Retrieval of ozone profiles from GOMOS limb scattered measurements

The GOMOS (Global Ozone Monitoring by Occultation of Stars) instrument on board the Envisat satellite measures the vertical composition of the atmosphere using the stellar occultation technique. While the night-time data of GOMOS are proved to be of good quality, the daytime observations are more challenging due to poorer signal-to-noise ratio. In this paper we present an alternative technique, which uses GOMOS limb scattered radiances instead of the stellar signal, to retrieve stratospheric ozone profiles. Like for many other limb-viewing instruments, GOMOS observations contain stray light at high altitudes. We introduce a method for removing the stray light and demonstrate its feasibility by comparing the corrected radiances against those from the OSIRIS (Optical Spectrograph & Infra Red Imaging System) instrument. For the retrieval of ozone profiles, an onion peeling method is used. The first validation results suggest that the retrieval of stratospheric ozone is possible with a typical accuracy better than 10% at 22-50 km. GOMOS has measured about 350 000 daytime profiles since 2002. The new retrieval method presented here makes this large amount of data finally available for scientific use.

[1]  Kenneth Levenberg A METHOD FOR THE SOLUTION OF CERTAIN NON – LINEAR PROBLEMS IN LEAST SQUARES , 1944 .

[2]  M. Guirlet,et al.  GOMOS data characterisation and error estimation , 2010 .

[3]  G. Berthet,et al.  Validation of GOMOS‐Envisat vertical profiles of O3, NO2, NO3, and aerosol extinction using balloon‐borne instruments and analysis of the retrievals , 2008 .

[4]  Alain Hauchecorne,et al.  First climatology of polar mesospheric clouds from GOMOS/ENVISAT stellar occultation instrument , 2009 .

[5]  Heinrich Bovensmann,et al.  SCIAMACHY - Exploring the Changing Earth's Atmosphere , 2011 .

[6]  M. Schlesinger,et al.  Atmospheric response to NOy source due to energetic electron precipitation , 2005 .

[7]  D. Fussen,et al.  GOMOS O 3 , NO 2 , and NO 3 observations in 2002–2008 , 2010 .

[8]  D. Fussen,et al.  GOMOS O3, NO2, and NO3 observations in 2002-2008 , 2010 .

[9]  A. Kokhanovsky,et al.  SCIATRAN 2.0 – A new radiative transfer model for geophysical applications in the 175–2400 nm spectral region , 2004 .

[10]  Piet Stammes,et al.  McSCIA: application of the equivalence theorem in a Monte Carlo radiative transfer model for spherical shell , 2006 .

[11]  W. Grant Ozone measuring instruments for the stratosphere , 1989 .

[12]  E. J. Llewellyn,et al.  The OSIRIS instrument on the Odin spacecraft , 2004 .

[13]  J. Burrows,et al.  Climatology of noctilucent cloud radii and occurrence frequency using SCIAMACHY , 2009 .

[14]  H. Bovensmann,et al.  Evolution of stratospheric ozone and water vapour time series studied with satellite measurements , 2009 .

[15]  E. Kyrölä,et al.  Multiple scattering radiance in limb‐viewing geometry , 1999 .

[16]  Veronika Eyring,et al.  Attribution of observed changes in stratospheric ozone and temperature , 2010 .

[17]  Adam E. Bourassa,et al.  SASKTRAN: A spherical geometry radiative transfer code for efficient estimation of limb scattered sunlight , 2008 .

[18]  Didier F. G. Rault,et al.  Ozone profile retrieval from Stratospheric Aerosol and Gas Experiment (SAGE III) limb scatter measurements , 2005 .

[19]  R. Mcpeters,et al.  Ozone profile retrieval from GOMOS limb scattering measurements , 2008 .

[20]  Attribution of stratospheric ozone trends to chemistry and transport: a modelling study , 2010 .

[21]  L. Oikarinen,et al.  LIMBTRAN: A pseudo three‐dimensional radiative transfer model for the limb‐viewing imager OSIRIS on the ODIN satellite , 2000 .

[22]  E. J. Llewellyn,et al.  Odin/OSIRIS limb observations of polar mesospheric clouds in 2001–2003 , 2006 .

[23]  D. Marquardt An Algorithm for Least-Squares Estimation of Nonlinear Parameters , 1963 .

[24]  K. Strawbridge,et al.  GOMOS ozone profile validation using ground-based and balloon sonde measurements , 2010 .

[25]  Philippe Keckhut,et al.  Pole‐to‐pole validation of Envisat GOMOS ozone profiles using data from ground‐based and balloon sonde measurements , 2004 .

[26]  O. V Postylyakov Radiative transfer model MCC++ with evaluation of weighting functions in spherical atmosphere for use in retrieval algorithms , 2004 .

[27]  J. Tamminen,et al.  Description and validation of a limb scatter retrieval method for Odin/OSIRIS , 2008 .