Intercalation of n-alkylamines into misfit layer sulfides

Novel intercalation complexes of (PbS)1.18( TiS2)2 and (PbS)1.14(TaS2)2 two representative compounds of misfit layer sulfides, have been prepared by direct reaction with n-alkylamines (CnH2n+ 1 NH2)(n= 1–9). From the observed amine stoichiometry and lattice expansions, the most likely configuration for the intercalated amine molecules is one in which the latter are located at the van der Waals gap between two adjacent TS2 slabs as a monolayer with the alkyl chain oriented parallel to the layers. Thermal deintercalation of the new phases occurred at temperatures below 250 °C and in the case of Ti intercalates, H2S was released simultaneously with the amine deintercalation process. The intercalation process was confirmed to be reversible. Thus, the product obtained from the thermal treatment recovered the main features of the original host structure and, when mixed with the amine, yielded an intercalate of similar structural characteristics to those found using the original sulfide.

[1]  J. Morales,et al.  Diffraction and XPS Studies of Misfit Layer Chalcogenides Intercalated with Cobaltocene , 1995 .

[2]  J. Jumas,et al.  119Sn Moessbauer Spectroscopy of Some Misfit Layer Sulfides , 1995 .

[3]  A. Meerschaut,et al.  Structure Determination of a Trilayer Misfit Compound (GdεSn1-εS)1.16(NbS2)3 , 1995 .

[4]  J. Morales,et al.  A new tantalum sulfur compound as electrode material for non-aqueous alkali metal batteries , 1994 .

[5]  J. Morales,et al.  Cobaltocene intercalation into misfit layer chalcogenides , 1994 .

[6]  J. Morales,et al.  Thermodynamic and kinetic properties of lithium insertion into titanium misfit layer sulfides , 1994 .

[7]  R. Schöllhorn.  Materials and Models: Faces of Intercalation Chemistry , 1994 .

[8]  H. Hayakawa,et al.  Preparation, characterization and intercalation of ternary selenides with layered composite crystal structures formed in the Pb-Nb-Se system , 1994 .

[9]  P. Joy,et al.  Intercalation of n-alkylamines in iron thiohypophosphate (FePS3) , 1993 .

[10]  J. Morales,et al.  Kinetics of intercalation of lithium and sodium into lead sulfide-niobium sulfide ((PbS)1.14(NbS2)2) , 1993 .

[11]  C. Haas,et al.  An X-ray photoemission spectroscopy study of interlayer charge transfer in some misfit layer compounds , 1993 .

[12]  Haas,et al.  Strong multiple resonances in the photoemission spectra of transition-metal-layer and misfit-layer compounds. , 1993, Physical review. B, Condensed matter.

[13]  P. Joy,et al.  The intercalation reaction of pyridine with manganese thiophosphate, MnPS3 , 1992 .

[14]  J. Morales,et al.  Electrochemical lithium intercalation into misfit layer sulfides , 1992 .

[15]  G. Wiegers,et al.  A LEED and photoemission spectroscopy study of the surface of the incommensurate misfit layer compound (SnS)1.16TaS2 , 1992 .

[16]  A. Meerschaut,et al.  Structure determination of a new misfit layer compound (PbS)1.18(TiS2)2 , 1992 .

[17]  R. Haange,et al.  Electrical Transport Properties of the Misfit Layer Compounds (SnS)1. 20TiS2 and (PbS)1.18TiS2 , 1991 .

[18]  Y. Ohno.  Interlayer interaction in misfit layer compounds MTS3 (M = Sn, Pb, La; T = Ti, Nb) , 1991 .

[19]  Ohno.  Electronic structure of the misfit-layer compounds PbTiS3 and SnNbS3. , 1991, Physical review. B, Condensed matter.

[20]  J. Akimoto,et al.  PREPARATION, CHARACTERIZATION, AND INTERCALATION OF (PBS)(TS2)2 ; (T=TI, NB, TA), NEW TERNARY SULFIDES WITH LAYERED COMPOSITE CRYSTAL STRUCTURE , 1990 .

[21]  M. Mckelvy,et al.  Molecular Intercalation Reactions in Lamellar Compounds , 1990 .

[22]  R. Haange,et al.  STRUCTURE AND PHYSICAL-PROPERTIES OF (SNS)1.18NBS2,SNNBS3, A COMPOUND WITH MISFIT LAYER STRUCTURE , 1988 .

[23]  K. Christe,et al.  Synthesis and characterization of tetrafluoroammonium(1+) tetrafluorobromate(1-) and tetrafluoroammonium(1+) tetrafluorooxobromate(1-) , 1986 .

[24]  R. Clement,et al.  Coordination chemistry of the lamellar MPS3 materials: metal-ligand cleavage as the source of an unusual cation-transfer intercalation process , 1986 .

[25]  S. Solin.  Alumino-Silicate Clays and Clay Intercalation Compounds , 1986 .

[26]  A. Jacobson.  7 – Organic and Organometallic Intercalation Compounds of the Transition Metal Dichalcogenides , 1982 .

[27]  Jack W. Johnson.  Amine intercalation in tantalum disulfide: The effect of small amounts of water , 1980 .

[28]  A. Lerf,et al.  Reversible topotactic redox reactions of layered dichalcogenides , 1975 .

[29]  R. Howard,et al.  Properties of intercalated 2H‐NbSe2, 4Hb‐TaS2, and 1T‐TaS2 , 1975 .

[30]  M. Whittingham.  The hydrated intercalation complexes of the layered disulfides , 1974 .

[31]  R. Schöllhorn,et al.  Schichteinlagerungsverbindungen des Niob- und Tantaldisulfids mit n-Alkylaminen / Layer Intercalation Compounds of Niobium and Tantalum Disulfide with n-Alkylamines , 1973 .

[32]  M Cais,et al.  Intercalation Complexes of Lewis Bases and Layered Sulfides: A Large Class of New Superconductors , 1971, Science.

[33]  B. Warren,et al.  X-Ray Diffraction , 2014 .

[34]  A R Stokes,et al.  A Numerical Fourier-analysis Method for the Correction of Widths and Shapes of Lines on X-ray Powder Photographs , 1948 .

[35]  W. Rachinger.  A Correction for the α1 α2 Doublet in the Measurement of Widths of X-ray Diffraction Lines , 1948 .