Solar Thermochemical Production of Fuels

High-temperature thermochemical processes efficiently convert concentrated solar energy into storable and transportable fuels. In the long run, H2O/CO2-splitting thermochemical cycles based on metal oxide redox reactions are developed to produce H2 and CO, which can be further processed to synthetic liquid fuels. In a transition period, carbonaceous feedstocks (fossil fuels, biomass, C-containing wastes) are solar-upgraded and transformed into valuable fuels via reforming, gasification and decomposition processes. The most promising solar thermochemical processes are discussed and the latest technological developments are summarized.

[1]  W. Chueh,et al.  Ceria as a thermochemical reaction medium for selectively generating syngas or methane from H(2)O and CO(2). , 2009, ChemSusChem.

[2]  Klaus S. Lackner,et al.  A Guide to CO2 Sequestration , 2003, Science.

[3]  Solar Syngas Production from H2O and CO2 via Two-Step Thermochemical Cycles Based on Zn/ZnO and FeO/Fe3O4 Redox Reactions: Kinetic Analysis; energy & fuels , 2010 .

[4]  Alan W. Weimer,et al.  Solar-driven biochar gasification in a particle-flow reactor , 2009 .

[5]  A Two-Step Thermochemical Water Splitting by Iron-Oxide on Stabilized Zirconia , 2006 .

[6]  Christian Sattler,et al.  Operational strategy of a two-step thermochemical process for solar hydrogen production , 2009 .

[7]  M. Dry,et al.  The Fischer–Tropsch process: 1950–2000 , 2002 .

[8]  Michael Epstein,et al.  Towards the Industrial Solar Carbothermal Production of Zinc , 2008 .

[9]  Anton Meier,et al.  Solar Fuels and Materials , 2004 .

[10]  Nathan P. Siegel,et al.  Metal oxide composites and structures for ultra-high temperature solar thermochemical cycles , 2008 .

[11]  A. Steinfeld,et al.  Co‐synthesis of H2 and ZnO by in‐situ Zn aerosol formation and hydrolysis , 2006 .

[12]  G. Flamant,et al.  Novel two-step SnO2/SnO water-splitting cycle for solar thermochemical production of hydrogen , 2008 .

[13]  A. Steinfeld,et al.  H2 production by steam-quenching of Zn vapor in a hot-wall aerosol flow reactor , 2009 .

[14]  R. Stone China. Internet blockade in Xinjiang puts a strain on science. , 2009, Science.

[15]  N. Siegel,et al.  Central-Station Solar Hydrogen Power Plant , 2007 .

[16]  Alan W. Weimer,et al.  Solar‐thermal production of renewable hydrogen , 2009 .

[17]  G. Flamant,et al.  Hydrogen production from mixed cerium oxides via three-step water-splitting cycles , 2009 .

[18]  Christian Sattler,et al.  Prospects of solar thermal hydrogen production processes , 2009 .

[19]  Pamela L. Spath,et al.  Using a Concentrating Solar Reactor to Produce Hydrogen and Carbon Black via Thermal Decomposition of Natural Gas: Feasibility and Economics , 2003 .

[20]  A. Steinfeld,et al.  Tomography based determination of permeability, Dupuit–Forchheimer coefficient, and interfacial heat transfer coefficient in reticulate porous ceramics , 2008 .

[21]  Nathan P. Siegel,et al.  Solar Thermochemical Water-Splitting Ferrite-Cycle Heat Engines , 2008 .

[22]  S. Jensen,et al.  Hydrogen and synthetic fuel production from renewable energy sources , 2007 .

[23]  A. Steinfeld Solar hydrogen production via a two-step water-splitting thermochemical cycle based on Zn/ZnO redox reactions , 2002 .

[24]  Aldo Steinfeld,et al.  CO2 capture from atmospheric air via consecutive CaO-carbonation and CaCO3-calcination cycles in a fluidized-bed solar reactor , 2009 .

[25]  Remo Felder,et al.  Well-To-Wheel Analysis of Solar Hydrogen Production and Utilization for Passenger Car Transportation , 2008 .

[26]  Giovanni Cerri,et al.  HYTHEC: An EC funded search for a long term massive hydrogen production route using solar and nuclear technologies , 2007 .

[27]  Gilles Flamant,et al.  Screening of water-splitting thermochemical cycles potentially attractive for hydrogen production by concentrated solar energy , 2006 .

[28]  Alan W. Weimer,et al.  Rapid High Temperature Solar Thermal Biomass Gasification in a Prototype Cavity Reactor , 2010 .

[29]  Christian Sattler,et al.  Economic comparison of solar hydrogen generation by means of thermochemical cycles and electrolysis , 2008 .

[30]  A. Steinfeld Solar thermochemical production of hydrogen--a review , 2005 .

[31]  Jane H. Davidson,et al.  Hydrolysis of evaporated Zn in a hot wall flow reactor , 2008 .

[32]  John Mantzaras,et al.  Catalytic Combustion of Syngas , 2008 .

[33]  Anton Meier,et al.  A Receiver-Reactor for the Solar Thermal Dissociation of Zinc , 2007 .

[34]  A. Steinfeld,et al.  Experimental investigation of a packed-bed solar reactor for the steam-gasification of carbonaceous feedstocks , 2009 .

[35]  P. Li,et al.  Hydrogen generation by hydrolysis of zinc powder aerosol , 2008 .

[36]  Takao Miura,et al.  Rotary-type solar reactor for solar hydrogen production with two-step water splitting process , 2007 .

[37]  Gilles Flamant,et al.  High-Temperature Solar Methane Dissociation in a Multitubular Cavity-Type Reactor in the Temperature Range 1823−2073 K , 2009 .

[38]  Aldo Steinfeld,et al.  Solar thermal cracking of methane in a particle-flow reactor for the co-production of hydrogen and carbon , 2009 .

[39]  Aldo Steinfeld,et al.  A 300kW Solar Chemical Pilot Plant for the Carbothermic Production of Zinc , 2006 .

[40]  Miss A.O. Penney (b) , 1974, The New Yale Book of Quotations.