Roman B. Laritchev

Iridium and Rhodium Complexes Containing Fluorinated Phenyl Ligands and Their Transformation to η2-Benzyne Complexes, Including the Parent Benzyne Complex IrCp*(PMe3)(C6H4)

C. Incarvito, A. Rheingold, R. Hughes, 2002 .

A simple route to difluorocarbene and perfluoroalkylidene complexes of iridium.

A. Rheingold, R. Hughes, J. Golen, 2005, Journal of the American Chemical Society.

Carbon-fluorine bond activation coupled with carbon-carbon bond formation at iridium. Confirmation of complete kinetic diastereoselectivity at the new carbon stereocenter by intramolecular trapping using vinyl as the migrating group.

L. Zakharov, A. Rheingold, R. Hughes, 2005, Journal of the American Chemical Society.

Reductive Activation of Carbon−Fluorine Bonds in Perfluoroalkyl Ligands: An Unexpected Route to the Only Known Tetrafluorobutatriene Transition Metal Complex: Ir(η5-C5Me5)(PMe3)(2,3-η2-CF2CCCF2)

L. Zakharov, A. Rheingold, R. Hughes, 2004 .

Unexpected Formation of an Organoplatinum(IV) Fluoride Complex in the Reaction of Pt(TMEDA)(CH3)2 with Perfluoro-sec-butyl Iodide

L. Zakharov, A. Rheingold, R. Hughes, 2005 .

Reactions of iridium and rhodium complexes containing η2-benzyne, η2-tetrafluorobenzyne, and η2-trifluorobenzyne ligands. Differential rates of arene elimination by protonation of isomeric fluoroaryl complexes and restricted rotation of PMe3 ligands in ortho-iodo and ortho-bromoaryl complexes

L. Zakharov, C. Incarvito, A. Rheingold, 2003 .