Milli-channel with metal foams under an applied gas–liquid periodic flow: Flow patterns, residence time distribution and pulsing properties

Abstract This work investigates the hydrodynamics of a square milli-channel filled with metallic open-cell-foams (OCFs) under an applied G–L Taylor flow. The hydrodynamic properties of the Taylor flow are not maintained but induce pulsations in the foam bed. Thus, flow patterns in the foam can be represented by liquid plug pulses alternating with meandering digital gas paths into quasi-stagnant liquid zones. The pulse study revealed that the flow behaviour is quite similar to that encountered in more classical granular media of lower porosity. Predictive correlations for pulse frequency and velocity are proposed. Liquid residence time distribution (RTD) experiments were performed and revealed that fluid velocities, liquid viscosity and foam geometrical properties control the system. High liquid hold ups up to 90% are estimated and a predictive correlation is proposed. Interestingly, the impacts of the foam and liquid properties on this liquid hold up appear less pronounced in contrast with literature on other granular media.

[1]  J. Moulijn,et al.  Scaling down trickle bed reactors , 2005 .

[2]  G. Groppi,et al.  Mass-Transfer Characterization of Metallic Foams as Supports for Structured Catalysts , 2005 .

[3]  J. Moulijn,et al.  Dispersion and Holdup in Multiphase Packed Bed Microreactors , 2008 .

[4]  Peter J.T. Verheijen,et al.  Scaling-up Multiphase Monolith Reactors: Linking Residence Time Distribution and Feed Maldistribution , 2005 .

[5]  Bettina Kraushaar-Czarnetzki,et al.  Mass transfer and pressure drop in ceramic foams: A description for different pore sizes and porosities , 2008 .

[6]  Wernher Brevis,et al.  Integrating cross-correlation and relaxation algorithms for particle tracking velocimetry , 2011 .

[7]  Masahiro Kawaji,et al.  The effect of channel diameter on adiabatic two-phase flow characteristics in microchannels ☆ , 2004 .

[8]  Chin Pan,et al.  Gas-liquid two-phase flow in micro-channels , 2002 .

[9]  David Edouard,et al.  Pressure drop measurements and modeling on SiC foams , 2007 .

[10]  M. Ashby,et al.  Cellular solids: Structure & properties , 1988 .

[11]  B. Kuster,et al.  Gas–liquid mass transfer and axial dispersion in solid foam packings , 2007 .

[12]  N. A. Tsochatzidis,et al.  Properties of pulsing flow in a trickle bed , 1995 .

[13]  C. Stemmet,et al.  Gas-Liquid Solid Foam Reactors: Hydrodynamics and Mass Transfer , 2005 .

[14]  Freek Kapteijn,et al.  Gas–liquid mass transfer of aqueous Taylor flow in monoliths , 2001 .

[15]  S. Kuhn,et al.  Scalar transport in a milli-scale metal foam reactor , 2010 .

[16]  Said I. Abdel-Khalik,et al.  Gas–liquid two-phase flow in microchannels: Part II: void fraction and pressure drop , 1999 .

[17]  Adeniyi Lawal,et al.  Numerical study on gas and liquid slugs for Taylor flow in a T-junction microchannel , 2006 .

[18]  M. S. Ananth,et al.  Hydrodynamics of two-phase cocurrent downflow through packed beds. Part I. Macroscopic model , 1983 .

[19]  Asterios Gavriilidis,et al.  Gas-liquid and gas-liquid-solid microstructured reactors : contacting principles and applications , 2005 .

[20]  Klavs F. Jensen,et al.  Microfabricated multiphase packed-bed reactors : Characterization of mass transfer and reactions , 2001 .

[21]  Jc Jaap Schouten,et al.  Gas-liquid mass transfer in rotating solid foam reactors , 2010 .

[22]  H. A. Becker,et al.  Mixing between a round jet and a transverse turbulent pipe flow , 1983 .

[23]  Klavs F. Jensen,et al.  Measurement of residence time distribution in microfluidic systems , 2005 .

[24]  Faïçal Larachi,et al.  Experimental study of a trickle-bed reactor operating at high pressure: two-phase pressure drop and liquid saturation , 1991 .

[25]  Jerome Vicente,et al.  Open Celled Material Structural Properties Measurement : From Morphology To Transport Properties , 2006 .

[26]  N. Midoux,et al.  FLOW PATTERN, PRESSURE LOSS AND LIQUID HOLDUP DATA IN GAS-LIQUID DOWNFLOW PACKED BEDS WITH FOAMING AND NONFOAMING HYDROCARBONS , 1976 .

[27]  Muhammad Akbar,et al.  On gas–liquid two-phase flow regimes in microchannels , 2003 .

[28]  Feike J. Leij,et al.  Modeling the Nonequilibrium Transport of Linearly Interacting Solutes in Porous Media: A Review , 1991 .

[29]  van der J John Schaaf,et al.  Hydrodynamics of gas¿liquid counter-current flow in solid foam packings , 2005 .

[30]  Götz Veser,et al.  Experimental and theoretical investigation of H2 oxidation in a high-temperature catalytic microreactor , 2001 .

[31]  Y. W. Kwon,et al.  Representative unit-cell models for open-cell metal foams with or without elastic filler , 2003 .

[32]  Faïçal Larachi,et al.  Hydrodynamics of gas–liquid micro-fixed beds – Measurement approaches and technical challenges , 2013 .

[33]  C. Pham‐Huu,et al.  Residence time distribution, axial liquid dispersion and dynamic–static liquid mass transfer in trickle flow reactor containing β-SiC open-cell foams , 2012 .

[34]  Vito Specchia,et al.  Pressure drop and liquid holdup for two-phase concurrent flow in packed beds , 1977 .

[35]  Charlotte Pham,et al.  Experimental measurements and multiphase flow models in solid SiC foam beds , 2008 .

[36]  A. Burghardt,et al.  Hydrodynamics of Pulsing Flow in Three-Phase Fixed-Bed Reactor Operating at an Elevated Pressure , 2004 .

[37]  J. van der Schaaf,et al.  Gas–liquid dynamics at low Reynolds numbers in pillared rectangular micro channels , 2010 .

[38]  M. Kreutzer Hydrodynamics of Taylor Flow in Capillaries and Monolith Reactors , 2003 .

[39]  Adrian Zenklusen,et al.  Axial dispersion in metal foams and streamwise-periodic porous media , 2011 .

[40]  Srinivas Garimella,et al.  Characterization of two-phase flow patterns in small diameter round and rectangular tubes , 1999 .

[41]  Ruben G. Carbonell,et al.  hydrodynamic parameters for gas-liquid cocurrent flow in packed beds , 1985 .

[42]  V. G. Rao,et al.  Pressure drop and hydrodynamic properties of pulses in two‐phase gas‐liquid downflow through packed columns , 1983 .

[43]  Markus Schubert,et al.  Hydrodynamic multiplicity in a tubular reactor with solid foam packings , 2013 .

[44]  Ioannis G. Kevrekidis,et al.  Dynamics of pulsing flow in trickle beds , 1990 .

[45]  R. M. Sullivan,et al.  A general tetrakaidecahedron model for open-celled foams , 2008 .

[46]  Cesar Zarcone,et al.  Numerical models and experiments on immiscible displacements in porous media , 1988, Journal of Fluid Mechanics.

[47]  A. Attou,et al.  Revue des aspects hydrodynamiques des réacteurs catalytiques gaz-liquide-solide à lit fixe arrosé , 1999 .

[48]  J. E. Myers,et al.  Fluid‐flow characteristics of concurrent gas‐liquid flow in packed beds , 1964 .

[49]  Sang Yong Lee,et al.  Pressure drop of two-phase plug flow in round mini-channels: Influence of surface wettability , 2008 .

[50]  A. Drinkenburg,et al.  Hydrodynamic properties of pulses in two-phase downflow operated packed columns , 1982 .

[51]  J. Boelhouwer Nonsteady operation of trickle-bed reactors : hydrodynamics, mass and heat transfer , 2001 .

[52]  Hui Liu,et al.  Hydrodynamics of Taylor Flow in Vertical Capillaries: Flow Regimes, Bubble Rise Velocity, Liquid Slug Length, and Pressure Drop , 2005 .