M. Brown

发表

Highly enantioselective Cu-catalyzed conjugate additions of dialkylzinc reagents to unsaturated furanones and pyranones: preparation of air-stable and catalytically active Cu-peptide complexes.

A. Hoveyda, M. K. Brown, S. Degrado, 2005, Angewandte Chemie.

Allenylidene Induced 1,2-Metalate Rearrangement of Indole-Boronates: Diastereoselective Access to Highly Substituted Indolines.

M. K. Brown, A. Simlandy, M. Brown, 2021, Angewandte Chemie.

Allenoates in Enantioselective [2+2] Cycloadditions: From a Mechanistic Curiosity to a Stereospecific Transformation.

J. Wiest, M. K. Brown, Michael L Conner, 2018, Journal of the American Chemical Society.

Ladderane Natural Products: From the Ground Up.

M. K. Brown, Erin N. Hancock, M. Brown, 2020, Chemistry.

Sulfonate N-Heterocyclic Carbene-Copper Complexes: Uniquely Effective Catalysts for Enantioselective C-C, C-B, C-H, and C-Si Bond Formation.

A. Hoveyda, S. Torker, M. K. Brown, 2020, Angewandte Chemie.

Stereoselective synthesis of all-carbon tetrasubstituted alkenes from in situ generated ketenes and organometallic reagents.

M. K. Brown, Yan Li, Wei You, 2013, Organic letters.

Photochemical intermolecular dearomative cycloaddition of bicyclic azaarenes with alkenes

F. Glorius, K. Houk, Xiaolong Zhang, 2021, Science.

Stereoselective [4+2]-Cycloaddition with Chiral Alkenylboranes.

K. Houk, Hong Zhang, M. K. Brown, 2020, Angewandte Chemie.

Recent advances in the synthesis of gem-dimethylcyclobutane natural products.

J. Wiest, M. K. Brown, Erin N. Hancock, 2019, Natural product reports.

An unexpected Lewis acid catalyzed Diels-Alder cycloaddition of aryl allenes and acrylates.

M. K. Brown, Michael L Conner, M. Brown, 2016, Tetrahedron.

Synthese von Cyclobutanen und Cyclobutenen: katalytische enantioselektive [2+2]‐Cycloadditionen

M. K. Brown, Y. Xu, Michael L Conner, 2015 .

Cyclobutane and cyclobutene synthesis: catalytic enantioselective [2+2] cycloadditions.

M. K. Brown, Y. Xu, Michael L Conner, 2015, Angewandte Chemie.

Stereoselective [2+2]-Cycloadditions of chiral allenic ketones and alkenes: Applications towards the synthesis of benzocyclobutenes and endiandric acids.

M. K. Brown, Renyu Guo, Brittany P. Witherspoon, 2022, Tetrahedron.

Boronic Ester Enabled [2 + 2]-Cycloadditions by Temporary Coordination: Synthesis of Artochamin J and Piperarborenine B.

M. K. Brown, Yanyao Liu, Dongshun Ni, 2022, Journal of the American Chemical Society.

Synthesis of ent-[3]-Ladderanol: Development and Application of Intramolecular Chirality Transfer [2+2] Cycloadditions of Allenic Ketones and Alkenes.

M. K. Brown, Erin N. Hancock, Nathan J. Line, 2017, Journal of the American Chemical Society.

Canvass: A Crowd-Sourced, Natural-Product Screening Library for Exploring Biological Space

Jared T. Shaw, Derek S. Tan, D. E. Olson, 2018, ACS central science.

Lewis acid-promoted ketene-alkene [2 + 2] cycloadditions.

Christopher M. Rasik, M. Kevin Brown, M. K. Brown, 2013, Journal of the American Chemical Society.

Enantioselective synthesis of all-carbon quaternary stereogenic centers by catalytic asymmetric conjugate additions of alkyl and aryl aluminum reagents to five-, six-, and seven-membered-ring beta-substituted cyclic enones.

A. Hoveyda, Tricia L. May, M. K. Brown, 2008, Angewandte Chemie.

A practical method for enantioselective synthesis of all-carbon quaternary stereogenic centers through NHC-Cu-catalyzed conjugate additions of alkyl- and arylzinc reagents to beta-substituted cyclic enones.

A. Hird, A. Hoveyda, M. K. Brown, 2006, Journal of the American Chemical Society.

Copper-catalyzed cross-coupling of boronic esters with aryl iodides and application to the carboboration of alkynes and allenes.

Kevin B. Smith, M. K. Brown, Wei You, 2014, Angewandte Chemie.

Mechanism of the enantioselective oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)-salen complexes.

E. Corey, M. Blewett, M. K. Brown, 2010, Journal of the American Chemical Society.

Copper-Catalyzed Borylacylation of Activated Alkenes with Acid Chlorides.

Kevin B. Smith, M. K. Brown, Yu’an Huang, 2017, Angewandte Chemie.

Catalyst-Controlled 1,2- and 1,1-Arylboration of α-Alkyl Alkenyl Arenes.

Kevin B. Smith, Kaitlyn M. Logan, S. Dorn, 2019, Angewandte Chemie.

Copper-Catalyzed Heteroarylboration of 1,3-Dienes with 3-Bromopyridines: A cine Substitution.

Kevin B. Smith, M. K. Brown, Yu’an Huang, 2018, Angewandte Chemie.

Catalytic Enantioselective Arylboration of Alkenylarenes.

Kaitlyn M. Logan, M. K. Brown, M. Brown, 2017, Angewandte Chemie.

Catalytic Enantioselective Diarylation of Alkenes.

M. K. Brown, Wei You, M. Brown, 2015, Journal of the American Chemical Society.

Diarylation of alkenes by a Cu-catalyzed migratory insertion/cross-coupling cascade.

M. K. Brown, Wei You, M. Brown, 2014, Journal of the American Chemical Society.

Synthesis of 1,3-Substituted Cyclobutanes by Allenoate-Alkene [2 + 2] Cycloaddition.

M. K. Brown, Michael L Conner, M. Brown, 2016, The Journal of organic chemistry.

Lessons in Strain and Stability: An Enantioselective Synthesis of (+)-[5]-Ladderanoic Acid.

D. Tantillo, Erin N. Hancock, E. Kuker, 2019, Angewandte Chemie.

Arylboration of Enecarbamates for the Synthesis of Borylated Saturated N‐Heterocycles

Pavel K. Mykhailiuk, M. K. Brown, Prashansa B. Kannangara, 2022, Angewandte Chemie.

[2]-Ladderanes as isosteres for meta-substituted aromatic rings and rigidified cyclohexanes

Thomas C. Fessard, J. Larrow, M. K. Brown, 2022, Nature Communications.

Photosensitized [2+2]‐Cycloadditions of Alkenylboronates and Alkenes

K. Raghavachari, J. Swierk, Yanyao Liu, 2022, Angewandte Chemie.

Photosensitized [2+2]-Cycloadditions of Alkenylboronates and Alkenes.

K. Raghavachari, J. Swierk, Yanyao Liu, 2022, Angewandte Chemie.

Thioallenoates in Catalytic Enantioselective [2+2]-Cycloadditions with Unactivated Alkenes.

J. Wiest, M. K. Brown, Michael L Conner, 2019, Tetrahedron.

Synthesis of (-)-Hebelophyllene E: An Entry to Geminal Dimethyl-Cyclobutanes by [2+2] Cycloaddition of Alkenes and Allenoates.

J. Wiest, M. K. Brown, Michael L Conner, 2018, Angewandte Chemie.

Catalyst Controlled Regiodivergent Arylboration of Dienes.

M. K. Brown, Stephen R Sardini, M. Brown, 2017, Journal of the American Chemical Society.

Intramolecular Chirality Transfer [2 + 2] Cycloadditions of Allenoates and Alkenes.

D. Tantillo, M. K. Brown, Y. Xu, 2017, Organic letters.

Regioselective Arylboration of Isoprene and Its Derivatives by Pd/Cu Cooperative Catalysis.

Kevin B. Smith, M. K. Brown, M. Brown, 2017, Journal of the American Chemical Society.

Copper/palladium synergistic catalysis for the syn- and anti-selective carboboration of alkenes.

Kevin B. Smith, Kaitlyn M. Logan, M. K. Brown, 2015, Angewandte Chemie.

Catalytic enantioselective allenoate-alkene [2 + 2] cycloadditions.

M. K. Brown, Y. Xu, Michael L Conner, 2015, Journal of the American Chemical Society.

Alkene carboboration enabled by synergistic catalysis.

Kevin B. Smith, Kaitlyn M. Logan, M. K. Brown, 2014, Chemistry.

Collaborative Total Synthesis: Routes to (±)-Hippolachnin A Enabled by Quadricyclane Cycloaddition and Late-Stage C-H Oxidation.

J. L. Wood, Christopher M. Rasik, M. K. Brown, 2016, Journal of the American Chemical Society.

Total synthesis of gracilioether F: development and application of lewis Acid promoted ketene-alkene [2+2] cycloadditions and late-stage C-H oxidation.

Christopher M. Rasik, M. K. Brown, C. Rasik, 2014, Angewandte Chemie.

Nickel-Catalyzed Stereoselective Arylboration of Unactivated Alkenes.

Kaitlyn M. Logan, M. K. Brown, Stephen R Sardini, 2018, Journal of the American Chemical Society.

(Hetero)arylboration of alkynes: a strategy for the synthesis of α,α-bis(hetero)arylketones.

M. K. Brown, Yu’an Huang, A. M. Bergmann, 2019, Organic & biomolecular chemistry.

Catalytic Arylboration of Spirocyclic Cyclobutenes: Rapid Access to Highly Substituted Spiro[3.n]alkanes.

M. K. Brown, A. Simlandy, Mao‐Yun Lyu, 2021, ACS catalysis.

Construction of congested Csp3–Csp3 bonds by a formal Ni-catalyzed alkylboration†

M. K. Brown, A. Simlandy, Stephen R Sardini, 2021, Chemical Science.

Three-Component Ni-Catalyzed Silylacylation of Alkenes.

M. K. Brown, Dongshun Ni, M. Brown, 2021, ACS catalysis.

Photochemical Dearomative Cycloadditions of Quinolines and Alkenes: Scope and Mechanism Studies.

F. Glorius, K. Houk, M. K. Brown, 2022, Journal of the American Chemical Society.

Strain-Release [2π + 2σ] Cycloadditions for the Synthesis of Bicyclo[2.1.1]hexanes Initiated by Energy Transfer.

Thomas C. Fessard, M. K. Brown, Christophe Salomé, 2022, Journal of the American Chemical Society.

Nickel-Catalyzed Stereoselective Diarylation of Alkenylarenes.

M. K. Brown, Pin Gao, Liang-An Chen, 2018, Journal of the American Chemical Society.

Ni-Catalyzed Arylboration of Unactivated Alkenes: Scope and Mechanistic Studies.

Peng Liu, M. K. Brown, H. Omer, 2019, Journal of the American Chemical Society.

Cooperative Pd/Cu Catalysis for Alkene Arylboration: Opportunities for Divergent Reactivity.

S. Dorn, M. K. Brown, M. Brown, 2022, ACS catalysis.

Regioselective Arylboration of 1,3-Butadiene.

Kevin B. Smith, M. K. Brown, A. M. Bergmann, 2019, Israel journal of chemistry.

Sulfonate N‐Heterocyclic Carbene–Copper Complexes: Uniquely Effective Catalysts for Enantioselective Synthesis of C−C, C−B, C−H, and C−Si Bonds

A. Hoveyda, S. Torker, M. K. Brown, 2020 .

Ni-catalyzed 1,2-benzylboration of 1,2-disubstituted unactivated alkenes† †Electronic supplementary information (ESI) available: Procedure, full characterization data, and copies of spectra. See DOI: 10.1039/c9sc04199k

A. M. Bergmann, Seewon Joung, M. Brown, 2019, Chemical science.

Nickel-Catalyzed Arylboration of Alkenylarenes: Synthesis of Boron-Substituted Quaternary Carbons and Regiodivergent Reactions.

M. K. Brown, Pin Gao, Liang-An Chen, 2019, Angewandte Chemie.

Modular Synthesis of a Versatile Double-Allylation Reagent for Complex Diol Synthesis.

S. Dorn, Annika E. Tharp, M. Brown, 2021, Angewandte Chemie.

Enantioselective Synthesis of (+)-Hippolide J and Reevaluation of Antifungal Activity.

D. Krysan, M. K. Brown, Renyu Guo, 2020, Organic letters.

Evolution of a Strategy for the Enantioselective Synthesis of (-)-Cajanusine.

M. K. Brown, Renyu Guo, Brittany P. Witherspoon, 2020, Journal of the American Chemical Society.

Intermolecular Ketene–Alkene [2+2] Cycloadditions: The Significance of Lewis Acid Promoted Variants

Christopher M. Rasik, M. Brown, 2014, Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry.

Lewis Acid-Promoted [2 + 2] Cycloadditions of Allenes and Ketenes: Versatile Methods for Natural Product Synthesis.

Renyu Guo, M. Brown, 2023, Accounts of chemical research.

Origins of diastereoselectivity in Lewis acid promoted ketene-alkene [2 + 2] cycloadditions.

D. Tantillo, Christopher M. Rasik, M. K. Brown, 2014, Organic letters.

Nickel-Catalyzed Dearomative Arylboration of Indoles: Regioselective Synthesis of C2- and C3-Borylated Indolines.

P. Liu, M. K. Brown, Rositha Kuniyil, 2021, Journal of the American Chemical Society.

Highly site- and enantioselective Cu-catalyzed allylic alkylation reactions with easily accessible vinylaluminum reagents.

Dennis G. Gillingham, A. Hoveyda, M. K. Brown, 2008, Journal of the American Chemical Society.

Catalytic enantioselective formation of chiral-bridged dienes which are themselves ligands for enantioselective catalysis.

E. Corey, M. K. Brown, M. Brown, 2010, Organic letters.

Catalytic enantioselective allenoate-alkene [2 + 2] cycloadditions.

Y. Xu, M. Brown, Michael L. Conner, 2015, Journal of the American Chemical Society.

All-carbon quaternary stereogenic centers by enantioselective cu-catalyzed conjugate additions promoted by a chiral N-heterocyclic carbene.

A. Hoveyda, Tricia L. May, M. K. Brown, 2007, Angewandte Chemie.

Ni-Catalyzed 1,1- and 1,3-Aminoboration of Unactivated Alkenes.

Shuming Chen, M. Brown, Mao-Yun Lyu, 2023, Journal of the American Chemical Society.

Nickel-Catalyzed Stereoselective Diarylation of Alkenylarenes.

Pin Gao, Liang-An Chen, M. Brown, 2018, Journal of the American Chemical Society.

Bringing Organic Chemistry to the Public: Structure and Scent in a Science Museum

Karen A. Jepson-Innes, L. Brown, M. K. Brown, 2017 .