Exploiting the reactivity of actinide fluoride bonds for the synthesis and characterization of a new class of monometallic bis(azide) uranium complexes

[1]  Marisa J. Monreal,et al.  Synthesis of Actinide Fluoride Complexes Using Trimethyltin Fluoride as a Mild and Selective Fluorinating Reagent , 2018 .

[2]  W. Lewis,et al.  Uranium–halide and –azide derivatives of the sterically demanding triamidoamine ligand TrenTPS [TrenTPS = {N(CH2CH2NSiPh3)3}3−] , 2017 .

[3]  F. Tuna,et al.  Molecular and electronic structure of terminal and alkali metal-capped uranium(V) nitride complexes , 2016, Nature Communications.

[4]  Marisa J. Monreal,et al.  New Twists and Turns for Actinide Chemistry: Organometallic Infinite Coordination Polymers of Thorium Diazide. , 2016, Angewandte Chemie.

[5]  J. Bachmann,et al.  Uranium-mediated electrocatalytic dihydrogen production from water , 2016, Nature.

[6]  Justin K. Pagano,et al.  Expanding the Chemistry of Actinide Metallocene Bromides. Synthesis, Properties and Molecular Structures of the Tetravalent and Trivalent Uranium Bromide Complexes: (C5Me4R)2UBr2, (C5Me4R)2U(O-2,6-iPr2C6H3)(Br), and [K(THF)][(C5Me4R)2UBr2] (R = Me, Et) , 2016 .

[7]  L. Maria,et al.  Uranium(III) redox chemistry assisted by a hemilabile bis(phenolate) cyclam ligand: uranium-nitrogen multiple bond formation comprising a trans-{RN═U(VI)═NR}(2+) complex. , 2015, Inorganic chemistry.

[8]  P. Fanwick,et al.  Synthesis of low-valent uranium fluorides by C-F bond activation. , 2015, Chemical communications.

[9]  C. Barnes,et al.  Synthesis of Thorium(IV) and Uranium(IV) Salicylaldiminate Pseudo‐Halide Complexes , 2015 .

[10]  Marc D. Walter,et al.  A thorium metallacyclopentadiene complex: a combined experimental and computational study. , 2015, Dalton transactions.

[11]  J. Lan,et al.  Terminal U≡E (E = N, P, As, Sb, and Bi) bonds in uranium complexes: a theoretical perspective. , 2015, The journal of physical chemistry. A.

[12]  S. Enthaler,et al.  Recycling Concept for End-of-Life Silicones: Boron Trifluoride Diethyl Etherate as Depolymerization Reagent to Produce Difluorodimethylsilane as Useful Commodity , 2015 .

[13]  K. Pandey,et al.  Effects of density functionals and dispersion interactions on geometries, bond energies and harmonic frequencies of EUX3 (E=N, P, CH; X=H, F, Cl). , 2014, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[14]  F. Heinemann,et al.  A series of uranium (IV, V, VI) tritylimido complexes, their molecular and electronic structures and reactivity with CO2. , 2014, Inorganic chemistry.

[15]  Marc D. Walter,et al.  Experimental and computational studies on the reactivity of a terminal thorium imidometallocene towards organic azides and diazoalkanes. , 2014, Angewandte Chemie.

[16]  R. Field,et al.  A retro Diels-Alder route to diphosphorus chemistry: molecular precursor synthesis, kinetics of P2 transfer to 1,3-dienes, and detection of P2 by molecular beam mass spectrometry. , 2014, Journal of the American Chemical Society.

[17]  S. Liddle,et al.  Progress in molecular uranium-nitride chemistry , 2014 .

[18]  M. Ephritikhine,et al.  Bent thorocene complexes with the cyanide, azide and hydride ligands. , 2013, Chemical communications.

[19]  A. J. Blake,et al.  Isolation and characterization of a uranium(VI)-nitride triple bond. , 2013, Nature chemistry.

[20]  Trevor W. Hayton,et al.  Recent developments in actinide-ligand multiple bonding. , 2013, Chemical communications.

[21]  A. J. Blake,et al.  Synthesis and Structure of a Terminal Uranium Nitride Complex , 2012, Science.

[22]  J. M. Kikkawa,et al.  Pentavalent uranium trans-dihalides and -pseudohalides. , 2012, Chemical communications.

[23]  Marc D. Walter,et al.  Synthesis, Structure, and Reactivity of a Thorium Metallocene Containing a 2,2′-Bipyridyl Ligand , 2012 .

[24]  M. Ephritikhine,et al.  Iodide, azide, and cyanide complexes of (N,C), (N,N), and (N,O) metallacycles of tetra- and pentavalent uranium. , 2011, Inorganic chemistry.

[25]  B. Scott,et al.  Uranium azide photolysis results in C-H bond activation and provides evidence for a terminal uranium nitride. , 2010, Nature chemistry.

[26]  B. Scott,et al.  Organometallic uranium(IV) fluoride complexes: preparation using protonolysis chemistry and reactivity with trimethylsilyl reagents. , 2010, Dalton transactions.

[27]  B. Scott,et al.  Synthesis, structure, spectroscopy and redox energetics of a series of uranium(IV) mixed-ligand metallocene complexes , 2010 .

[28]  John E. Bercaw,et al.  NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist , 2010 .

[29]  Guang Wu,et al.  U(IV) and U(V) azide complexes supported by amide or aryloxide ligands. , 2010, Dalton transactions.

[30]  J. Ziller,et al.  Reactivity of Methyl Groups in Actinide Metallocene Amidinate and Triazenido Complexes with Silver and Copper Salts , 2010 .

[31]  T. Hartmann,et al.  Reaction sequence and kinetics of uranium nitride decomposition. , 2009, Inorganic chemistry.

[32]  B. Scott,et al.  Noble reactions for the actinides: safe gold-based access to organouranium and azide complexes , 2009 .

[33]  B. Scott,et al.  Evidence for the involvement of 5f orbitals in the bonding and reactivity of organometallic actinide compounds: thorium(IV) and uranium(IV) bis(hydrazonato) complexes. , 2008, Journal of the American Chemical Society.

[34]  B. Scott,et al.  Probing the chemistry, electronic structure and redox energetics in organometallic pentavalent uranium complexes. , 2008, Inorganic chemistry.

[35]  J. Pécaut,et al.  A nitrido-centered uranium azido cluster obtained from a uranium azide. , 2008, Angewandte Chemie.

[36]  B. Scott,et al.  Organometallic uranium(V)-imido halide complexes: from synthesis to electronic structure and bonding. , 2008, Journal of the American Chemical Society.

[37]  B. Scott,et al.  Facile access to pentavalent uranium organometallics: one-electron oxidation of uranium(IV) imido complexes with copper(I) salts. , 2007, Journal of the American Chemical Society.

[38]  B. Scott,et al.  Systematic studies of early actinide complexes: uranium(IV) fluoroketimides. , 2007, Inorganic chemistry.

[39]  J. Ziller,et al.  Analysis of uranium azide and nitride complexes by atmospheric pressure chemical ionization mass spectrometry. , 2007, Inorganic chemistry.

[40]  B. Scott,et al.  Systematic studies of early actinide complexes: thorium(IV) fluoroketimides. , 2007, Journal of the American Chemical Society.

[41]  A. Ellern,et al.  UN21(3-): a structurally characterized binary actinide heptaazide anion. , 2005, Angewandte Chemie.

[42]  M. Ephritikhine,et al.  Lanthanide(III)/actinide(III) differentiation in the cerium and uranium complexes [M(C5Me5)2(L)]0,+ (L=2,2'-bipyridine, 2,2':6',2''-terpyridine): structural, magnetic, and reactivity studies. , 2005, Chemistry.

[43]  M. Walter,et al.  Preparation and Reactions of Base-Free Bis(1,2,4-tri-tert-butylcyclopentadienyl)uranium Oxide, Cp‘2UO , 2005 .

[44]  J. Kiplinger,et al.  Trends in Electronic Structure and Redox Energetics for Early-Actinide Pentamethylcyclopentadienyl Complexes , 2004 .

[45]  B. Scott,et al.  Thorium(IV) and Uranium(IV) Ketimide Complexes Prepared by Nitrile Insertion into Actinide−Alkyl and −Aryl Bonds , 2004 .

[46]  K. Meyer,et al.  Uranium tris-aryloxide derivatives supported by triazacyclononane: engendering a reactive uranium(III) center with a single pocket for reactivity. , 2003, Journal of the American Chemical Society.

[47]  B. Scott,et al.  The First f-Element Ketimido Complex: Synthesis and Characterization of (C5Me5)2U(−NCPh2)2 , 2002 .

[48]  B. Scott,et al.  Enhancing the reactivity of uranium(VI) organoimido complexes with diazoalkanes. , 2002, Chemical communications.

[49]  C. Burns,et al.  Uranium-Mediated Ring Opening of Tetrahydrofuran. Crystal Structure of UI(2)(OCH(2)CH(2)CH(2)CH(2)I)(2)(Ph(3)P=O)(2). , 1996, Inorganic chemistry.

[50]  J. Huffman,et al.  Solution study of the ambient temperature monomer-dimer equilibrium Th{sub 2}(OR){sub 8}{rightleftharpoons} 2Th(OR){sub 4} (R = CH-i-Pr{sub 2}) and X-ray crystal structures of Th{sub 2}(OCH-i-Pr{sub 2}){sub 8}, Th(OCH-i-Pr{sub 2}){sub 4}(quin), and ThI(OCH-i-Pr{sub 2}){sub 3}(py){sub 2} , 1995 .

[51]  W. A. Nugent,et al.  Metallacycle Transfer from Zirconium to Main Group Elements: A Versatile Synthesis of Heterocycles , 1994 .

[52]  D. L. Clark,et al.  Facile solution routes to hydrocarbon-soluble Lewis base adducts of thorium tetrahalides. Synthesis, characterization, and x-ray structure of ThBr4(THF)4 , 1992 .

[53]  M. Ephritikhine,et al.  Tricyclopentadienyluranium azide complexes , 1991 .

[54]  G. Orellana,et al.  Hydrogen-1 and carbon-13 NMR coordination-induced shifts in a series of tris(.alpha.-diimine)ruthenium(II) complexes containing pyridine, pyrazine, and thiazole moieties , 1988 .

[55]  K. W. Bagnall,et al.  Some phosphine oxide complexes of thorium(IV) and uranium(IV) tetrachloride and tetra-N-thiocyanates , 1984 .

[56]  K. W. Bagnall,et al.  Cyclopentadienyl complexes of uranium(IV) chlorides. Crystal structures of trichloro(?5-cyclopentadienyl)bis(triphenylphosphine oxide)uranium(IV) tetrahydrofuran solvate and of trichloro(?5-cyclopentadienyl)bis(hexamethylphosphoramide)uranium(IV) , 1984 .

[57]  K. W. Bagnall,et al.  Some urea and phosphine oxide complexes of thorium(IV) and uranium(IV) trihalogenoacetates , 1984 .

[58]  K. W. Bagnall,et al.  Some oxygen-donor complexes of cyclopentadienyluranium(IV)N-thiocyanate; steric considerations and stability , 1982 .

[59]  T. Marks,et al.  Synthesis and properties of bis(pentamethylcyclopentadienyl) actinide hydrocarbyls and hydrides. A new class of highly reactive f-element organometallic compounds , 1982 .

[60]  K. W. Bagnall,et al.  Some oxygen-donor complexes of cyclopentadienyluranium(IV) halides , 1978 .

[61]  M. P. Phillips,et al.  Comparisons of proton and carbon NMR chemical shifts for low spin d6 complexes of pyridine and substituted pyridines as probes of .pi. back-bonding , 1977 .

[62]  K. W. Bagnall,et al.  Phosphine oxide complexes of thorium(IV), uranium(IV), neptunium(IV), and dioxouranium(VI) nitrates , 1974 .

[63]  D. C. Smith,et al.  Infrared Spectra of Phosphorus Compounds , 1951 .