Self-healing and expansion characteristics of cementitious composites with high volume fly ash and MgO-type expansive agent

Abstract Discovering new cement based materials characterised with self-healing capability is essential for sustainable infrastructure with longer service life. Engineered cementitious composite (ECC) with high potential of micro-crack healing can enhance ductility and durability of concrete structures. MgO-type expansive agent (MEA) having low water demand and with the ability of densification of concrete microstructure was utilized in this research to develop ECC-MgO self-healing system. The effect of dosages of MEA and fly ash of different types as cement replacements was investigated based on lower expansion characteristics of ECC-MgO bar specimens through both water and autoclave linear expansion tests. The performance of ECC-MgO self-healing system was examined based on compressive strength recovery of pre-cracked cubic specimens and matrix micro-structural densification through Scanning Electron Microscope (SEM). Test results indicated that 5% lightly burnt MgO in combination with high volume of Class-F fly ash with 55% cement replacement should be used to design ECC-MgO self-healing system just to heal micro-cracks without affecting the durability. The higher compressive strength of 50% and 80% pre-cracked ECC-MgO cubic specimens cured under accelerated autoclaved conditions compared to ECC-control (without MEA) confirmed the self-healing capability and potential of the proposed ECC-MgO system.

[1]  S. Ghosh,et al.  Self‐Healing Materials: Fundamentals, Design Strategies, and Applications , 2009 .

[2]  Carola Edvardsen,et al.  Water Permeability and Autogenous Healing of Cracks in Concrete , 1999 .

[3]  Min Deng,et al.  Effects of MgO-based expansive additive on compensating the shrinkage of cement paste under non-wet curing conditions , 2012 .

[4]  R. Helmuth,et al.  Reappraisal of the Autoclave Expansion Test , 1998 .

[5]  P. Dubruel,et al.  Self-healing cementitious materials by the combination of microfibres and superabsorbent polymers , 2014 .

[6]  T. Mingshu,et al.  MgO-type delayed expansive cement , 1991 .

[7]  P. K. Mehta Influence of fly ash characteristics on the strength of portland-fly ash mixtures , 1985 .

[8]  Hui Lin,et al.  Production of MgO-type expansive agent in dam concrete by use of industrial by-products , 2008 .

[9]  Fangxian Li,et al.  INFLUENCE OF MgO EXPANSIVE AGENT ON BEHAVIOR OF CEMENT PASTES AND CONCRETE , 2010 .

[10]  V. Li,et al.  Influence of aggregate type and size on ductility and mechanical properties of engineered cementitious composites , 2009 .

[11]  M. Shehata The effects of fly ash and silica fume on alkali-silica reaction in concrete , 2001 .

[12]  Hwai Chung Wu,et al.  Matrix design for pseudo-strain-hardening fibre reinforced cementitious composites , 1995 .

[13]  Chongjiang Du A Review of Magnesium Oxide in Concrete , 2005 .

[14]  A. Neville Properties of Concrete , 1968 .

[15]  Takatsune Kikuta,et al.  Experimental Study on Self-Healing Capability of FRCC Using Different Types of Synthetic Fibers , 2012 .

[16]  M. Tang,et al.  MgO expansive cement and concrete in China: Past, present and future , 2014 .

[17]  A. Mullick,et al.  Volume stabilisation of high MgO cement: effect of curing conditions and fly ash addition , 1998 .

[18]  Pk Mehta,et al.  History and Status of Performance Tests for Evaluation of Soundness of Cements , 1978 .

[19]  S. S. Rehsi Magnesium Oxide in Portland Cement , 1983 .

[20]  Michael D. Lepech,et al.  Water permeability of engineered cementitious composites , 2009 .

[21]  Tomoya Nishiwaki,et al.  Self-Healing Capability of Fiber Reinforced Cementitious Composites , 2011 .

[22]  P. Dubruel,et al.  Visualization of water penetration in cementitious materials with superabsorbent polymers by means of neutron radiography , 2012 .

[23]  Mustafa Şahmaran,et al.  Self-healing of mechanically-loaded self consolidating concretes with high volumes of fly ash , 2008 .

[24]  V. M. Malhotra,et al.  Strength development and temperature rise in large concrete blocks containing high volumes of low-calcium (ASTM Class F) fly ash , 1992 .

[25]  Victor C. Li,et al.  Multiple Cracking Sequence and Saturation in Fiber Reinforced Cementitious Composites , 1998 .

[26]  Victor C. Li,et al.  Engineered Cementitious Composites with High-Volume Fly Ash , 2007 .

[27]  V. Li On Engineered Cementitious Composites (ECC) , 2003 .

[28]  En-Hua Yang,et al.  Use of High Volumes of Fly Ash to Improve ECC Mechanical Properties and Material Greenness , 2007 .

[29]  Shengxing Wu,et al.  Soundness evaluation of concrete with MgO , 2007 .

[30]  Victor C. Li,et al.  Engineered Cementitious Composites (ECC) - Tailored Composites Through Micromechanical Modeling , 1998 .

[31]  P. K. Mehta,et al.  Concrete: Microstructure, Properties, and Materials , 2005 .

[32]  Lei Shen,et al.  Analysis of material flow and consumption in cement production process , 2016 .

[33]  V. M. Malhotra,et al.  Performance of high-volume fly ash concrete in large experimental monoliths , 1994 .

[34]  Masoud Ghodsian,et al.  The effects of nanoscale expansive agents on the mechanical properties of non-shrink cement-based composites: The influence of nano-MgO addition , 2013 .

[35]  H. Justnes,et al.  Influence of plasticizers on the rheology and early heat of hydration of blended cements with high content of fly ash , 2016 .

[36]  Shunzhi Qian,et al.  Influence of curing condition and precracking time on the self-healing behavior of Engineered Cementitious Composites , 2010 .