Room-temperature one-step immobilization of rod-like helical polymer onto hydrophilic substrates.

A facile, one-pot immobilization method for a rigid rod-like helical polysilane, poly(n-decyl-i-butylsilane), was developed onto hydrophilic surfaces at room temperature in the presence of triethylamine as a catalyst.

[1]  J. Watanabe,et al.  Optically Active Polysilanes. Ten Years of Progress and New Polymer Twist for Nanoscience and Nanotechnology , 2003 .

[2]  K. Furukawa.  End-grafted polysilane--an approach to single polymer science. , 2003, Accounts of chemical research.

[3]  Jillian M Buriak,et al.  Organometallic chemistry on silicon and germanium surfaces. , 2002, Chemical reviews.

[4]  Frank Simon,et al.  Synthesis of Adaptive Polymer Brushes via “Grafting To” Approach from Melt , 2002 .

[5]  Yoram Cohen,et al.  Multilayer Alkoxysilane Silylation of Oxide Surfaces , 2001 .

[6]  M. Fujiki.  Optically Active Polysilylenes: State-of-the-Art Chiroptical Polymers , 2001 .

[7]  M. Fujiki,et al.  One‐Dimensional Silicon Chain Architecture: Molecular Dot, Rope, Octopus, and Toroid , 2000 .

[8]  W. Brittain,et al.  Polymer brushes: surface-immobilized macromolecules , 2000 .

[9]  A. Pinhas,et al.  Dehydrocoupling Polymerization of Bis-silanes and Disilanols to Poly(silphenylenesiloxane) As Catalyzed by Rhodium Complexes† , 2000 .

[10]  Yuning Li,et al.  Synthesis and Properties of Polymers Containing Silphenylene Moiety via Catalytic Cross-Dehydrocoupling Polymerization of 1,4-Bis(dimethylsilyl)benzene , 1999 .

[11]  K. Furukawa,et al.  Synthesis and Characterization of End-Grafted Polysilane on a Substrate Surface , 1998 .

[12]  J. Chruściel.  EFFECT OF ADDITION OF LICL ON REACTION RATES IN DEHYDROCOUPLING OF HYDROSILANES WITH HYDROXYL CONTAINING NUCLEOPHILES, IN DMF CATALYZED BY ZNCL2 , 1997 .

[13]  Jun Hu,et al.  Imaging of Single Extended DNA Molecules on Flat (Aminopropyl)triethoxysilane−Mica by Atomic Force Microscopy , 1996 .

[14]  S. Granick,et al.  Formation and Characterization of a Highly Ordered and Well- Anchored Alkylsilane Monolayer on Mica by Self -Assembly , 1991 .

[15]  K. Sakamoto,et al.  Novel anionic polymerization of masked disilenes to polysilylene high polymers and block copolymers , 1989 .

[16]  R. J. Klingler,et al.  Silane-silanol dehydrocondensation. The microscopic reverse of hydrogen activation by an organometallic oxide complex , 1988 .

[17]  K. Matyjaszewski,et al.  Preparation of polysilanes in the presence of ultrasound , 1988 .