Steven J. Malcolmson

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CCDC 1548670: Experimental Crystal Structure Determination

Paige E. Daniel, Alexandria E. Weber, Steven J. Malcolmson, 2017 .

CCDC 1548671: Experimental Crystal Structure Determination

Paige E. Daniel, Alexandria E. Weber, Steven J. Malcolmson, 2017 .

CCDC 1548669: Experimental Crystal Structure Determination

Paige E. Daniel, Alexandria E. Weber, Steven J. Malcolmson, 2017 .

Catalytic enantioselective olefin metathesis in natural product synthesis. Chiral metal-based complexes that deliver high enantioselectivity and more.

Steven J. Malcolmson, A. Hoveyda, S. Meek, 2010, Angewandte Chemie.

Strategies for the Catalytic Enantioselective Synthesis of α-Trifluoromethyl Amines.

Steven J. Malcolmson, Chibueze I Onyeagusi, 2020, ACS catalysis.

Umpolung Synthesis of 1,3-Amino Alcohols: Stereoselective Addition of 2-Azaallyl Anions to Epoxides.

Paige E. Daniel, Alexandria E. Weber, Steven J. Malcolmson, 2017, Organic letters.

2-Azadienes as Enamine Umpolung Synthons for the Preparation of Chiral Amines

Steven J. Malcolmson, X. Shao, Kangnan Li, 2019, Synlett.

Diastereoselective and Enantiospecific Synthesis of 1,3-Diamines via 2-Azaallyl Anion Benzylic Ring-Opening of Aziridines.

Alexandria E. Weber, Steven J. Malcolmson, Kangnan Li, 2017, Organic letters.

Palladium-Catalyzed Synthesis of α-Trifluoromethyl Benzylic Amines via Fluoroarylation of gem-Difluoro-2-azadienes Enabled by Phosphine-Catalyzed Formation of an Azaallyl-Silver Intermediate.

Paige E. Daniel, Steven J. Malcolmson, A. Ribeiro, 2018, ACS catalysis.

The posttranslational modification cascade to the thiopeptide berninamycin generates linear forms and altered macrocyclic scaffolds

Steven J. Malcolmson, C. Walsh, J. Ruby, 2013, Proceedings of the National Academy of Sciences.

Nine enzymes are required for assembly of the pacidamycin group of peptidyl nucleoside antibiotics.

Steven J. Malcolmson, N. Kelleher, C. Walsh, 2011, Journal of the American Chemical Society.

Catalyst‐Controlled Stereoselective Olefin Metathesis

Steven J. Malcolmson, A. Hoveyda, S. Torker, 2015 .

Bipyridine Adducts of Molybdenum Imido Alkylidene and Imido Alkylidyne Complexes.

Steven J. Malcolmson, R. Schrock, P. Müller, 2012, Organometallics.

Design and stereoselective preparation of a new class of chiral olefin metathesis catalysts and application to enantioselective synthesis of quebrachamine: catalyst development inspired by natural product synthesis.

Steven J. Malcolmson, R. Schrock, E. Sattely, 2009, Journal of the American Chemical Society.

Highly efficient molybdenum-based catalysts for enantioselective alkene metathesis

Steven J. Malcolmson, R. Schrock, E. Sattely, 2008, Nature.

Development and Mechanistic Investigations of Enantioselective Pd-Catalyzed Intermolecular Hydroaminations of Internal Dienes

Steven J. Malcolmson, Sangjune Park, 2018, ACS Catalysis.

A Diastereodivergent and Enantioselective Approach to syn- and anti-Diamines: Development of 2-Azatrienes for Cu-Catalyzed Reductive Couplings with Imines That Furnish Allylic Amines.

Steven J. Malcolmson, X. Shao, Pengfei Zhou, 2021, Journal of the American Chemical Society.

Catalytic Enantio- and Regioselective Addition of Nucleophiles in the Intermolecular Hydrofunctionalization of 1,3-Dienes

Steven J. Malcolmson, N. J. Adamson, 2019, ACS Catalysis.

Enantioselective Synthesis of anti-1,2-Diamines by Cu-Catalyzed Reductive Couplings of Azadienes with Aldimines and Ketimines.

Steven J. Malcolmson, X. Shao, Kangnan Li, 2018, Journal of the American Chemical Society.

2-Azadienes as Reagents for Preparing Chiral Amines: Synthesis of 1,2-Amino Tertiary Alcohols by Cu-Catalyzed Enantioselective Reductive Couplings with Ketones.

Steven J. Malcolmson, X. Shao, Kangnan Li, 2018, Journal of the American Chemical Society.

Enantioselective Intermolecular Addition of Aliphatic Amines to Acyclic Dienes with a Pd-PHOX Catalyst.

Steven J. Malcolmson, E. Hull, N. J. Adamson, 2017, Journal of the American Chemical Society.

Enantioselective synthesis of P-stereogenic phosphinates and phosphine oxides by molybdenum-catalyzed asymmetric ring-closing metathesis.

Steven J. Malcolmson, R. Schrock, A. Hoveyda, 2009, Angewandte Chemie.

Catalytic Enantio- and Diastereoselective Cyclopropanation of 2-Azadienes for the Synthesis of Aminocyclopropanes Bearing Quaternary Carbon Stereogenic Centers.

Steven J. Malcolmson, X. Shao, 2019, Organic letters.

Brønsted acid and Pd–PHOX dual-catalysed enantioselective addition of activated C-pronucleophiles to internal dienes

Steven J. Malcolmson, Sangjune Park, N. J. Adamson, 2019, Chemical science.

Enantioselective Intermolecular Pd-Catalyzed Hydroalkylation of Acyclic 1,3-Dienes with Activated Pronucleophiles.

Steven J. Malcolmson, N. J. Adamson, K. Wilbur, 2018, Journal of the American Chemical Society.

Preparation of Chiral Allenes through Pd-Catalyzed Intermolecular Hydroamination of Conjugated Enynes: Enantioselective Synthesis Enabled by Catalyst Design.

Steven J. Malcolmson, Haleh Jeddi, N. J. Adamson, 2019, Journal of the American Chemical Society.

Enantio- and Diastereoselective Synthesis of Homoallylic α-Trifluoromethyl Amines by Catalytic Hydroalkylation of Dienes.

Steven J. Malcolmson, X. Shao, Chibueze I Onyeagusi, 2020, Organic letters.

Molybdenum, [(S)‐3,3′‐Bis(1,1‐dimethylethyl)‐5,5′, 6,6′‐tetramethyl[1,1′‐biphenyl]‐2,2′‐diolato(2−)‐κO,κO′]‐2‐methyl‐2‐phenylpropylidene)[tricyclo[3.3.1.1]decan‐1‐aminato(2−)]

Steven J. Malcolmson, R. Schrock, A. Hoveyda, 2007 .

Direct Hyperpolarization of Nitrogen-15 in Aqueous Media with Parahydrogen in Reversible Exchange.

Steven J. Malcolmson, M. C. Feiters, B. Blümich, 2017, Journal of the American Chemical Society.

Hyperpolarization of Nitrogen-15 Schiff Bases by Reversible Exchange Catalysis with para-Hydrogen.

Steven J. Malcolmson, T. Theis, W. Warren, 2016, Chemistry.

Direct and cost-efficient hyperpolarization of long-lived nuclear spin states on universal 15N2-diazirine molecular tags

Steven J. Malcolmson, V. Blum, W. Huhn, 2016, Science Advances.

Diazirines as Potential Molecular Imaging Tags: Probing the Requirements for Efficient and Long-Lived SABRE-Induced Hyperpolarization.

Steven J. Malcolmson, T. Theis, W. Warren, 2017, Angewandte Chemie.

Enantioselective Construction of Quaternary Stereogenic Centers by the Addition of an Acyl Anion Equivalent to 1,3-Dienes.

Steven J. Malcolmson, Pengfei Zhou, Sangjune Park, 2020, Organic letters.

Racing against unwanted isomerization

Steven J. Malcolmson, 2021, Science.

Dihydrophenylalanine: a prephenate-derived Photorhabdus luminescens antibiotic and intermediate in dihydrostilbene biosynthesis.

Steven J. Malcolmson, C. Walsh, J. Crawford, 2011, Chemistry & biology.

Generalizing, Extending, and Maximizing Nitrogen-15 Hyperpolarization Induced by Parahydrogen in Reversible Exchange

Steven J. Malcolmson, E. Chekmenev, T. Theis, 2017, The journal of physical chemistry. C, Nanomaterials and interfaces.

Catalytic Enantioselective Olefin Metathesis and Natural Product Synthesis

Steven J. Malcolmson, A. Hoveyda, S. Meek, 2010 .

Enantioselective synthesis of cyclic enol ethers and all-carbon quaternary stereogenic centers through catalytic asymmetric ring-closing metathesis.

Steven J. Malcolmson, R. Schrock, A. Hoveyda, 2006, Journal of the American Chemical Society.

Three ring posttranslational circuses: insertion of oxazoles, thiazoles, and pyridines into protein-derived frameworks.

Steven J. Malcolmson, C. Walsh, T. Young, 2012, ACS chemical biology.

The significance of degenerate processes to enantioselective olefin metathesis reactions promoted by stereogenic-at-Mo complexes.

Steven J. Malcolmson, R. Schrock, Bo Li, 2009, Journal of the American Chemical Society.

Rational ligand choice extends the SABRE substrate scope.

Steven J. Malcolmson, V. Blum, E. Chekmenev, 2020, Chemical communications.

The significance of degenerate processes to enantioselective olefin metathesis reactions promoted by stereogenic-at-Mo complexes.

Steven J. Malcolmson, R. Schrock, Bo Li, 2009, Journal of the American Chemical Society.

Steven J. Malcolmson, R. Schrock, A. Hoveyda, 2009, Journal of the American Chemical Society.

Palladium-Catalyzed Regiodivergent Three-Component Alkenylamination of 1,3-Dienes with Alkyl and Aryl Amines.

Steven J. Malcolmson, Xiaoxiao Ma, 2023, Journal of the American Chemical Society.