A. Choplin

发表

Tetraneopentyltitanium Derived Silica Supported Complexes: Part 2. Influence of the Hydrophobic Character of Silica on the Catalytic Properties

F. Quignard, S. Holmes, A. Choplin, 1998 .

Palladium(0)-catalyzed substitution of allylic substrates in perfluorinated solvents

W. Leitner, R. Kling, F. Quignard, 1998 .

Surface organometallic chemistry: A new approach to heterogeneous Catal.ysis ?

J. Basset, A. Choplin, 1983 .

Surface organometallic chemistry: formation of HFe3(CO)11- from Fe3(CO)12and Fe(CO)5on silica, alumina, magnesia, and zinc oxide

M. Primet, Y. Taârit, A. K. Smith, 1982 .

Some recent aspects of surface organometallic chemistry

C. Santini, J. Candy, J. Basset, 1989 .

Catalytic Cleavage of the C-H and C-C Bonds of Alkanes by Surface Organometallic Chemistry: An EXAFS and IR Characterization of a Zr-H Catalyst

F. Quignard, V. Dufaud, F. Lefebvre, 1996, Science.

Surface organometallic chemistry: hydrogenation of ethylene with Os3(CO)10(.mu.-H)(.mu.-OSi.rscharw.) and Os3(CO)10(.mu.-H)(.mu.-OPh). Evidence for cluster catalysis

J. Basset, R. Sánchez-Delgado, B. Besson, 1988 .

Catalysis by supported clusters: two examples of catalytic reactions that involve a molecular cluster frame

A. Théolier, B. Besson, J. Basset, 1982, Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences.

Microwave spectrum and ring structure of cyclopropyl cyanide

V. Laurie, R. Pearson, A. Choplin, 1975 .

Microwave spectrum of cyclopropane(1,1)dicarbonitrile

J. Schwartz, V. Laurie, R. Pearson, 1975 .

A molecular route towards silica supported zirconium catalysts active for the mild oxidation of olefins with H2O2

F. Quignard, A. Choplin, R. Teissier, 1997 .

Heterogeneous catalysts from organometallic precursors: how to design isolated, stable and active sites. Applications to zirconium catalyzed organic reactions

F. Quignard, P. Leyrit, A. Choplin, 1997 .

Palladium(0) allylic alkylation in a two-phase system or with a supported aqueous phase catalyst

F. Quignard, D. Sinou, A. Choplin, 1998 .

From supported homogeneous catalysts to heterogeneous molecular catalysts

F. Quignard, A. Choplin, 1998 .

cis and trans structures for bis-pyridine adducts of Nickel (II) β-diketonates

A. Choplin, R. Hugel, 1974 .

Chemical grafting of tin alkyl complexes on the external surface of mordenite: A method for controlling the size of the pore entrances of zeolites

F. Lefebvre, J. Basset, A. Théolier, 1994 .

Cellulose: a new bio-support for aqueous phase catalysts

F. Quignard, A. Choplin, 2001 .

Surface organometallic chemistry on zeolites: control of the pore opening of mordenite by grafting of thermally stable GeBu3 fragments

J. Basset, E. Benazzi, J. Joly, 1994 .

Group 4 alkyl complexes as precursors of silica anchored molecular catalysts for the reduction of ketones by hydrogen transfer

F. Quignard, O. Graziani, A. Choplin, 1999 .

Surface organometallic chemistry of tin: reactivity of tetraalkyltin complexes and tributyltin hydride toward silica

F. Lefebvre, J. Basset, A. Théolier, 1993 .

From clusters and surfaces to clusters on surfaces: an opening toward surface organometallic chemistry

F. Quignard, C. Santini, J. Candy, 1991 .

The structures of alkenyl- and allyl-magnesium intermediates in the self-hydrogenation of prpyne and allene of magnesium films

Y. Gault, A. Choplin, 1979 .

From synthesis to chemical reactivity of supported d0 complexes. Part 1. An in situ infrared spectroscopic study of silica-anchored zirconium hydrides

F. Quignard, J. Basset, C. Lecuyer, 1994 .

9.9 – Supported Metal Complexes as Catalysts

F. Quignard, A. Choplin, 2003 .

Tetraneopentyltitanium Derived Supported Catalysts: Part 1. Synthesis and Catalytic Properties for the Epoxidation of Cyclohexene with Aqueous Hydrogen Peroxide

F. Quignard, S. Holmes, A. Choplin, 1998 .

A novel heterogeneous molecular catalyst for the Meerwein-Ponndorf-Verley and Oppenauer reactions

F. Quignard, P. Leyrit, A. Choplin, 1996 .

From synthesis to chemical reactivity of supported d0 complexes. Part 2. Reactivity of silica-anchored alkylzirconium complexes. An attempt toward functionaltzation of alkanes

F. Quignard, J. Basset, A. Choplin, 1994 .

Surface organometallic chemistry : molecular approaches to surface catalysis

Bruce C. Gates, Jean-Marie Basset, Jean-Pierre Candy, 1988 .

Alkane activation by a highly electrophilic zirconium hydride complex supported on silica

F. Quignard, J. Basset, A. Choplin, 1991 .

Surface Organometallic Chemistry of Tin: Reaction of Hydridotris(butyl)tin with the Surfaces of Partially Dehydroxylated Aluminas

F. Lefebvre, J. Basset, E. Benazzi, 1994 .

Surface Organometallic Chemistry of Tin: Reaction of (n-C4H9)3SnH with the Surface of a Silica-Alumina. A 13C and 119Sn Solid-State NMR Investigation

F. Lefebvre, J. Basset, A. Choplin, 1994 .

Formation of iron-osmium, iron-ruthenium, and iron-cobalt bimetallic particles by thermal decomposition of heteropolynuclear clusters supported on partially dehydroxylated magnesia

P. Gallezot, J. Basset, A. Théolier, 1986 .

Bimetallic catalysts starting from heteropolymetallic clusters: Surface organometallic chemistry and Fischer-Tropsch activity of an Fe—Os system

M. Leconte, J. Basset, S. Shore, 1983 .

Catalytic hydrogenation of ethylene with (H)Os3(CO)10(OSi): spectroscopic evidence for a cluster catalysed reaction

J. Basset, B. Besson, A. Choplin, 1982 .

IR studies and hydrogenation catalytic activity of heterogeneous catalysts prepared by thermal treatments of a face-bridged triruthenium carbonyl cluster supported on silica and alumina

A. Théolier, J. A. Cabeza, J. Fernández‐Colinas, 1995 .

The characterization and thermal stability of a cluster grafted on silica surface

J. Basset, A. Théolier, C. Sourisseau, 1983 .

A surface organometallic approach to the process of formation of bimetallic particles from bimetallic supported molecular clusters

J. Basset, S. Shore, R. Mathieu, 1989 .

From clusters and surfaces to clusters on surfaces: an opening toward surface organometallic chemistry

F. Quignard, C. Santini, J. Candy, 1991 .

Surface organometallic chemistry: formation of the grafted dianionic cluster [Rh6(CO)15]2− upon adsorption of Rh6(CO)16 on a partially-hydroxylated magnesia

P. Dufour, J. Basset, R. Sánchez-Delgado, 1988 .

Surface supported metal cluster carbonyls. Chemisorption, reactivity, and decomposition of Ru3(CO)12 on silica

R. Psaro, J. Basset, A. Théolier, 1985 .

Sonogashira coupling: silica supported aqueous phase palladium catalysts versus their homogeneous analogs

F. Quignard, A. Choplin, Severine Larbot, 2002 .

Organometallic chemistry as a basis for understanding heterogeneous catalysis

F. Quignard, M. Leconte, S. Scott, 1994 .

Surface Organometallic Chemistry on Oxides, on Zeolites and on Metals

J. Candy, M. Leconte, J. Basset, 1990 .

Surface organometallic chemistry: formation of the grafted anionic clusters [HFeOs3(CO)13]−, [HFeRu3(CO)13]−, and [FeCo3(CO)12]− on a hydroxylated magnesia

J. Basset, S. Shore, R. Mathieu, 1986 .

Formation of Fe-Os, Fe-Ru, and Fe-Co bimetallic particles by thermal decomposition of heteropolynuclear clusters supported on a partially dehydroxylated magnesia

P. Gallezot, J. Basset, A. Théolier, 1986 .

Mechanistic Relationships Between Homogeneous and Heterogeneous Catalysis: Some Concepts Arising from Surface Organometallic Chemistry.

P. Dufour, J. Candy, J. Basset, 1988 .

Surface organometallic chemistry of rhenium: Attempts to characterize a surface carbene in metathesis of olefins with the catalyst CH3ReO3/Nb2O5

W. Herrmann, M. Leconte, J. Basset, 1992 .

Models for partially hydroxylated silica and alumina and the modeling of metal-support interaction of triosmium clusters on silica and alumina

J. Basset, L. Hsu, S. Shore, 1994 .

Microwave spectrum and dipole moment of norbornane

A. Choplin, 1980 .

A surface organometallic approach to the synthesis of rhenium-based catalysts for the metathesis of olefins: CH3ReO3/Nb2O5

A. Auroux, W. Herrmann, F. Lefebvre, 1992 .

Molecular heterogeneous metathesis catalysts: an attempted synthesis of surface-anchored alkylidenetungsten complexes

M. Leconte, J. Basset, R. Buffon, 1994 .

The reaction of tungsten(VI) alkylidyne complexes with inorganic oxides: involvement of the resulting alkylidene ligand in olefin metathesis

M. Leconte, J. Basset, R. Buffon, 1993 .

Microwave spectrum of the 13C-ring-monosubstituted toluenes and structure of toluene

J. Demaison, G. Roussy, A. Choplin, 1981 .

Allylic substitution catalysed by silica-supported aqueous phase palladium(0) catalysts

F. Quignard, D. Sinou, A. Choplin, 2000 .

Supported Aqueous Phase Catalysts for the C-C and C-N Bond Formation

F. Quignard, D. Sinou, A. Choplin, 1998 .

ALLYLIC ALKYLATION WITH A SUPPORTED AQUEOUS PHASE PALLADIUM CATALYST

F. Quignard, P. Schneider, D. Sinou, 1996 .

Surface Organometallic Chemistry of Germanium: Evidence for the Formation of Highly Thermally Stable .tplbond.Si-O-GeR3 Fragments by Reaction of GeR4 Complexes (R = n-Bu, Et) with the Surface of Silica

J. Basset, E. Benazzi, A. Choplin, 1994 .

Monodisperse colloidal metal particles from nonaqueous solutions: Catalytic behavior in hydrogenation of but-1-ene of platinum, palladium, and rhodium particles supported on pumice

P. Stenius, G. Maire, M. Boutonnet, 1987 .

Thermal decomposition of Fe3(CO)12 adsorbed on silica: A study by gas-phase analysis, infrared spectroscopy, magnetization measurements, ferromagnetic resonance and Mössbauer spectroscopy

J. Dalmon, J. Basset, P. Bussière, 1985 .

Surface Organometallic Chemistry on Oxides: Selective Catalytic Low‐Temperature Hydrogenolysis of Alkanes by a Highly Electrophilic Zirconium Hydride Complex Supported on Silica

F. Quignard, J. Basset, C. Lecuyer, 1991 .

Oxidative dimerization of methane: a surface organometallic approach to lithium doped magnesia or silica catalysts

P. D. L. Piscina, J. Basset, M. Ceruso, 1989 .

Supported Aqueous-Phase Palladium Catalysts for the Reaction of Allylic Substitution: Toward an Understanding of the Catalytic System

Y. Tong, J. Dutasta, D. Sinou, 1998 .

Surface Organometallic Chemistry: A New Approach to Heterogeneous Catalysis?

J. Basset, A. Choplin, 1984 .

Separation properties of an H-Mordenite modified by anchored tris(methyl)-tin and -germanium complexes

J. Basset, A. Théolier, E. Benazzi, 1994 .

A Surface Organometallic Approach for Controlling the Pore Opening Size of Zeolites: the Case of Mordenite Modified via Grafting of Dineopentylmagnesium†

J. Basset, A. Théolier, F. Raatz, 1990 .

Metal-support interaction: (μ-H)(μ-OSiEt3)Os3(CO)10, A molecular analogue of a surface complex and the computer modelled surface structures of (μ-H)(μ-OSi)Os3(CO)10 and (μ-OSi)2Os3(CO)10

J. Basset, L. Hsu, S. Shore, 1988 .

Metal-Support Interaction: (μ-H)(μ-OSiEt3)Os3(CO)10, a Molecular Analogue of a Surface Complex and the Computer Modelled Surface Structures of (μ-H)(μ-OSi-)Os3(CO)10 and (μ-OSi-)2Os3(CO)10

J. Basset, L. Hsu, S. Shore, 1989 .

Surface organometallic chemistry on zeolites: A tool for modifying the sorption properties of zeolites

A. Choplin, 1994 .

Surface organometallic chemistry of zirconium: Application to the stoichiometric activation of the CH bonds of alkanes and to the low-temperature catalytic hydrogenolysis of alkanes

F. Quignard, J. Basset, D. Olivier, 1992 .