Javier A. Cabeza

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2,2′-Bibenzimidazolate anions as bridging ligands in cationic heteronuclear gold(I)–rhodium(I) complexes. Crystal structure of [(Ph3P)2Au2(µ-bbzim)Rh(cod)][ClO4]·CHCl3

L. Oro, M. Ciriano, R. Usón, 1983 .

New biimidazole and bibenzimidazole derivatives: mono and binuclear palladium(II) or platinum(II) complexes and heterobinuclear palladium(II)-rhodium(I) or platinum(II)-rhodium(I) complexes

L. Oro, R. Usón, J. A. Cabeza, 1983 .

Dipyrromethane‐Based PGeP Pincer Methylgermyl and Methoxidogermyl Nickel and Palladium Complexes

J. A. Cabeza, P. García‐Álvarez, Carlos J. Laglera‐Gándara, 2021 .

Phosphane-functionalized heavier tetrylenes: synthesis of silylene- and germylene-decorated phosphanes and their reactions with Group 10 metal complexes.

J. A. Cabeza, P. García‐Álvarez, Carlos J. Laglera‐Gándara, 2020, Dalton transactions.

Reactivity of Amidinatosilylenes and Amidinatogermylenes with [PtMe2(η4-cod)]: cis- versus trans-[PtMe2L2] Complexes and Cyclometalation Reactions

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2020 .

Mesityl(amidinato)tetrylenes as ligands in iridium(i) and iridium(iii) complexes: silicon versus germanium and simple κ1-coordination versus cyclometallation.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2019, Dalton transactions.

Synthesis and some coordination chemistry of the PSnP pincer-type stannylene Sn(NCH2PtBu2)2C6H4, attempts to prepare the PSiP analogue, and the effect of the E atom on the molecular structures of E(NCH2PtBu2)2C6H4 (E = C, Si, Ge, Sn).

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2018, Dalton transactions.

2-(Methylamido)pyridine-Borane: A Tripod κ(3)-N,H,H Ligand in Trigonal Bipyramidal Rhodium(I) and Iridium(I) Complexes with an Asymmetric Coordination of Its BH3 Group.

A. Kennedy, J. A. Cabeza, P. García‐Álvarez, 2016, Inorganic chemistry.

[MnBrL(CO)4] (L = Amidinatogermylene): Reductive Dimerization, Carbonyl Substitution, and Hydrolysis Reactions

R. Gobetto, C. Nervi, J. A. Cabeza, 2016 .

Reactivity Studies on a Binuclear Ruthenium(0) Complex Equipped with a Bridging κ(2)N,Ge-Amidinatogermylene Ligand.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2015, Inorganic chemistry.

Amidinatogermylene derivatives of ruthenium carbonyl: new insights into the reactivity of [Ru3(CO)12] with two-electron-donor reagents of high basicity.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2015, Inorganic chemistry.

Mononuclear η6-p-cymeneosmium(II) complexes and their reactions with Al2Me6 and other methylating reagents

P. Maitlis, J. A. Cabeza, Javier A. Cabeza, 1985 .

A dipyrromethane-based diphosphane-germylene as precursor to tetrahedral copper(i) and T-shaped silver(i) and gold(i) PGeP pincer complexes.

Israel Fernández, J. A. Cabeza, P. García‐Álvarez, 2019, Dalton transactions.

From a PGeP Pincer-Type Germylene to Metal Complexes Featuring Chelating (Ir) and Tripodal (Ir) PGeP Germyl and Bridging (Mn2) and Chelating (Ru) PGeP Germylene Ligands

P. García‐Álvarez, E. Pérez-Carreño, J. Brugos, 2018 .

Synthesis and initial transition metal chemistry of the first PGeP pincer-type germylene.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2017, Chemical communications.

Expanding the coordination chemistry of donor-stabilized group-14 metalenes.

J. A. Cabeza, P. García‐Álvarez, D. Polo, 2013, Dalton transactions.

The transition-metal chemistry of amidinatosilylenes, -germylenes and -stannylenes

J. A. Cabeza, P. García‐Álvarez, D. Polo, 2015 .

Alternative Conceptual Approach to the Design of Bifunctional Catalysts: An Osmium Germylene System for the Dehydrogenation of Formic Acid

Miguel A. Esteruelas, E. Oñate, J. A. Cabeza, 2021, Inorganic chemistry.

A Z-type PGeP pincer germylene ligand in a T-shaped palladium(0) complex.

J. A. Cabeza, P. García‐Álvarez, Carlos J. Laglera‐Gándara, 2020, Chemical communications.

The Transition Metal Chemistry of PGeP and PSnP Pincer Heavier Tetrylenes

J. A. Cabeza, P. García‐Álvarez, Carlos J. Laglera‐Gándara, 2020, European Journal of Inorganic Chemistry.

A Germylene Supported by Two 2-Pyrrolylphosphane Groups as Precursor to PGeP Pincer Square-Planar Group 10 Metal(II) and T-Shaped Gold(I) Complexes.

Israel Fernández, J. A. Cabeza, J. Fernández-Colinas, 2019, Chemistry.

Dinuclear Methoxy, Cyclooctadiene, and Barrelene Complexes of Rhodium(I) and Iridium(I)

L. Oro, R. Usón, J. A. Cabeza, 2007 .

Organic Amides as Suitable Precursors to Stabilize Stannylenes

J. A. Cabeza, P. García‐Álvarez, D. Polo, 2013 .

Reversible Carbene Insertion into a Ge-N Bond and Insights into CO and Carbene Substitution Reactions Involving Amidinatogermylenes and Fischer Carbene Complexes.

M. Gómez-Gallego, M. Sierra, Alba D Merinero, 2018, Chemistry.

From a Diphosphanegermylene to Nickel, Palladium, and Platinum Complexes Containing Germyl PGeP Pincer Ligands.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2017, Chemistry.

Amidinatogermylene Metal Complexes as Homogeneous Catalysts in Alcoholic Media

J. A. Cabeza, P. García‐Álvarez, J. Fernández‐Colinas, 2016 .

From an N-methyl N-heterocyclic carbene to carbyne and carbide ligands via multiple C-H and C-N bond activations.

D. Miguel, J. A. Cabeza, M. Sánchez-Vega, 2008, Angewandte Chemie.

Two Types of σ-Allenyl Complexes from Reactions of Silylenes and Germylenes with Chromium Fischer Alkynyl(alkoxy)carbenes.

M. Gómez-Gallego, M. Sierra, Alba D Merinero, 2019, Chemistry.

Unexpected Zwitterionic Allenyls from Silylenes and a Fischer Alkynylcarbene: A Remarkable Silylene-Promoted Rearrangement.

M. Gómez-Gallego, M. Sierra, Alba D Merinero, 2019, Chemistry.

First Insertions of Carbene Ligands into Ge-N and Si-N Bonds.

M. Gómez-Gallego, M. Sierra, Alba D Merinero, 2017, Chemistry.

Cationic heterocycles as ligands: synthesis and reactivity with anionic nucleophiles of cationic triruthenium clusters containing C-metalated N-methylquinoxalinium or N-methylpyrazinium ligands.

J. A. Cabeza, E. Pérez-Carreño, Vanessa Pruneda, 2009, Chemistry.

Reactivity of the 1-azavinylidene cluster [Ru3(μ-H)(μ-NCPh2)(CO)10] with hydrogen, tertiary silanes and tertiary stannanes

V. Riera, C. Bois, J. A. Cabeza, 1998 .

Triosmium carbonyl complexes containing bridging ligands derived from ortho-functionalized anilines

S. García‐Granda, D. Ardura, V. Riera, 1996 .

Tri- and binuclear ruthenium carbonyl complexes containing bridging ligands derived from ortho-substituted anilines. A comparative study of their syntheses using RuCl3 · nH2O or [Ru3(CO)12] as starting materials

S. García‐Granda, V. Riera, J. A. Cabeza, 1996 .

Synthesis, characterization, reactivity, and catalytic hydrogenation activity of the hexanuclear hexahydrido carbonyl cluster compound [Ru6(μ-H)60(μ3,ν2-ampy)2(CO)14 ] (Hampy = 2-amino-6-methylpyridine)

I. D. Rı́o, V. Riera, J. A. Cabeza, 1995 .

Reactivity of Indene, Fluorene, Azulene, and Acenaphthylene with a Basal-Edge-Bridged Square-Pyramidal Hexaruthenium Dihydride

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2007 .

A new coordination mode for (pyrid-2-yl)thiolate (L) ligands: Synthesis and characterization of [Ru6(μ3-H)(μ5-κ2-L)(μ-CO)(CO)15]

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2007 .

Synthesis and structural characterization of triruthenium cluster complexes containing bridging .eta.1-phenyl and terminal .eta.1-phenyl ligands arising from the cleavage of triphenylphosphine ligands

L. Ouahab, V. Riera, J. A. Cabeza, 1993 .

.eta.1-Aryl-bridged triruthenium cluster complexes

V. Riera, J. A. Cabeza, E. Pérez-Carreño, 1994 .

Reaction of [Ru3(CO)12] with Phenazine: Synthesis of C-Metalated Derivatives That Formally Arise from a C–H Oxidative Addition or a Long-Distance C-to-N Prototropy

J. A. Cabeza, P. García‐Álvarez, Vanessa Pruneda, 2012 .

Two octahedral σ-borane metal (MnI and RuII) complexes containing a tripod κ3N,H,H-ligand: Synthesis, structural characterization, and theoretical topological study of the charge density

J. A. Cabeza, P. García‐Álvarez, J. F. Van der Maelen, 2020 .

Octahedral manganese(i) and ruthenium(ii) complexes containing 2-(methylamido)pyridine-borane as a tripod κ3N,H,H-ligand.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2017, Dalton transactions.

2-(Methylamido)pyridine-Borane: A Tripod κ(3)-N,H,H Ligand in Trigonal Bipyramidal Rhodium(I) and Iridium(I) Complexes with an Asymmetric Coordination of Its BH3 Group.

A. Kennedy, E. Pérez-Carreño, J. Brugos, 2016, Inorganic Chemistry.

A topological analysis of the bonding in [M2(CO)10] and [M3(μ-H)3(CO)12] complexes (M = Mn, Tc, Re)

J. A. Cabeza, J. F. V. D. Maelen, Javier A. Cabeza, 2016, Theoretical Chemistry Accounts.

QTAIM analysis of the bonding in Mo-Mo bonded dimolybdenum complexes.

J. A. Cabeza, J. F. Van der Maelen, Javier A. Cabeza, 2012, Inorganic chemistry.

Theoretical topological analysis of the electron density in a series of triosmium carbonyl clusters

S. García‐Granda, J. A. Cabeza, J. F. V. D. Maelen, 2011 .

Topological Analysis of the Electron Density in the N-Heterocyclic Carbene Triruthenium Cluster [Ru3(μ-H)2(μ3-MeImCH)(CO)9] (Me2Im = 1,3-dimethylimidazol-2-ylidene)

S. García‐Granda, J. A. Cabeza, J. F. V. D. Maelen, 2009 .

The N-heterocyclic carbene chemistry of transition-metal carbonyl clusters.

J. A. Cabeza, P. García‐Álvarez, Javier A. Cabeza, 2011, Chemical Society reviews.

Different Reactivities of Pyrid-2-yl- and 6-Picol-2-yl-Functionalized NHC Ligands with [Ru3(CO)12]: C(sp2)−H and Double C(sp3)−H Bond Activation Reactions

J. A. Cabeza, P. García‐Álvarez, M. Damonte, 2011 .

Synthesis and reactivity of cationic triruthenium clusters derived from 2-methyl- and 4-methylpyrimidines: from conventional cyclometalated ligands to novel types of N-heterocyclic carbenes.

E. Pérez-Carreño, Vanessa Pruneda, Javier A. Cabeza, 2013, Chemistry.

Reactivity of 2‐(Diphenylphosphanyl)thiophenol (HSC6H4PPh2) with Ruthenium and Osmium Carbonyl Complexes; Breaking of HSC6H4PPh2 into Sulfide, Phenyl and Diphenylphosphanyl Ligands on a Triruthenium Cluster

S. García‐Granda, D. Ardura, V. Riera, 2000 .

Derivative Chemistry of [Ru2(μ-bdt)(CO)6], a Binuclear Ruthenium(I) Carbonyl Complex Containing a Bridging Benzene-1,2-dithiolate Ligand

S. García‐Granda, D. Ardura, V. Riera, 1999 .

The chemical and electrochemical oxidation of pyridonate-bridged ruthenium(I) dimers. X-Ray structure of [Ru2(μ-pyO)2(CO)4(pyOH)2] (pyOH = 2-pyridone)

S. García‐Granda, G. Mori, V. Riera, 1991 .

The addition of protons and metallic electrophiles to the electron-rich RuRu bond of [Ru2(μ,-dan)(CO)4(PiPr3)2]. X-ray structure of [Ru2(μ-AgPPh3)(μ-dan)(CO)4(PiPr3)2][BF4]·CH2Cl2 (dan=1,8-diamidonaphthalene)

S. García‐Granda, V. Riera, J. A. Cabeza, 1991 .

Improved synthesis, solution and solid-state structure, and reactivity of [Ru2(µ-SePh)2(CO)6]

S. García‐Granda, V. Riera, D. Miguel, 1991 .

A dipyrromethane-based diphosphane-germylene as precursor to tetrahedral copper(i) and T-shaped silver(i) and gold(i) PGeP pincer complexes.

Israel Fernández, Carlos J. Laglera‐Gándara, Javier A. Cabeza, 2019, Dalton transactions.

Easy activation of two C-H bonds of an N-heterocyclic carbene N-methyl group.

D. Miguel, J. A. Cabeza, M. Sánchez-Vega, 2005, Chemical communications.

The cyclometallation of benzoic acid to give rhodium, iridium, and osmium C,O-benzoates. X-Ray structure determination of the dibenzoate [(C5Me5)Rh(OOCPh)2(H2O)]

H. Adams, J. Kisenyi, Glenn J. Sunley, 1987 .

Deprotonation of C-alkyl groups of cationic triruthenium clusters containing cyclometalated C-alkylpyrazinium ligands: experimental and computational studies.

J. A. Cabeza, P. García‐Álvarez, E. Pérez-Carreño, 2013, Chemistry.

Reactivity of Cationic Triruthenium Carbonyl Clusters: From Pyrimidinium Ligands to N-Heterocyclic Carbenes

I. D. Rı́o, E. Pérez-Carreño, Vanessa Pruneda, 2011 .

The synthesis of di- and tetra-nuclear p-cymene–osmium hydride complexes; characterisation by 1H(187Os) reverse INEPT two-dimensional nuclear magnetic resonance spectroscopy

P. Maitlis, B. Mann, C. Brevard, 1988 .

Carbonyl Clusters as Homogeneous Catalysts. Kinetic and Molecular Aspects of the Hydrogenation of Diphenylacetylene Promoted by an Alkenyl-Bridged Triruthenium Cluster Complex

S. García‐Granda, V. Riera, J. A. Cabeza, 1994 .

Tricyclohexylphosphine- versus Triphenylphosphine-Substituted Derivatives of a Face-Bridged Triruthenium Carbonyl Cluster Complex. A Comparative Study of Their Synthesis, Structure, and Catalytic Activity in the Homogeneous Hydrogenation of Diphenylacetylene

I. D. Rı́o, L. Ouahab, V. Riera, 1994 .

Ruthenium(I) complexes containing bridging N-donor ligands: structure, synthesis and reactivity patterns

J. A. Cabeza, J. Fernández‐Colinas, Javier A. Cabeza, 1993 .

Extensive substitution, protonation, and methoxidation reactions of triruthenium carbonyl clusters containing 2-amino-6-methylpyridinato (.mu.3-ampy) as a face-bridging ligand. X-ray structures of [Ru3(.mu.-H)(.mu.3-ampy)(CO)7(PPh3)2] and [Ru3(.mu.-H)2(.mu.3-ampy)(CO2Me)(CO)6(PPh3)2].cntdot.MeOH

M. Pellinghelli, V. Riera, J. A. Cabeza, 1991 .

Mononuclear ruthenium complexes containing chiral aminooxazolines: Syntheses, X-ray studies and catalytic activity

Robert A. Gossage, I. D. Rı́o, D. Miguel, 2007 .

Hexaruthenium and octaruthenium carbonyl cluster complexes derived from 2-amino-6-methylpyridine : Novel coordination modes for 2-imidopyridines

I. D. Rı́o, D. Miguel, J. A. Cabeza, 2006 .

Edge-bridging and face-capping coordination of alkenyl ligands in triruthenium carbonyl cluster complexes derived from hydrazines: synthetic, structural, theoretical, and kinetic studies.

S. García‐Granda, J. A. Cabeza, E. Pérez-Carreño, 2004, Chemistry.

Influence of the bridging ligand on the substitution chemistry of neutral and cationic triruthenium carbonyl cluster complexes derived from 1,1-dimethylhydrazine

S. García‐Granda, I. D. Rı́o, V. Riera, 2003 .

Carbonyl substitution chemistry of neutral and cationic triruthenium cluster complexes derived from 1,1-dimethylhydrazine.: Incorporation of two and three phosphane ligands

S. García‐Granda, I. D. Rı́o, V. Riera, 2002 .

Reactivity of Triosmium Carbonyl Clusters with 1,8-Diaminonaphthalene − Synthesis and Structural Characterization of Amido, Diamido, and C-Metalated Trinuclear Derivatives

H. Nöth, J. A. Cabeza, M. Rosales-Hoz, 2000 .

Reactivity of the Anionic Carbonyltrirhenium Cluster [Re3(µ-H)3(µ3-ampy)(CO)9]− − Synthesis of Neutral Phosphane and Alkenyl Derivatives

F. Grepioni, Rajiv Trivedi, V. Riera, 2000 .

Preparation and Characterization of 92-Electron Hexahydridohexaruthenium Carbonyl Cluster Complexes. Their Potential Significance in Homogeneous Catalytic Hydrogenation

S. García‐Granda, V. Riera, F. López-Ortiz, 1994 .

Reactivity of [Ru3(μ-H)(μ-Me2pz)(CO)10] with 2,4-hexadiyne. Characterization of the first tetranuclear ynenyl complex

V. Riera, J. A. Cabeza, M. Rosales-Hoz, 2001 .