Isolated d-f pairs in supramolecular complexes with tunable structural and electronic properties

The use of predisposed segmental ligands in multi-component self-assembly processes allows the preparationof triple-helical heterodimetallic d–f complexes in whicheach pair of metal ions is isolated and protected fromexternal interactions. The selection of the programmedheterodimetallic edifice within the ‘dynamic virtual library’arising from the mixture of the reacting componentsrelies on a judicious matching between the stereochemicalpreferences of the metal ions and the binding abilities of thereceptors combined with a reliable characterisation of the

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