Fab-compatible nano-lens array integration for optically efficient flexible top-emitting organic light-emitting diodes

This work extends the kinds of organic materials that can form nano-lens arrays (NLAs). We have previously addressed fabrication of a N,N'-di(1-naphthyl)-N,N'-diphenyl-(1,1'-biphenyl)-4,4'-diamine (NPB) NLA and explained the formation mechanism as NPB crystallization and the resulting increase in surface tension. Here, we report a Tris(8-hydroxyquinolinato)aluminum (Alq3) NLA fabricated by the same deposition method as a NPB NLA. Grazing-incidence small-angle X-ray scattering experiments indicate that the formation mechanism of the Alq3 NLA is the same as that of the NPB NLA. Furthermore, this study broadens the application of NLAs from rigid to flexible organic light-emitting diodes (OLEDs). Here, flexible stainless steel-based devices using a low-temperature thermal release film, atomic layer deposition and NPB NLA processes are fabricated and characterized. With a NLA, current efficiency is increased 1.4 times, indicating that fab-compatible NLA technology is also available for flexible OLEDs.

[1]  K. Ueno,et al.  Heteroepitaxial growth by Van der Waals interaction in one-, two- and three-dimensional materials , 1991 .

[2]  Jin‐Wook Shin,et al.  Random nano-structures as light extraction functionals for organic light-emitting diode applications , 2014 .

[3]  Chi-Sun Hwang,et al.  Light-adaptable display for the future advertising service , 2016 .

[4]  Chang-Ki Moon,et al.  Highly Enhanced Light Extraction from Surface Plasmonic Loss Minimized Organic Light‐Emitting Diodes , 2013, Advanced materials.

[5]  C. Oldham,et al.  Atmospheric pressure atomic layer deposition of Al₂O₃ using trimethyl aluminum and ozone. , 2014, Langmuir : the ACS journal of surfaces and colloids.

[6]  Hyunsu Cho,et al.  A Facile Route to Efficient, Low‐Cost Flexible Organic Light‐Emitting Diodes: Utilizing the High Refractive Index and Built‐In Scattering Properties of Industrial‐Grade PEN Substrates , 2015, Advanced materials.

[7]  Jang‐Joo Kim,et al.  Highly enhanced light extraction from organic light emitting diodes with little image blurring and good color stability , 2015 .

[8]  M. Hersam,et al.  Mixed-dimensional van der Waals heterostructures. , 2016, Nature materials.

[9]  Changhee Lee,et al.  Non-interlayer hybrid white organic light-emitting diodes via a bipolar mixed host for the blue-fluorescent-emitting layer , 2017 .

[10]  Chih-Jen Yang,et al.  Microcavity top-emitting organic light-emitting devices integrated with microlens arrays: Simultaneous enhancement of quantum efficiency, cd/A efficiency, color performances, and image resolution , 2007 .

[11]  Y. Duan,et al.  Realization of Thin Film Encapsulation by Atomic Layer Deposition of Al2O3 at Low Temperature , 2013 .

[12]  K. Thomas,et al.  Highly efficient deep-blue organic light emitting diode with a carbazole based fluorescent emitter , 2018 .

[13]  H. Ågren,et al.  Principles of phosphorescent organic light emitting devices. , 2014, Physical chemistry chemical physics : PCCP.

[14]  A. Moewes,et al.  Electronic structure of NPB and BCP molecules probed by x-ray emission spectroscopy. , 2007, The Journal of chemical physics.

[15]  Jin‐Wook Shin,et al.  Luminescence enhancement of OLED lighting panels using a microlens array film , 2018, Journal of Information Display.

[16]  L. Francis,et al.  Microstructure and performance of block copolymer modified epoxy coatings , 2014 .

[17]  S. George Atomic layer deposition: an overview. , 2010, Chemical reviews.

[18]  Jun Yeob Lee,et al.  Recent progress of green thermally activated delayed fluorescent emitters , 2017 .

[19]  S. George,et al.  Low-Temperature Al2O3 Atomic Layer Deposition , 2004 .

[20]  M. Ahmadian,et al.  Novel graphene‐based optical MEMS accelerometer dependent on intensity modulation , 2018, ETRI Journal.

[21]  Two-Dimensional van der Waals Epitaxy Kinetics in a Three-Dimensional Perovskite Halide , 2015, 1509.08119.

[22]  Tetsuo Tsutsui,et al.  Doubling Coupling‐Out Efficiency in Organic Light‐Emitting Devices Using a Thin Silica Aerogel Layer , 2001 .

[23]  Dalip Singh Mehta,et al.  A review on the light extraction techniques in organic electroluminescent devices , 2009 .

[24]  Souheng Wu Polymer Interface and Adhesion , 2017 .

[25]  Jang‐Joo Kim,et al.  Crystallization-assisted nano-lens array fabrication for highly efficient and color stable organic light emitting diodes. , 2017, Nanoscale.

[26]  Porous cellulose paper as a light out coupling medium for organic light-emitting diodes , 2018, Journal of Information Display.

[27]  Jang‐Joo Kim,et al.  Optical Analysis of Power Distribution in Top-Emitting Organic Light Emitting Diodes Integrated with Nanolens Array Using Finite Difference Time Domain. , 2018, ACS applied materials & interfaces.

[28]  Chunliang Lin,et al.  Methodology for optimizing viewing characteristics of top-emitting organic light-emitting devices , 2004 .

[29]  Jang‐Joo Kim,et al.  Direct formation of nano-pillar arrays by phase separation of polymer blend for the enhanced out-coupling of organic light emitting diodes with low pixel blurring. , 2016, Optics express.

[30]  Jang‐Joo Kim,et al.  Vacuum Nanohole Array Embedded Phosphorescent Organic Light Emitting Diodes , 2015, Scientific Reports.

[31]  Min-Cheol Oh,et al.  A Light Scattering Layer for Internal Light Extraction of Organic Light-Emitting Diodes Based on Silver Nanowires. , 2016, ACS applied materials & interfaces.