Liquid azide salts and their reactions with common oxidizers IRFNA and N2O4.

Several imidazolium-based ionic liquid azides with saturated and unsaturated side chains were prepared, and their physical and structural properties were investigated. The reactivity of these new as well as some previously reported ionic liquid azides with strong oxidizers, N 2O 4 and inhibited, red-fuming-nitric acid (IRFNA), was studied.

[1]  Krishnan Raghavachari,et al.  Gaussian-2 theory for molecular energies of first- and second-row compounds , 1991 .

[2]  M. Gordon,et al.  Enthalpies of formation of gas-phase N3, N3-, N5+, and N5- from Ab initio molecular orbital theory, stability predictions for N5(+)N3(-) and N5(+)N5(-), and experimental evidence for the instability of N5(+)N3(-). , 2004, Journal of the American Chemical Society.

[3]  J. R. Wazer,et al.  Accuracy in ab initio reaction-energy computations. 1. Compounds of first-row elements , 1990 .

[4]  D. Rogers,et al.  G2 ab initio calculations of the enthalpy of formation of hydrazoic acid, methyl azide, ethyl azide, methyl amine, and ethyl amine , 1995 .

[5]  M. Finn,et al.  Click Chemistry: Diverse Chemical Function from a Few Good Reactions. , 2001 .

[6]  E. Klein,et al.  The Heats of Combustion of Diazoaminobenzene, Benzotriazole and 2-Triazoethanol , 1953 .

[7]  Dennis W. Smith,et al.  ALKENE- AND ALKYNE-SUBSTITUTED METHYLIMIDAZOLIUM BROMIDES: STRUCTURAL EFFECTS AND PHYSICAL PROPERTIES , 2007 .

[8]  R. D. Verma,et al.  Energetic nitrogen-rich salts and ionic liquids. , 2006, Angewandte Chemie.

[9]  S. Gabriel Ueber Vinylamin und Bromäthylamin. (II.) , 1888 .

[10]  J. Pedley Thermochemical data and structures of organic compounds , 1994 .

[11]  T. Klapötke,et al.  Nitrosyl Azide, N4O, an Intrinsically Unstable Oxide of Nitrogen , 1993 .

[12]  Kwang S. Kim,et al.  Theory and applications of computational chemistry : the first forty years , 2005 .

[13]  L. Glasser,et al.  Lattice potential energy estimation for complex ionic salts from density measurements. , 2002, Inorganic chemistry.

[14]  Theodor Curtius Neues vom Stickstoffwasserstoff , 1891 .

[15]  A. Vij,et al.  Liquid azide salts. , 2008, Inorganic chemistry.

[16]  Ghanshyam L. Vaghjiani,et al.  Highly Accurate Ignition Delay Apparatus for Hypergolic Fuel Research (PREPRINT) , 2005 .

[17]  A. Bondi van der Waals Volumes and Radii , 1964 .

[18]  A. Padwa 1,3-Dipolar Cycloaddition Chemistry , 1984 .

[19]  J. Murray,et al.  Statistically-based interaction indices derived from molecular surface electrostatic potentials: a general interaction properties function (GIPF) , 1994 .