An unprecedented 2D covalent organic framework with an htb net topology.

A 2D imine-linked COF with a hitherto unreported htb type topology was synthesized from a linear diamine linker and a judiciously designed tetra-aldehyde building block. This work opens the door to the development of COFs with unprecedented topologies and may broaden the scope of COF functional materials by pore size and pore surface engineering.

[1]  Haiyan Mao,et al.  Reticular Synthesis of Multinary Covalent Organic Frameworks. , 2019, Journal of the American Chemical Society.

[2]  Bing Sun,et al.  Stable Hydrazone-Linked Covalent Organic Frameworks Containing O,N,O'-Chelating Sites for Fe(III) Detection in Water. , 2019, ACS applied materials & interfaces.

[3]  Arne Thomas,et al.  3D Anionic Silicate Covalent Organic Framework with srs Topology. , 2018, Journal of the American Chemical Society.

[4]  Yan Liu,et al.  Chiral 3D Covalent Organic Frameworks for High Performance Liquid Chromatographic Enantioseparation. , 2018, Journal of the American Chemical Society.

[5]  Jun Fan,et al.  Construction of a hydrazone-linked chiral covalent organic framework-silica composite as the stationary phase for high performance liquid chromatography. , 2017, Journal of chromatography. A.

[6]  Yinghua Jin,et al.  Tessellated multiporous two-dimensional covalent organic frameworks , 2017 .

[7]  Yan Liu,et al.  Chiral Covalent Organic Frameworks with High Chemical Stability for Heterogeneous Asymmetric Catalysis. , 2017, Journal of the American Chemical Society.

[8]  G. Jiang,et al.  Toward Covalent Organic Frameworks Bearing Three Different Kinds of Pores: The Strategy for Construction and COF-to-COF Transformation via Heterogeneous Linker Exchange. , 2017, Journal of the American Chemical Society.

[9]  O. Yaghi,et al.  The atom, the molecule, and the covalent organic framework , 2017, Science.

[10]  S. Xu,et al.  Construction of 2D covalent organic frameworks by taking advantage of the variable orientation of imine bonds. , 2017, Chemical communications.

[11]  S. Xu,et al.  Precision Construction of 2D Heteropore Covalent Organic Frameworks by a Multiple-Linking-Site Strategy. , 2016, Chemistry.

[12]  Yingchao Yu,et al.  Rationally Designed 2D Covalent Organic Framework with a Brick-Wall Topology. , 2016, ACS macro letters.

[13]  D. Jiang,et al.  Covalent organic frameworks: a materials platform for structural and functional designs , 2016, Nature Reviews Materials.

[14]  Wei Wang,et al.  Constructing Crystalline Covalent Organic Frameworks from Chiral Building Blocks. , 2016, Journal of the American Chemical Society.

[15]  K. Nishimura,et al.  Multiple-component covalent organic frameworks , 2016, Nature Communications.

[16]  Xiu‐Ping Yan,et al.  Bottom-up synthesis of chiral covalent organic frameworks and their bound capillaries for chiral separation , 2016, Nature Communications.

[17]  S. Xu,et al.  Construction of Covalent Organic Frameworks Bearing Three Different Kinds of Pores through the Heterostructural Mixed Linker Strategy. , 2016, Journal of the American Chemical Society.

[18]  Guiqing Lin,et al.  A Pyrene-Based, Fluorescent Three-Dimensional Covalent Organic Framework. , 2016, Journal of the American Chemical Society.

[19]  Ming Dong,et al.  Thioether-Based Fluorescent Covalent Organic Framework for Selective Detection and Facile Removal of Mercury(II). , 2016, Journal of the American Chemical Society.

[20]  Yinghua Jin,et al.  Desymmetrized Vertex Design for the Synthesis of Covalent Organic Frameworks with Periodically Heterogeneous Pore Structures. , 2015, Journal of the American Chemical Society.

[21]  Wenchuan Wang,et al.  Systematic Tuning and Multifunctionalization of Covalent Organic Polymers for Enhanced Carbon Capture. , 2015, Journal of the American Chemical Society.

[22]  S. Irle,et al.  Rational design of crystalline supermicroporous covalent organic frameworks with triangular topologies , 2015, Nature Communications.

[23]  Zhiqiang Liang,et al.  A microporous lanthanum metal-organic framework as a bi-functional chemosensor for the detection of picric acid and Fe(3+) ions. , 2015, Dalton transactions.

[24]  S. Xu,et al.  One-step construction of two different kinds of pores in a 2D covalent organic framework. , 2014, Journal of the American Chemical Society.

[25]  F. Toma,et al.  Tunable electrical conductivity in oriented thin films of tetrathiafulvalene-based covalent organic framework , 2014 .

[26]  Jing Li,et al.  Luminescent metal-organic frameworks for chemical sensing and explosive detection. , 2014, Chemical Society reviews.

[27]  A. Nagai,et al.  An azine-linked covalent organic framework. , 2013, Journal of the American Chemical Society.

[28]  T. Bein,et al.  A photoconductive thienothiophene-based covalent organic framework showing charge transfer towards included fullerene. , 2013, Angewandte Chemie.

[29]  Michael O'Keeffe,et al.  Deconstructing the crystal structures of metal-organic frameworks and related materials into their underlying nets. , 2012, Chemical reviews.

[30]  Jiaguo Yu,et al.  Visible-light-induced photoelectrochemical behaviors of Fe-modified TiO2 nanotube arrays. , 2011, Nanoscale.

[31]  William R. Dichtel,et al.  Oriented 2D Covalent Organic Framework Thin Films on Single-Layer Graphene , 2011, Science.

[32]  S. Nagase,et al.  Synthesis of metallophthalocyanine covalent organic frameworks that exhibit high carrier mobility and photoconductivity. , 2011, Angewandte Chemie.

[33]  Michael O’Keeffe,et al.  A crystalline imine-linked 3-D porous covalent organic framework. , 2009, Journal of the American Chemical Society.

[34]  Sang Soo Han,et al.  Covalent organic frameworks as exceptional hydrogen storage materials. , 2008, Journal of the American Chemical Society.

[35]  Michael O'Keeffe,et al.  Designed Synthesis of 3D Covalent Organic Frameworks , 2007, Science.

[36]  Michael O'Keeffe,et al.  Porous, Crystalline, Covalent Organic Frameworks , 2005, Science.