Sulfenamide-enabled ortho thiolation of aryl iodides via palladium/norbornene cooperative catalysis

[1]  Guangbin Dong,et al.  Palladium/Norbornene Cooperative Catalysis. , 2019, Chemical reviews.

[2]  Z. Gu,et al.  Selective Ortho Thiolation Enabled by Tuning the Ancillary Ligand in Palladium/Norbornene Catalysis. , 2019, Organic letters.

[3]  Guangbin Dong,et al.  Redox-Neutral ortho Functionalization of Aryl Boroxines via Palladium/Norbornene Cooperative Catalysis. , 2019, Chem.

[4]  Guangbin Dong,et al.  Palladium/Norbornene-Catalyzed Indenone Synthesis from Simple Aryl Iodides: Concise Syntheses of Pauciflorol F and Acredinone A. , 2019, Angewandte Chemie.

[5]  Yong‐Min Liang,et al.  Carboxylate Ligand-Exchanged Amination/C(sp3)–H Arylation Reaction via Pd/Norbornene Cooperative Catalysis , 2018, ACS Catalysis.

[6]  C. Chen,et al.  Expeditious Synthesis of 6-Fluoroalkyl-Phenanthridines via Palladium-Catalyzed Norbornene-Mediated Dehydrogenative Annulation. , 2018, Organic letters.

[7]  Qianghui Zhou,et al.  Alkylating Reagents Employed in Catellani-Type Reactions. , 2018, Chemistry.

[8]  Z. Gu,et al.  Development of New Electrophiles in Palladium/Norbornene-Catalyzed ortho-Functionalization of Aryl Halides , 2018, Synlett.

[9]  Weiwei Lv,et al.  Palladium-Catalyzed Ortho-Silylation of Aryl Iodides with Concomitant Arylsilylation of Oxanorbornadiene: Accessing Functionalized ( Z)-β-Substituted Vinylsilanes and Their Analogues. , 2018, Organic letters.

[10]  Guangbin Dong,et al.  Complementary site-selectivity in arene functionalization enabled by overcoming the ortho constraint in palladium/norbornene catalysis , 2018, Nature Chemistry.

[11]  Guangbin Dong,et al.  Modular ipso/ ortho Difunctionalization of Aryl Bromides via Palladium/Norbornene Cooperative Catalysis. , 2018, Journal of the American Chemical Society.

[12]  Yanghui Zhang,et al.  Disilylation of Palladacycles that were Generated through the C−H Activation of Aryl Halides , 2018, Asian Journal of Organic Chemistry.

[13]  Guangbin Dong,et al.  Direct Annulation between Aryl Iodides and Epoxides through Palladium/Norbornene Cooperative Catalysis. , 2018, Angewandte Chemie.

[14]  Guangfu Yang,et al.  Sulfur-Containing Agrochemicals , 2017, Topics in Current Chemistry.

[15]  Eun Kwang Lee,et al.  Toward Environmentally Robust Organic Electronics: Approaches and Applications , 2017, Advanced materials.

[16]  jin-quan yu,et al.  Ligand Promoted meta-C-H Chlorination of Anilines and Phenols. , 2016, Journal of the American Chemical Society.

[17]  Z. Gu,et al.  Cleavage of the C(O)—S Bond of Thioesters by Palladium/Norbornene/Copper Cooperative Catalysis: An Efficient Synthesis of 2‐(Arylthio)aryl Ketones. , 2016 .

[18]  Guangbin Dong,et al.  Reagent-Enabled ortho-Alkoxycarbonylation of Aryl Iodides via Palladium/Norbornene Catalysis , 2016 .

[19]  C. Kokotos,et al.  Green Organocatalytic Oxidation of Sulfides to Sulfoxides and Sulfones , 2016, Synthesis.

[20]  M. Fontana,et al.  Pd/Norbornene: A Winning Combination for Selective Aromatic Functionalization via C-H Bond Activation. , 2016, Accounts of chemical research.

[21]  Z. Gu,et al.  Cleavage of the C(O)-S Bond of Thioesters by Palladium/Norbornene/Copper Cooperative Catalysis: An Efficient Synthesis of 2-(Arylthio)aryl Ketones. , 2016, Journal of the American Chemical Society.

[22]  Steven H. Liang,et al.  Sulfur Containing Scaffolds in Drugs: Synthesis and Application in Medicinal Chemistry. , 2016, Current topics in medicinal chemistry.

[23]  Z. Gu,et al.  Palladium‐Catalyzed Catellani ortho‐Acylation Reaction: An Efficient and Regiospecific Synthesis of Diaryl Ketones. , 2016 .

[24]  N. Chatani,et al.  Palladium(ii)-catalyzed synthesis of dibenzothiophene derivatives via the cleavage of carbon–sulfur and carbon–hydrogen bonds† †Electronic supplementary information (ESI) available: Experimental procedures and characterization data for all new compounds. See DOI: 10.1039/c5sc04890g , 2016, Chemical science.

[25]  Chuanhu Lei,et al.  Palladium-Catalyzed Heteroarylation and Concomitant ortho-Alkylation of Aryl Iodides. , 2015, Angewandte Chemie.

[26]  Juntao Ye,et al.  Palladium-catalysed norbornene-mediated C-H functionalization of arenes. , 2015, Nature chemistry.

[27]  Guangbin Dong,et al.  Ortho C-H Acylation of Aryl Iodides by Palladium/Norbornene Catalysis. , 2015, Angewandte Chemie.

[28]  Z. Gu,et al.  Palladium-Catalyzed Catellani ortho-Acylation Reaction: An Efficient and Regiospecific Synthesis of Diaryl Ketones. , 2015, Angewandte Chemie.

[29]  Xiao‐Hong Zhang,et al.  Pd(II)-catalyzed selective sulfenylation of arene C-H bonds using N-arylthiobenzamides as thiolation reagent and oxidant , 2015 .

[30]  Qixing Huang,et al.  Palladium-Catalyzed Acylation/Alkenylation of Aryl Iodide: A Domino Approach Based on the Catellani–Lautens Reaction , 2015 .

[31]  F. Glorius,et al.  Heterogeneously catalyzed direct C-H thiolation of heteroarenes. , 2015, Angewandte Chemie.

[32]  Guangbin Dong,et al.  Simple Amine-Directed Meta-Selective C-H Arylation via Pd/Norbornene Catalysis. , 2015, Journal of the American Chemical Society.

[33]  T. Ritter,et al.  Modular C-H functionalization cascade of aryl iodides. , 2015, Journal of the American Chemical Society.

[34]  W. Gong,et al.  Ligand-enabled meta-C–H activation using a transient mediator , 2015, Nature.

[35]  Yuhong Zhang,et al.  Direct ortho-thiolation of arenes and alkenes by nickel catalysis. , 2015, Organic letters.

[36]  Pinhong Chen,et al.  Palladium-catalyzed cascade C-H trifluoroethylation of aryl iodides and Heck reaction: efficient synthesis of ortho-trifluoroethylstyrenes. , 2014, Angewandte Chemie.

[37]  Y. Nishihara,et al.  Palladium-catalyzed direct thiolation of aryl C-H bonds with disulfides. , 2014, Chemistry.

[38]  P. Anbarasan,et al.  Palladium catalyzed aryl(alkyl)thiolation of unactivated arenes. , 2014, Organic letters.

[39]  Guangbin Dong,et al.  Ortho vs ipso: site-selective Pd and norbornene-catalyzed arene C-H amination using aryl halides. , 2013, Journal of the American Chemical Society.

[40]  S. Buchwald,et al.  Synthesis of aryl sulfonamides via palladium-catalyzed chlorosulfonylation of arylboronic acids. , 2013, Journal of the American Chemical Society.

[41]  F. Terrier.  Modern Nucleophilic Aromatic Substitution: Terrier/Modern Nucleophilic Aromatic Substitution , 2013 .

[42]  Z. Gu,et al.  Pd-catalyzed chemoselective Catellani ortho-arylation of iodopyrroles: rapid total synthesis of rhazinal. , 2013, Journal of the American Chemical Society.

[43]  T. Bach,et al.  Palladium-catalyzed direct 2-alkylation of indoles by norbornene-mediated regioselective cascade C-H activation. , 2011, Journal of the American Chemical Society.

[44]  V. Ananikov,et al.  Transition-metal-catalyzed C-S, C-Se, and C-Te bond formation via cross-coupling and atom-economic addition reactions. , 2011, Chemical reviews.

[45]  M. Lautens,et al.  A route to annulated indoles via a palladium-catalyzed tandem alkylation/direct arylation reaction. , 2005, Journal of the American Chemical Society.

[46]  M. Catellani,et al.  A new reaction sequence involving palladium-catalyzed unsymmetrical aryl coupling. , 2004, Journal of the American Chemical Society.

[47]  Lautens,et al.  A New Route to Fused Aromatic Compounds by Using a Palladium-Catalyzed Alkylation - Alkenylation Sequence This work was supported by the NSERC (Canada) and the University of Toronto. S.P. thanks the Fondation Bettencourt - Schueller for a postdoctoral fellowship. , 2000, Angewandte Chemie.

[48]  Rajender S. Varma and,et al.  The Urea−Hydrogen Peroxide Complex: Solid-State Oxidative Protocols for Hydroxylated Aldehydes and Ketones (Dakin Reaction), Nitriles, Sulfides, and Nitrogen Heterocycles , 1999 .

[49]  H. Kurosawa,et al.  The First Evidence of Insertion of Isocyanide into a Metal−Sulfur Bond: Catalytic and Stoichiometric Behavior of Isocyanide and Thiolate Ligands on Palladium and Platinum , 1997 .

[50]  Armando Rangoni,et al.  A Complex Catalytic Cycle Leading to a Regioselective Synthesis of o,o′‐Disubstituted Vinylarenes , 1997 .

[51]  D. Barañano,et al.  Carbon-Heteroatom Bond-Forming Reductive Elimination. Mechanism, Importance of Trapping Reagents, and Unusual Electronic Effects during Formation of Aryl Sulfides , 1995 .

[52]  J. Roncali.  Conjugated poly(thiophenes): synthesis, functionalization, and applications , 1992 .

[53]  M. Raban,et al.  The chemistry of sulfenamides , 1989 .

[54]  Linus Pauling,et al.  THE NATURE OF THE CHEMICAL BOND. IV. THE ENERGY OF SINGLE BONDS AND THE RELATIVE ELECTRONEGATIVITY OF ATOMS , 1932 .