Crystals for sustainability – structuring Al-based MOFs for the allocation of heat and cold

Several Al-based MOFs of the CAU family have been investigated for application in the adsorption driven allocation of heat and cold. The special water adsorption behaviour of CAU-10-H makes it ideal for application in adsorption driven heat pumps and chillers. For increased performance, CAU-10-H crystals have been grown directly on both γ-alumina and metallic aluminium. Crystal growth on these surfaces can be controlled by the addition of acids.

[1]  Mark Goldsworthy,et al.  Measurements of water vapour sorption isotherms for RD silica gel, AQSOA-Z01, AQSOA-Z02, AQSOA-Z05 and CECA zeolite 3A , 2014 .

[2]  A. Morsali,et al.  Synthesis and characterization of different nanostructured copper(II) metal–organic frameworks by a ligand functionalization and modulation method , 2014 .

[3]  F. Kapteijn,et al.  Molecular promoting of aluminum metal-organic framework topology MIL-101 by N,N-dimethylformamide. , 2014, Inorganic chemistry.

[4]  E. Proverbio,et al.  Synthesis of SAPO-34 on graphite foams for adsorber heat exchangers , 2013 .

[5]  C. Janiak,et al.  Programming MOFs for water sorption: amino-functionalized MIL-125 and UiO-66 for heat transformation and heat storage applications. , 2013, Dalton transactions.

[6]  C. Janiak,et al.  Grafting of hydrophilic ethylene glycols or ethylenediamine on coordinatively unsaturated metal sites in MIL-100(Cr) for improved water adsorption characteristics , 2013 .

[7]  Michael J. Katz,et al.  A facile synthesis of UiO-66, UiO-67 and their derivatives. , 2013, Chemical communications.

[8]  M. Dincǎ,et al.  Postsynthetic tuning of hydrophilicity in pyrazolate MOFs to modulate water adsorption properties , 2013 .

[9]  Yuri I. Aristov,et al.  Challenging offers of material science for adsorption heat transformation: A review , 2013 .

[10]  B. Dawoud.  Water vapor adsorption kinetics on small and full scale zeolite coated adsorbers; A comparison , 2013 .

[11]  J. Marrot,et al.  First keto-functionalized microporous Al-based metal-organic framework: [Al(OH)(O2C-C6H4-CO-C6H4-CO2)]. , 2013, Inorganic chemistry.

[12]  T. Verbiest,et al.  Structures, Sorption Characteristics, and Nonlinear Optical Properties of a New Series of Highly Stable Aluminum MOFs , 2013 .

[13]  E. Chen,et al.  Tuning the aspect ratio of NH2-MIL-53(Al) microneedles and nanorods via coordination modulation , 2013 .

[14]  B. Gil,et al.  A new Al-MOF based on a unique column-shaped inorganic building unit exhibiting strongly hydrophilic sorption behaviour. , 2012, Chemical communications.

[15]  M. Thommes,et al.  Surface and Pore Structure Assessment of Hierarchical MFI Zeolites by Advanced Water and Argon Sorption Studies , 2012 .

[16]  S. Kitagawa,et al.  Mesoscopic architectures of porous coordination polymers fabricated by pseudomorphic replication. , 2012, Nature materials.

[17]  S. Kitagawa,et al.  Effect of functional groups in MIL-101 on water sorption behavior , 2012 .

[18]  Krista S. Walton,et al.  Effect of Water Adsorption on Retention of Structure and Surface Area of Metal–Organic Frameworks , 2012 .

[19]  Jun Ni,et al.  MOF-5 composites exhibiting improved thermal conductivity , 2012 .

[20]  Mark Feyand,et al.  CAU-3: a new family of porous MOFs with a novel Al-based brick: [Al2(OCH3)4(O2C-X-CO2)] (X = aryl). , 2012, Dalton transactions.

[21]  Hongjie Zhang,et al.  Combining Coordination Modulation with Acid–Base Adjustment for the Control over Size of Metal–Organic Frameworks , 2012 .

[22]  Peter Behrens,et al.  Modulated synthesis of Zr-based metal-organic frameworks: from nano to single crystals. , 2011, Chemistry.

[23]  C. Serre,et al.  High-throughput and time-resolved energy-dispersive X-ray diffraction (EDXRD) study of the formation of CAU-1-(OH)2: microwave and conventional heating. , 2011, Chemistry.

[24]  A. Matzger,et al.  Water stability of microporous coordination polymers and the adsorption of pharmaceuticals from water. , 2010, Langmuir : the ACS journal of surfaces and colloids.

[25]  S. Kitagawa,et al.  Highly Porous and Stable Coordination Polymers as Water Sorption Materials , 2010 .

[26]  A. Benin,et al.  Virtual high throughput screening confirmed experimentally: porous coordination polymer hydration. , 2009, Journal of the American Chemical Society.

[27]  Daniel Gunzelmann,et al.  [Al4(OH)2(OCH3)4(H2N-bdc)3] x xH(2)O: a 12-connected porous metal-organic framework with an unprecedented aluminum-containing brick. , 2009, Angewandte Chemie.

[28]  Stefan Kaskel,et al.  Characterization of metal-organic frameworks by water adsorption , 2009 .

[29]  Christoph Janiak,et al.  MOFs as adsorbents for low temperature heating and cooling applications. , 2009, Journal of the American Chemical Society.

[30]  Hiroyuki Kakiuchi,et al.  The Evaluation of Direct Cooling and Heating Desiccant Device Coated with FAM , 2007 .

[31]  Alan J. H. McGaughey,et al.  Thermal conductivity of a metal-organic framework (MOF-5): Part II. Measurement , 2007 .

[32]  R. E. Critoph,et al.  Review of trends in solid sorption refrigeration and heat pumping technology , 2005 .

[33]  Hiroyuki Kakiuchi,et al.  Novel water vapor adsorbent FAM-Z01 and its applicability to an adsorption heat pump , 2005 .

[34]  Hiroyuki Kakiuchi,et al.  Water vapor adsorbent FAM-Z02 and its applicability to adsorption heat pump , 2005 .

[35]  Giovanni Restuccia,et al.  A zeolite-coated bed for air conditioning adsorption systems: parametric study of heat and mass transfer by dynamic simulation , 2002 .

[36]  Rajiv K. Kalia,et al.  DYNAMICS OF OXIDATION OF ALUMINUM NANOCLUSTERS USING VARIABLE CHARGE MOLECULAR-DYNAMICS SIMULATIONS ON PARALLEL COMPUTERS , 1999 .

[37]  Melkon Tatlier,et al.  A novel approach to enhance heat and mass transfer in adsorption heat pumps using the zeolite–water pair , 1999 .

[38]  R. Wollast,et al.  Coordination chemistry of weathering: Kinetics of the surface-controlled dissolution of oxide minerals , 1990 .

[39]  K. Sing.  Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984) , 1985 .

[40]  K. Sing,et al.  Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Provisional) , 1982 .