Stephen Sproules

发表

On the possibility of magneto-structural correlations: detailed studies of dinickel carboxylate complexes.

E. McInnes, A. Barra, R. Winpenny, 2014, Inorganic chemistry.

A step beyond the Feltham-Enemark notation: spectroscopic and correlated ab initio computational support for an antiferromagnetically coupled M(II)-(NO)- description of Tp*M(NO) (M = Co, Ni).

K. Wieghardt, S. DeBeer, T. Petrenko, 2011, Journal of the American Chemical Society.

Electrocatalytic hydrogen production by dinuclear cobalt(II) compounds containing redox-active diamidate ligands: a combined experimental and theoretical study.

H. Miras, A. Keramidas, M. Papanikolaou, 2020, Dalton transactions.

Dithiolene Radicals: Sulfur K-Edge X-Ray Absorption Spectroscopy and Harry's Intuition

K. Wieghardt, S. Sproules, Stephen Sproules, 2011 .

Enhanced Fe-Centered Redox Flexibility in Fe–Ti Heterobimetallic Complexes

Connie C. Lu, James T Moore, L. Gagliardi, 2019, Inorganic chemistry.

One- and two-electron reduced 1,2-diketone ligands in [CrIII(L*)3] (S = 0) and Na2(Et2O)2[VIV(LRed)3] (S = 1/2).

K. Wieghardt, E. Bill, T. Weyhermüller, 2008, Inorganic chemistry.

Fully Reduced and Mixed-Valent Multi-Copper Aggregates Supported by Tetradentate Diamino Bis(thiolate) Ligands

J. Mague, S. Sproules, S. Ferrara, 2023, Inorganic chemistry.

Oxo versus Sulfido Coordination at Tungsten: A Spectroscopic and Correlated Ab Initio Electronic Structure Study.

Stephen Sproules, 2021, Inorganic chemistry.

Modulating Iron Spin States with Radical Ligands: A Density Functional Theoretical Study

S. Sproules, Ludovica Credendino, Stephen Sproules, 2020, Asian Journal of Organic Chemistry.

Towards a better understanding of the electrosynthesis of 2,5-dicarboxy-2,5-dihydrofurans: structure, mechanism and influence over stereochemistry

M. Symes, M. Shipman, Claire Wilson, 2019, Royal Society Open Science.

Ligand Radicals as Modular Organic Electron Spin Qubits.

H. Miras, S. Sproules, Emma Richards, 2018, Chemistry.

Heteroleptic samarium(iii) halide complexes probed by fluorescence-detected L3-edge X-ray absorption spectroscopy

K. Lancaster, S. Sproules, D. Mills, 2018, Dalton transactions.

Proton-Coupled-Electron Transfer Enhances the Electrocatalytic Reduction of Nitrite to NO in a Bioinspired Copper Complex

P. Wheatley, R. Morris, M. Symes, 2018 .

Directed Self-Assembly, Symmetry Breaking, and Electronic Modulation of Metal Oxide Clusters by Pyramidal Heteroanions.

L. Cronin, D. Long, H. Miras, 2018, Chemistry.

Unprecedented Inequivalent Metal Coordination Environments in a Mixed‐Ligand Dicobalt Complex

M. Symes, Claire Wilson, Giacomo Cioncoloni, 2017 .

Contrasting the group 6 metal-metal bonding in sodium dichromate(ii) and sodium dimolybdate(ii) polymethyl complexes: synthetic, X-ray crystallographic and theoretical studies.

S. Sproules, A. Kennedy, R. McLellan, 2017, Dalton transactions.

Radicals in carbonaceous residue deposited on mordenite from methanol

Nicholas A. Spencer, J. Hargreaves, S. Sproules, 2016 .

Electronic structures of homoleptic [tris(2,2'-bipyridine)M]n complexes of the early transition metals (M = Sc, Y, Ti, Zr, Hf, V, Nb, Ta; n = 1+, 0, 1-, 2-, 3-): an experimental and density functional theoretical study.

K. Wieghardt, Jason England, T. Weyhermüller, 2013, Inorganic chemistry.

Scrutinizing low-spin Cr(II) complexes.

Christian J. Doonan, K. Wieghardt, C. Doonan, 2012, Inorganic chemistry.

Electronic structures of the [V(tbpy)3]z (z = 3+, 2+, 0, 1-) electron transfer series.

K. Wieghardt, S. Sproules, A. Bowman, 2012, Inorganic chemistry.

The rhenium tris(dithiolene) electron transfer series: calibrating covalency.

K. Wieghardt, T. Weyhermüller, R. Goddard, 2011, Inorganic chemistry.

Electronic structures and spectroscopy of the electron transfer series [Fe(NO)L2]z (z = 1+, 0, 1-, 2-, 3-; L = dithiolene).

F. Neese, K. Wieghardt, S. Sproules, 2011, Inorganic chemistry.

Electronic and molecular structures of the members of the electron transfer series [Cr(tbpy)3]n (n = 3+, 2+, 1+, 0): an X-ray absorption spectroscopic and density functional theoretical study.

K. Wieghardt, S. DeBeer, T. Weyhermüller, 2011, Inorganic chemistry.

Monoanionic molybdenum and tungsten tris(dithiolene) complexes: a multifrequency EPR study.

K. Wieghardt, Yong Yan, P. Banerjee, 2011, Inorganic chemistry.

The molecular and electronic structures of monomeric cobalt complexes containing redox noninnocent o -aminobenzenethiolate ligands

K. Wieghardt, Nabarun Roy, T. Weyhermüller, 2010 .

Polynuclear complexes containing the redox noninnocent Schiff base ligand 2-[(E)-2-mercaptophenylimino]methyl-4,6-di-tert-butylphenolate(2-)

Karl Wieghardt, Nabarun Roy, K. Wieghardt, 2009 .

Spectroscopic Studies of the Chan-Lam Amination: A Mechanism-Inspired Solution to Boronic Ester Reactivity.

Julien C. Vantourout, H. Miras, Albert Isidro-Llobet, 2017, Journal of the American Chemical Society.

Outer-sphere contributions to the electronic structure of type zero copper proteins.

Frank Neese, Harry B Gray, Mahesh Sundararajan, 2012, Journal of the American Chemical Society.

Outer-sphere effects on reduction potentials of copper sites in proteins: the curious case of high potential type 2 C112D/M121E Pseudomonas aeruginosa azurin.

H. Gray, J. Richards, K. Lancaster, 2010, Journal of the American Chemical Society.

A self-assembled Cu(II)4 [2 × 2] grid with organic radicals.

A. Powell, E. McInnes, D. Collison, 2013, Dalton transactions.

Paramagnetic titanium(III) and zirconium(III) metallocene complexes as precatalysts for the dehydrocoupling/dehydrogenation of amine-boranes.

I. Manners, M. Haddow, G. Lloyd‐Jones, 2013, Angewandte Chemie.

Redox-switchable ring-closing metathesis: catalyst design, synthesis, and study.

V. Lynch, C. Bielawski, S. Sproules, 2013, Chemistry.

Platinum(ii) complexes of mixed-valent radicals derived from cyclotricatechylene, a macrocyclic tris-dioxolene† †Electronic supplementary information (ESI) available: Experimental procedures for the physical and computational characterisation of the compounds in this work; crystallographic figures,

E. McInnes, M. Hardie, M. Halcrow, 2015, Chemical science.

Anion directed cation templated synthesis of three ternary copper(II) complexes with a monocondensed N2O donor Schiff base and different pseudohalides

P. Bhowmik, S. Chattopadhyay, S. Sproules, 2015 .

Tris(dithiolene) Chemistry: a Golden Jubilee

S. Sproules, Stephen Sproules, 2014 .

Investigating Complex Magnetic Anisotropy in a Co(II) Molecular Compound: A Charge Density and Correlated Ab Initio Electronic Structure Study.

J. Overgaard, H. Miras, Simon Grabowsky, 2020, Inorganic chemistry.

Separation and isolation of tautomers of 2-hydroxy-4-naphthoquinone-1-oxime derivatives by liquid chromatography: Antiproliferative activity and DFT studies

V. B. Konkimalla, S. Sproules, S. Salunke-Gawali, 2014, Journal of Chemical Sciences.

Rigidification of a macrocyclic tris-catecholate scaffold leads to electronic localisation of its mixed valent redox product.

E. McInnes, Kevin B. Vincent, M. Halcrow, 2019, Chemical communications.

Switchable Interaction in Molecular Double Qubits

Alessandro Chiesa, Iñigo J. Vitorica-Yrezabal, Stefano Carretta, 2016 .

g-Engineering in Hybrid Rotaxanes To Create AB and AB2 Electron Spin Systems: EPR Spectroscopic Studies of Weak Interactions between Dissimilar Electron Spin Qubits.

Grigore A. Timco, Richard E. P. Winpenny, Christopher A. Muryn, 2015, Angewandte Chemie.

Electronically Stabilized Nonplanar Phenalenyl Radical and Its Planar Isomer.

L. Cronin, D. Long, M. Symes, 2015, Journal of the American Chemical Society.

Alkali Cation Effects on Redox-Active Formazanate Ligands in Iron Chemistry.

Patrick L. Holland, B. Mercado, E. Bill, 2018, Inorganic chemistry.

Electronic structure of the [tris(dithiolene)chromium](z) (z = 0, 1-, 2-, 3-) electron transfer series and their manganese(IV) analogues. An X-ray absorption spectroscopic and density functional theoretical study.

K. Wieghardt, P. Banerjee, T. Weyhermüller, 2009, Inorganic chemistry.

o-Dithiolene and o-aminothiolate chemistry of iron: Synthesis, structure and reactivity

K. Wieghardt, S. Sproules, Stephen Sproules, 2010 .

Kinetic Control of Interpenetration in Fe-Biphenyl-4,4'-dicarboxylate Metal-Organic Frameworks by Coordination and Oxidation Modulation.

Sanliang Ling, B. Slater, Claire Wilson, 2019, Journal of the American Chemical Society.

Kinetic Control of Interpenetration in Fe-Biphenyl-4,4′-dicarboxylate MOFs by Coordination and Oxidation Modulation

B. Slater, Claire Wilson, S. Sproules, 2018 .

Electronic Structures of the Electron Transfer Series [M(bpy)3]n, [M(tpy)2]n, and [Fe(tbpy)3]n (M = Fe, Ru; n = 3+, 2+, 1+, 0, 1–): A Mössbauer Spectroscopic and DFT Study

K. Wieghardt, Jason England, T. Weyhermüller, 2012 .

Paramagnetic oxotungsten(V) complexes containing the hydrotris(3,5-dimethylpyrazol-1-yl)borate ligand.

C. G. Young, J. White, R. Gable, 2011, Inorganic chemistry.

Transparent-to-dark photo- and electrochromic gels

H. Cui, Hao Su, D. Adams, 2018, Communications Chemistry.

Molecular and electronic structure of the dithiooxalato radical ligand stabilised by rare earth coordination.

H. Miras, Claire Wilson, S. Sproules, 2019, Dalton transactions.

An Unsymmetric Ligand Framework for Noncoupled Homo- and Heterobimetallic Complexes.

Corinna R. Hess, S. Sproules, R. M. Haas, 2017, Inorganic chemistry.

A macrocyclic 'Co0' complex: the relevance of ligand non-innocence to reactivity.

A. Pöthig, Corinna R. Hess, Philipp J. Altmann, 2017, Chemical communications.

Redox-controlled interconversion between trigonal prismatic and octahedral geometries in a monodithiolene tetracarbonyl complex of tungsten.

J. Mague, Yong Yan, S. DeBeer, 2012, Inorganic chemistry.

Heteroleptic Samarium(III) Chalcogenide Complexes: Opportunities for Giant Exchange Coupling in Bridging σ- and π-Radical Lanthanide Dichalcogenides

Conrad A. P. Goodwin, K. Lancaster, S. Sproules, 2020, Inorganic chemistry.

Synthesis and molecular structure of a zinc complex of the vitamin K3 analogue phthiocol

V. Puranik, S. Haram, S. Sproules, 2013 .

Experimental fingerprints for redox-active terpyridine in [Cr(tpy)2](PF6)n (n = 3-0), and the remarkable electronic structure of [Cr(tpy)2]1-.

K. Wieghardt, S. DeBeer, T. Weyhermüller, 2012, Inorganic chemistry.

Six-membered electron transfer series [V(dithiolene)(3)](z) (z = 1+, 0, 1-, 2-, 3-, 4-). An X-ray absorption spectroscopic and density functional theoretical study.

K. Wieghardt, S. DeBeer, T. Weyhermüller, 2010, Inorganic chemistry.

Characterization and electronic structures of five members of the electron transfer series [Re(benzene-1,2-dithiolato)3](z) (z = 1+, 0, 1-, 2-, 3-): a spectroscopic and density functional theoretical study.

K. Wieghardt, E. Bill, T. Weyhermüller, 2009, Inorganic chemistry.

Molecular and electronic structure of the square planar bis(o-amidobenzenethiolato)iron(III) anion and its bis(o-quinoxalinedithiolato)iron(III) analogue.

K. Wieghardt, Nabarun Roy, E. Bill, 2008, Inorganic chemistry.

Ancillary ligand effects upon dithiolene redox noninnocence in tungsten bis(dithiolene) complexes.

J. Mague, Yong Yan, S. DeBeer, 2013, Inorganic chemistry.

An alternative method to access diverse N,N′-diquaternised-3,3′-biquinoxalinium “biquinoxen” dications

A. Powell, S. Sproules, Nicolas Leblanc, 2017 .

Approaching the limit of Cu(II)/Cu(I) mixed valency in a Cu(I)Br2-N-methylquinoxalinium hybrid compound.

A. Powell, H. Raffy, P. Auban-Senzier, 2015, Chemical communications.

ltifaceted redox-active chelating ligand : introducing the N , N 0-dimethyl-3 , 3 0-biquinoxalinium “ methylbiquinoxen ” platform †

A. Powell, E. Levillain, P. Rosa, 2016 .

Controlling Photoconductivity in PBI Films by Supramolecular Assembly

M. Zwijnenburg, R. Schweins, D. Adams, 2018, Chemistry.

Controlled Tuning of the Properties in Optoelectronic Self-Sorted Gels.

R. Schweins, D. Adams, Emily R. Draper, 2018, Journal of the American Chemical Society.

A fascinating multifaceted redox-active chelating ligand: introducing the N,N′-dimethyl-3,3′-biquinoxalinium “methylbiquinoxen” platform† †Electronic supplementary information (ESI) available. CCDC 1043174, 1043175 and 1437399. For ESI and crystallographic data in CIF or other electronic format see

A. Powell, E. Levillain, P. Rosa, 2016, Chemical science.

Heterotrimetallic Assemblies with 1,2,4,5-Tetrakis(diphenylphosphino)benzene Bridges: Constructs for Controlling the Separation and Spatial Orientation of Redox-Active Metallodithiolene Groups

J. Mague, R. Schmehl, R. Pascal, 2022, Inorganic chemistry.