论文信息 - Clausius-Clapeyron equation analysis of two- dimensional vaporization

Clausius-Clapeyron equation analysis of two- dimensional vaporization

Abstract The temperature dependence of the work function change caused by adsorption of Cu, Ag, Au, Ni and Pd on W(110) and of Ag and Au on W(211) is analyzed with the aid of the Clausius-Clapeyron equation. It is found that the heat of two-dimensional evaporation has a high and a low temperature value which indicates evaporation from smooth island edges at low temperature and rough edges at high temperature. A two-dimensional roughening transition is implied.

E. Bauer | J. Kołaczkiewicz | J. Kołaczkiewicz | Ernst Bauer

[1] E. Bauer,et al. Thermal desorption of metals from tungsten single crystal surfaces , 1975 .

[2] E. Bauer,et al. Adsorption and condensation of Cu on W single‐crystal surfaces , 1974 .

[3] V. Pokrovsky,et al. On the properties of monolayers of adsorbed atoms , 1978 .

[4] A. Beerbower,et al. In: Films on Solid Surfaces , 1976 .

[5] T. Riste. Ordering in strongly fluctuating condensed matter systems , 1980 .

[6] A. Thomy,et al. Two-dimensional phase transitions as displayed by adsorption isotherms on graphite and other lamellar solids , 1981 .

[7] E. Bauer,et al. The adsorption and early stages of condensation of Ag and Au on W single-crystal surfaces , 1977 .

[8] E. Bauer,et al. Properties of ultrathin layers of palladium on a tungsten {110} surface , 1980 .

[9] D. Abraham. Solvable Model with a Roughening Transition for a Planar Ising Ferromagnet , 1980 .

[10] E. Kaldis. Current Topics in Materials Science , 1980 .

[11] E. Bauer,et al. The adsorption of Ni on W (110) and (211) surfaces , 1984 .

[12] Monte Carlo simulation of a planar Ising model roughening transition , 1981 .

[13] E. Bauer,et al. Temperature Dependence of the Work Function of Adsorbate-Covered Metal Surfaces: A New Method for the Study of Two-Dimensional Phase Transitions , 1984 .

[14] B. Poelsema,et al. Direct Evidence for Two-Dimensional Xe Gas-Solid Phase Transition on Pt(111) by Means of Thermal He Scattering , 1983 .