical Synthesis of the First P-Phosphinoylmethyl-λ5-phosphazenes

C. Lopez-Leonardo, D. Bautista, M. Alajarín, 2000 .

Thermal cyclization of N-[2-(2-propenyl)-1-naphthyl] ketenimines: intramolecular Diels–Alder reaction versus [1,5] hydrogen migration. Synthesis of dibenz[b,h]acridines and benzo[h]quinolines

A. Vidal, M. Alajarín, María-Mar Ortín, 2005 .

Palladium complexes derived from N,N-bidentate NH-iminophosphorane ligands: synthesis and use as catalysts in the Sonogashira reaction.

Raúl-Ángel Orenes, C. Lopez-Leonardo, D. Bautista, 2012, Dalton transactions.

Regio- and stereoselective nucleophilic additions of amines, thiols and aminophosphanes to the CC bond of P,P-diphenyl-P-(2-phenylethynyl)-λ5-phosphazenes

C. Lopez-Leonardo, M. Alajarín, R. Raja, 2007 .

π‐Insertion Reactions of Benzynes into P=N and P=S Double Bonds

F. López-Ortiz, C. Lopez-Leonardo, M. Alajarín, 2014 .

Lewis acid catalyzed [3 + 2] annulation of ketenimines with donor-acceptor cyclopropanes: an approach to 2-alkylidenepyrrolidine derivatives.

A. Vidal, Raúl-Ángel Orenes, M. Alajarín, 2016, Organic & biomolecular chemistry.

Unprecedented intramolecular [3 + 2] cycloadditions of azido-ketenimines and azido-carbodiimides. Synthesis of indolo[1,2-a]quinazolines and tetrazolo[5,1-b]quinazolines.

A. Vidal, Raúl-Ángel Orenes, Baltasar Bonillo, 2011, Organic & biomolecular chemistry.

Synthesis of 2-substituted 4H-3,1-benzoxazin-4-ones by thermally induced cyclization of N-(2-benzyloxycarbonyl)phenyl ketenimines; oxygen-to- carbon migration of a benzyl group

A. Vidal, D. Bautista, M. Alajarín, 2005 .

Synthesis and molecular structure of beta-phosphinoyl carboxamides: an unexpected case of chiral discrimination of hydrogen-bonded dimers in the solid state.

P. Sánchez-Andrada, J. Berná, Aurelia Pastor, 2010, Chemistry.

Chemodivergent Conversion of Ketenimines Bearing Cyclic Dithioacetalic Units into Isoquinoline-1-thiones or Quinolin-4-ones as a Function of the Acetalic Ring Size.

A. Vidal, Marta Marín‐Luna, P. Sánchez-Andrada, 2019, The Journal of organic chemistry.

1,5-(H, RO, RS) shift/6π-electrocyclic ring closure tandem processes on N-[(α-heterosubstituted)-2-tolyl]ketenimines: a case study of relative migratory aptitudes and activating effects.

A. Vidal, Raúl-Ángel Orenes, Baltasar Bonillo, 2012, Organic & biomolecular chemistry.

Functionalization of Acetalic C(sp3)-H Bonds by Scandium(III) Triflate-Catalyzed Intramolecular Redox Reactions: Tandem 1,4-Hydride Transfer/1,5-Cyclization Processes Leading to Protected 1-Indanones

A. Vidal, Marta Marín‐Luna, M. Alajarín, 2011 .

Domino reactions initiated by intramolecular hydride transfers from tri(di)arylmethane fragments to ketenimine and carbodiimide functions.

A. Vidal, P. Sánchez-Andrada, Raúl-Ángel Orenes, 2010, Organic & biomolecular chemistry.

Intramolecular ketenimine-ketenimine [2 + 2] and [4 + 2] cycloadditions.

A. Vidal, P. Sánchez-Andrada, Baltasar Bonillo, 2007, The Journal of organic chemistry.

Hydricity-promoted [1,5]-H shifts in acetalic ketenimines and carbodiimides.

A. Vidal, P. Sánchez-Andrada, Baltasar Bonillo, 2006, Organic letters.

Tandem pseudopericyclic reactions: [1,5]-X sigmatropic shift/6pi-electrocyclic ring closure converting N-(2-X-carbonyl)phenyl ketenimines into 2-X-quinolin-4(3H)-ones.

A. Vidal, P. Sánchez-Andrada, M. Alajarín, 2006, The Journal of organic chemistry.

From ketenimines to ketenes to quinolones: two consecutive pseudopericyclic events.

A. Vidal, P. Sánchez-Andrada, D. Bautista, 2005, Organic letters.

Stereocontrol in the Synthesis of β-Lactams Arising from the Interlocked Structure of Benzylfumaramide-Based Hydrogen-Bonded [2]Rotaxanes

J. Berná, A. Martínez-Cuezva, C. Lopez-Leonardo, 2019, Synlett.

Tripod–Tripod Coupling of Triazides with Triphosphanes. The Synthesis, Characterization, and Stability in Solution of New Cage Compounds: Chiral Macrobicyclic Triphosphazides

A. Vidal, J. Berná, M. Alajarín, 1998 .

4,6-Diphenyl-2-methylthio-pyrylium Tetrafluoroborate: A New Reagent for the Dehydration of Aldoximes

P. Molina, M. Alajarín, M. Vilaplana, 1982 .

Cyclization of interlocked fumaramides into β-lactams: experimental and computational mechanistic assessment of the key intercomponent proton transfer and the stereocontrolling active pocket

Marta Marín‐Luna, J. Berná, Aurelia Pastor, 2020, Chemical science.

A new modular and flexible approach to [1,2,3]triazolo[1,5-a][1,4]benzodiazepines

M. Alajarin, Aurelia Pastor, J. M. Villalgordo, 2007 .

The Reaction of N-Substituted 4, 6-Diphenyl-1, 2-Dihydropyridine-2-Thiones With Mercury (II) Acetate: Conversion of Amines into Acetates

P. Molina, M. P. D. Vega, M. Alajarín, 1983 .

A Generalized and Efficient Preparation of a Novel Class of Macrocyclic Bis(guanidines) from Cyclic Bis(carbodiimides)

P. Molina, J. Sanz-Aparicio, P. Sánchez-Andrada, 1998 .

Tandem 1,5‐Hydride Shift/6π Electrocyclization of Ketenimines and Carbodiimides Substituted with Cyclic Acetal and Dithioacetal Functions: Experiments and Computations

A. Vidal, P. Sánchez-Andrada, Baltasar Bonillo, 2011 .

First radical addition onto ketenimines: a novel synthesis of indoles

A. Vidal, M. Alajarín, María-Mar Ortín, 2003 .

N‐Phenyl‐1,2,4‐triazoline‐3,5‐dione (PTAD) as a Dienophilic Dinitrogen Equivalent: A Simple Synthesis of 3‐Amino‐1,2,4‐benzotriazines from Arylcarbodiimides

M. Alajarin, A. Vidal, Marta Marín‐Luna, 2010 .

Polar hetero-Diels-Alder reactions of 4-alkenylthiazoles with 1,2,4-triazoline-3,5-diones: an experimental and computational study.

P. Sánchez-Andrada, Aurelia Pastor, D. Bautista, 2008, The Journal of organic chemistry.

Thermal cyclization of phenylallenes that contain ortho-1,3-dioxolan-2-yl groups: new cascade reactions initiated by 1,5-hydride shifts of acetalic H atoms.

M. Alajarin, A. Vidal, Marta Marín‐Luna, 2013, Chemistry.

Synthetic applications of bis(iminophosphoranes). One-pot preparation of rigid bicyclic guanidines

P. Molina, A. Vidal, M. Alajarín, 1993 .

One-pot preparation of rigid bicyclic guanidines from bis(iminophosphoranes) by a consecutive five-step process

P. Molina, A. Vidal, M. Alajarín, 1992 .

Diels-Alder reactions of 4-alkenylthiazoles: a new approach to thiazole functionalization.

P. Sánchez-Andrada, Aurelia Pastor, D. Bautista, 2007, The Journal of organic chemistry.

The Consecutive [2 + 2] Cycloaddition-Ring Expansion Route to Diastereomeric 1,4-Diazepin-5-ones from Imino-Ketenimines. Alternative Intramolecular Transamidation of β-Lactams.

A. Vidal, Fulgencio Tovar, M. Alajarín, 2005 .

C=C‐Conjugated Carbodiimides as 2‐Azadienes in Intramolecular (4 + 2) Cycloadditions. One‐Pot Preparation of Quinoline, α‐Carboline, and Quinindoline Derivatives.

P. Molina, A. Vidal, P. Sánchez-Andrada, 1992 .

Preparation of 4H-1,3,4-Thiadiazolo[2,3-c]-1,2,4-triazin-4-one Derivatives

P. Molina, M. Alajarín, R. Benzal, 1983 .

Acid-promoted cycloisomerizations of phenylallenes bearing acetalic functions at the ortho position: a stereocontrolled entry to indeno-fused dioxepanes, dioxocanes and thioanalogues.

A. Vidal, Marta Marín‐Luna, Raúl-Ángel Orenes, 2015, Organic & biomolecular chemistry.

Co-conformational Exchange Triggered by Molecular Recognition in a Di(acylamino)pyridine-Based Molecular Shuttle Containing Two Pyridine Rings at the Macrocycle.

Marta Marín‐Luna, J. Berná, Aurelia Pastor, 2016, Chemphyschem : a European journal of chemical physics and physical chemistry.

Tandem Processes in C-Aryl Ketenes and Ketenimines Triggered by [1,5]-Hydride-Like Migration of an Acetalic Hydrogen Atom

A. Vidal, Marta Marín‐Luna, M. Alajarín, 2014 .

Determination of the absolute configuration of the enantiomers of dihydroquinolines, isolated by chiral chromatography, by non empirical analysis of circular dichroism spectra and X-ray analysis

A. Vidal, C. Rosini, G. Mazzeo, 2011 .

Regio- and Stereoselective Nucleophilic Additions of Amines, Thiols and Aminophosphanes to the CC Bond of P,P-Diphenyl-P-(2-phenylethynyl)-λ5-phosphazenes.

C. Lopez-Leonardo, M. Alajarín, R. Raja, 2008 .

Aminophosphanes as Iminophosphoranyl Synthons: Efficient P-H Addition to Activated C=C Bonds

C. Lopez-Leonardo, M. Alajarín, Pilar Llamas-Lorente, 2004 .

The Alkylation of Aminophosphanes: A New Synthesis of Iminophosphoranes

C. Lopez-Leonardo, M. Alajarín, Pilar Llamas-Lorente, 2003 .

Synthesis and molecular structure of a new class of bi- and ter-dentate palladium complexes with iminophosphorane containing ligands

C. Lopez-Leonardo, D. Bautista, M. Alajarín, 2003 .

An efficient entry to monoiminophosphoranes derived from 1,2-bis(diphenylphosphino)ethane: new bidentate P,N ligands

C. Lopez-Leonardo, M. Alajarín, Pilar Llamas-Lorente, 2001 .

Tandem processes promoted by a hydrogen shift in 6-arylfulvenes bearing acetalic units at ortho position: a combined experimental and computational study

A. Vidal, Marta Marín‐Luna, P. Sánchez-Andrada, 2016, Beilstein journal of organic chemistry.

Iminophosphorane-substituted proton sponges. Part 5. Structures in the solid state. Correlation between solid state 31P MAS NMR spectra and crystal structures

P. Molina, A. Vidal, J. Elguero, 1994 .

Tandem [1,5]-H shift/6π-electrocyclizations of ketenimines bearing 1,3-oxathiane units. Computational assessment of the experimental diastereoselection

Pilar Sanchez-Andrada, Mateo Alajarin, Angel Vidal, 2012 .

Benzylic Newman–Kwart rearrangement of O-azidobenzyl thiocarbamates triggered by phosphines: pseudopericyclic [1,3] shifts via uncoupled concerted mechanisms

A. Vidal, Marta Marín‐Luna, P. Sánchez-Andrada, 2009 .

A regioselective entry to azirino[1,2-a]indole derivatives by epoxidation/staudinger reaction of o-allylphenyl azides

P. Molina, M. Alajarín, Antonia López-Lázaro, 1992 .

New Cage Compounds: Preparation and Characterization of Chiral C3-Symmetric Macrobicyclic Tris(phosphazides)†

P. Molina, C. Foces-Foces, M. Alajarín, 1997 .

Azodicarboxamides as template binding motifs for the building of hydrogen-bonded molecular shuttles.

J. Berná, Raúl-Ángel Orenes, M. Alajarín, 2010, Journal of the American Chemical Society.

A Practical Synthesis of the First P-Phosphinoylmethyl-λ5-phosphazenes.

C. Lopez-Leonardo, D. Bautista, M. Alajarín, 2001 .

Labile P C bonds: P -(phosphinoyl)methyl-λ 5 -phosphazenes and related compounds

C. Lopez-Leonardo, M. Alajarín, Pilar Llamas-Lorente, 2001 .

Ab initio SCF-MO study of the Staudinger phosphorylation reaction between a phosphane and an azide to form a phosphazene†

H. Rzepa, M. Alajarín, Carlota Conesa, 1999 .

Design and synthesis of a new macrobicyclic tris(phosphazide)

A. Vidal, J. Berná, C. Lopez-Leonardo, 1998 .

Exploring the Conversion of Macrocyclic 2,2'-Biaryl Bis(thioureas) into Cyclic Monothioureas: An Experimental and Computational Investigation.

A. Vidal, P. Sánchez-Andrada, Aurelia Pastor, 2018, The Journal of organic chemistry.

An efficient preparation of macrocycles containing two tetra-coordinate phosphorus atoms

P. Molina, A. Vidal, A. Arques, 1997 .

A NEW AND EFFICIENT PREPARATION OF CYCLIC CARBODIIMIDES FROM BIS(IMINOPHOSPHORANES) AND THE SYSTEM BOC2O/DMAP

P. Molina, J. Elguero, M. Jimeno, 1994 .

The X-ray crystal structure of a ternary cocrystallization compound : N,N-dimethyl-o-phenylenediamine-fluoroboric acid-triphenylphosphine oxide

P. Molina, A. Vidal, J. Elguero, 1991 .

Versatile control of the submolecular motion of di(acylamino)pyridine-based [2]rotaxanes† †Electronic supplementary information (ESI) available: Experimental procedures, spectroscopic and mass spectrometry data for all new compounds, electrochemical studies, and full crystallographic details of 1c a

M. Alajarin, M. Symes, J. Berná, 2015, Chemical science.

Homo and heteroassembly of amide-based [2]rotaxanes using α,α'-dimethyl-p-xylylenediamines.

J. Berná, A. Martínez-Cuezva, C. Lopez-Leonardo, 2019, Chemical communications.

Small-molecule recognition for controlling molecular motion in hydrogen-bond-assembled rotaxanes.

J. Berná, Aurelia Pastor, A. Martínez-Cuezva, 2014, Angewandte Chemie.

Redox divergent conversion of a [2]rotaxane into two distinct degenerate partners with different shuttling dynamics

J. Berná, M. Alajarín, Catalina Marín-Rodríguez, 2012 .

Ring‐to‐Thread Chirality Transfer in [2]Rotaxanes for the Synthesis of Enantioenriched Lactams

Marta Marín‐Luna, J. Berná, A. Martínez-Cuezva, 2022, Angewandte Chemie.

Mechanical bonding activation in rotaxane-based organocatalysts

M. Alajarin, J. Berná, M. Martins, 2021 .

Interlocking the Catalyst: Thread versus Rotaxane-Mediated Enantiodivergent Michael Addition of Ketones to β-Nitrostyrene.

Marta Marín‐Luna, J. Berná, D. Alonso, 2019, Organic letters.

Competitive binding for triggering a fluorescence response in a hydrazodicarboxamide-based [2]rotaxane.

J. Berná, M. Alajarín, Carlos Franco-Pujante, 2014, Organic & biomolecular chemistry.

Helical sense bias induced by point chirality in cage compounds.

M. Alajarin, A. Vidal, J. Steed, 2002, Angewandte Chemie.

Component exchange as a synthetically advantageous strategy for the preparation of bicyclic cage compounds.

J. Steed, J. Berná, C. Lopez-Leonardo, 2008, Chemical communications.

Highly diastereoselective self-assembly of chiral tris(m-ureidobenzyl)amino capsules.

M. Alajarin, J. Steed, A. Goeta, 2008, Chemical communications.

Self-assembly of tris(ureidobenzyl)amines: flexible bricks for robust architectures.

M. Alajarin, J. Steed, Aurelia Pastor, 2010, Chemical communications.

Dimeric self-assembling capsules derived from the highly flexible tribenzylamine skeleton.

J. Steed, Aurelia Pastor, Raúl-Ángel Orenes, 2002, The Journal of organic chemistry.

Nitrate-selective electrode based on a cyclic bis-thiourea ionophore

L. Bachas, V. Gavalas, ARTHUR CAMMERS, 2007 .

Self-assembly of tris(2-ureidobenzyl)amines: a new type of capped, capsule-like dimeric aggregates derived from a highly flexible skeleton.

J. Steed, R. Arakawa, Aurelia Pastor, 2004, Chemistry.

Structure, stability and guest affinity of tris(3-ureidobenzyl)amine capsules in solution.

Aurelia Pastor, Raúl-Ángel Orenes, P. Pregosin, 2007, Chemistry.

Pulsed gradient spin echo (PGSE) diffusion measurements as a tool for the elucidation of a new type of hydrogen-bonded bicapsular aggregate.

Aurelia Pastor, Raúl-Ángel Orenes, P. Pregosin, 2006, Chemistry.

A GENERALIZED AND EFFICIENT PREPARATION OF A NOVEL CLASS OF MACROCYCLIC BIS(GUANIDINES)

P. Molina, P. Sánchez-Andrada, M. Alajarín, 1995 .

Use of a guanidinium ionophore in a hydrogen sulfite-selective electrode

A. Vidal, L. Bachas, R. S. Hutchins, 1994 .

General Methods

M. Alajarin, A. Vidal, Marta Marín‐Luna, 2008 .

Dampened circumrotation by CH···π interactions in hydrogen bonded [2]rotaxanes.

J. Berná, M. Martins, Raúl-Ángel Orenes, 2012, Chemical communications.

Remote Photoregulated Ring Gliding in a [2]Rotaxane via a Molecular Effector.

N. McClenaghan, J. H. Tucker, J. Berná, 2017, Organic letters.

Effects on Rotational Dynamics of Azo and Hydrazodicarboxamide-Based Rotaxanes †

J. Berná, A. Martínez-Cuezva, Juan S. Martinez‐Espin, 2017, Molecules.

Dethreading of Tetraalkylsuccinamide-Based [2]Rotaxanes for Preparing Benzylic Amide Macrocycles.

M. Alajarin, J. Berná, C. Frizzo, 2015, The Journal of organic chemistry.

Mechanically Interlocked Profragrances for the Controlled Release of Scents.

J. Berná, Aurelia Pastor, M. Alajarín, 2021, The Journal of organic chemistry.

Light-responsive peptide [2]rotaxanes as gatekeepers of mechanised nanocontainers.

J. Berná, A. Martínez-Cuezva, M. Alajarín, 2015, Chemical communications.

Macrobicyclic triphosphazides and tri-λ5-phosphazenes derived from PhC(CH2PPh2)3. Two propeller-shaped diastereoisomers in the crystals

J. Steed, J. Berná, C. Lopez-Leonardo, 2007 .

Dimerization of tris(o-ureidobenzyl)amines: a novel class of aggregates

J. Steed, R. Arakawa, Aurelia Pastor, 2001 .

Unraveling the computed non-least motion pathway for the homodimerization of superchameleonic isocyanides: the peculiar nonsymmetrical (F-NC)2 reactant complex.

Marta Marín‐Luna, M. Alajarín, 2021, Physical chemistry chemical physics : PCCP.

Medium- and large-membered rings from bis(iminophosphoranes): An efficient preparation of cyclic carbodiimides

P. Molina, P. Sánchez-Andrada, M. Alajarín, 1993 .

Synthesis of an Adamantane-Based Tetralactam and Its Association with Dicarboxamides

J. Berná, A. Martínez-Cuezva, M. Alajarín, 2019, Proceedings.

A Facile Iminophosphorane-Mediated Synthesis of 1,2,4-Triazolo[5,1-c] [1,2,4]triazine Derivatives

P. Molina, M. Alajarín, J. Saez, 1984 .

Convenient Improved Syntheses of Isocyanates or Isothiocyanates from Amines

P. Molina, M. Alajarin, A. Arques, 1982 .

Lunularin Producers versus Non-producers: Novel Human Metabotypes Associated with the Metabolism of Resveratrol by the Gut Microbiota

J. Espín, M. Selma, F. Vallejo, 2022, Journal of agricultural and food chemistry.

5-Alkenylthiazoles as In-Out Dienes in Polar [4+2] Cycloaddition Reactions

P. Sánchez-Andrada, Aurelia Pastor, D. Bautista, 2013 .

A New Entry to the Thiazolo(3,2-a)Pyridine Ring System: Bromination of 1-Alkenyl-1,2-Dihydropyridine-2-Thiones

P. Molina, M. P. D. Vega, M. Alajarín, 1983 .

Preparation of fused meso-ionic compounds from 1-amino-4,6-diphenyl-2-pyridone

P. Molina, M. Alajarín, 1981 .

New Cyclization Mode of [N‐(Diarylmethyleneamino)carbonimidoyl]ketenes: Synthesis of 9H‐Pyrazolo[3,2‐b][1,3]benzoxazines

P. Sánchez-Andrada, M. Alajarín, N. Lisowskaya, 2006 .

Reactivity of 1,3-diaryl-2,4-bis(heteroarylimino)-1,3-diazetidines. Formation of N1,N2,N3,N4,N5-pentasubstituted biguanides

P. Molina, J. Elguero, F. H. Cano, 1989 .

Main Determinants Affecting the Antiproliferative Activity of Stilbenes and Their Gut Microbiota Metabolites in Colon Cancer Cells: A Structure–Activity Relationship Study

J. Espín, M. Selma, A. González‐Sarrías, 2022, International journal of molecular sciences.

4-Hydroxydibenzyl: a novel metabolite from the human gut microbiota after consuming resveratrol.

J. Espín, M. Selma, F. Vallejo, 2022, Food & function.

Theoretical study of the mechanism of dimerization of N,C-disubstituted carbodiimides

P. Molina, J. Bertrán, J. Elguero, 1992 .

The network simulation method: a useful tool for locating the kinetic-thermodynamic switching point in complex kinetic schemes.

Manuel Caravaca, Pilar Sanchez-Andrada, Antonio Soto, 2014, Physical chemistry chemical physics : PCCP.

Hydrogen sulfite optical sensor based on a lipophilic guanidinium ionophore

A. Vidal, I. Badr, L. Bachas, 1999 .

On the mechanism of phthalimidine formation via o-phthalaldehyde monoimines. New [1,5]-H sigmatropic rearrangements in molecules with the 5-aza-2,4-pentadienal skeleton.

P. Sánchez-Andrada, C. Lopez-Leonardo, M. Alajarín, 2005, The Journal of organic chemistry.

Iminophosphorane-substituted proton sponges. Part 4. Comparison of X-ray molecular structures with solution properties (pKa, 1H and 13C NMR spectroscopy)

P. Molina, A. Vidal, J. Elguero, 1993 .

Salicylate-selective electrode based on a biomimetic guanidinium ionophore.

A. Vidal, L. Bachas, R. S. Hutchins, 1997, Analytical chemistry.

On the protonation of a macrobicyclic cage: an inert tribenzylamine fragment and three robust aminophosphonium units

J. Steed, J. Berná, C. Lopez-Leonardo, 2006 .

Helical chirality transmission through a p-phenylene fragment in a hexa-lambda5-phosphazene.

J. Berná, C. Lopez-Leonardo, M. Alajarín, 2007, Organic letters.

Control of the assembly of a cyclic hetero[4]pseudorotaxane from a self-complementary [2]rotaxane

D. Quiñonero, J. Berná, Aurelia Pastor, 2023, Chemical science.

An Efficient Regioselective Synthesis of 7-Substituted 1,3-Dimethyl-4-oxo-4H-1,3,4-thiadiazolo[2,3-c]-1,2,4-triazinium Cations.

P. Molina, M. Alajarín, F. Navarro, 1986 .

New Models for the Study of the Racemization Mechanism of Carbodiimides. Synthesis and Structure (X-ray Crystallography and (1)H NMR) of Cyclic Carbodiimides.

P. Molina, J. Anderson, J. Elguero, 1996, The Journal of organic chemistry.

An AM1 and PM3 molecular orbital study of the pericyclic reactivity of aryl carbodiimides.

P. Molina, A. Vidal, H. Rzepa, 1992 .

Two C3‐symmetrical tris(ortho‐substituted) tribenzylamines

P. Molina, A. Llamas-Saiz, C. Foces-Foces, 1999 .

On the mechanism of conversion of N-acyl-4-acyloxy-beta-lactams into 2-substituted 1,3-oxazin-6-ones. Can a low-barrier transition state be antiaromatic?

A. Arrieta, F. Cossío, P. Sánchez-Andrada, 2001, The Journal of organic chemistry.

Self-assembly of tris(ureidobenzyl)amines: flexible bricks for robust architectures.

J. Steed, Aurelia Pastor, Raúl-Ángel Orenes, 2010, Chemical communications.

Violations to the principle of least motion: the shortest path is not always the fastest.

Marta Marín‐Luna, M. C. Reis, M. Alajarín, 2022, Physical Chemistry, Chemical Physics - PCCP.

Iminophosphorane-substituted proton sponges. Part 1. X-ray molecular structures of 1,8-diaminonaphthalene and 1-amino-8-triphenylphosphoranylideneaminonaphthalene

José Elguero, Mateo Alajarin, Concepción Foces-Foces, 1991 .

Host-guest compounds. x-ray structure, differential scanning calorimetry, and thermogravimetry of methanol, ethanol, isopropanol, tert-butanol and dioxame Inclusion compounds in 7-benzoyl-6-phenyl-6,7-dihydro-1-methyl-3-methylthio-5-1.2,4-triazolo[3.4-][1,3,4]thiadiazinium bromide

P. Molina, J. Elguero, C. Foces-Foces, 1988 .

Homo and heteroassembly of amide-based [2]rotaxanes using α,α'-dimethyl-p-xylylenediamines.

J. Berná, C. Lopez-Leonardo, D. Bautista, 2019, Chemical Communications.

Photoswitchable interlocked thiodiglycolamide as a cocatalyst of a chalcogeno-Baylis–Hillman reaction

J. Berná, Raúl-Ángel Orenes, Cristian Navarro, 2017, Chemical science.

Azodicarboxamides as template binding motifs for the building of hydrogen-bonded molecular shuttles.

J. Berná, Raúl-Ángel Orenes, M. Alajarín, 2010, Journal of the American Chemical Society.

Light-responsive peptide [2]rotaxanes as gatekeepers of mechanised nanocontainers.

J. Berná, M. Alajarín, S. Valero-Moya, 2015, Chemical communications.

Lewis Acid-mediated Formation of 1,3-Disubstituted Spiro[cyclopropane-1,2'-indanes]: The Activating Effect of the Cyclopropane Walsh Orbital.

M. Alajarin, A. Vidal, Marta Marín‐Luna, 2020, The Journal of organic chemistry.

Unlocking the synthetic potential of aziridine and cyclopropane-fused quinolin-2-ones by regioselective fragmentation of its three-membered rings

A. Vidal, P. Sánchez-Andrada, Raúl-Ángel Orenes, 2020 .

Molecular containers: design approaches and applications

A. Pastor, M. Alajarín, D. Turner, 2004 .